This application relates to adhesives and, more particularly, to thermoreversible adhesives.
Throughout the life of an aircraft—from manufacturing to in-flight service, and during maintenance—there is often a need to temporarily secure or install a part or feature, whether internally or externally of the aircraft. While various adhesives are known and have been certified for use in the aerospace industry, the unique properties of thermoreversible adhesives make them particularly attractive when parts are only temporarily secured or installed on an aircraft.
Thermoreversible adhesives are unique vis-a-vis traditional adhesives because the adhesive properties of thermoreversible adhesives are temperature dependent. Specifically, at certain lower temperatures, thermoreversible adhesives present their maximum bond strength, while at certain elevated temperatures, thermoreversible adhesives lose their adhesiveness. Therefore, such thermoreversible adhesives are useful for repairs.
Traditional thermoreversible adhesives are epoxy-based adhesives that reversibly couple and uncouple at about 60° C. and about 90° C., respectively. Such epoxy-based thermoreversible adhesives are formulated by homogenizing a maleimide, such as 1,1′-(methylenedi-4,1-phenylene)bismaleimide, with furfuryl glycidyl ether at a temperature above the Diels-Alder decoupling temperature. Then, an amine-terminated polypropylene oxide species, such as JEFFAMINE® D-230 polyetheramine, is added to react with the epoxy groups, and then cast at elevated temperature to form a film adhesive.
Unfortunately, the furfuryl glycidyl ether required for epoxy-based thermoreversible adhesives can be difficult to source and, when available, can be quite expensive.
Accordingly, those skilled in the art continue with research and development efforts in the field of adhesives.
Disclosed are thermoreversible urethane-based adhesive compositions.
In one example, the disclosed thermoreversible urethane-based adhesive composition comprises the reaction product of a multifunctional maleimide species and a furan-endcapped prepolymer, wherein the furan-endcapped prepolymer comprises the reaction product of a monofunctional furan species and an isocyanate-terminated prepolymer, wherein the isocyanate-terminated prepolymer comprises the reaction product of a diisocyanate and a difunctional oligomer that is terminated at a first end with an alpha moiety, wherein the alpha moiety is a hydroxyl group or an amine group, and that is terminated at a second end, opposed from the first end, with an omega moiety, wherein the omega moiety is a hydroxyl group or an amine group.
In another example, the disclosed thermoreversible urethane-based adhesive composition comprises the reaction product of 1,1′-(methylenedi-4,1-phenylene)bismaleimide and a furan-endcapped prepolymer, wherein the furan-endcapped prepolymer comprises the reaction product of at least one of furfurylamine and furan-3-methanol, and an isocyanate-terminated prepolymer, wherein the isocyanate-terminated prepolymer comprises the reaction product of a diisocyanate and a difunctional polyetheramine.
In yet another example, the disclosed thermoreversible urethane-based adhesive composition may be in the form of film.
Also disclosed are two-part adhesive systems.
In one example, the disclosed two-part adhesive system includes a first part comprising the reaction product of a monofunctional furan species and an isocyanate-terminated prepolymer, wherein the isocyanate-terminated prepolymer comprises the reaction product of a diisocyanate and a difunctional oligomer that is terminated at a first end with an alpha moiety, wherein the alpha moiety is a hydroxyl group or an amine group, and that is terminated at a second end, opposed from the first end, with an omega moiety, wherein the omega moiety is a hydroxyl group or an amine group; and a second part comprising a multifunctional maleimide species, wherein mixing together the first part with the second part yields a thermoreversible urethane-based adhesive composition.
Also disclosed are methods for bonding a first adherend with a second adherend, and associated bonded articles.
In one example, the disclosed method for bonding a first adherend with a second adherend includes steps of (1) positioning a thermoreversible urethane-based adhesive composition in physical contact with the first adherend and the second adherend, the thermoreversible urethane-based adhesive composition comprises the reaction product of a multifunctional maleimide species and a furan-endcapped prepolymer, wherein the furan-endcapped prepolymer comprises the reaction product of a monofunctional furan species and an isocyanate-terminated prepolymer, wherein the isocyanate-terminated prepolymer comprises the reaction product of a diisocyanate and a difunctional oligomer that is terminated at a first end with an alpha moiety, wherein the alpha moiety is a hydroxyl group or an amine group, and that is terminated at a second end, opposed from the first end, with an omega moiety, wherein the omega moiety is a hydroxyl group or an amine group; (2) heating the thermoreversible urethane-based adhesive composition; and (3) after the heating, cooling the thermoreversible urethane-based adhesive composition.
Other examples of the disclosed thermoreversible urethane-based adhesive compositions, two-part adhesive systems, bonding methods, and bonded articles will become apparent from the following detailed description, the accompanying drawings, and the appended claims.
Disclosed are thermoreversible adhesives used to bond substrates such as plastics, metals (e.g., aluminum, titanium, and the like), rubbers, composites (e.g., carbon fiber-reinforced plastics), ceramics, and the like. These thermoreversible urethane-based adhesive compositions, which are based on urethane linkages, with additional Diels-Alder thermoreversible bonds incorporated therein, can be softened at elevated temperatures, but then achieve maximum adhesive strength when cooled below the softening temperature.
Depending on the specific composition, the disclosed thermoreversible urethane-based adhesive compositions may have relatively low softening temperatures. In one specific, nonlimiting example, the disclosed thermoreversible urethane-based adhesive compositions may begin to soften at a temperature of about 60° C. or more. In another specific, nonlimiting example, the disclosed thermoreversible urethane-based adhesive compositions may begin to soften at a temperature of about 70° C. or more. In another specific, nonlimiting example, the disclosed thermoreversible urethane-based adhesive compositions may begin to soften at a temperature of about 80° C. or more. In another specific, nonlimiting example, the disclosed thermoreversible urethane-based adhesive compositions may begin to soften at a temperature of about 90° C. or more. In yet another specific, nonlimiting example, the disclosed thermoreversible urethane-based adhesive compositions may begin to soften at a temperature of about 100° C. or more.
The disclosed thermoreversible urethane-based adhesive compositions are the reaction product of a multifunctional maleimide species and a furan-endcapped prepolymer, as shown by Equation 1.
The multifunctional maleimide species of Equation 1 may have a functionality of f=2 or greater. Various multifunctional maleimide species may be used without departing from the scope of the present disclosure. In one specific, non-limiting example, the multifunctional maleimide species of Equation 1 may be 1,1′-(methylenedi-4,1-phenylene)bismaleimide. Other examples of suitable multifunctional maleimide species include, but are not limited to, bismaleimidoethane, dithio-bis-maleimidoethane, N,N′-(1,4-phenylene)dimaleimide, N,N′-(o-phenylene)dimaleimide, and N,N′-(1,3-phenylene)dimaleimide. Using combinations of multifunctional maleimide species is also contemplated.
The furan-endcapped prepolymer is the reaction product of a monofunctional furan species and an isocyanate-terminated prepolymer, as shown by Equation 2.
Various monofunctional furan species may be used without departing from the scope of the present disclosure. In one general, non-limiting example, the monofunctional furan species of Equation 2 is a monoamine. In one specific, non-limiting example, the monofunctional furan species is furfurylamine. In another general, non-limiting example, the monofunctional furan species of Equation 2 is a monoalcohol. In one specific, non-limiting example, the monofunctional furan species is furan-3-methanol.
The isocyanate-terminated prepolymer is the reaction product of a diisocyanate and a difunctional oligomer, as shown by Equation 3.
Various diisocyanates may be used without departing from the scope of the present disclosure. In one specific, non-limiting example, the diisocyanate of Equation 3 may be 4,4′-diisocyanato dicyclohexylmethane, which is commonly referred to as hydrogenated MDI or HMDI. Other examples of suitable diisocyanates include, but are not limited to, isophorone diisocyanate, toluene diisocyanate, methylenebis(phenyl isocyanate), and hexamethylene diisocyanate. Using combinations thereof is also contemplated.
The difunctional oligomer is terminated at a first end with an alpha moiety, wherein the alpha moiety is a hydroxyl group or an amine group. The difunctional oligomer is terminated at a second end, opposed from the first end, with an omega moiety, wherein the omega moiety is a hydroxyl group or an amine group.
Various difunctional alpha moiety, omega moiety terminated oligomers may be used as the difunctional oligomer of Equation 3. In one general, non-limiting expression, the difunctional oligomer may be a polyether, a polyester, and/or a polysiloxane. In one specific, non-limiting expression, the difunctional oligomer may be polyethylene glycol, polypropylene glycol, 1,3-polypropane diol, and/or polytetrahydrofuran.
Various examples of suitable difunctional oligomers will become apparent to those skilled in the art upon reading and understanding the present disclosure. As one general, non-limiting example, the difunctional oligomer of Equation 3 may be a polyetheramine. The polyetheramine may be a primary amine, and may have a number average molecular weight within a range spanning from about 200 to about 2500, or from about 230 to about 2000. As one specific, non-limiting example, the difunctional oligomer of Equation 3 may be JEFFAMINE® D-230 polyetheramine, which has a number average molecular weight of about 230. As another specific, non-limiting example, the difunctional oligomer of Equation 3 may be JEFFAMINE® D-2000 polyetheramine, which has a number average molecular weight of about 2000. Combinations of suitable difunctional oligomers is also contemplated.
Optionally, the disclosed thermoreversible urethane-based adhesive compositions may be presented in the form of a two-part adhesive system: a first part that includes the furan-endcapped prepolymer and a second part that includes the multifunctional maleimide species. See Equation 1. Mixing together the first part with the second part yields the disclosed thermoreversible urethane-based adhesive composition.
Referring now to
Referring now to
The disclosed method 100 further includes the step of heating 120 the thermoreversible urethane-based adhesive composition. The step of heating 120 is performed while the first adherend 210 (
The step of heating 120 may include heating at least to a temperature at which the thermoreversible urethane-based adhesive composition begins to soften (i.e., to a temperature at or above the softening temperature). As one example, the step of heating 120 may include heating to a temperature of at least 60° C. As another example, the step of heating 120 may include heating to a temperature of at least 70° C. As another example, the step of heating 120 may include heating to a temperature of at least 80° C. As another example, the step of heating 120 may include heating to a temperature of at least 90° C. As yet another example, the step of heating 120 may include heating to a temperature of at least 100° C.
The disclosed method 100 further includes the step of cooling 140 the thermoreversible urethane-based adhesive composition. The step of cooling 140 the disclosed thermoreversible urethane-based adhesive composition is performed after the heating 120 step. The step of cooling 140 the disclosed thermoreversible urethane-based adhesive composition is also performed while the first adherend 210 (
The step of cooling 140 may include cooling at least to a temperature at which the thermoreversible urethane-based adhesive composition is solid (i.e., to a temperature below the softening temperature) and, more particularly, to a temperature at (or below) which the disclosed thermoreversible urethane-based adhesive composition achieves maximum adhesive strength. As one example, the step of cooling 140 may include cooling the disclosed thermoreversible urethane-based adhesive composition to a temperature of at most 50° C. As another example, the step of cooling 140 may include cooling the disclosed thermoreversible urethane-based adhesive composition to a temperature of at most 40° C. As another example, the step of cooling 140 may include cooling the disclosed thermoreversible urethane-based adhesive composition to a temperature of at most 30° C. As yet another example, the step of cooling 140 may include cooling the disclosed thermoreversible urethane-based adhesive composition to a temperature of at most 20° C.
The disclosed method 100 may further include the step of pressing 130 the disclosed thermoreversible urethane-based adhesive composition between the first adherend 210 (
Referring now to
To prepare the isocyanate-terminated prepolymer, 4,4′-diisocyanato dicyclohexylmethane (“HDMI”) (2 equivalents, 1.27 g) was added to JEFFAMINE® D-2000 polyetheramine (1 equivalent, 5.00 g) in a Flacktek cup and mixed in the Flacktek for 30 seconds at 2000 RPM to homogenize. The mixture was left for 15 minutes at room temperature to ensure the reaction ran to completion.
While HMDI/JEFFAMINE® D-2000 mixture was cooling, 1,1′-(methylenedi-4,1-phenylene)bismaleimide (“BMI”) (1 equivalent, 0.87 g) was added to 1,4-dioxane (7.83 g) in a separate Flacktek cup to achieve a 10 wt % solids solution. The BMI solution was mixed for 1 minute at 2000 rpm in the Flacktek and then placed on an 80° C. hot plate to fully incorporate BMI into the dioxane.
After the 15 minute resting period, furfurylamine (a monofunctional furan species) (1 equivalent, 0.47 g) was added to the HMDI/JEFFAMINE® D-2000 mixture and mixed for 2 minutes at 2000 rpm in the Flacktek. The resulting furan-endcapped prepolymer was the left in an 80° ° C. oven for 5-10 minutes.
The 10 wt % BMI in dioxane solution (make sure all BMI is dissolved in the Dioxane) was then added at once to the furan-endcapped prepolymer and mixed for 1 minute at 2000 rpm in the Flacktek. The reaction was immediately placed in an 80° C. water bath for 1 hour. The reaction was then removed from the water bath and left at room temperature overnight.
The following morning, the resulting thermoreversible urethane-based adhesive composition was placed back into the 80° C. water bath for 1 hr, and then Flackteked for 1 minute at 2000 rpm. This was done to ensure homogeneity from any undispersed regions following the initial mix. The reaction was placed back into the 80° C. water bath for 5-10 minutes. The reaction contents were then quickly cast on a sheet of silanized Mylar on top of a glass plate. This was completed in under 45 seconds to ensure the polymer did not cool below the softening temperature before casting. The film was left at room temperature for 24 hours under a hood, followed by 2 hours at 105° C. to flash off remaining dioxane, and finally left at room temperature for 3 hours to cool.
Lap shear joints were formed from 5 mil thick film adhesive by cutting 1 inch by 1 inch shapes from the thermoreversible urethane-based adhesive composition sheet while on the Mylar release film backing. The adhesive pieces were placed between and in contact with 1 inch by 4 inch aluminum lap shear bars. The lap shear coupons were placed in an oven (115° C. or 120° C.) for 1 hour before combing pairs to form lap shear coupons. The lap shear coupons were subjected to Instron testing and the results are provided in Table 1.
To prepare the isocyanate-terminated prepolymer, JEFFAMINE® D-2000 (0.8 equivalents, 5.00 g) was added to JEFFAMINE® D-230 (0.2 equivalents, 0.15 g) in a Flacktek cup and mixed for 1 minute at 2000 rpm. 4,4′-diisocyanato dicyclohexylmethane (“HDMI”) (2 equivalents, 1.59 g) was added to the JEFFAMINE® D-2000/JEFFAMINE® D-230 mixture and mixed in the Flacktek for 30 seconds at 2000 RPM to homogenize. The mixture was left for 15 minutes at room temperature to ensure the reaction ran to completion.
While the HMDI/JEFFAMINE® D-2000/JEFFAMINE® D-230 mixture was cooling, 1,1′-(methylenedi-4,1-phenylene)bismaleimide (“BMI”) (1 equivalent, 1.09 g) was added to 1,4-dioxane (9.79 g) in a separate Flacktek cup to achieve a 10 wt % solids solution. The BMI solution was mixed for 1 minute at 2000 rpm in the Flacktek and then placed on an 80° C. hot plate to fully incorporate BMI into the dioxane.
After the 15 minute resting period, furfurylamine (1 equivalent, 0.59 g) was added to the HMDI/JEFFAMINE® D-2000/JEFFAMINE® D-230 mixture and mixed for 2 minutes at 2000 rpm in the Flacktek. The resulting furan-endcapped prepolymer was the left in an 80° C. oven for 5-10 minutes.
The 10 wt % BMI in dioxane solution (making sure all BMI is dissolved in the dioxane) was then added at once to the furan-endcapped prepolymer and mixed for 1 minute at 2000 rpm in the Flacktek. The reaction was immediately placed in an 80° C. water bath for 1 hour. The reaction was then removed from the water bath and left at room temperature overnight.
The following morning, the polymer was placed back into the 80° C. water bath for 1 hr, and then Flackteked for 1 minute at 2000 rpm or until homogenous. The reaction was placed back into the 80° C. water bath for 5-10 minutes. The reaction contents were then quickly cast on a sheet of silanized Mylar on top of a glass plate. This was completed in under 45 seconds to ensure the polymer does not cool below the softening temperature before casting. The film was left at room temperature for 24 hours under a hood, followed by 2 hours at 105° C. to flash off remaining dioxane, and finally left at room temperature for 3 hours to cool.
The ratio of JEFFAMINE® D-2000 to JEFFAMINE® D-230 was 8:2. It should be noted that this recipe can be changed to achieve different ratios of JEFFAMINE® D-2000 to JEFFAMINE® D-230 (e.g., 7:3, 6:4, etc.). Those skilled in the art will appreciate that doing so will require corresponding changes to the quantities of the other chemical components (e.g., HDMI, furfurylamine, BMI, dioxane) being used.
Examples of the subject matter disclosed herein may be described in the context of aircraft manufacturing and service method 1100 as shown in
Each of the processes of illustrative method 1100 may be performed or carried out by a system integrator, a third party, and/or an operator (e.g., a customer). For the purposes of this description, a system integrator may include, without limitation, any number of aircraft manufacturers and major-system subcontractors; a third party may include, without limitation, any number of vendors, subcontractors, and suppliers; and an operator may be an airline, leasing company, military entity, service organization, and so on.
As shown in
The disclosed thermoreversible urethane-based adhesive compositions may be employed during any one or more of the stages of the manufacturing and service method 1100. For example, components or subassemblies corresponding to component and subassembly manufacturing (block 1108) may be fabricated or manufactured using the disclosed thermoreversible urethane-based adhesive compositions. Also, one or more examples of the disclosed thermoreversible urethane-based adhesive compositions may be utilized during production stages (block 1108 and block 1110), for example, by substantially expediting assembly of or reducing the cost of aircraft 1102. Similarly, one or more examples of the disclosed thermoreversible urethane-based adhesive compositions may be utilized, for example and without limitation, while aircraft 1102 is in service (block 1114) and/or during maintenance and service (block 1116).
Although various examples of the disclosed thermoreversible urethane-based adhesive compositions, two-part adhesive systems, bonding methods, and bonded articles have been shown and described, modifications may occur to those skilled in the art upon reading the specification. The present application includes such modifications and is limited only by the scope of the claims.