Claims
- 1. A thermosetting composition comprising a co-reactable solid, particulate mixture of:(a) capped polyisocyanate crosslinking agent; and (b) hydroxy functional nonrandom copolymer prepared by atom transfer radical polymerization initiated in the presence of an initiator having at least one radically transferable group, and in which said polymer contains at least one of the following polymer chain structures: Φ-[—(M)p—(G)q—]x—T orΦ-[—(G)q—(M)p—]x—T wherein M is a residue, that is free of hydroxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; G is a residue, that has hydroxy functionality, of at least one ethylenically unsaturated radically polymerizable monomer; Φ is a residue from the initiator, free from the radically transferable group, selected from the group consisting of sulfonyl compounds, diethyl malonates and mixtures thereof; T is or is derived from the radically transferable group and is selected from the group consisting of halides and a dehalogenation reaction product of a limited radically polymerizable ethylenically unsaturated compound; p and q represent average numbers of residues occurring in a block of residues in each polymer chain structure; and p, q and x are each individually at least 1 and are selected for each structure such that said active hydrogen functional polymer has a number average molecular weight of at least 250 to 16,000.
- 2. The composition of claim 1 wherein the capping group of said capped polyisocyanate crosslinking agent is selected from the group consisting of hydroxy functional compounds, 1H-azoles, lactams, ketoximes and mixtures thereof.
- 3. The composition of claim 2 wherein the capping group is selected from the group consisting of phenol, p-hydroxy methylbenzoate, 1H-1,2,4-triazole, 1H-2,5-dimethyl pyrazole, 2-propanone oxime, 2-butanone oxime, cyclohexanone oxime, e-caprolactam and mixtures thereof.
- 4. The composition of claim 1 wherein the polyisocyanate of said capped polyisocyanate crosslinking agent is selected from the group consisting of 1,6-hexamethylene diisocyanate, cyclohexane diisocyanate, α,α′-xylylene diisocyanate, α,α,α′,α′-tetramethylxylylene diisocyanate, 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane, diisocyanato-dicyclohexylmethane, dimers of said polyisocyanates, trimers of said polyisocyanates and mixtures thereof.
- 5. The composition of claim 1 wherein said crosslinking agent (a) is selected from the group consisting of (i) capped polyisocyanate functional polymer having at least two capped isocyanate groups, (ii) oligomeric capped polyisocyanate functional adduct and mixtures thereof, said capped polyisocyanate functional polymer and said oligomeric capped polyisocyanate functional adduct each containing structural linkages selected from the group consisting of urethane, thiourethane, urea and combinations thereof.
- 6. The composition of claim 5 wherein said capped polyisocyanate functional polymer is a capped polyisocyanate functional polyurethane having a number average molecular weight of from 1,000 to 10,000.
- 7. The composition of claim 1 wherein the hydroxyl functional polymer has a number average molecular weight of from 500 to 10,000, and a polydispersity index of less than 2.0.
- 8. The composition of claim 1 wherein said initiator is selected from the group consisting of methanesulfonyl halides, p-toluenesulfonyl halides, diethyl 2-halo-2-methylmalonates and mixtures thereof.
- 9. The composition of claim 1 wherein said hydroxy functional polymer has a hydroxy equivalent weight of from 100 to 10,000 grams/equivalent.
- 10. The composition of claim 1 wherein M is derived from at least one of vinyl monomers, allylic monomers and olefins.
- 11. The composition of claim 10 wherein M is derived from at least one of alkyl (meth)acrylates having from 1 to 20 carbon atoms in the alkyl group, vinyl aromatic monomers, vinyl halides, vinyl esters of carboxylic acids and olefins, and G is derived from hydroxyalkyl (meth)acrylates having from 1 to 20 carbon atoms in the alkyl group.
- 12. A thermosetting composition comprising a co-reactable solid, particulate mixture of:(a) a capped polyisocyanate crosslinking agent; and (b) hydroxy functional nonrandom copolymer prepared by atom transfer radical polymerization, in the presence of an initiator having at least one radically transferable group, and in which said polymer contains at least one of the following polymer chain structures: Φ-[[—(M)p—(G)q]x—(M)r—T]z andΦ-[[—(G)q—(M)p]x—(G)s—T]z wherein M is a residue, that is free of hydroxyl functionality, of at least one ethylenically unsaturated radically polymerizable monomer; G is a residue, that has hydroxyl functionality, of at least one ethylenically unsaturated radically polymerizable monomer; Φ is a residue from the initiator, free from the radically transferable group, selected from the group consisting of sulfonyl compounds, diethyl 2-halo-2-methylmalonates and mixtures thereof; T is or is derived from the radically transferable group and is selected from the group consisting of halides and a dehalogenation reaction product of a limited radically polymerizable ethylenically unsaturated compound; p and q represent average numbers of residues occurring in a block of residues in each polymer chain structure; x represents the number of radically transferable groups; x is independently from 1 to 100 for each structure; p and q are each independently within the range of 1 to 100 for each x-segment and for each structure; r and s are each independently for each structure within the range of 1 to 100; z is independently for each structure at least 1; and said hydroxyl functional polymer has a number average molecular weight of at least 250 to 16,000 and a polydispersity index of less than 2.0.
- 13. The composition of claim 12 wherein said hydroxy functional polymer has a number average molecular weight of from 500 to 10,000, and a polydispersity index of less than 1.8.
- 14. The composition of claim 12 wherein p is independently selected for each structure within the range of 1 to 20; and q is independently selected for each structure within in the range of 1 to 20.
- 15. The composition of claim 12 wherein x is independently selected for each structure within the range of 1 to 50.
- 16. The composition of claim 12 wherein T is halide.
- 17. The composition of claim 16 wherein T is derived from a dehalogenation post-reaction.
- 18. The composition of claim 17 wherein said dehalogenation post-reaction comprises contacting said active hydrogen functional polymer with a limited radically polymerizable ethylenically unsaturated compound.
- 19. The composition of claim 18 wherein said limited radically polymerizable ethylenically unsaturated compound is selected from the group consisting of 1,1-dimethylethylene, 1,1-diphenylethylene, isopropenyl acetate, alpha-methyl styrene, 1,1-dialkoxy olefin and combinations thereof.
- 20. The composition of claim 1 wherein the equivalent ratio of isocyanate equivalents in said capped polyisocyanate crosslinking agent (a) to hydroxy equivalents in said hydroxy functional polymer (b) is within the range of 1:3 to 3:1.
- 21. The composition of claim 1 wherein said capped polyisocyanate crosslinking agent is present in an amount of from 1 to 45 percent by weight, based on total weight of resin solids, and said hydroxy functional polymer is present in an amount of from 55 to 99 percent by weight, based on total weight of resin solids.
CROSS-REFERENCE TO RELATED APPLICATION
This application claims the benefit of U.S. Provisional Application Ser. No. 60/098,605, filed Aug. 31, 1998, which is hereby incorporated by reference.
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Foreign Referenced Citations (5)
Number |
Date |
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0 773 267 A1 |
May 1997 |
EP |
9630421 |
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Provisional Applications (1)
|
Number |
Date |
Country |
|
60/098605 |
Aug 1998 |
US |