The present invention relates generally to the fields of optics, solar energy, and the concentration of insolate energy for the purpose of photovoltaic energy conversion without the use of imaging devices. An optical waveguide circuit system, with a relatively flat form factor, for collecting solar energy, concentrating it, and transmitting it to point of energy conversion is presented. This invention relates generally to solar panels and their improvement, and more particularly, to photonic based waveguides for concentrator solar panels.
The following discussion is provided solely to assist the understanding of the reader, and does not constitute an admission that any of the information discussed or references cited constitute prior art to the present invention.
Solar cells are the most expensive part of solar panels. Current state-of-the-art photovoltaic (PV) cell technology can only convert a fraction of the sunlight received into electricity. This inefficiency requires solar panel manufacturers to use a sizable number of expensive solar cells to deliver a substantial amount of electricity. The high cost of solar panels has prevented solar power from becoming a significant or even primary source of electricity.
Many solutions have been sought to reduce the cost of solar panels. One of these solutions, concentrated photovoltaics (CPV), is to use inexpensive optical elements, such as lenses and mirrors, to concentrate sunlight onto a small surface such that smaller amounts of PV cells can be used. However, since optical elements have non-zero focal length, CPV modules are generally tall and bulky, as opposed to the flat panel design of standard solar modules. Additionally, most CPV systems require active mechanisms to move the entire panel or optical elements to track the position of the sun throughout the day or year. Otherwise, as the sun moves the area of solar concentration moves away from the underlying PV cell, resulting is less or no electricity generation.
Conventional solar modules are made up of silicon solar cells. Due to the inherent temperature limits of silicon solar cells, the amount of solar concentration cannot exceed more than about six for acceptable conversion efficiency performance or before causing possible damage in the case of passive cooling. Therefore, most CPV systems use small amounts of expensive high performance solar cells made from type III-V semiconductor materials that can handle high concentration ratios and high temperatures. While these systems may be economical on small scale installations, III-V compounds are scarce natural materials and cannot be used as the primary material for the world's solar panels. Therefore, silicon solar panels are projected to make up a majority of the PV market in the foreseeable future.
One of the major issues in CPV is the tracking required due to seasonal and daily motion of the sun. This issue is typically addressed using active tracking which requires physical motion of the solar elements, mirrors and concentrators to track the movement of the sun. Such elaborate equipment adds complexity and cost. It is possible to do tracking passively. This approach requires collecting elements that collect the sun rays very efficiency over large solid angles. Design of such collection element has been studied by many different authors. The simplest design is shown in
The concentration of the collector, C, is given by the ratio of the areas of the input and output apertures when all light is collected. Studies indicate that to efficiently collect over a large solid angle with a concentration of several times, the element has to be relatively long; the length can be more than 10 times the width of the output aperture. Therefore this design becomes impractical even with modest concentration ratios if a commercial solar cell is attached to its output aperture. For example a 6″ rectangular silicon solar cell could need a concentrator longer than 60″ or 5 feet.
In recent years much progress has been made in regard to forming high quality microstructures and nanostructures using optical quality polymers. The LCD and optical communications industries have contributed to this progress. Processes involving hot embossing, micro-contact printing, reel-to-reel with a master die, casting with molds, photosensitive polymers and grey-scale photolithograhy all have made progress towards the scaling down of polymeric structures with relatively inexpensive and easily implemented processing schemes for high-volume production.
Much work has involved 3D routing of waveguides for optical interconnects between communication routing boards. Heat resistant blends also make it possible for the circuits to endure higher operating temperatures, which is pertinent to operating in sunlight. Research has also uncovered methods for increased optical efficiency and the reduction of intensity losses due to absorption of light in the polymer and scattering due to surface roughness. Hence, the technology of making optical waveguide microstructures from polymers which are heat resistant, optically efficient, and more flexible in terms of processing than glass, is rapidly maturing. This technology has matured to the point where it can offer solutions for the fabrication of optical components for solar cell concentrators, especially at lower concentrations and relatively lower temperatures.
The present invention provides a highly advantageous device for concentrating incident light, and is particularly applicable to photovoltaic systems, and in particular to increasing the performance of conventional photovoltaic cells and panels. Using these devices enables the light incident on photovoltaic cells to be increased, thereby reducing the photovoltaic cell area needed for a particular level of power generation. Furthermore, the light concentration and resulting decreased photovoltaic cell area can be accomplished without requiring a tracking mechanism to keep the cells oriented to the sun. The devices are useful for essentially any flat panel photovoltaic system, including silicon-based panels and Group III-V panels. Thus, the present light concentrators provide more efficient use of photovoltaic materials without the complexity of producing hybrid cells.
The invention provides a number of design variants. Particularly desirable are designs which incorporate light concentration through the use of collector-concentrator structures, as well as concentration within the plane of a planar waveguide circuit (PWC). In such designs, it can also be advantageous to incorporate diffusers to spread the light more evenly over the surface of the solar cell. A number of design options are described below.
Thus, a first aspect of the invention concerns a flat solar concentrator and photovoltaic device, which includes a flat array of wide angle solar concentrators mounted on and optically coupled with a waveguide layer, and a flat photovoltaic panel, where the flat array and the flat photovoltaic panel are optically connected such that light concentrated by the solar concentrator is directed onto the photovoltaic panel thereby producing electricity.
In particular embodiments, the flat array is mounted on top of the photovoltaic panel; the photovoltaic panel is mounted on an edge of the flat array.
In advantageous embodiments, the waveguide layer includes a first set of mirror surfaces (e.g., dielectric or metal-coated mirror surfaces) which redirect light exiting the concentrators substantially in the plane of the waveguide layer, and optionally the waveguide layer includes a second set of mirror surfaces which redirect light from the first set of mirror surfaces to a direction substantially perpendicular to the plane of the flat array; the concentrators are optically coupled to the waveguide layer through waveguide bends.
In certain embodiments, the flat array concentrates insolate light by a factor of at least 1.5, 2, 3, 4, 5, 6, 7, or 8.
In particular embodiments, the concentrators are hexagonal, square, near square (e.g., with the ratio of length to width of the inlet aperture no more than 4:1, 3:1, 2.5:1, 2:1, 1.5:1, or 1.2:1), or trough concentrators; concentrator of a type as just specified are in a close-packed array; the PWC has a single layer having a waveguide which includes at least one S-bend and at least one junction; the PWC includes at least one layer (e.g., 1, 2, 3, 4, or more layers), where each of those layers includes a waveguide which includes at least one S-bend and at least one junction; the at least one PWC layer includes an in-plane concentrator (e.g., a taper structure); the waveguide has lateral air cladding and/or vertical air cladding (i.e., air gaps between layers of the PWC); the PWC includes a plurality of layers (e.g., 2, 3, 4, 5, or more layers) separated by air gap defined by spacers between said layers (preferably with spacers located in non-light conducting areas of the layers).
Also in certain embodiments, a waveguide is optically coupled to a spreader (e.g., an expanding taper) and/or a diffuser (e.g., an inverted cone) which spreads light from the waveguide over the surface of a photovoltaic cell in the photovoltaic panel.
In further embodiments the device includes a wavelength separator which separates light of different ranges of the light spectrum, e.g., within or adjacent to a waveguide); the device includes an IR separator and/or a UV separator; the separator is or includes a thin film interference filter (e.g., located at or near the narrow end of an in-plane concentrator); the device includes a wavelength separator (e.g., as part of or adjacent to one or more waveguides) which preferentially separates and removes light in a particular portion of the light spectrum (e.g., IR and/or UV light) from light which is conducted to the photovoltaic panel, for example a thin film interference filter.
A related aspect concerns a flat solar concentrator which includes a flat array of wide angle solar concentrators mounted on and optically coupled with a waveguide layer, where the waveguide layer is configured such that light exiting from the concentrators is redirected within the waveguide layer to a direction parallel to the plane of waveguide layer.
In particular embodiments, the flat solar concentrator is as described for the preceding aspect or an embodiment thereof or otherwise described herein for the present invention.
Another related aspect concerns a method for making a flat solar concentrator, involving optically coupling a flat array of wide angle solar micro-concentrators having an incident light area with a waveguide layer, where the waveguide layer accepts output light from the concentrators and outputs light into a light output area smaller than the incident light area.
In particular embodiments, the light output area is from about 0.7 to 0.05, 0.5 to 0.1, 0.5 to 0.15, or 0.3 to 0.15 times the incident light area; the waveguide layer includes a plurality of sub-layers, e.g., 2 to 5, 3 to 8, 4 to 10, 7 to 15, 10 to 20, or at least 4, 6, 8, 10, 15, or 20 layers.
In certain embodiments, the flat array has a thickness of about 0.1 to 5.0, 0.1 to 3.0, 0.1 to 3.0, 0.1 to 2.5, 0.1 to 2.0, 0.1 to 1.5, 0.1 to 1.0, 0.1 to 0.7, 0.2 to 5.0, 0.2 to 4.0, 0.2 to 3, 0.2 to 2.0, 0.2 to 1.0, 0.2 to 1.0, 0.2 to 0.7, 0.3 to 5.0, 0.3 to 4.0, 0.3 to 3.0, 0.3 to 2.0, 0.3 to 1.0, 0.3 to 0.7, 0.3 to 0.6 cm, 0.5 to 5.0, 0.5 to 4.0, 0.5 to 3.0, 0.5 to 2.0, 0.5 to 1.5, 1.0 to 5.0, 1.0 to 4.0, 1.0 to 3.0, 1.0 to 2.0, 2.0. to 5.0, or 2.0 to 4.0 cm; the waveguide layer has a thickness of less than about 5.0, 4.0, 3.0, 2.0, 1.0, 0.9, 0.8, 0.7, 0.6, 0.5, 0.4, 0.3, 0.2, or 0.1 cm; the thickness of the flat solar concentrator is about 0.2 to 5.0, 0.2 to 4.0, 0.2 to 3.0, 0.2 to 2.0, 0.2 to 1.5, 0.2 to 1.2, 0.2 to 1.0, 0.3 to 5.0, 0.3 to 4.0, 0.3 to 3.0, 0.3 to 2.0, 0.3 to 1.5, 0.3 to 1.2, 0.3 to 1.0, 0.3 to 0.7, 0.5 to 5.0, 0.5 to 4.0, 0.5 to 3.0, 0.5 to 2.0, 1.0 to 5.0, 1.0 to 4.0, 1.0 to 3.0 cm; the solar concentrator includes a flat array and a waveguide layer where the respective thicknesses of the flat array and the waveguide layer are any discrete combination of the flat array thickness and waveguide layer thickness specified for previous embodiments.
Also in certain embodiments, the flat array is bonded with the waveguide layer.
In particular embodiments, the resulting flat solar concentrator is as described for the preceding aspect or an embodiment thereof or otherwise described herein for the present invention.
Still another related aspect concerns a method for reducing the photovoltaic panel area required in a photovoltaic power system of a specified electrical power generation capacity, by including in the system a flat solar concentrator as specified in any preceding aspect, optically coupled with at least one photovoltaic panel in the system.
Additional embodiments will be apparent from the Detailed Description and from the claims.
The invention presented here concerns a thin and flat solar concentrator for direct placement on top of solar cells, obtained by coupling the principles of optical solar concentrators and photonics waveguide circuitry and techniques. The design of this present invention can be configured as a low value concentrator (e.g., for placement on top of silicon solar cells), or as a high value concentrator (e.g., for placement on top of high performance III-V solar cells). An advantageous embodiment of the solar concentrator in this invention is a thin optical layer that can replace the glass layer in standard flat solar panel designs. Certain advantageous embodiments utilize in-plane concentrators as part of the waveguide circuit, in addition to the initial collector-concentrators which are typically oriented with the optical axis perpendicular to the plane of the solar cell surface.
Thus the invention includes a photonics-based planar solar concentrator designed for collecting and guiding insolate radiation from one side of the concentrator, to solar cells for energy conversion on another side. In general, the planar solar concentrator includes two sections. The top section has a matrix (usually a close-packed matrix) of micro-size wide-angle solar concentrators for the collection of input light. The use of micro-size wide-angle solar concentrators can, in a many cases, eliminate the need for tracking mechanisms and achieves a thin profile. The output of each micro-concentrator is coupled to a photonics waveguide, where the light is directed to an output area on the opposing side (or to an edge) through the use of a network of waveguides (often a multi-layered network) and micro-mirrors (usually 45 degree micro-mirrors) and/or curved waveguides. The effective geometric concentration ratio of the concentrator of this invention is calculated as: (concentration ratio)=(aggregate collection area of the micro-concentrators)/(aggregate output area of the waveguides).
For the flat solar concentrator invention presented here, the Collector-Concentrator layer serves to collect from a total specified insolated area, Ac, of an arbitrary boundary, and the passive planar waveguide circuit distributes the concentrated light energy over a total output area, Ao , of an arbitrary boundary. Ac/Ao is the effective concentration ratio of the concentrator in this invention modulated by a waveguide circuit factor, which is dependent on how the light is directed and combined, passively and linearly, in an additive manner. Any device utilizing the concentrated light can be attached to the output area, preferably a photovoltaic solar cell.
The need for tracking mechanisms and equipment in conventional solar concentrators is solved or at least significantly reduced by this invention by the matrix of micro-concentrators. Each micro-concentrator has small input and output apertures, and as a result can be very short, e.g., several millimeters, while having a very wide collection angle. The light at the output apertures from the plane of micro-concentrators is coupled into multi-mode optical waveguides using reflectors, usually 45° reflectors, or curved waveguides. Therefore, the micro-concentrators can be used as passive (static) tracking elements that couple the sunlight into planar optical waveguide circuits.
In addition to collection and concentration using the micro-concentrator waveguide structure, sunlight can optionally be further spectrally processed (e.g., in the waveguide layer) and diverted onto any type of solar cell, e.g. the redirection of specific bands of wavelengths for particular solar cells. The coupling of the collected light onto the solar cell can be done by again using reflectors (e.g., using 45° turning mirrors) or curved waveguides at the final output aperture below the plane of the waveguides. These mirrors or curved waveguides direct the insolate concentrated radiation in the waveguide through apertures in the final output plane, providing a plane of concentrated light, e.g., for solar cells in a module.
Advantageous embodiments of this invention include the following common characteristics:
As indicated in the discussion above and in the drawings, micro-concentrators may be shaped and configured in various ways. Thus, micro-concentrators may, for example, be circular, square, rectangular, hexagonal, or other shape in cross-section perpendicular to a line connecting the centers of the input and output apertures of the micro-concentrators. In any case, the shapes, dimensions and materials are selected such that light which enters the top of the micro-concentrator over a capture angle is directed by reflection and/or refraction down the concentrator and out through an output aperture. In this context, the input and output apertures refer to the light entry and exit areas for the concentrator, even if the interior of the concentrator is filled.
As indicated, the micro-concentrators (also referred to as collector-concentrators) can be configured in various ways, which can include different relative areas of inlet and output apertures. Those relative areas determine the initial light concentration. Commonly, the micro-concentrators provide about a 2× concentration factor, although micro-concentrators with many other concentration factors (either higher or lower) may be utilized.
In order to efficiently use space, it is beneficial to select a micro-concentrator shape which allows close packing of the concentrators in a flat array. Thus, for example, square and hexagonal micro-concentrators can advantageously be used to form the array or matrix. Such micro-concentrators are schematically illustrated in
An advantage of using micro-concentrators is that the flat array can form a relatively thin layer or sheet. The depth of the layer will, of course, depend on the design and size of the micro-concentrators, but commonly will be less than 1 cm, and preferably less than 0.7, 0.5, or even 0.3 cm.
As also discussed elsewhere, the micro-concentrators may be empty (e.g., air-filled) or may be filled with a solid (e.g., a transparent plastic such as PMMA). Further, the micro-concentrator may be designed such that a reflective layer is deposited on the wall of the micro-concentrator and/or light may be maintained and directed within and through the micro-concentrator using refraction/reflection effects due to changes in refractive index of materials through which the light is passing within the concentrator. An example of micro-concentrators which utilize differences in refractive index is shown in
In addition to the array of micro-concentrators, the present devices advantageously utilize a flat or planar waveguide (which frequently will have multiple layers) which is usually mounted to the underside of the collector array, e.g., using a clear bonding layer. Utilization of such a planar waveguide allows the overall device to be relatively thin, e.g., preferably less than 5, 4, 3, 2, 1.5, 1.2, 1.0, 0.9, 0.8, 0.7 cm or even thinner.
The waveguide is constructed such that light entering the waveguide from a concentrator is diverted (e.g., using a mirror surface or curved waveguide) so that it travels essentially in the plane of waveguide. In many cases, a second mirror surface or curved waveguide is used which then diverts the light from traveling the plane of waveguide to traveling substantially perpendicular to the plane of the waveguide, exiting the waveguide at a location directly below the second mirror or below the exit aperture of the curved waveguide or extension thereto. Highly preferably, the waveguide circuits have negligible reflection, diffraction, absorption, and scattering in the waveguide layers.
Some of the possibilities for waveguide layout and overall design are described below and in the drawings.
Particularly advantageous designs for collector and waveguide is illustrated in
An example of a two-layer PWC for a collector-concentrator array is illustrated in
In the illustrated examples, the light is collected in an array of collector-concentrators (e.g., an array in which the collector-concentrators have square or near square rectangular upper apertures which narrow to a rectangular lower aperture. Three different types of coupling elements between the collector-concentrator and the PWC are shown in
Another simplified schematic of this type of design is shown in
The PWC is an important part of this invention. As indicated above, the solar radiation captured by the collecting/concentrating cones is coupled to the PWC, e.g., thorough 45° dielectric mirrors, 45° metal coated mirrors, or 90° waveguide bends.
As indicated above, a dielectric mirror reflects the solar radiation from the waveguide extension based on total internal reflection (TIR). In principle, this reflection could approach 100% for a smooth planar dielectric mirror surface. However depending on the collector/concentrator design, the angle of incidence (the angle between the normal to the mirror surface and the incident ray) of some of the rays exiting from the waveguide extension may be less than the critical angle needed for TIR and coupling into the PWC layer. In such cases ray leakage and light loss can result. This leakage and light loss can be significantly reduced using a metal coated mirror. Reflectivity of certain metals such as aluminum, silver, and gold over the solar spectrum can be very high, approaching 98% [Optics, E. Hecht and A. Zajac, Addison-Wesley Publishing Company, Reading, Mass., 4th edition, 1974, p. 88]. As illustrated, another approach to couple the solar radiation into the PWC is a waveguide bend, typically a 90° waveguide bend. Such a bend can be shaped to have essentially 100% transmission through it [see, e.g., No-loss bent light pipe with an equiangular spiral, Shu-Chun Chu and Jyh-Long Chern, OPTICS LETTERS, Vol. 30, No. 22, Nov. 15, 2005]. Therefore it is possible to divert the solar radiation into the PWC with minimal loss using such a bend structure.
Once the light is in PWC, it is manipulated further to improve or adjust the level of concentration (that is, the light intensity), to do spectral separation if desired, and to divert it to the solar cell underneath. All these are accomplished using established guided wave techniques. Light is trapped into a multi-mode waveguide, and guided and manipulated along this waveguide. Single or multiple waveguide layers can be used for the PWC layer.
Light couples from the collecting/concentrating cones into the PWC as described above. Coupling takes place in the lightly shaded rectangular areas labeled as “exit aperture of the cone/collector and coupling element into PWC”. In this implementation light is focused into an optical waveguide using a taper, in effect an in-plane concentrator. The light in this waveguide is combined with the light already in another waveguide containing the already collected and combined light from the previous cones. In this case the combining is done using a Y-branch. Waveguide containing the previously collected light is bent using an S-curve or a Y-branch bend. In this implementation the taper, Y-branch and the S-curve bend form a basic unit that can be cascaded several times until the desired degree of combining and concentration is achieved.
The combining and concentration can be done using other waveguide geometries and components or basic units. Some of these other basic unit possibilities are shown in
Such combining can be done a number of times until the desired level of concentration is obtained. If the size of the basic units shown in
If the level of light concentration is too high for a single element diffuser, a power splitter can be used before the taper and cone diffuser to split the power into two or more waveguides.
If the size of the basic units, e.g., as shown in
It should be noted that there is no need to shape a PWC layer such that only the waveguides, tapers, S-bends, etc. is left behind (i.e., only those light carrying elements are present in a layer). In other words there is no need to leave only the light carrying parts. One can, for example, start with a solid sheet of material and carve out thin cuts bounding the tapers, waveguides, and other elements to form the air claddings of the waveguides and waveguide elements as shown in
This approach leaves substantial area in the PWC plane that does not carry light. Such areas in two different planes can be used to connect two different PWC planes with spacers.
To summarize this type of design, light collected by collector-concentrators (preferably in a close-packed array) is directed via mirrors or other coupling structure to waveguides within a layer. The waveguides are relatively narrow compared to the width of the collectors, and can be made even narrower by using tapers or in-plane concentrators. The waveguides need not be straight, but rather can be angles and/or curved to provide an uninterrupted path and/or to allow for the placement of other elements, such as waveguide combiners, spectrum separators, waveguide combiners, and light spreaders. In most cases, S-bend elements will be included to fit the waveguides to the geometric constraints. In particularly advantageous designs, air cladding (e.g., provided by narrow cuts adjacent to the various optical elements) can be used to provide the index of refraction difference needed for effective TIR. Similarly, air gaps can be provided between layers for the same purpose; spacers to maintain the gaps properly can be included, highly preferably in non-light conducting portions of the layers.
In a basic example of another design, a collector-concentrator, having rows and columns of micro-concentrators with a relatively thin profile (e.g. 5 mm in height) serves as a low value collector and concentrator of insolate light. Additionally, the collected light is coupled to a waveguide circuit, e.g., through micro-mirrors oriented at 45 degrees (from the plane of light's path) from the downward direction of the light at the bottom of the Collector-Concentrator, diverting the light by 90 degrees from its original path and directing it laterally within the waveguide layer.
The path of the concentrated light, then parallel to the insolate surface of the concentrator, is in many cases transferred to an output aperture, again by a micro-mirror oriented at 45 degrees, by diverting it another 90 degrees to the downward direction where a solar cell device may be placed. Alternatively, the output aperture may be located at a lateral edge of the waveguide layer; in this case, the second mirror is not necessary. The concept of re-directing insolate radiation is illustrated in
In designs similar to those illustrated in Embodiment 2, in order to arbitrarily map an area of light collection to an area of concentrated light, and to arbitrarily increase the concentration ratio, and use as few waveguide layers as possible, the basic PWC can be enhanced with additional optical circuit elements. As shown in
Optionally in the PWC, a wavelength separator may be introduced to split off infrared light to reduce solar cell temperatures, as shown in
Spectral filtering structures can be introduced that modify the spectrum of light which the output pixel area receives.
The Collector-Concentrator initially concentrates by a factor Cf, and the output of the Collector-Concentrator is ‘combined’ by a PWC (multi mode combiner) with M inputs, then split to N outputs ‘pixels’ by a splitter (an inverted combiner) for a given ‘unit’ PWC circuit on one layer. For a given layer, then, the concentration factor, Cf, of the Collector-Concentrator is modulated by the combiners/splitters such that the overall concentration for a ‘pixel’ is given by
Cp=Cf×M/N.
There is an additional factor, Ac/Ap, the ratio of the areas of the Collector-Concentrator output aperture and the output aperture at the ‘pixels’, which we have assumed here is unity.
The interdigitated PWC array, with concentration Cp, can be repeated on additional upper levels (level 2 and above) by layering techniques, as shown in
The design allows for ‘spatially-adjustable light concentration transformations’ through the combination of micro-concentrators coupled to multiplex light circuits and manifolds. That is, the array of micro-concentrators coupled to interdigitated PWCs allows for an arbitrary transformation of a planar area of light collection to another plane of illuminated area, where a solar cell may be attached. The intensity of illumination over the output pixel area can arbitrarily be made to vary spatially or be made to be uniform, and can be made to accommodate any type of solar cell.
A design example focusing on the Planar Waveguide Circuit (along with some alternatives) is show in
As pointed out above, in some cases it will be desirable to incorporate wavelength separation in the device, e.g., to separate infrared (IR) and/or ultraviolet (UV) wavelengths. Such separation can, for example be beneficial to reduce heating of the solar cells and/or to reduce UV-induced damage to materials. A useful approach wavelength separation is described below as applied to IR wavelength separation.
The IR part of the solar spectrum is not absorbed by silicon and other inorganic solar absorbers and, as a result, IR does not contribute to the electrical output of the solar cell. However, its presence results in heating the surrounding materials and solar cell and reduces efficiency of the solar cell. Therefore separating IR and diverting it away from the solar cell increases the efficiency. This can be done using wavelength selective reflective surfaces once the solar radiation is in the PWC. Such surfaces can be constructed out of thin film interference filter elements that are attached to part of the PWC before concentrated solar radiation is diverted to the solar cell.
Over the length of the thin film interference filter, reflection at the waveguide/filter interface is due to filter reflection instead of total internal reflection. Therefore the desired part of the solar radiation in the PWC reflects very strongly at this interface and is kept in the waveguide. On the other hand the IR part transmits through the filter and is radiated out. Since the solar cell element is placed further away from the thin film interference filter area, IR radiation essentially completely misses the solar cell and IR separation is achieved. The thin film interference filter can be placed anywhere under the PWC and its length should be adjusted so that most of the IR is separated out.
By adjusting the reflection spectra of the thin film interference filter or by providing another filter section adapted for passing different wavelengths, the UV, especially the deep UV) part of the spectrum can also or alternatively be filtered out. This part of the spectrum is not usefully absorbed by silicon either and causes efficiency reduction due to heating and potentially due to UV degradation of some system components.
The thin film interference filter can also be fabricated during the fabrication of the PWC. The required multi-layer dielectric stack can be made out of air and PWC material. This provides a very high index contrast stack and the number of required layers can be significantly reduced. One approach to established and maintain the proper spacing of the stack layers is to use spacers of appropriate thickness separating layers of appropriate thickness made out of the PWC material as shown in
Thus,
The various optical components may be fabricated and assembled in a number of different ways, commonly using readily available fabrication techniques. Examples of methods and materials for making the present devices are described below, but those materials and methods should not be regarded as exclusive or limiting. However, for fabrication ease and cost considerations, it is preferred that primarily polymeric materials are used in the fabrication of the entire flat solar concentrator.
As indicated above, the micro-collectors (collector-concentrators) can be constructed in various configurations. For example, useful individual micro-collectors may be formed in a range of different shapes and sizes, and may utilize reflective coatings or refractive index differences for guiding light from the collector input aperture to output aperture. The fabrication of the collector-concentrator layer can be accomplished using any of a number of different fabrication techniques. Suitable fabrication techniques for forming micro-features as in the present invention can, for example, include injection molding, hot embossing, etching, and the like.
Injection Molding
One advantageous method of fabricating collector-concentrators is using injection molding and is illustrated in
As an alternative to a metallic mirror, a polymer of a higher refractive index than the body of the Collector-Concentrator can be injected into the center of the micro-concentrators. This process would require a more complex fabrication process, with an advantage of directing light towards the center of the micro-concentrator prior to reaching the output aperture. A solid sheet at the top surface of the micro-concentrators array, which serves to provide mechanical rigidity, can be incorporated into the injection molding process or bonded separately using an optical adhesive.
Hot Embossing
Concentrators can also be formed using hot embossing when the dimensions are suitable. In the hot embossing process, a pattern in a master is transferred to a thermoplastic material. If the dimensions are relatively large (>100 μm), the master can be made with conventional machining. Smaller dimensions can be produced by other known methods, e.g., using nickel electroplated through patterned photoresist.
To perform the hot embossing, the master is pressed into the thermoplastic (e.g., PMMA, polycarbonate, polypropylene) just above the material's glass transition temperature. The master and plastic are cooled while in contact, are then separated, leaving a pattern in the plastic. This general process is illustrated in
Hot embossing is used in micro-fluidics, for example, for creating trenches in substrates of thermoplastic. Several substrates can then be bonded together. Aspect ratios over 10 can be achieved, with the minimum feature size limited by the master.
Hot roller embossing of optical polymer sheets can also be used for the creation of microstructures. A polymer is selected that has a low index of refraction, such as native PMMA. After the hot-embossing process, the cavities formed for the light guides can be filled with a polymer of higher index, such as doped PMMA. A Collector-Concentrator is thus formed from the cavity in the polymer sheet, which not only has the proper geometric profile for the collection and concentration of sunlight, but also acts as a more efficient waveguide because of the filled interior. This structure seals the Collector-Concentrator array and efficiently directs light downward towards the output aperture. A schematic illustration of reel-to-reel hot embossing is shown in
Dimensions of the mould master die can be replicated down to about 100 μm features within 2% tolerance, with greater than 85% of the mould depth embossed. Feature sizes down to 50 μm and feature depths up to 30 μm are achievable.
In
The Collector-Concentrator can alternatively be fabricated by embossing in the opposite manner, in which the cavities are formed between micro-concentrators, leaving filled micro-concentrators with the polymer sheet material. The difference in this case is that the sheet is sealed and flexibility is greater, which could be desired if the final sealing process is reel-to-reellamination. The cavity between micro-concentrators is now comprised of air; hence the solid polymer micro-concentrators of a much higher index are waveguides to direct incoming light from the surface to the bottom output aperture.
Waveguides may be formed using a number of different suitable materials. Persons familiar with this field can select appropriate waveguide materials.
Many polymers are commercially available which are suitable for fabrication of the optical elements. One requirement is that the optical density must be sufficiently low to avoid absorption losses in the optical path. Optical grade PMMA, CR-39, select Topas and Zeonex polymers are example of higher quality polymers.
PMMA can be produced with very low optical density (ReidenBach and Bodem), and therefore could be the material of choice in the polymer family. PMMA can be used for this invention if manufactured with sufficiently low optical density that is consistent for achieving acceptable optical efficiency
One way of forming waveguides from a material such as PMMA uses PDMS (polydimethylsiloxane). PDMS is a silicon elastomer which is flexible and deformable, and provides a method for making microstructures through casting. It is a common material used for fabricating waveguides. A suitable type of PDMS can be readily selected by those familiar with such casting methods. Thus, PDMS can be used to fabricate waveguides for the present invention, e.g., by the following process, which is illustrated schematically in
Step 1: micro-structuring of master positive. Various materials can be used, e.g. diamond-like-carbon coated stainless steel.
Step 2: casting of PDMS negative onto structured master.
Step 3: curing of PDMS negative and release from positive and invert substrate.
Step 4: casting of PMMA with high refractive index onto the PDMS negative.
Step 5: pressing low refractive index liquid PMMA plate onto the liquid polymer using a weight; volatilize solvent.
Step 6: Release PDMS mold and invert substrate
Step 7: Diamond blade machining of beveled edges for 45° mirrors. For a given length of a waveguide in a design, multiple blades with a specific spacing can be used to define the waveguide ends to reduce process time.
Step 8: Aluminum or silver sputter metallization, photolithograhy patterning, and chemical wet etch back to fabricate mirrors on beveled surfaces.
Step 9: Coating of un-doped PMMA for cladding layer. Steps complete for planar waveguide
Another exemplary process is illustrated in
Of course, many other methods and variations can be used for constructing PWCs.
The construction of the micro-collector concentrator arrays and PWC layer assemblies can be carried out in a variety of ways.
For example, one option for the encapsulation process to make the final product of the invention, which is a flat and thin sheet of the integrated layers, includes a registration and bonding process of the layers. The Collector Concentrators are bonded to an upper sheet of thin glass or rigid polymer, while the PWC layers are bonded to a lower sheet of glass or rigid polymer. An optical grade epoxy can be spray deposited or otherwise placed at selected positions on either layer, then the layers are compressed and cured. Curing can be accomplished by UV light for example. Alignment can be accomplished by pattern recognition of fiducials in the layers during fabrication. Such a construct is illustrated in
As used in connection with this invention, the terms “insolate light”, insolate radiation“, “insolate energy”, and the like refer to sun exposure light, radiation, energy, etc., and thus involve incident sunlight.
As used herein, the term “photovoltaic” has its usual meaning, referring to the conversion of light, especially sunlight, into electrical energy, and includes both the process and devices and systems for such conversion.
In reference to micro-concentrator arrays and waveguides, the term “flat” as used herein means the indicated component or device is extended in two orthogonal dimensions (which can be considered as defining a plane) and relatively thin in the third dimension (i.e., the thickness is substantially less than either of the orthogonal plane dimensions. In many cases, such a component or device the thickness will be no more than 0.2, 0.1, 0.05, 0.02, or 0.01 times the less of the two planar dimensions.
In the context of this invention and in reference to light, the term “concentrate” and similar terms mean that incident light over an incidence area is manipulated such that it is transferred to an output area which is less than the incidence area, resulting in a higher average light intensity over the output area as compared to the incidence area.
As used herein, the term “micro-concentrator” refers to a small light concentrator, typically having a depth less than a few centimeters, and highly preferably less than 1.5, 1.2, 1.0, 0.7, or 0.5 cm or even less. In the context of such light collectors or collector-concentrators, the term “wide angle” refers to the full angle over which the majority of incident light on the light input aperture of the collector will be collected (and in the case of concentrators, also concentrated) being a wide angle, preferably at least 45, 50, 60, 65, 70, 80, 90, 100, or 120 degrees.
The term “collector-concentrator” as used herein refers to a light collector which is constructed such that light which enters the collector through its input aperture (i.e., inlet aperture) is concentrated to pass through an outlet aperture which is significantly smaller in cross-sectional area than the inlet aperture.
A “trough-type concentrator” or “trough concentrator” refers to a light concentrator which is generally trough-shaped, that is, the inlet aperture is generally rectangular (although it may have rounded corners) with a length at least 4, and usually at last 7 or 10 times the width. As described for concentrators herein the interior of the concentrator may be empty or may be filled with a material having a suitable refractive index, and/or the walls may be bare or coated, e.g., with reflective metal.
The term “in-plane concentrator” refers to a structure in a PWC layer or plane which concentrates inlet light. A common structure for such an in-plane concentrator is a taper, where the inlet aperture is the wide end of the taper and the outlet aperture is at the narrow end of the aperture. Conversely, a reverse taper or inverted taper may be used to spread light received from a waveguide or the like.
As used in connection with waveguides, the term “S-bend” refers to a shape which is bent or curved first in one direction and then bent or curved back toward the original direction, generally within the same plane. The shape can also be regarded as somewhat sigmoid.
In reference to waveguides, the terms “junction” and “combiner” refer to a structure in a PWC where two or more waveguides connect such that light from multiple inlet waveguides passes out through a common waveguide. An example is a Y-combiner.
Conversely, the term “splitter” refers to a structure in a PWC where two or more waveguides connect such that light from one or more inlet waveguides passes out through a number of waveguides which is greater than the number of inlet waveguides. In most cases, there will be one inlet waveguide and two or more outlet waveguides.
As used in connection with optical elements in the present devices, the term “cladding” refers to a material with is immediately adjacent to and forms a boundary with the reference structure. For example, “air cladding” refers to an air layer which is adjacent to a reference structure (e.g., in-plane concentrator, waveguide, junction, splitter, or other optical element in a PWC). In this case, the cladding material will have a lower refractive index than the material of the reference structure to which it is adjacent.
In the present context, indication that two components or devices are “optically connected” or “optically coupled” means there is a light path by which light is directed from one component to the other.
All patents and other references cited in the specification are indicative of the level of skill of those skilled in the art to which the invention pertains, and are incorporated by reference in their entireties, including any tables and figures, to the same extent as if each reference had been incorporated by reference in its entirety individually.
One skilled in the art would readily appreciate that the present invention is well adapted to obtain the ends and advantages mentioned, as well as those inherent therein. The methods, variances, and compositions described herein as presently representative of preferred embodiments are exemplary and are not intended as limitations on the scope of the invention. Changes therein and other uses will occur to those skilled in the art, which are encompassed within the spirit of the invention, are defined by the scope of the claims.
It will be readily apparent to one skilled in the art that varying substitutions and modifications may be made to the invention disclosed herein without departing from the scope and spirit of the invention. For example, variations can be made to the materials used and the dimensions of the parts. Thus, such additional embodiments are within the scope of the present invention and the following claims.
The invention illustratively described herein suitably may be practiced in the absence of any element or elements, limitation or limitations which is not specifically disclosed herein. Thus, for example, in each instance herein any of the terms “comprising”, “consisting essentially of” and “consisting of” may be replaced with either of the other two terms. The terms and expressions which have been employed are used as terms of description and not of limitation, and there is no intention that in the use of such terms and expressions of excluding any equivalents of the features shown and described or portions thereof, but it is recognized that various modifications are possible within the scope of the invention claimed. Thus, it should be understood that although the present invention has been specifically disclosed by preferred embodiments and optional features, modification and variation of the concepts herein disclosed may be resorted to by those skilled in the art, and that such modifications and variations are considered to be within the scope of this invention as defined by the appended claims.
In addition, where features or aspects of the invention are described in terms of Markush groups or other grouping of alternatives, those skilled in the art will recognize that the invention is also thereby described in terms of any individual member or subgroup of members of the Markush group or other group.
Also, unless indicated to the contrary, where various numerical values or value range endpoints are provided for embodiments, additional embodiments are described by taking any 2 different values as the endpoints of a range or by taking two different range endpoints from specified ranges as the endpoints of an additional range. Such ranges are also within the scope of the described invention. Further, specification of a numerical range including values greater than one includes specific description of each integer value within that range.
Thus, additional embodiments are within the scope of the invention and within the following claims.
Number | Date | Country | Kind |
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PCT/US2010/037667 | Jun 2010 | US | national |
Pursuant to 35 U.S.C. §366, this U.S. national patent application claims the benefit under 35 U.S.C. §365(a) and 35 U.S.C. §119(a) to the Jun. 7, 2010 filing date of International patent application serial number PCT/US2010/037667 (“the parent PCT application”). Except for paragraph 0001 of the parent PCT application, the contents of the parent PCT application are incorporated herein by reference in its entirety.