The present invention relates to thin circular polarizers and methods of making thin circular polarizers, wherein embodiments of said thin circular polarizers are used to reduce reflections from an electronic image display device particularly in applications pertaining to flexible or bendable display devices.
Reducing reflections of ambient lighting from a display improves the contrast ratio of the display, and therefore enables better image quality. Electronic displays, and in particular organic light-emitting diode (OLED) displays, may be operated with a single circular polarizer adhered to the viewing side of the display device to reduce reflections. An example of such usage of a circular polarizer is described in U.S. Pat. No. 6,549,335 (Trapani et al., issued Apr. 15, 2003).
In the field of circular polarizers, U.S. Pat. No. 9,766,384 (Kamada et al., issued Sep. 19, 2017) describes the use of a circular polarizer that includes a liquid crystal (LC) retarder with a hybrid aligned nematic configuration in combination with a linear polarizer to reduce reflections from a display device. U.S. Pat. No. 9,159,958 (Jeon et al., issued Oct. 13, 2015) describes the use of a circular polarizer that includes a reactive mesogen (RM) quarter wave plate retarder, a non-retardation triacetate cellulose protective layer, a linear polarizer, and a further protective layer to reduce reflections from a display device, wherein the RM quarter wave plate retarder is coated directly on top of an OLED display. U.S. Pat. No. 7,638,796 (Kwak et al., issued Dec. 29, 2009) describes the use of a circular polarizer that includes a phase difference film, a wire grid polarizer, and a dye-based polarizer to reduce reflections from a display device. US 2017007517 (Lee et al., published Mar. 16, 2017) describes the use of a circular polarizer that includes a polarizer, a photoalignment layer, and a liquid crystal layer wherein the polarizer includes a polyolefin and dichroic dye. U.S. Pat. No. 7,169,447 (Su Yu et al., issued Jan. 30, 2007) describes the use of a circular polarizer that includes a quarter wave plate retarder, a half wave plate retarder, and a linear polarizer to reduce reflections from a display device.
As generally illustrative of such devices,
Recently, flexible or bendable display systems have been developed, which have several advantages over rigid display systems. For example, flexible or bendable display systems may be bent, curved, rolled, and/or folded for compact storage, for protection of the viewing side components, to provide unique types of image presentation, and the like. A conventional circular polarizer with a thickness 130-170 μm, however, is not particularly suitable for a display system that is designed to be flexible or bendable because the circular polarizer thickness is too thick in the viewing z direction to be non-rigid. Essentially, a circular polarizer of such thickness adds significant stiffness to the overall display system to preclude a flexible or bendable display system.
Thinner circular polarizers, therefore, have been developed to be suitable for flexible or bendable display applications. For example,
The present invention pertains to circular polarizer configurations and related methods of forming a circular polarizer that decrease the thickness of the circular polarizer relative to conventional configurations. A circular polarizer adhered to the viewing side (i.e. the front) of an electronic display device reduces reflections of ambient lighting (such as sunshine, room lighting or other external lighting) from the display device. Reducing ambient reflections from a display device is beneficial because contrast ratio is improved and thus enables better image quality. In addition, with the configurations and methods of this disclosure, the thickness of the circular polarizer is decreased relative to conventional configurations so as to be more suitable for use in flexible or bendable display systems.
The disclosed configurations and manufacturing methods yield thin circular polarizers with a thickness of less than 70 μm (excluding adhesive layer 16 of
An aspect of the invention, therefore, is a flexible circular polarizer that is more suitable for flexible and bendable display systems as compared to conventional configurations. In exemplary embodiments, a flexible circular polarizer includes from a viewing side: a substrate; a liquid crystal (LC) polarizer layer; and a quarter wave plate reactive mesogen (RM) retarder layer. An optical axis of the RM retarder is aligned in a first direction and a transmission axis of the LC polarizer is aligned in a second direction different from the first direction, and an angle between the first and second directions has a value of 45°±15°. At least one of the substrate and the LC polarizer has a surface configuration that imparts an alignment to an adjacent non-viewing side layer.
For example, the LC polarizer layer may have a surface configuration that imparts an alignment to the RM retarder in the first direction, and/or the substrate may have a surface configuration that imparts an alignment to the LC polarizer in the second direction. During manufacture, the layer with the surface configuration that imparts alignment to a non-viewing side layer may be subjected to an aligning process prior to depositing the adjacent non-viewing side layer. For example, an aligning process may be performed on the LC polarizer prior to depositing the RM retarder, and the aligning process forms a surface configuration on the LC polarizer that imparts an alignment to the RM retarder in the first direction; and/or an aligning process is performed on the substrate prior to depositing the LC polarizer, and the aligning process forms a surface configuration on the substrate that imparts an alignment to the LC polarizer in the second direction. The aligning process may be a rubbing process and/or an ultraviolet radiation exposure process. The flexible circular polarizer is repeatedly reconfigurable between a planar state and a non-planar state, such as being bent, folded, rolled, flexed, and/or curved from the planar state.
Accordingly, another aspect of the invention is a flexible display system that includes from a viewing side the flexible circular polarizer according to any of the embodiments, and a display device that is adhered to the flexible circular polarizer. The flexible display system in turn is repeatedly reconfigurable between a planar state and a non-planar state, such as being bent, folded, rolled, flexed, and/or curved from the planar state.
To the accomplishment of the foregoing and related ends, the invention, then, comprises the features hereinafter fully described and particularly pointed out in the claims. The following description and the annexed drawings set forth in detail certain illustrative embodiments of the invention. These embodiments are indicative, however, of but a few of the various ways in which the principles of the invention may be employed. Other objects, advantages and novel features of the invention will become apparent from the following detailed description of the invention when considered in conjunction with the drawings.
The present invention pertains to circular polarizer configurations and related methods of forming a circular polarizer that decrease the thickness of the circular polarizer relative to conventional configurations. A circular polarizer adhered to the viewing side (i.e. the front) of an electronic display device reduces reflections of ambient lighting (such as sunshine, room lighting, or other external lighting) from the display device. Reducing ambient reflections from a display device is beneficial because contrast ratio is improved and thus enables better image quality. In addition, with the configurations of methods of this disclosure, the thickness of the circular polarizer is decreased relative to conventional configurations so as to be more suitable for use in flexible or bendable display systems.
The notion of a flexible or bendable display system has not been specifically or universally defined in the art. As used herein, terms such as “bendable display”, “foldable display”, “flexible display”, “curved display” and the like refer to display devices that generally are configured to be modified intentionally and repeatedly between a first state that is a conventional planar state and a second state that is a non-planar state for ordinary usage, storage, transport, or the like. Examples of non-planar states include flexed, folded, rolled, bent, and curved states and the like. The disclosed configurations and manufacturing methods yield thin circular polarizers with a thickness of less than 70 μm (excluding adhesive layer 16 of
The formation of the described circular polarizers generally is achieved via application of optical layers to a substrate. Such optical layers may include, for example, various combinations of an LC polarizer alignment layer, an LC polarizer with an RM retarder alignment layer function, an LC polarizer without an RM retarder alignment layer function, an RM retarder alignment layer, an RM retarder layer, and a hard coat. The deposition of any given layer may be performed using any suitable deposition process. Examples include a slot die coating process, a spray coating process, a spin coating process, a roll coating process, a printing process, an evaporation process, or a drop casting process. Various configurations employing different layer structures of such or a subset of such components are described in connection with the subsequent figures. The substrate may be a thin (e.g., <50 μm) polymer substrate, a polymer substrate with an LC polarizer alignment layer function, a polymer substrate with a polarizer function, or a polymer substrate with both a polarizer function and an RM retarder alignment layer function. Generally, as used herein, the term LC (liquid crystal) encompasses liquid crystal materials that may be a reactive mesogen (RM) LC layer, a lyotropic LC layer, a nematic LC layer, and/or a smectic LC layer.
The described configurations of a circular polarizer generally employ a linear polarizer and an RM retarder, wherein a transmission axis of the linear polarizer differs from an alignment direction of the RM retarder layer, such as by approximately 45°. In addition, the transmission axis of the linear polarizer is independent of a surface property of a layer that aligns the RM retarder. In this manner, a single layer, for example the linear polarizer or substrate or other base layer, may perform a dual function including appropriate orienting or transmission of light combined with alignment of an adjacent layer. With such dual functionality of certain layers in the various circular polarizer configurations, additional layers that are present in conventional configurations may be eliminated, thereby resulting in an overall thinner configuration that is more suitable for flexible display applications.
An aspect of the invention, therefore, is a flexible circular polarizer that is more suitable for flexible and bendable display systems as compared to conventional configurations. In exemplary embodiments, a flexible circular polarizer includes from a viewing side: a substrate; a liquid crystal (LC) polarizer layer; and a quarter wave plate reactive mesogen (RM) retarder layer. An optical axis of the RM retarder is aligned in a first direction and a transmission axis of the LC polarizer is aligned in a second direction different from the first direction, and an angle between the first and second directions has a value of 45°±15°. At least one of the substrate and the LC polarizer has a surface configuration that imparts an alignment to an adjacent non-viewing side layer.
For example, the LC polarizer layer may have a surface configuration that imparts an alignment to the RM retarder in the first direction, and/or the substrate may have a surface configuration that imparts an alignment to the LC polarizer in the second direction. During manufacture, the layer with the surface configuration that imparts alignment to a non-viewing side layer may be subjected to an aligning process prior depositing the adjacent non-viewing side layer. For example, an aligning process may be performed on the LC polarizer prior to depositing the RM retarder, and the aligning process forms a surface configuration on the LC polarizer that imparts an alignment to the RM retarder in the first direction; and/or an aligning process is performed on the substrate prior to depositing the LC polarizer, and the aligning process forms a surface configuration on the substrate that imparts an alignment to the LC polarizer in the second direction. The aligning process may be a rubbing process and/or an ultraviolet radiation exposure process. The flexible circular polarizer is repeatedly reconfigurable between a planar state and a non-planar state, such as being bent, folded, rolled, flexed, and/or curved from the planar state.
In accordance with such features,
The LC polarizer alignment layer 44 is coated onto the substrate 42 and may be a conventional LC alignment layer, such as for example polyimide (PI). After the LC polarizer alignment layer 44 is deposited onto the substrate 42, the LC polarizer alignment layer 44 may be subjected to a baking process (up to 280° C.). After the baking process, the exposed surface of the LC polarizer alignment layer 44 may be subjected to an aligning process. In general, the purpose of an aligning process in this context is to create a template on the surface of a given layer so that said layer can impart an alignment direction to other materials (such as LCs and RMs) that are subsequently deposited on said layer. The aligning process of the LC polarizer alignment layer 44 may be a rubbing process and/or a UV (ultraviolet) radiation exposure process as are known in the art. As examples, when a UV radiation exposure process is used as the aligning process for the LC polarizer alignment layer 44, the UV radiation may have a wavelength of approximately 254 nm for a bond breaking process, and/or the UV radiation may have a wavelength of approximately around 365 nm for a bond making process, depending upon the nature of the desired resultant alignment effect and the material comprising the LC polarizer alignment layer 44. The UV radiation also may be linearly polarized. The LC polarizer alignment layer 44 aligning process is performed before deposition of the LC polarizer 46, so that the LC polarizer alignment layer 44 has a surface configuration that can then impart an alignment to align the transmission axis of the LC polarizer 46 in a direction that is in the x-y plane.
As is typical for a circular polarizer, the LC polarizer 46 is a linear polarizer, and the LC polarizer 46 is deposited on the LC polarizer alignment layer 44. As referenced above, the LC polarizer alignment layer 44 has a surface configuration that aligns the transmission axis of the LC polarizer 46 in the x-y plane. The LC polarizer 46 may be a guest-host type LC polarizer, i.e. a dye doped LC polarizer, whereby a dye or a mixture of dyes and an LC material are mixed and deposited on the LC polarizer alignment layer 44. The LC material of the LC polarizer 46 may be an RM material, or may be a mixture of an LC material and polymer-precursors that can be subsequently polymerized to form a solid film. As another example, the LC polarizer 46 may be a lyotropic LC dye or a mixture of lyotropic LC dyes, or a mixture of lyotropic LC and a dye or a mixture of dyes. The lyotropic LC, the dye, or both may be polymerized to a solid film. In the case of a lyotropic LC, the polymerization may occur before, during or after evaporation of the lyotropic LC solvent. The LC polarizer 46 alternatively may be polymerized via a UV radiation exposure and/or a heating process.
After the LC polarizer 46 has been deposited on the LC polarizer alignment layer 44 and polymerized (if applicable), a non-viewing side surface of the LC polarizer 46 is then subjected to an aligning process. The purpose of the aligning process in this context is to create a template on the exposed (non-viewing side) surface of the LC polarizer 46 so that the LC polarizer 46 has a surface configuration that can impart a predefined alignment direction to another material layer that is subsequently deposited onto the LC polarizer 46, such as for example another LC layer or an RM layer. An aligning process is not performed on the LC polarizer in conventional circular polariser configurations.
Without such additional aligning process, then another material layer (such as LC and RM) that is subsequently deposited, in general, will tend to align either parallel to perpendicular to the transmission axis of the LC polarizer 46. In contrast, the aligning process of the LC polarizer 46 enables the LC polarizer 46 to have a transmission axis in a second direction, while the surface configuration of the LC polarizer 46 imparts an alignment in a first direction to LC materials (including RMs and lyotropic LCs) that are subsequently deposited on the LC polarizer 46. The first and second directions are in the x-y plane, and the second direction is different from the first direction by a predetermined amount suitable for a particular application, and such difference is determined by the aligning process applied to the LC polarizer 46.
The aligning process of the LC polarizer 46 may be a rubbing process and/or a UV (ultra-violet) radiation exposure process as described above. Again, in an example when a UV radiation exposure process is used as the aligning process for the LC polarizer 46, the UV radiation may have a wavelength of approximately 254 nm for a bond breaking process, and/or a wavelength of approximately 365 nm for a bond making process depending upon the desired alignment result and the material comprising the LC polariser 46. The UV radiation also may be linearly polarized, and a wavelength of approximately 254 nm for a bond breaking process has been determined to be particularly suitable for achieving the circular polarizer device shown in
Referring to the specific configuration of
As referenced above, the first direction (RM alignment direction) and second direction (polarizer transmission axis) are both in the x-y plane. In exemplary embodiments, the angle, φ, between the first direction and the second direction is 45°±15° and preferably 45°, i.e. the angle, φ, between the optical axis of the RM retarder 46 and the transmission axis of the LC polarizer 46 is 45°±15° and preferably 45°. The RM retarder 48 is a quarter wave plate (QWP) that can convert linearly polarized light to circularly polarized light and vice versa. The RM retarder 48 may have a positive dispersion curve, a flat dispersion curve, or a negative dispersion curve. An RM retarder 48 with a negative dispersion curve has an advantage that the RM retarder 48 is able to convert a wider range of optical wavelengths into circularly polarized light than an RM retarder with either a flat dispersion curve or positive dispersion curve. An RM retarder 48 with a negative dispersion curve, in combination with the LC polarizer 46, is therefore able to reduce reflections from the display device more effectively, which enables better image quality in ambient lighting. On a comparable basis, an RM retarder 48 with a flat dispersion curve is advantageous over an RM retarder with a positive dispersion curve.
As referenced above, in this embodiment the substrate 52 operates as the dual function layer. The first function of the substrate 52 is a substrate function to act as the base layer on which subsequent layers are deposited. In addition, as the second function the substrate 52 aligns the LC polarizer 54 in the second direction. The substrate 52 may be manufactured in such a way, for example, using a stretching process to have a surface configuration that has an intrinsic alignment function that aligns the LC polarizer 52. Alternatively, an aligning process such as described above may be applied to the non-viewing side surface of the substrate 52 form a surface configuration that is able to align the LC polarizer 54 in the second direction. The aligning process applied to substrate 52 may be a rubbing process and/or a UV (ultraviolet) radiation exposure process similarly as the aligning process performed on the LC polarizer 46 of the previous embodiment. Accordingly, in an example when a UV radiation exposure process is used as the aligning process for the substrate 52, the UV radiation may have a wavelength of approximately 254 nm (a bond breaking process) and/or a wavelength of approximately 365 nm (a bond making process), and the UV radiation may be linearly polarized. The substrate 52 aligning process is performed before deposition of the LC polarizer 54 and functions to form a surface configuration to align the optical axis of the LC polarizer 54 in the second direction. By configuring the surface configuration of substrate 52 to perform the alignment of the LC polarizer 54, the LC polarizer alignment layer 26 of the conventional configuration of
As in the previous embodiment, the LC polarizer 54 is a linear polarizer that has a transmission axis in the second direction, which is in the x-y plane. The LC polarizer 54 may have a material composition comparably as the LC polarizer of the previous embodiment. In the embodiment of
Again, the first direction corresponding to the RM retarder alignment (RM retarder optical axis) and the second direction corresponding to the LC polarizer alignment (polarizer transmission axis) are both in the x-y plane and are different from each other. Comparably as above, the angle, φ, between the first direction and the second direction is 45°±15° and preferably 45°.
Accordingly, the first function of substrate 62 is to act as a base layer upon which the other layers are subsequently deposited, as is conventional. The second function of substrate 62 is to impart an alignment to the LC polarizer 64 in the second direction, which is not performed in conventional configurations. In this manner, the separate LC polarizer alignment layer 26 of the conventional configuration of
Similarly as in previous embodiments, the first direction corresponding to the RM retarder alignment (RM retarder optical axis) and the second direction corresponding to the LC polarizer alignment (polarizer transmission axis) are both in the x-y plane and are different from each other. Comparably as above, the angle, φ, between the first direction and the second direction is 45°±15° and preferably 45°.
Accordingly, the first function of the combined substrate/polarizer 72 is to act as a base layer upon which the other layers are subsequently deposited, as is conventional. The second function of the combined substrate/polarizer 72 is to act as a linear polarizer that transits light that is linearly polarized in the second direction. The combination of a substrate function and a linear polarizer function into a single layer differs from the conventional configurations. In this manner, the separate LC polarizer 28 and the additional LC polarizer alignment layer 26 of the conventional configuration of
In the embodiment of
Also similarly as in previous embodiments, the first direction corresponding to the RM retarder alignment (RM retarder optical axis) and the second direction corresponding to the combined substrate/polarizer 72 transmission axis are both in the x-y plane and are different from each other. Comparably as above, the angle, φ, between the first direction and the second direction is 45°±15° and preferably 45°.
In the embodiment of
Accordingly, the combined substrate/polarizer 82 of this embodiment is processed to be configured to perform three functions. The first function of the combined substrate/polarizer 82 is to act as a base layer upon which the RM retarder layer is subsequently deposited, as is conventional. The second function of the combined substrate/polarizer 82 is to act as a linear polarizer that transits light that is linearly polarized in the second direction. The third function of the combined substrate/polarizer 82 is to impart an alignment direction to set the optical axis of the RM retarder 84. The combination of a substrate function, a linear polarizer function, and an RM retarder alignment function into a single layer differs from the conventional configurations. In this manner, the separate LC polarizer 28, the additional LC polarizer alignment layer 26, and the additional RM retarder alignment layer 30 of the conventional configuration of
Also similarly as in previous embodiments, the first direction corresponding to the RM retarder alignment (RM retarder optical axis) and the second direction corresponding to the combined substrate/polarizer 82 transmission axis are both in the x-y plane and are different from each other. Comparably as above, the angle, φ, between the first direction and the second direction is 45°±15° and preferably 45°.
With respect to the various embodiments described above, an overall thickness in the viewing z direction of the circular polarizers is less than 70 μm. Such a thickness renders a circular polarizer according to any of the embodiments particularly suitable for use in flexible or bendable display devices. Accordingly, another aspect of the invention is a flexible display system that includes from a viewing side the flexible circular polarizer according to any of the embodiments, and a display device that is adhered to the flexible circular polarizer. The flexible display system in turn is repeatedly reconfigurable between a planar state and a non-planar state, such as being bent, folded, rolled, flexed, and/or curved from the planar state.
The display device 94 may be a liquid crystal display (LCD) or an organic light-emitting display (OLED). Alternatively, the display device 94 may be a quantum material light-emitting display (QMLED), whereby the quantum material includes quantum dots and/or quantum rods and/or nanocrystals. In a QMLED, direct electrical stimulation of the quantum material is used to produce light. The color of the light emitted from the quantum material may be a function of the chemical structure of the quantum material, the size of the quantum material particles, and/or the shape of the quantum material particles. The use of a circular polarizer according to any of the embodiments in conjunction with an OLED or QMLED type display device is particularly suitable to reduce ambient reflections from these types of display device because the electrodes associated with OLEDs and QMLEDs are typically reflective.
Referring to
Again, in this example the first side 102 is the viewing side, meaning in the folded state images cannot be viewed. Such a configuration, for example, may be suitable to protect the viewing side components for compact storage or transport. The viewing and non-viewing sides may be reversed, however, with the second side 104 being the viewing side. In such configuration, therefore, images are viewable in the folded state which may provide unique viewing modes, such as for example being able to view images from both sides of the display system (and also can provide a more compact arrangement for storage and transport).
An aspect of the invention is a flexible circular polarizer that is more suitable for flexible and bendable display systems as compared to conventional configurations. In exemplary embodiments, a flexible circular polarizer includes from a viewing side: a substrate; a liquid crystal (LC) polarizer layer; and a quarter wave plate reactive mesogen (RM) retarder layer. An optical axis of the RM retarder is aligned in a first direction and a transmission axis of the LC polarizer is aligned in a second direction different from the first direction, and an angle between the first and second directions has a value of 45°±15°. At least one of the substrate and the LC polarizer has a surface configuration that imparts an alignment to an adjacent non-viewing side layer. The flexible polarizer may include one or more of the following features, either individually or in combination.
In an exemplary embodiment of the flexible circular polarizer, the LC polarizer layer has a surface configuration that imparts an alignment to the RM retarder in the first direction.
In an exemplary embodiment of the flexible circular polarizer, the flexible circular polarizer further includes an LC polarizer alignment layer deposited between the substrate and the LC polarizer that imparts an alignment to the LC polarizer in the second direction.
In an exemplary embodiment of the flexible circular polarizer, the substrate has a surface configuration that imparts an alignment to the LC polarizer in the second direction.
In an exemplary embodiment of the flexible circular polarizer, the flexible circular polarizer further includes an RM retarder alignment layer deposited between the LC polarizer and the RM retarder that imparts an alignment to the RM retarder in the first direction.
In an exemplary embodiment of the flexible circular polarizer, the LC polarizer has a surface configuration that imparts an alignment to the RM retarder in the first direction, and the substrate has a surface configuration that imparts an alignment to the LC polarizer in the second direction.
In an exemplary embodiment of the flexible circular polarizer, the substrate and the LC polarizer are combined into a single layer, and the combined substrate/LC polarizer has a surface configuration that imparts an alignment to the RM retarder layer in the first direction.
In an exemplary embodiment of the flexible circular polarizer, the substrate is an optically transparent and colorless polymer, and LC polarizer includes either an RM material or a lyotropic LC material.
In an exemplary embodiment of the flexible circular polarizer, the substrate includes at least one of the following materials: polyethylene terephthalate (PET), Poly(methyl methacrylate) (i.e. PMMA), Polyethylene naphthalate (PEN), cyclo olefin polymer (COP), cyclo olefin copolymer (COC), polycarbonate (PC), high temperature polycarbonate (HTPC), polyetherimide (PEI), polyarcylate (PAR), polyphenylene sulfide (PPS), polyethersulfone (PES), polyether ether ketone (PEEK), polyimide (PI) or polyamide imide (PAI).
In an exemplary embodiment of the flexible circular polarizer, the flexible circular polarizer further includes a hard coat layer deposited on a viewing side of the substrate.
In an exemplary embodiment of the flexible circular polarizer, the flexible circular polarizer has a thickness of less than 70 μm.
In an exemplary embodiment of the flexible circular polarizer, the flexible circular polarizer is repeatedly reconfigurable between a planar state and a non-planar state.
In an exemplary embodiment of the flexible circular polarizer, the non-planar state includes a folded state and/or a rolled state.
In an exemplary embodiment of the flexible circular polarizer, in the non-planar state the flexible circular polarizer has a region having a radius of curvature of less than 10 mm.
Another aspect of the invention is a flexible display system that includes from a viewing side the flexible circular polarizer according to any of the embodiments, and a display device that is adhered to the flexible circular polarizer. The display system may include one or more of the following features, either individually or in combination.
In an exemplary embodiment of the display system, the display system further includes an antireflection coating deposited on a viewing side of the flexible circular polarizer.
In an exemplary embodiment of the display system, the display system is repeatedly reconfigurable between a planar state and a non-planar state.
In an exemplary embodiment of the display system, the non-planar state includes a folded state and/or a rolled state.
In an exemplary embodiment of the display system, in the non-planar state the display system has a region having a radius of curvature of less than 10 mm.
Another aspect of the invention is a method of forming a flexible circular polarizer comprising steps of depositing from a viewing side: a substrate; a liquid crystal (LC) polarizer layer; and a quarter wave plate reactive mesogen (RM) retarder layer; wherein an optical axis of the RM retarder is aligned in a first direction and a transmission axis of the LC polarizer is aligned in a second direction different from the first direction, and an angle between the first and second directions has a value of 45°±15°; and prior to depositing an adjacent non-viewing side layer, performing an aligning process on at least one of the substrate and the LC polarizer to form a surface configuration that imparts an alignment to the adjacent non-viewing side layer. The method may include one or more of the following features, either individually or in combination.
In an exemplary embodiment of the method of forming a flexible circular polarizer, an aligning process is performed on the LC polarizer prior to depositing the RM retarder, and the aligning process forms a surface configuration on the LC polarizer that imparts an alignment to the RM retarder in the first direction.
In an exemplary embodiment of the method of forming a flexible circular polarizer, the method further includes depositing an LC polarizer alignment layer between the substrate and the LC polarizer that imparts an alignment to the LC polarizer in the second direction.
In an exemplary embodiment of the method of forming a flexible circular polarizer, an aligning process is performed on the substrate prior to depositing the LC polarizer, and the aligning process forms a surface configuration on the substrate that imparts an alignment to the LC polarizer in the second direction.
In an exemplary embodiment of the method of forming a flexible circular polarizer, the method further includes depositing an RM retarder alignment layer between the LC polarizer and the RM retarder that imparts an alignment to the RM retarder in the first direction.
In an exemplary embodiment of the method of forming a flexible circular polarizer, an aligning process is performed on the substrate prior to depositing the LC polarizer, and the aligning process forms a surface configuration on the substrate that imparts an alignment to the LC polarizer in the second direction; and an aligning process is performed on the LC polarizer prior to depositing the RM retarder, and the aligning process forms a surface configuration on the LC polarizer that imparts an alignment to the RM retarder in the first direction.
In an exemplary embodiment of the method of forming a flexible circular polarizer, the substrate and the LC polarizer are combined into a single layer, an aligning process is performed on the combined substrate/LC polarizer prior to depositing the RM retarder, and the aligning process forms a surface configuration on the combined substrate/LC polarizer that imparts an alignment to the RM retarder in the first direction.
In an exemplary embodiment of the method of forming a flexible circular polarizer, the aligning process is at least one of a rubbing process or an ultraviolet radiation exposure process.
In an exemplary embodiment of the method of forming a flexible circular polarizer, the method further includes depositing a hard coat layer on a viewing side of the substrate.
In an exemplary embodiment of the method of forming a flexible circular polarizer, the flexible circular polarizer has a thickness of less than 70 μm.
Although the invention has been shown and described with respect to a certain embodiment or embodiments, it is obvious that equivalent alterations and modifications will occur to others skilled in the art upon the reading and understanding of this specification and the annexed drawings. In particular regard to the various functions performed by the above described elements (components, assemblies, devices, compositions, etc.), the terms (including a reference to a “means”) used to describe such elements are intended to correspond, unless otherwise indicated, to any element which performs the specified function of the described element (i.e., that is functionally equivalent), even though not structurally equivalent to the disclosed structure which performs the function in the herein illustrated exemplary embodiment or embodiments of the invention. In addition, while a particular feature of the invention may have been described above with respect to only one or more of several illustrated embodiments, such feature may be combined with one or more other features of the other embodiments, as may be desired and advantageous for any given or particular application.
Embodiments of the present invention relate to configurations and manufacturing methods of circular polarizers. The circular polarizers may be adhered to electronic display devices to reduce ambient reflections from said display devices and therefore improve contrast ratio. The electronic display devices may include, but are not limited to, mobile phones, smartphones, personal digital assistants (PDAs), tablet and laptop computers. The electronic display devices may be an emissive type, such as organic light emitting diode (OLED). Principles of the present invention in particular are applicable to display devices that are intended to be bent, folded, rolled, curved, and/or otherwise flexed from a conventional planar configuration for ordinary usage, storage, transport, and the like.