This invention relates to fuel cell assemblies.
Proton exchange membrane (PEM) fuel cells are electrochemical devices that convert chemical energy of hydrogen into electrical energy without combustion. They have high potential to offer an environmentally friendly, high-energy density, efficient, and renewable power source for various applications from portable devices to vehicles and stationary power plants.
PEM fuel cells operate at relatively low temperatures, have higher power density than direct methanol fuel cells, and can quickly respond to changes in power demand. For portable power applications, PEM fuel cells might be light weight and compact size to compete with conventional batteries, and various arts have been developed and are being developed to address the weight and size issue of PEM fuel cells.
A basic single PEM fuel cell unit (
In some conventional designs, multiple fuel cell units are stacked together to form a fuel cell stack. One major shortcoming of such conventional fuel cell assemblies is contact resistance between layers of material in the fuel cell and layers of different fuel cells, which causes power loss and internal heat generation. The layers must be held in intimate electrical contract with each other to reduce the fuel cell's internal resistance. One conventional design to reduce contact resistance is to clam the single fuel cell or a fuel cell stack through the use of end plates, bolts and screws. Considerable compression force is needed to achieve minimum contact resistance, requiring the end plates to have high structure strength. End plates are often made of metals such as aluminum or ePoxy fiber composites. This is an effective approach to reduce contact resistance, however it adds significant complexity, weight and size to the fuel cell, making it not suitable for portable applications where light weight and compact size are required.
One additional problem found in conventional fuel cell assemblies is that reactant gas flow channels need to be machined, etched or molded on the plates. The gas flow channels create sealing problems and add weight, size and cost to the fuel cell. It is advantageous if the flow channels could be replaced.
Some prior art systems introduced micro fabrication techniques for compact fuel cell designs. U.S. Pat. No. 6,864,010 introduced a fuel cell of which a porous substrate is filled with electrolyte and catalyst and current collector layers are deposited through a thin film coating approach, such as sputtering, electroless plating, electroplating, soldering, physical vapor deposition, chemical vapor deposition, etc. U.S. Pat. No. 5,631,099 disclosed a planar fuel cell design which uses thin film coating technology to coat catalyst layer to a composite membrane and coats the current collector layer to the catalyst layer or gas diffusion layer. Compared to conventional technologies, those prior art systems do have improvements in the area of fuel cell power density, especially for fuel cells less than 10 watts, however, those thin film coating technologies are still very complicated and costly, not suitable for mass producing low cost fuel cells.
For a fuel cell to compete with conventional batteries, it must not only have the desired performance and cost, but also be capable of being mass-produced. Lamination is a preferred method for fuel cell assembly and it would enable a roll-to-roll manufacturing process for fuel cells, which is a mass manufacturing technique widely applied within many industries. It is also important to design the fuel cell as simply as possible to reduce unnecessary parts and components, as well as to improve its reliability.
One objective of certain embodiments of the invention is to reduce the fuel cell's contact resistance between layers without clamping the fuel cell or applying thin film deposition technology, so that a very light weight and very compact size fuel cell can be manufactured.
A second objective of certain embodiments of the invention is to reduce the amount of fuel cell components and parts through innovative designs, thus further reducing the weight and size of fuel cells, improving product reliability, and minimizing material and production costs.
A third objective of certain embodiments of the invention is to provide a fuel cell design which can adopt a simple lamination process for fuel assembly, eventually enabling roll-to-roll manufacturing of fuel cells.
To achieve at least some of the above objectives, a highly conductive and high polymer content gas diffusion material is used in the fuel cell assembly to replace the conventional carbon fiber paper or carbon fiber cloth. Porous current collectors are used to replace conventional graphite plates or metal plates, and a thin gas supply material is used to replace conventional reactant gases flow channels.
A membrane electrode assembly and current collector sub-unit can be made in a one step or multi-step lamination process by placing a catalyst coated membrane between two highly conductive and high polymer content gas diffusion layers, and placing two porous current collectors on the outer sides of both gas diffusion layers. A hydrogen supply layer can be further laminated to the sub-unit to form a fuel cell assembly.
The details of one or more embodiments of the invention are set forth in the accompanying drawings and the description below. Other features, objects, and advantages of the invention will be apparent from the description and drawings, and from the claims.
A conventional fuel cell (
Various embodiments of the invention use highly conductive and high-polymer content gas diffusion layer to replace the low or no-polymer content gas diffusion layers such as carbon fiber paper, carbon fiber cloth, carbon fiber paper coated with a micro-porous layer, or carbon fiber cloth coated with a micro-porous layer. Under pressure and heat, the polymer inside the highly conductive and high polymer content gas diffusion layer will melt and deform so good adhesions of the gas diffusion layer to the porous current collectors 10,11 such as thin metal film and to the catalyst layers and to the membrane can be achieved. Contact resistances between layers can be greatly reduced and a high efficiency, high power density fuel cell can be made as a result.
The highly conductive and high polymer content gas diffusion layers are made of polymers selected from thermal plastics materials such as PTFE, PVDF, ETFE, PP, PE etc., and conductive materials selected from carbon black, graphite power, soot, carbon fiber, gold, platinum, ruthenium, and any combinations, etc. A preferred polymer is PTFE and a preferred conductive material is carbon black. Carbon fiber can be added to increase the in plane conductivity. The highly conductive and high polymer content material contains 15%-80% of polymer and 20%-85% of conductive materials. Conductivity decreases when the polymer content in the gas diffusion layers increases, and the preferred polymer weight percentage is from 25% to 70%. The conductivity of the layer is typically less than 20 mohoms-cm2 or preferably less than 10 mohoms-cm2. The highly conductive and high polymer content gas diffusion layers are commercially available from suppliers such as Taiqiao Electronics in China.
The current collectors need to be porous to allow reactant gases to diffuse. Porous metal mesh, carbon fiber paper, carbon fiber cloth and graphite film are suitable. The material should have high in plane conductivity and good corrosion resistance. Metal materials such as titanium, nickel, stainless steel, gold, platinum, ruthenium, etc. can be used and titanium, nickel and stainless steel, are preferred due to their conductivity and anti-corrosion capability. The titanium mesh, nickel mesh and stainless stain mesh can be further anti-corrosion treated. Thin TiN, CrN, Au, Ru, RuO and graphite film can be formed on the surfaces on the metal meshes. Surface treatment techniques are well-know in the industry and thus are not discussed in detail here.
To make a membrane electrode assembly and current collector sub-unit
Alternatively, the highly conductive and high polymer content gas diffusion layers 4, 5 are laminated to the porous current collectors 10, 11 first, and then a catalyst coated membrane 1, 2, 3 is sandwiched between the two gas diffusion layers 4, 5 and laminated. Alternatively, the above multi layers of materials can be laminated in a single step process or in a multiple step process.
Referring to
The membrane electrode assembly and current collect sub unit can be hold in a thin frame 14. The edges of the sub-unit are embedded in the frame 14 and sealed gas tight. The hydrogen supply layer is glued or laminated to the frame forming a hydrogen chamber. Alternatively, the hydrogen supply layer can be glued or laminated directly to the edges of the anode side of the sub-unit. The preferred glue is a silicon rubber adhesive.
A hydrogen inlet 15 and a hydrogen outlet 16 are installed to the hydrogen chamber formed by the non-porous layer 13 and the edges of the sub-unit.
A 5 cm×5 cm highly conductive and high polymer content gas diffusion layer is laminated to a 5 cm×5 cm titanium film (porous current collector) under pressure of 200 B and temperature of 160° C. for 1 minute. A catalyst ink with a Pt loading of 0.4 mg/cm2 is coated to the gas diffusion layer. The laminated and catalyst coated material is cut into four pieces, each with a size of 2.5 cm×2.5 cm. A 5.5 cm×2.5 cm proton exchange membrane is placed in between the two pieces and laminated at below 200 Bar and at a temperature of 160 C for 2 minutes. A membrane electrode assembly and current collector sub-unit with two cells is produced.
The sub-unit is placed in two pieces of plastics frame and laminated. Then a non-porous plastic film is further laminated to the anode side of the sub-unit and a hydrogen inlet needle and a hydrogen outlet needle are installed on the fuel cell unit.
After supplying hydrogen to the fuel cell and connecting it to a load, a voltage of 1.4V and current of 0.15 A are observed.
A 2.5 cm×2.5 cm CCM is sandwiched between two 2.5 cm×2.5 cm highly conductive and high polymer content gas diffusion layers, and two 2.5 cm×2.5 cm titanium film (porous current collector) are disposed on the outer sides of both gas diffusion layers. The entire five layers are laminated under a pressure of 200 Bar and at a temperature of 160° C. for 2 minutes, to form a membrane electrode assembly and current collector sub-unit.
The sub-unit is placed in two pieces of plastics frame and laminated. Then a non-porous plastics film is further laminated to the anode side of the sub-unit and a hydrogen inlet needle and a hydrogen outlet needle are installed on the fuel cell unit.
After supplying hydrogen to the fuel cell and connecting it to a load, a voltage of 0.7 and current of 0.15 A are observed.
Other embodiments are within the following claims.
This application claims the benefit of U.S. Provisional Application No. 60/729,951, filed Oct. 25, 2005, the contents of which are incorporated herein by reference.
Number | Date | Country | |
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60729951 | Oct 2005 | US |