The present invention relates to a thin film transistor and a method of producing the same.
Thin film transistors (hereinafter, “TFT”) are used as switching elements on an active matrix substrate of a display apparatus such as a liquid crystal display apparatus or an organic EL display apparatus, for example. In the present specification, such TFTs will be referred to as “pixel TFTs”. As pixel TFTs, amorphous silicon TFTs whose active layer is an amorphous silicon film (hereinafter abbreviated as an “a-Si film”), polycrystalline silicon TFTs whose active layer is a polycrystalline silicon (polysilicon) film (hereinafter abbreviated as a “poly-Si film”), and the like have been widely used. Generally speaking, a poly-Si film has a higher field-effect mobility than that of an a-Si film, and therefore a polycrystalline silicon TFT has a higher current driving power (i.e., a larger ON current) than that of an amorphous silicon TFT.
A TFT having a gate electrode disposed at the substrate side of the active layer is referred to as a “bottom-gate type TFT”, whereas a TFT having a gate electrode disposed above its active layer (i.e., the opposite side from the substrate) is referred to as a “top-gate type TFT”. In some cases, forming bottom-gate type TFTs as the pixel TFTs may have cost advantages relative to forming top-gate type TFTs.
Known types of bottom-gate type TFTs are channel-etch type TFTs (hereinafter “CE-type TFT”) and etch-stop type TFTs (hereinafter “ES-type TFT”). In a CE-type TFT, an electrically conductive film is formed directly upon an active layer, and this electrically conductive film is patterned to provide a source electrode and a drain electrode (source-drain separation). On the other hand, in an ES-type TFT, a source-drain separation step is performed while a channel section of the active layer is covered with an insulating layer that functions as an etchstop (hereinafter referred to as a “protective insulating layer”).
Polycrystalline silicon TFTs are usually of top-gate type, but polycrystalline silicon TFTs of bottom-gate type have also been proposed. For example, Patent Document 1 discloses a polycrystalline silicon TFT of bottom-gate type (ES-type).
As display apparatuses become larger in size and higher-definitioned, it is required to further enhance the channel mobility of TFTs and improve the ON characteristics thereof.
An embodiment of the present invention has been made in view of the above circumstances, and an objective thereof is to provide a thin film transistor of bottom-gate type that can have high ON characteristics and a method of producing the same.
A thin film transistor according to an embodiment of the present invention comprises: a substrate; a gate electrode supported by the substrate; a gate insulating layer covering the gate electrode; a semiconductor layer being disposed on the gate insulating layer and including a polysilicon region, the polysilicon region including a first region, a second region, and a channel region that is located between the first region and the second region; a source electrode electrically connected to the first region; a drain electrode electrically connected to the second region; the thin film transistor further comprises, above a portion of the channel region, at least one protecting section that is spaced apart from at least one of the first region and the second region; the at least one protecting section has a multilayer structure including an i type semiconductor layer composed of an intrinsic semiconductor and a protective insulating layer disposed on the i type semiconductor layer; the i type semiconductor layer has a band gap larger than that of the polysilicon region; and the i type semiconductor layer is directly in contact with the channel region.
In one embodiment, the at least one protecting section comprises a plurality of protecting sections disposed at a space from one another.
In one embodiment, the thin film transistor is covered by an inorganic insulating layer, the inorganic insulating layer is directly in contact with the channel region at the space between the plurality of protecting sections.
In one embodiment, when viewed from a normal direction of the substrate, a total area of portions of the channel region that are in contact with the i type semiconductor layer in the at least one protecting section accounts for not less than 20% and not more than 90% of an area of the entire channel region.
In one embodiment, the i type semiconductor layer includes a plurality of i type semiconductor islets disposed in a discrete manner.
One embodiment further comprises: a first contact layer being disposed between the source electrode and the first region and connecting between the source electrode and the first region; and a second contact layer being disposed between the drain electrode and the second region and connecting between the drain electrode and the second region.
In one embodiment, the at least one protecting section includes: a first protecting section disposed between the first contact layer and the first region; and a second protecting section disposed between the second contact layer and the second region.
In one embodiment, when viewed from the normal direction of the substrate, the at least one protecting section further includes another protecting section that is disposed between the first protecting section and the second protecting section.
In one embodiment, the first contact layer includes an n+ type a-Si layer being composed of an n+ type amorphous silicon and disposed so as to be directly in contact with the first region; and the second contact layer includes an n+ type a Si layer being composed of an n+ type amorphous silicon and disposed so as to be directly in contact with the second region.
In one embodiment, in the at least one protecting section, a side surface of the protective insulating layer and a side surface of the i type semiconductor layer are aligned.
In one embodiment, when viewed from the normal direction of the substrate, the semiconductor layer further includes an amorphous silicon region located outside the polysilicon region.
In one embodiment, the i type semiconductor layer is an i type a-Si layer composed of an intrinsic amorphous silicon.
A display apparatus according to an embodiment of the present invention comprises the thin film transistor of any of the above, wherein the display apparatus has a displaying region including a plurality of pixels; and the thin film transistor is disposed in each of the plurality of pixels.
A method of producing a thin film transistor according to an embodiment of the present invention is a method of producing a thin film transistor supported by a substrate, the method comprising: a step of forming on the substrate a gate electrode, a gate insulating layer covering the gate electrode, and a semiconductor layer including a polysilicon region; a step of forming on the semiconductor layer an i type semiconductor film and a protective insulating film in this order, the i type semiconductor film being composed of an intrinsic semiconductor; a step of patterning the i type semiconductor film and the protective insulating film to form at least one protecting section, the at least one protecting section having a multilayer structure including an i type semiconductor layer formed from the i type semiconductor film and a protective insulating layer formed from the protective insulating film, wherein the at least one protecting section is disposed above a part of a portion to become a channel region of the semiconductor layer so as to be spaced apart from at least one of a first region and a second region that are located on opposite sides of the portion of the semiconductor layer to become the channel region, and exposes the first region and the second region; a step of forming a silicon film for contact layer formation and an electrically conductive film in this order so as to cover the semiconductor layer and the at least one protecting section; an source-drain separation step of patterning the silicon film for contact layer formation and the electrically conductive film by using the at least one protecting section as an etchstop, to form from the silicon film for contact layer formation a first contact layer that is in contact with the first region and a second contact layer that is in contact with the second region, and to form from the electrically conductive film a source electrode that is in contact with the first contact layer and a drain electrode that is in contact with the second contact layer; and a step of forming an inorganic insulating layer that covers the semiconductor layer, the at least one protecting section, the source electrode, and the drain electrode, the inorganic insulating layer being directly in contact with a portion of the portion of the semiconductor layer to become the channel region that is not covered by the at least one protecting section.
In one embodiment, in the step of forming the at least one protecting section, a plurality of protecting sections are formed in the portion to become the channel region so as to be spaced apart from one another.
In one embodiment, the i type semiconductor film is formed by utilizing an initial phase of growth of film formation by a CVD technique.
In one embodiment, the i type semiconductor film has an islanded structure including a plurality of i type semiconductor islets disposed in a discrete manner.
In one embodiment, the i type semiconductor layer is an i type a-Si layer composed of an intrinsic amorphous silicon.
A method of producing a display apparatus according to an embodiment of the present invention is a method of producing a display apparatus comprising the thin film transistor of any of the above, wherein the display apparatus has a displaying region including a plurality of pixels, the thin film transistor being disposed in each of the plurality of pixels of the displaying region; the method of producing comprises a semiconductor layer forming step of forming the semiconductor layer of the thin film transistor; and the semiconductor layer forming step comprises a crystallization step of irradiating only a portion of a semiconductor film that is formed on the gate insulating layer and composed of an amorphous silicon with laser light to crystallize the portion of the semiconductor film, wherein the polysilicon region is formed in the portion of the semiconductor film while leaving a portion of the semiconductor film that has not been irradiated with the laser light so as to remain amorphous.
According to an embodiment of the present invention, there is provided a thin film transistor of bottom-gate type that can have high ON characteristics and a method of producing the same.
The inventors have studied various structures in order to improve channel mobility of TFTs, and found that a high channel mobility is obtained in a ITT having an interface at which a polysilicon layer (poly-Si layer) and an intrinsic amorphous silicon layer (i type a-Si layer) forms a junction. As will be described later, it is considered that the poly-Si layer and the i type a-Si layer have formed a heterojunction and that a two-dimensional electron gas (hereinafter “2DEG”) has been generated, as in a high-electron mobility transistor (HEMT).
2DEG refers to, when a junction is formed between two kinds of semiconductors of different band gap energies, a layer of electrons (i.e., a two-dimensional distribution of electrons) that is created at that interface (in a region which is about 10 nm thick near the interface). 2DEG is known to be composed of a compound semiconductor that may be GaAs-based, InP-based, GaN-based, SiGe-based, etc. However, it has not been known that 2DEG can ever occur at a junction interface between a poly-Si layer and any other semiconductor layer (e.g., an i type a-Si layer) having a band gap energy larger than that of poly-Si.
In the present specification, a junction between two semiconductor layers of different band gap energies (e.g., a junction between an i type a-Si layer and a poly-Si layer) is referred to a “semiconductor heterojunction”, and a junction between two semiconductor layers of similar band gap energies (e.g., a junction between an i type a-Si layer and an n+ type a-Si layer) is referred to as a “semiconductor homojunction”.
The poly-Si layer has a band gap energy Eg1 of about 1.1 eV, whereas the i type a-Si layer has a band gap energy Eg2 of about 1.88 eV. A depletion layer is formed at the poly-Si layer side. In
When a positive voltage is applied to the gate electrode (not shown), as illustrated by a broken line in
The region where 2DEG has been generated (hereinafter referred to as a “2DEG region”) can have a higher mobility than that of the poly-Si layer. Therefore, by creating a semiconductor heterojunction in a channel section of the TFT so that a high-mobility 2DEG region emerges, it becomes possible to enhance the channel mobility of the TFT. In the present specification, the mobility of a portion of the active layer of a TFT to become the channel is referred to as the “channel mobility”, as distinguished from the mobility of the material of the active layer itself.
In order for the 2DEG region to contribute to the improvement of the channel mobility of the TFT, the poly-Si layer in the semiconductor heterojunction needs to be located closer to the gate electrode than is the i type a-Si layer. Moreover, in order to generate a quantum well qw at the interface of the semiconductor heterojunction, it is preferable that a polysilicon layer that does not contain any conductivity type-imparting impurity (i.e., non-doped) is used as the poly-Si layer. Note that the Fermi levels of the poly-Si layer and the i type a-Si layer prior to junction may be of any relationship that allows the aforementioned quantum well qw to emerge as a result of the junction; the poly-Si layer may contain an impurity so long as this relationship is satisfied.
In the above description, a junction interface between an i type a-Si layer and a poly-Si layer was taken as an example; however, a similar 2DEG region may also occur at a junction interface between any layer of intrinsic semiconductor other than a-Si (i type semiconductor layer) and a poly-Si layer. The i type semiconductor layer may at least have a Fermi level (pre-junction Fermi level) such that the aforementioned quantum well qw will be created near the junction interface with the poly-Si layer, and may be a layer of wide band gap semiconductor, such as an intrinsic oxide semiconductor (e.g., an In—Ga—Zn—O-based semiconductor).
Next, a capacitance measurement which was conducted by the inventors in order to confirm an occurrence of 2DEG at the interface of a semiconductor heterojunction will be described.
The heterojunction-containing TFT 801 includes: a gate electrode 2 formed on a substrate; a gate insulating layer 3 covering the gate electrode 2; a semiconductor layer (active layer) 4 formed on the gate insulating layer 3; a protective insulating layer (etch stop layer) 5 covering a channel region of the semiconductor layer 4; and a source electrode 8s and a drain electrode 8d. The semiconductor layer 4 is a polysilicon layer (poly-Si layer). Between the semiconductor layer 4 and protective insulating layer 5 and the source electrode 8s, and between the semiconductor layer 4 and protective insulating layer 5 and the drain electrode 8d, an i type a-Si layer 6 composed of an intrinsic amorphous silicon and an n+ type a-Si layer 7 composed of n+ type amorphous silicon are disposed in this order as contact layers. The i type a-Si layer 6 and the semiconductor layer 4 are directly in contact. The junction g1 between the semiconductor layer 4, which is a poly-Si layer, and the i type a-Si layer 6 is a semiconductor heterojunction.
On the other hand, the homojunction-containing TFT 802 is similar in configuration to the heterojunction-containing TFT 801, except that an amorphous silicon layer (a-Si layer) is used as the semiconductor layer 4 and that an n+ type a-Si layer 7 is used as the only contact layer. The junction g2 between the semiconductor layer 4, which is an a-Si layer, and the n+ type a-Si layer 7 is a semiconductor homojunction.
By using a TFT monitor and applying an AC current (10 kHz) between the gate and the source, measurements of a capacitance C between the gate and the source were taken for the heterojunction-containing TFT 801 and the homojunction-containing TFT 802.
From
Hereinafter, with reference to the drawings, embodiments of the present invention will be described specifically.
A thin film transistor (TFT) according to a first embodiment is a polycrystalline silicon TFT. The TFT of the present embodiment is applicable to circuit boards for active matrix substrates or the like, various display apparatuses such as liquid crystal display apparatuses and organic EL display apparatuses, image sensors, electronic appliances, and so on.
The TFT 101 is supported on a substrate 1 such as a glass substrate, and includes: a gate electrode 2; a gate insulating layer 3 covering the gate electrode 2; a semiconductor layer (active layer) 4 disposed on the gate insulating layer 3; and a source electrode 8s and a drain electrode 8d electrically connected to the semiconductor layer 4.
The semiconductor layer 4, which layer functions as an active layer of the TFT 101, includes a polysilicon region (poly-Si region) 4p. As shown in the figure, the semiconductor layer 4 may include a poly-Si region 4p and an amorphous silicon region (a-Si region) 4a that mainly contains an amorphous silicon. Alternatively, the entire semiconductor layer 4 may be the poly-Si region 4p.
The poly-Si region 4p includes: a first region Rs and a second region Rd; and a channel region Rc which is located between them and in which a channel of the TFT 101 is formed. The channel region Rc is disposed so as to overlap the gate electrode 2 via the gate insulating layer 3. The first region Rs is electrically connected to the source electrode 8s, whereas the second region Rd is electrically connected to the drain electrode 8d.
Above the channel region Rc of the semiconductor layer 4, a plurality (e.g., two herein) of protecting sections 20s and 20d (which hereinafter may be collectively referred to as “the protecting sections 20”) are disposed so as to be spaced apart from each other. Each protecting section 20 is disposed so as to cover a portion of the channel region Rc but not to cover the first region Rs and the second region Rd. Each protecting section 20 is spaced apart from at least one of the first region Rs and the second region Rd. Three or more protecting sections 20 may be disposed above the channel region Rc, or, as will be described later, only one protecting section 20 may be provided above a portion of the channel region Rc. Each protecting section 20 may be island-shaped.
Each protecting section 20 has a multilayer structure including an i type a-Si layer 10 composed of an amorphous silicon that contains substantially no impurity (i.e., intrinsic) and a protective insulating layer 5 disposed on the i type a-Si layer 10. The i type a-Si layer 10 is directly in contact with an upper face of the poly-Si region 4p (channel region Rc). The thickness of the i type a-Si layer may be smaller than the thickness of the protective insulating layer 5. The i type a-Si layer 10 and the protective insulating layer 5 may have been patterned by using the same mask. In that case, the side surface of the i type a-Si layer is aligned with the side surface of the protective insulating layer 5.
The semiconductor layer 4, the protecting section 20, the source electrode 8s, and the drain electrode 8d are covered by an inorganic insulating layer (passivation film) 11. The inorganic insulating layer 11 may be directly in contact with a portion of the channel region Rc of the semiconductor layer 4 that is not in contact with the protecting sections 20 (i type a-Si layer 10) (i.e., the portion located between the two protecting sections 20s and 20d in this example).
In the present embodiment, as shown in
On the other hand, the portion of the channel region Rc that is not in contact with the i type a-Si layer 10 is in contact with the inorganic insulating layer 11, for example. No 2DEG is generated in this portion. In the present specification, the region 19 of the semiconductor layer 4 which is not in contact with the intrinsic amorphous silicon and in which no 2DEG is generated (or 2DEG is unlikely to be generated) is referred to a “non-2DEG region”. In this example, when viewed from the normal direction of the substrate 1, the non-2DEG region 19 is located between the two adjacent protecting sections 20. Thus, since the non-2DEG region 19 is formed so as to split the 2DEG regions 9 apart, the 2DEG regions 9 are not formed throughout the way from the first region Rs, via the channel region Rc, to the second region Rd along the channel length direction. In other words, the 2DEG regions 9 are not formed so as to bridge between the first region Rs and the second region Rd. This can prevent electrical conduction from being established between the source electrode 8s and the drain electrode 8d via the 2DEG regions 9.
In the channel region Rc, at least the portion(s) of the poly-Si region 4p that is in contact with the i type a-Si layer 10 is preferably a polysilicon region that is non-doped (i.e., formed without intentional addition of an n type impurity). This allows the 2DEG regions 9 to be formed at the junction interface between the poly-Si region 4p and the i type a-Si layer 10 with greater certainty.
Between the semiconductor layer 4 and the source electrode 8s, a first contact layer Cs may be provided; and between the semiconductor layer 4 and the drain electrode 8d, a second contact layer Cd may be provided. The source electrode 8s is electrically connected to the first region Rs of the semiconductor layer 4 via the first contact layer Cs. The drain electrode 8d is electrically connected to the second region Rd of the semiconductor layer 4 via the second contact layer Cd.
Ends of the first contact layer Cs and/or the second contact layer Cd may be located above the protecting sections 20. In this example, the protecting section (first protecting section) 20s is disposed between the first contact layer Cs and the semiconductor layer 4, whereas the protecting section (second protecting section) 20d is disposed between the second contact layer Cd and the semiconductor layer 4. An end of the first contact layer Cs is located on an upper face of the first protecting section 20s, whereas an end of the second contact layer Cd is located on an upper face of the second protecting section 20d.
The first contact layer Cs and the second contact layer Cd include an impurity-containing silicon layer (which may be an a-Si layer or a poly-Si layer) that contains a conductivity type-imparting impurity. The impurity-containing silicon layers in the first contact layer Cs and the second contact layer Cd are spaced apart from each other. In this example, the impurity-containing silicon layers are type a-Si layers 7 to which an n type-imparting impurity has been added. The n+ type a-Si layer 7 in the first contact layer Cs may be directly in contact with the first region Rs, whereas the n+ type a-Si layer 7 in the second contact layer Cd may be directly in contact with the second region Rd. The first contact layer Cs and the second contact layer Cd may have a single-layer structure, or a multilayer structure.
The first contact layer Cs and the second contact layer Cd may each be a single layer of impurity-containing silicon, or have a multilayer structure including an impurity-containing silicon layer as the lowermost layer. This allows the impurity-containing silicon layers in the first contact layer Cs and the second contact layer Cd (which herein are n+ type a-Si layers 7) to be disposed so as to be in contact with the first region Rs and the second region Rd, respectively, of the semiconductor layer 4. With this configuration, as can be seen from the energy band structure (see
In the TFT 101 of the present embodiment, the 2DEG regions 9 having a higher mobility than that of the poly-Si region 4p is disposed in portions of the channel region Rc. This allows the channel mobility of the TFT 101 to be improved, and enhances the ON current. Moreover, in the channel region Rc, the non-2DEG region 19 is formed in a manner of splitting the 2DEG regions 9 apart, and therefore the 2DEG regions 9 are not formed so as to bridge between the first region Rs and the second region Rd. This restrains the 2DEG regions 9 from causing an increase in the off-leak current, or establishing electrical conduction between the source and the drain, thereby ensuring OFF characteristics. Thus, according to the present embodiment, it becomes possible to enhance the ON characteristics while maintaining the OFF characteristics; as a result, the ON/OFF ratio can be improved.
Furthermore, in the present embodiment, the channel mobility of the TFT 101 can be controlled by utilizing the 2DEG regions 9, so that variations in the characteristics associated with variation in the crystal grain sizes of the poly-Si region 4p can be suppressed. As a result, reliability of the TFT 101 can be improved.
The channel region Rc includes portions which are in contact with the i type a-Si layer 10 (portions in which the 2DEG regions 9 is formed) and a portion which is in contact with the inorganic insulating layer 11 (a portion to become the non-2DEG region 19). When viewed from the normal direction of the substrate 1, a ratio AR of the total area of portions of the channel region Rc that are in contact with the i type a-Si layer 10 to the area of the entire channel region Rc may be not less than 20% and not more than 90%, for example. When it is not less than 20%, channel mobility can be enhanced more effectively. The ratio AR may be not less than 50%. When the ratio AR is not more than 90%, increase in the off-leak current can be suppressed with greater certainty.
The structure of the protecting sections 20 is not limited to the examples shown in
The protecting sections 20 may not be island-shaped. In that case, as illustrated in
Moreover, the example shown in
In this example, an i type a-Si layer 10 having an islanded structure is disposed between the semiconductor layer 4 and the protective insulating layer 5. In other words, one or more i type a-Si islets is/are formed between the protective insulating layer 5 and the semiconductor layer 4. As shown in the figure, a plurality of i type a-Si islets of mutually different sizes may be randomly disposed. For example, an initial phase of growth by the CVD technique may be utilized to form an intrinsic amorphous silicon film, whereby the i type a-Si layer 10 having an islanded structure as shown in the figure can be obtained. In this case, the aforementioned area ratio AR can be adjusted by controlling conditions such as growth time.
Furthermore, the number and arrangement of protecting sections 20 are not limited to the example shown in
As shown in
Although not shown, two or more middle protecting sections 20c may be disposed so as to be spaced apart from one another, between the first protecting section 20s and the second protecting section 20d.
As shown in
Note that, instead of a middle protecting section 20c, only the first protecting section 20s or the second protecting section 20d alone (
The TFT 101 of the present embodiment can be suitably used for an active matrix substrate of a display apparatus or the like, for example. An active matrix substrate (or a display apparatus) has a plurality of source bus lines extending along the column direction, a plurality of gate bus lines extending along the row direction, a displaying region that includes a plurality of pixels and a non-displaying region (also referred to as a peripheral region) other than the displaying region. For each pixel, a pixel TFT is provided as a switching element. In the peripheral region, gate drivers or other driving circuits may be monolithically formed. The driving circuits include a plurality of TFTs (“referred to as circuit TFTs”). The TFT 101 may be used as each pixel TFT and/or each circuit TFT.
In the pixel, a TFT 101 functioning as a pixel TFT and a pixel electrode 13 are disposed. The source electrode 8s of the TFT 101 is electrically connected to one corresponding source bus line SL, whereas the drain electrode 8d is electrically connected to the pixel electrode 13. Moreover, the gate electrode 2 is electrically connected to one corresponding gate bus line GL. The gate electrode 2 may be a portion of the gate bus line GL.
Although
The aforementioned active matrix substrate is suitably used for a liquid crystal display apparatus. For example, a counter substrate having a counter electrode and a color filter layer may be provided; the active matrix substrate and the counter substrate may be attached together via a sealant; and liquid crystal may be injected between these substrates, a liquid crystal display apparatus is obtained.
Without being limited to a liquid crystal display apparatus, any material of which optical property can be modulated or which can emit light upon voltage application may be used as a display medium layer, whereby various display apparatuses can be obtained. For example, the active matrix substrate according to the present embodiment can be suitably used for display apparatuses such as an organic EL display apparatus or an inorganic EL display apparatus in which an organic or inorganic phosphor material is used as a display medium layer. Furthermore, it can also be suitably used as an active matrix substrate for use in an X-ray sensor, a memory device, or the like.
<Method of Producing TFT 101>
Next, an example of a method of producing the TFT 101 will be described.
First, as shown in
As the substrate 1, a substrate having a dielectric surface, e.g., a glass substrate, a silicon substrate, or a plastic substrate (resin substrate) having heat resistance, can be used.
The gate electrode 2 is formed by forming an electrically conductive film for the gate on the substrate 1, and patterning it. Herein, for example, an electrically conductive film for the gate (thickness: e.g. about 500 nm) is formed on the substrate 1 by sputtering, and the metal film is patterned by using a known photolithography process. For the etching of the gate electrically conductive film, wet etching may be used, for example.
The material of the gate electrode 2 may be: an elemental metal such as molybdenum (Mo), tungsten (W), copper (Cu), chromium (Cr), tantalum (Ta), aluminum (Al), or titanium (Ti); a material composed of these with nitrogen, oxygen, or other metals contained therein; or a transparent electrically conductive material such as indium tin oxide (ITO).
The gate insulating layer 3 is formed on the substrate 1 having the gate electrode 2 formed thereon, by a plasma CVD technique, for example. As the gate insulating layer (thickness: e.g. about 0.4 μm) 3, for example, a silicon oxide (SiO2) layer, a silicon nitride (SiNx) layer, or a multilayer film of an SiO2 layer(s) and an SiNx layer(s) may be formed.
The a-Si film 40 for the active layer may be formed by a CVD technique by using a hydrogen gas (H2) and a silane gas (SiH4), for example. The a-Si film 40 for the active layer may be a non-doped amorphous silicon film that substantially does not contain any n type impurity. A non-doped amorphous silicon film is an a-Si film which is formed without intentional addition of an n type impurity (e.g. by using a material gas that does not contain any n type impurity). Note that the a-Si film 40 for the active layer may contain an n type impurity at a relatively low concentration. The thickness of the a-Si film 40 for the active layer may be not less than 20 nm and not more than 70 nm (e.g. 50 nm).
Next, as shown in
There is no particular limitation as to the crystallization method using laser light 30. For example, laser light 30 from a laser light source may be passed through a microlens array so that the laser light 30 is converged onto only a portion of the a-Si film 40 for the active layer, thereby partly crystallizing the a-Si film 40 for the active layer. In the present specification, this crystallization method is referred to as “local laser annealing”. By using local laser annealing, as compared to the conventional laser annealing where the entire surface a-Si film is scanned with linear laser light, the time required for crystallization can be greatly reduced, whereby mass producibility can be promoted.
The microlens array includes a two-dimensional or linear arrangement of microlenses. When a plurality of TFTs are formed on the substrate 1, the laser light 30 is converged by the microlens array so as to be incident, within the a-Si film 40 for the active layer, only on a plurality of predetermined regions (irradiation regions) which are spaced apart from one another. Each irradiation region is disposed correspondingly to the portion of a TFT to become the channel region. The positions, number, shapes, sizes, etc., of irradiation regions can be controlled by the size and the array pitch of the microlens array (which is not limited to lenses under 1 mm), the opening positions in a mask that is disposed on the light source side of the microlens array, and the like. As a result, each region of the a-Si film 40 for the active layer that has been irradiated with the laser light 30 is heated to melt and solidify, thus becoming the poly-Si region 4p. Any region that has not been irradiated with the laser light remains as the a-Si region 4a. When viewed from the normal direction of the substrate 1, the a-Si region 4a may be disposed outside the poly-Si region 4p, for example.
As to the more specific method of local laser annealing, the configuration (including the microlens array, mask structure) of the apparatus used for local laser annealing, the entire disclosure of International Publication No. 2011/055618, International Publication No. 2011/132559, International Publication No. 2016/157351, and International Publication No. 2016/170571 is incorporated herein by reference.
Next, as shown in
The a-Si film for 2DEG generation 100 can be formed by utilizing an initial phase of growth by the CVD technique. This allows a thin a-Si film for 2DEG generation 100 to be easily formed as desired. Although not particularly limited, the deposition time for the a-Si film for 2DEG generation 100 by the CVD technique may be not less than 2 seconds and not more than 150 seconds, for example.
Moreover, by controlling film formation conditions such as deposition time, an a-Si film for 2DEG generation (thickness: e.g. not less than 2 nm and not more than 5 nm) 100 having an islanded structure may be formed, for example. Herein, although not particularly limited, the deposition time may be not less than 0.2 seconds and not more than 1.0 seconds, for example. When it is not more than 1.0 seconds, the a-Si film for 2DEG generation 100 can be deposited in an island shape(s) with greater certainty. When it is not less than 0.2 seconds, the 2DEG regions 9 can be formed between the a-Si film for 2DEG generation 100 and the poly-Si region 4p with greater certainty. In the case of utilizing an initial phase of growth by the CVD technique to form the a-Si film for 2DEG generation 100 having an islanded structure, the size and the position at which each islet is formed, the number of them within one channel region Rc, etc. will be random. Therefore, the 2DEG regions 9 will also be formed in a random manner (see
Note that the method of forming the a-Si film for 2DEG generation 100 is not limited to the CVD technique, but other known methods may also be used.
Next, as shown in
Then, as shown in
In this example, above the channel region Rc, the first protecting section 20s and the second protecting section 20d are disposed so as to be spaced apart from each other. When viewed from the normal direction of the substrate 1, the portions of the poly-Si region 4p that are located between the protecting sections 20s and 20d are exposed.
Next, as shown in
Alternatively, as the Si film for the contact layers, by the plasma CVD technique, a multilayer film including an i type a-Si film (thickness: e.g. about 0.1 μm) and an n+ type a-Si film (thickness: e.g. about 0.05 μm) that contains an n type impurity (e.g. phosphorus) may be formed. As the material gases for the i type a-Si film, a hydrogen gas and a silane gas are used. As the material gas for the n+ type a-Si film, a gaseous mixture of silane, hydrogen, and phosphine (PH3) is used.
Next, on the Si film for the contact layers (which herein is an n+ type a-Si film 70), an electrically conductive film for the source and the drain electrode (thickness: e.g. about 0.3 μm) and a resist mask M are formed. The electrically conductive film for the source and the drain electrode is formed with a material similar to that for the electrically conductive film for the gate, by a method similar to that used for the electrically conductive film for the gate.
Thereafter, by using the resist mask M, the electrically conductive film for the source and the drain electrode and the n+ type a-Si film 70 are patterned by dry etching, for example. As a result, as shown in
In order to deactivate dangling bonds in the poly-Si region 4p and reduce the defect density, the poly-Si region 4p may be subjected to a hydrogen plasma treatment after the source-drain separation step.
In the case where the TFT 101 is used as a pixel TST of an active matrix substrate, as shown in
As the inorganic insulating layer 11, a silicon oxide layer, a silicon nitride layer, or the like may be used. Herein, as the inorganic insulating layer 11, an SiNx layer (thickness: e.g. about 200 nm) is formed by the CVD technique, for example. The inorganic insulating layer 11 is in contact with the protective insulating layer 5 in (a gap) between the source electrode 8s and the drain electrode 8d.
The organic insulating layer 12 may be an organic insulating film (thickness: e.g. 1 to 3 μm) containing a photosensitive resin material, for example. Thereafter, the organic insulating layer 12 is patterned, and an aperture is formed therein. Next, by using the organic insulating layer 12 as a mask, the inorganic insulating layer 11 is etched (dry etching). As a result, a contact hole CH that reaches the drain electrode 8d is formed in the inorganic insulating layer 11 and the organic insulating layer 12.
Next, a transparent electrically conductive film is formed on the organic insulating layer 12 and in the contact hole CH. As the material for the transparent electrode film, a metal oxide such as indium-tin oxide (ITO), indium-zinc oxide, or MO can be used. Herein, by e.g. sputtering, an indium-zinc oxide film (thickness: e.g. about 100 nm) is formed as the transparent electrically conductive film.
Thereafter, the transparent electrically conductive film is patterned by e.g. wet etching, thereby providing a pixel electrode 13. The pixel electrode 13 is to be disposed so as to be each spaced apart, from pixel to pixel. Each pixel electrode 13 is in contact with the drain electrode 8d of the corresponding TFT within the contact hole. Although not illustrated, the source electrode 8s of the TFT 101 is electrically connected to a source bus line (not shown), while the gate electrode 2 is electrically connected to a gate bus line (not shown).
The semiconductor layer 4, the first contact layer Cs, and the second contact layer Cd may be patterned into island shapes in the region where the TFT 101 is formed (TFT formation region). Alternatively, the semiconductor layer 4, the first contact layer Cs, and the second contact layer Cd may extend to regions other than the region where the TFT 101 is formed (TFT formation region). For example, the semiconductor layer 4 may extend so as to overlap a source bus line that is connected to the source electrode 8s. It suffices if the portion of the semiconductor layer 4 that is located in the TFT formation region contains the poly-Si region 4p; the portion extending to regions other than the TST formation region may be the a-Si region 4a.
Moreover, the crystallization method of the a-Si film 40 for the active layer is not limited to the aforementioned local laser annealing. A part or a whole of the a-Si film 40 for the active layer may be crystallized by using other known methods.
Furthermore, instead of the i type a-Si layer 10, a semiconductor layer (i type semiconductor layer) that is composed of any other intrinsic semiconductor (which may be amorphous or crystalline) may be used. The i type semiconductor layer has a greater band gap than that of the poly-Si region 4p, and forms a semiconductor heterojunction with the poly-Si region 4p. As the i type semiconductor layer, for example, a semiconductor layer composed of a wide band gap semiconductor such as an intrinsic oxide semiconductor (e.g. an In—Ga—Zn—O-based semiconductor) can be used. The i type semiconductor layer has a Fermi level (pre-junction Fermi level) such that the aforementioned quantum well qw is formed near the junction interface with the poly-Si region 4p. The i type semiconductor layer may be formed through a process similar to that for the i type a-Si layer 10, for example. The i type semiconductor layer may include a plurality of i type semiconductor islets that are disposed in a discrete manner (see
In the case where an i type oxide semiconductor layer composed of an intrinsic oxide semiconductor is used as the i type semiconductor layer, the oxide semiconductor may be amorphous or crystalline. The crystalline oxide semiconductor may be a polycrystalline oxide semiconductor, a microcrystalline oxide semiconductor, a crystalline oxide semiconductor whose c axis is oriented essentially perpendicular to the layer plane, for example. The material, structure, method of film formation, etc., of an amorphous or crystalline oxide semiconductor are described in the specification of Japanese Patent No. 6275294, for example. The entire disclosure of the specification of Japanese Patent No. 6275294 is incorporated herein by reference.
(Embodiment for Reference)
Hereinafter, a TFT according to Embodiment for Reference and experimental results indicating that TFT characteristics can be improved by utilizing the 2DEG regions will be described.
The TFT according to Embodiment for Reference is a polycrystalline silicon TFT of channel-etch (CE) type.
In the TFT 102, between a semiconductor layer 4 and a source electrode 8s and a drain electrode 8d, no protecting section that includes an etch stop layer covering the channel region Rc (as in the protecting section 20 shown in
In the TFT 102, too, as shown in
Between the source electrode 8s and the drain electrode 8d, an inorganic insulating layer 11 is directly in contact with the i type a-Si islet(s) 6a and the portion of the semiconductor layer 4 that is not covered by the i type a-Si islet(s) 6a. Otherwise, its structure may be similar to that of the TFT 101 shown in
In this example, the first contact layer Cs and the second contact layer Cd may have a multilayer structure including an i type a-Si layer 6 directly in contact with the semiconductor layer 4 and an n+ type a-Si layer disposed on the i type a-Si layer 6, for example. In this manner, an i type a-Si islet(s) 6a can be formed by using the same silicon film as that for the i type a-Si layer 6. For example, in the source-drain separation step, etching may be performed under conditions such that the i type a-Si layer 6 will remain locally above the channel region Rc, thereby forming the i type a-Si islet(s) 6a. In this case, the i type a-Si islet(s) 6a will be thinner than the i type a-Si layers 6 of the first contact layer Cs and the second contact layer Cd. As shown in the figure, a plurality of i type a-Si islets 6a of different sizes may be randomly disposed on the channel region Rc.
First, as shown in
Next, as shown in
Next, as shown in
Note that the aforementioned patterning may be conducted under conditions such that only the surface portion of the portion of the i type a-Si film 60 that is not covered by the resist mask is removed (i.e., thin-filmed). In this case, the thin-filmed i type a-Si film 60 may separately be patterned into island shapes to form the i type a-Si islet(s) 6a. Forming the i type a-Si islet(s) 6a through patterning allows the i type a-Si islet(s) 6a to be formed into a predetermined pattern. For example, the i type a-Si islets 6a may be disposed as shown in
Alternatively, after the source-drain separation step is performed, another i type a-Si film may be formed so as to cover the channel region and patterned to form the i type a-Si islet(s) 6a. In this case, it is not necessary to use the i type a-Si film 60 as an Si film for the contact layers. As a result, no 2DEG is generated between the contact layers Cs and Cd and the semiconductor layer 4, whereby a GIDL can be suppressed.
<Experimental Results>
In order to confirm that it is possible to improve TFT characteristics by utilizing 2DEG, thin film transistors according to Reference Example and Comparative Examples were produced, and their TFT characteristics were measured; the methods and results thereof will now be described.
First, by the method described above with reference to
Next, by a similar method to that of Reference Example except for the etching condition (e.g. etching time) in the source-drain separation step, thin film transistors according to Comparative Examples 1 and 2 were produced. In Comparative Example 1, etching was performed under conditions such that, between the source electrode 8s and the drain electrode 8d, only the surface portion of the i type a-Si layer 6 was removed, and that the i type a-Si layer 6 remained so as to cover substantially the entire channel region Rc, thereby providing thin film transistors s3 and s4. In Comparative Example 2, etching was performed under conditions such that, between the source electrode 8s and the drain electrode 8d, the i type a-Si layer 6 was completely removed, and that the surface portion of the semiconductor layer 4 was overetched, thereby providing a thin film transistor s5.
Furthermore, in Comparative Example 3, a source-drain separation step was performed while the channel region Rc was covered with the protective insulating layer (SiO2 layer) 5, thereby providing a thin film transistor s6 of ES-type. The protective insulating layer 5 and the channel region Rc are directly in contact, and no a-Si islets are provided between them.
Next, TFT characteristics of the thin film transistors s1 to s6 according to Reference Example and Comparative Examples 1 to 3 were evaluated.
It can be seen from
It can also be seen that the ON current the thin film transistor s5 according to Comparative Example 2 is lower than those of the thin film transistors s1 and s2 according to Reference Example. This is presumably because the i type a-Si layer 6 does not remain above the channel region and thus no 2DEG occurs, so that high-mobility effects due to 2DEG cannot be obtained.
Note that the ON current of the thin film transistor s5 according to Comparative Example 2 is lower than that of the thin film transistor s6 according to Comparative Example 3. The presumable reason for this is that, in the thin film transistor s5, the surface portion of the semiconductor layer 4 is overetched so that the polycrystalline silicon layer is considerably removed, most of which becoming a layer of small crystal grain sizes or an amorphous layer, or the channel section has become damaged or the semiconductor layer 4 has become varied in thickness, thus resulting in a lower ON current than that of the thin film transistor s6, in which the semiconductor layer 4 is protected at the surface.
On the other hand, the thin film transistors s1 and s2 according to Reference Example attain higher ON currents than those of the thin film transistor s5 according to Comparative Example 2 and the thin film transistor s6 according to Comparative Example 3. This is presumably because, in the thin film transistors s1 and s2 according to Reference Example, the high-mobility 2DEG region(s) 9 is formed at the junction portion between the channel region Rc and the i type a-Si islet(s) 6a, thus resulting in a higher channel mobility of the TFT. Moreover, the portions of the channel region Rc that are not in contact with the i type a-Si islet 6a constitute a non-2DEG region in which 2DEG is not generated. This is presumably because a non-2DEG region exists in a portion of the channel region Rc to prevent the 2DEG region(s) 9 from being formed throughout the way from the first region Rs to the second region Rd along the channel length direction (i.e., so as to bridge between the source and the drain), thereby suppressing a punch-through.
Thus, the results shown in
Although CE-type TFTs were taken as examples of the thin film transistor according to Reference Example, an ES-type TFT according to the embodiment shown in
The structure of a TFT according to the present invention is not limited to the structure described above with reference to
Embodiments of the present invention are broadly applicable to apparatuses and electronic appliances that include TFTs, for example: circuit boards of active matrix substrates or the like; display apparatuses such as liquid crystal display apparatuses, organic electroluminescence (EL) display apparatus, and inorganic electroluminescence display apparatuses; imaging devices such as radiation detectors and image sensors; electronic devices such as image input devices and fingerprint reader devices, and the like.
1: substrate, 2: gate electrode, 3: gate insulating layer, 4: semiconductor layer, 4a: a-Si region, 4p: poly-Si region, 5: protective insulating layer, 7: n+ type a-Si layer, 8d: drain electrode, 8s: source electrode, 9: 2DEG region, 10: i type a-Si layer, 11: inorganic insulating layer, 12: organic insulating layer, 13: pixel electrode, 20, 20s, 20d, 20c: protecting section, 30: laser light, 40: a-Si film for the active layer, 50: insulating film, 80: electrically conductive film, Cs: first contact layer, Cd: second contact layer, M: resist mask, Rc: channel region, Rd: second region, Rs: first region
Filing Document | Filing Date | Country | Kind |
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PCT/JP2018/021922 | 6/7/2018 | WO | 00 |