Semiconductor devices such as thin-film transistors (TFTs) are used in a variety of electronic devices. In part, the performance (e.g., speed) of such electronic devices is a function of the performance and electrical characteristics of such transistors.
For a detailed description of exemplary embodiments of the invention, reference will now be made to the accompanying drawings in which:
Certain terms are used throughout the following description and claims to refer to particular system components. As one skilled in the art will appreciate, technology companies may refer to a component by different names. This document does not intend to distinguish between components that differ in name but not function. In the following discussion and in the claims, the terms “including” and “comprising” are used in an open-ended fashion, and thus should be interpreted to mean “including, but not limited to . . . .” Also, the term “couple” or “couples” is intended to mean either an indirect, direct, optical or wireless electrical connection. Thus, if a first device couples to a second device, that connection may be through a direct electrical connection, through an indirect electrical connection via other devices and connections, through an optical electrical connection, or through a wireless electrical connection.
The following discussion is directed to various embodiments of the invention. Although one or more of these embodiments may be preferred, the embodiments disclosed should not be interpreted, or otherwise used, as limiting the scope of the disclosure, including the claims. In addition, one skilled in the art will understand that the following description has broad application, and the discussion of any embodiment is meant only to be exemplary of that embodiment, and not intended to intimate that the scope of the disclosure, including the claims, is limited to that embodiment.
As described herein, embodiments of the disclosure are directed to semiconductor devices having an extended oxide channel and to related manufacturing methods. As used herein, an “extended channel” refers to a channel that extends beyond a gate electrode (i.e., the drain electrode is laterally offset from the gate electrode). Thus, the extended oxide channel has a first portion that is gated and a second portion that is ungated. In accordance with at least some embodiments, the second (ungated) portion extends about 2 μm or more beyond the gate electrode. In other words, the drain electrode is laterally offset from the gate electrode by a length (e.g., at least about 2 μm), which is greater than common misalignments in the manufacturing process. The extended oxide channel may comprise zinc oxide (ZnO), tin oxide (SnO2), indium oxide (In2O3), gallium oxide (Ga2O3), or combinations thereof such as zinc indium oxide (ZIO), zinc tin oxide (ZTO), indium gallium oxide (IGO), and indium gallium zinc oxide (IGZO).
The disclosed devices and methods were developed as a high-voltage thin-film transistor (HVTFT) technology, including HVTFTs that are at least partially transparent. However, embodiments are not necessarily limited to HVTFTs or transparent applications. Desirable features of the disclosed extended oxide channel technology include high-mobility performance (e.g., approximately 10 cm2/Vs) and low-temperature processing (e.g., less than around 175° Celsius). Disclosed HVTFT embodiments are able to control high voltages (hundreds of volts) at the drain electrode using low voltages (tens of volts) applied at the gate electrode (with the voltage reference being the source electrode) and will enable improved performance and capabilities for semiconductor devices that employ HVTFTs. For example, a desired HVTFT may operate with at least 100 volts applied to the drain material and less than 20 volts applied to the gate material. Examples of semiconductor devices that employ HVTFTs include, for example, micro-electro-mechanical systems (MEMS), active matrix displays, logic circuitry, and amplifiers. Additionally, low-temperature processing as disclosed herein enables the manufacture of HVTFTs on flexible surfaces.
Unless otherwise indicated, all numbers expressing quantities of ingredients, reaction conditions, and so forth used in the specification and claims are to be understood as being modified in all instances by the term “about.” Accordingly, unless indicated to the contrary, the numerical parameters set forth in the following specification and attached claims are approximations that may vary depending upon the desired properties sought to be obtained by the present disclosure. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques.
In various embodiments, such as in the double-gate embodiments shown in
In each of
A more detailed description of an embodiment of a HVTFT is illustrated in
Moreover, in the various embodiments, the HVTFT 200 can be included in a number of devices including MEMS devices, active matrix display screen devices, logic circuitry, and amplifiers. In various embodiments, HVTFT 200 may be part of a transparent and/or flexible device.
As shown in
In the embodiment of
The gate dielectric 206 shown in
The various layers of the transistor structures described herein can be formed using a variety of techniques. For example, the gate dielectric 206 may be deposited by sputter deposition from a sintered HfO2 ceramic target. Examples of thin-film deposition techniques include, but are not limited to, evaporation (e.g., thermal, e-beam), sputter deposition (e.g., dc reactive sputtering, rf magnetron sputtering, ion beam sputtering), chemical vapor deposition (CVD) including plasma-enhanced CVD (PECVD), atomic layer deposition (ALD), pulsed laser deposition (PLD) and molecular beam epitaxy (MBE). Additionally, alternate methods may also be employed for depositing the various transistor layers of the embodiments of the present disclosure. Such alternate methods can include anodization (electrochemical oxidation) of a metal film, as well as deposition from a liquid precursor such as by spin coating, spray coating, slot coating, or ink-jet printing including thermal and piezoelectric drop-on-demand printing. Film patterning may employ photolithography combined with etching or lift-off processes, or may use alternate techniques such as shadow masking. Chemical and/or electronic doping of one or more of the layers (e.g., the extended oxide channel 208 illustrated in
In the various embodiments, the source electrode 210 and the drain electrode 212 are separately positioned adjacent the gate dielectric 206, and in direct contact with the extended channel layer 208. Although not required, the source and drain electrodes 210, 212 may be formed from the same materials as those discussed with regard to the gate electrode 204. In
In accordance with various embodiments, the extended oxide channel 208 comprises zinc oxide (ZnO), tin oxide (SnO2), indium oxide (In2O3), gallium oxide (Ga2O3), or combinations thereof, including zinc indium oxide (ZIO), zinc tin oxide (ZTO), indium gallium oxide (IGO), and indium gallium zinc oxide (IGZO). The materials used for the extended oxide channel 208 may correspond to amorphous films, although crystalline or mixed-phase structures are possible as well. For example, a zinc tin oxide composition may comprise an amorphous film characterized by particular composition (e.g., a particular zinc to tin ratio) but without a well-defined structural order associated with a particular crystalline phase or structure. Alternately, a zinc tin oxide composition may comprise a single-phase crystalline (including poly-crystalline) structure such as Zn2SnO4; a mixed-phase crystalline (including poly-crystalline) structure of segregated ZnO and SnO2 regions; or a mixed-phase structure of segregated crystalline regions (such as ZnO, SnO2, or Zn2SnO4) and amorphous regions (characterized by composition but not by a crystalline phase or structure).
In at least some embodiments, the source, drain, and gate electrodes may include a substantially transparent material. By using substantially transparent materials for the source, drain, and gate electrodes, areas of the thin-film transistor can be transparent to the portion of the electromagnetic spectrum that is visible to the human eye. In the transistor arts, a person of ordinary skill will appreciate that devices such as active matrix liquid crystal displays having display elements (pixels) coupled to TFTs having substantially transparent materials for selecting or addressing the pixel to be on or off may benefit display performance by allowing more light to be transmitted through the display.
In the embodiment of
The use of the extended oxide channel 208 illustrated in the embodiments of the present disclosure is beneficial for a wide variety of thin-film applications in integrated circuit structures. For example, such applications include transistors, as discussed herein, such as thin-film transistors, top-gate, bottom-gate, coplanar electrode, staggered electrode, single-gate, and double-gate, to name only a few. In the various embodiments, transistors (e.g., TFTs) of the present disclosure can be provided as switches or amplifiers, where applied voltages to the gate electrodes of the transistors can affect a flow of electrons through the extended oxide channel 208. As one of ordinary skill will appreciate, when the transistor is used as a switch, the transistor can operate in the saturation region, and where the transistor is used as an amplifier, the transistor can operate in the linear region. In addition, transistors incorporating the extended oxide channel 208 may be incorporated into integrated circuits and structures such as visual display panels (e.g., active matrix LCD displays) as is shown and described in connection with
Embodiments of the present disclosure also include methods of forming metallic films on a surface of a substrate or substrate assembly, such as a glass substrate, with or without layers or structures formed thereon, to form integrated circuits, and in particular HVTFTs as described herein. It is to be understood that methods of the present disclosure are not limited to deposition on glass substrates. For example, other substrate types such as flexible substrates including organics (“plastics”), metal foils, or combinations thereof may be used as well. Furthermore, the methods disclosed herein may be applied to non-wafer substrates such as fibers or wires. In general, the films can be formed directly on the lowest surface of the substrate, or they can be formed on any of a variety of the layers (surfaces) as in a patterned wafer, for example.
In block 320, an extended oxide channel contacting the drain electrode and the source electrode is deposited. For example, the extended oxide channel can be deposited between the drain electrode and the source electrode so as to electrically couple the two electrodes. At block 330, a gate electrode and a gate dielectric are provided, with the gate dielectric positioned between the gate electrode and the extended oxide channel. In accordance with embodiments, only part of the extended oxide channel is gated and the drain electrode is laterally offset from the gate electrode.
In accordance with at least some embodiments, depositing the extended oxide channel layer (as in block 320) may include providing a precursor composition including one or more precursor compounds. Various combinations of the precursor compounds described herein can be used in the precursor composition. Thus, as used herein, a “precursor composition” refers to a solid or liquid that includes one or more precursor compounds of the formulas described herein optionally mixed with one or more compounds of formulas other than those described herein. As used herein, “liquid” refers to a solution or a neat liquid (a liquid at room temperature or a solid at room temperature that melts at an elevated temperature). As used herein, a “solution” does not call for complete solubility of the solid; rather, the solution may have some undissolved material. More desirably, however, there is a sufficient amount of the material that can be carried by the organic solvent into the vapor phase for chemical vapor deposition processing. The precursor compounds can also include one or more organic solvents suitable for use in a chemical vapor deposition system, as well as other additives, such as free ligands, that assist in the vaporization of the desired compounds.
Although not required, the extended oxide channel layer may have a uniform composition of zinc oxide (ZnO), tin oxide (SnO2), indium oxide (In2O3), gallium oxide (Ga2O3), or combinations thereof, throughout its thickness. Alternatively, the concentrations of materials in the extended oxide channel may vary as the layer is formed. As will be appreciated, the thickness of the extended oxide channel layer will be dependent upon the application for which it is used. For example, the thickness for the extended oxide channel layer may have a range of about 5 nanometer to about 300 nanometers.
The embodiments described herein may be used for fabricating chips, integrated circuits, monolithic devices, semiconductor devices, MEMS, and microelectronic devices such as display devices. For example,
As another example,
As another example,
Although specific exemplary embodiments have been illustrated and described herein, those of ordinary skill in the art will appreciate that an arrangement calculated to achieve the same techniques can be substituted for the specific exemplary embodiments shown. This disclosure is intended to cover adaptations or variations of the embodiments of the invention. It is to be understood that the above description has been made in an illustrative fashion, and not a restrictive one.
In the foregoing Detailed Description, various features are grouped together in a single exemplary embodiment for the purpose of streamlining the disclosure. This method of disclosure is not to be interpreted as reflecting an intention that the embodiments of the invention necessitate more features than are expressly recited in each claim. Rather, as the following claims reflect, inventive subject matter lies in less than all features of a single disclosed exemplary embodiment. Thus, the following claims are hereby incorporated into the Detailed Description, with each claim standing on its own as a separate embodiment.