This application is the U.S. National Stage of International Application No. PCT/EP2010/005563, filed Sep. 10, 2010, which claims the benefit of German Patent Application DE 10 2009 041 583.1, filed Sep. 15, 2009, both of which are hereby incorporated by reference to the extent not inconsistent with the disclosure herewith.
The present invention relates to a thin-film element having an interference layer structure for security papers, value documents and the like, having at least two semitransparent, i.e. partially transparent absorber layers and at least one dielectric spacing layer arranged between the at least two absorber layers. The present invention further relates to a see-through security element and a data carrier having such a thin-film element, as well as, for a printing ink, optically variable color pigments that are formed by such thin-film elements.
For protection, data carriers, such as value or identification documents, or other valuable articles, such as branded articles, are often provided with security elements that permit the authenticity of the data carriers to be verified, and that simultaneously serve as protection against unauthorized reproduction. For several years now, see-through windows have proven to be attractive security elements in polymer and, most recently, also in paper banknotes, since they permit the use of a number of security features.
Security elements having viewing-angle-dependent effects play a special role in safeguarding authenticity, as these cannot be reproduced even with the most modern copiers. Here, the security elements are furnished with optically variable elements that, from different viewing angles, convey to the viewer a different image impression and, depending on the viewing angle, display for example another color or brightness impression and/or another graphic motif.
In this connection, it is known to use security elements having multilayer thin-film elements whose color impression for the viewer changes with the viewing angle, and when the thin-film element is tilted, shifts for example from green to blue, from blue to magenta or from magenta to green. The occurrence of such color changes when a thin-film element is tilted is referred to in the following as a color-shift effect.
Proceeding from this, the object of the present invention is to specify a thin-film element of the kind cited above having an attractive visual appearance having high counterfeit security.
This object is solved by the thin-film element, the see-through security element, the optically variable color pigments and the data carrier having the features of the independent claims. Developments of the present invention are the subject of the dependent claims.
According to the present invention, in a generic thin-film element, the two absorber layers are each formed from a material having a complex refractive index N=n+ik whose real part n and imaginary part k differ at least in a portion of the visible spectral range by a factor of 5 or more.
Here, the two absorber layers can be formed from the same material or also from different materials. The use of different materials can be advantageous especially from production technology perspectives, for example to ensure a good layer adhesion also of the top absorber layer. In a preferred embodiment, the two absorber layers are thus formed from different materials, the real part n1 and imaginary part k1 of the material of one of the two absorber layers differing at least in a portion of the visible spectral range by a factor of 5 or more, and the real part n2 and imaginary part k2 of the material of the other of the two absorber layers by a factor of 8 or more, preferably by a factor of 10 or more, particularly preferably by a factor of 15 or more.
In advantageous embodiments, the real part n and imaginary part k of the materials of both absorber layers differ at least in a portion of the visible spectral range by even a factor of 8 or more, preferably by a factor of 10 or more, particularly preferably by a factor of 15 or more. Preferably, the real part n and imaginary part k of the material of at least one of the two absorber layers differ even in the entire visible spectral range by a factor of 5 or more, by a factor of 8 or more, by a factor of 10 or more or by a factor of 15 or more.
At least one of the absorber layers, preferably both absorber layers, are advantageously formed from silver. Also embodiments in which one of the absorber layers or both absorber layers are formed from aluminum have proven reliable. The most colorful colors in transmission are currently achieved with silver/dielectric/silver layer systems. Somewhat less colorful, but easier to manufacture, are thin-film elements having an aluminum/dielectric/aluminum layer system. Likewise easy to manufacture are silver/dielectric/aluminum layer systems whose colorfulness lies between the two above-mentioned layer systems and that, for a top-lying aluminum layer, likewise permit manufacture without the occurrence of layer adhesion problems.
The layer thicknesses of the two absorber layers and the dielectric layer are preferably coordinated with each other in such a way that the thin-film element exhibits a sufficient transmission corresponding to a brightness L*, specified in the CIELAB color space, of between 10% and 70%, preferably between 20% and 50%. When silver is used as the absorber material, the layer thickness of the silver layers is advantageously between 20 nm and 30 nm.
In an advantageous variant of the present invention, the interference layer structure of the thin-film element is a symmetrical three-layer structure having a first absorber layer, a dielectric spacing layer and a second absorber layer that consists of the same material as the first absorber layer and exhibits the same layer thickness as the first absorber layer. Here, the interference layer structure can especially be a silver/dielectric/silver layer system or an aluminum/dielectric/aluminum layer system.
In an alternative, likewise advantageous variant of the present invention, the interference layer structure is an asymmetrical three-layer structure having a first absorber layer composed of a first material, a dielectric spacing layer and a second absorber layer composed of a second, different material. In this case, the interference layer structure is especially a silver/dielectric/aluminum layer system.
The dielectric spacing layer is advantageously formed from SiOx or MgF2. The layer thickness of the dielectric spacing layer is typically between 90 nm and 400 nm. Since the layer thickness of the dielectric spacing layer substantially determines the color impression of the thin-film element, as explained in greater detail below, it is chosen according to the desired color impression and the desired intensity of the color-shift effect.
In an advantageous embodiment, the thin-film element appears shiny metallic and substantially color neutral when viewed in reflected light, and appears colored in transmitted light. Here, in transmitted light, the thin-film element advantageously exhibits, specified in the CIELAB color space, a chroma C*ab of more than 15, preferably of more than 20, particularly preferably of more than 25.
In an advantageous variant of the present invention, when viewed vertically in transmitted light, the thin-film element appears green and exhibits a chroma C*ab of more than 30, preferably of more than 40. In another advantageous variant of the present invention, when viewed vertically in transmitted light, the thin-film element appears yellow and exhibits a chroma C*ab of more than 10, preferably of more than 20. In a further advantageous variant of the present invention, when viewed vertically in transmitted light, the thin-film element appears red and exhibits a chroma C*ab of more than 20, preferably of more than 30. In yet a further advantageous variant of the present invention, when viewed vertically in transmitted light, the thin-film element appears blue and exhibits a chroma C*ab of more than 20, preferably of more than 30.
In a preferred variant of the present invention, the thin-film element appears colored in transmitted light and, in transmitted light, exhibits a color-shift effect in which the color impression changes in transmitted light when the thin-film element is tilted. Here, the color impression in transmitted light can change, for example, from magenta when looked through vertically to green when looked through obliquely. In an alternative, likewise advantageous variant of the present invention, the thin-film element appears colored in transmitted light and, when tilted, remains substantially color constant, but with a changed chroma C*ab of the see-through color. Here, the color impression in transmitted light can be, for example, blue, the chroma of the blue see-through color changing from a high value when looked through vertically to a lower value when looked through obliquely. In this variant, when the thin-film element is tilted, only the saturation of the perceived blue see-through color changes.
In a development of the present invention, the thin-film element is combined with a color filter, preferably a colored printing layer or a colored vapor deposition layer. Here, the thin-film element and the color filter can be coordinated with each other in such a way that, in a predetermined viewing direction, the thin-film element and the color filter each transmit substantially only in different, non-overlapping wavelength ranges. IFor this viewing direction, the combination of thin-film element and color filter then appears black, since no color is simultaneously transmitted by both elements. For other viewing directions, the wavelength range in which the thin-film element transmits shifts such that said wavelength range overlaps with the wavelength range in which the color filter transmits. Consequently, a certain portion of the light is transmitted by both elements. In this way, see-through security elements can be created that display a shift from black or to black and that often seem particularly striking for the viewer.
In advantageous embodiments, the thin-film element is present in the form of patterns, characters or a code. This also includes the possibility that a contiguous thin-film element is provided with gaps in the form of patterns, characters or a code.
The thin-film element according to the present invention can advantageously be combined with a relief structure, such as a diffractive relief structure (e.g. hologram), a microoptical relief structure (e.g. microlens structure, 3D depiction composed of sawtooth structures) or a sub-lambda structure (e.g. subwavelength gratings, moth-eye structures) and can especially be applied to such a relief structure. In this way, it is possible to combine the optically variable effects of the mentioned relief structures with the described conspicuous transmission color effect and, if applicable, the conspicuous transmission color-shift effect.
The thin-film element according to the present invention can also be combined with other optically variable coatings, especially with coatings that themselves exhibit a combination of color variable and color constant regions.
The present invention also comprises a see-through security element for security papers, value documents and the like, having a support and, applied to the support, a thin-film element of the kind described. Here, the thin-film element is advantageously applied to the support in the form of a motif. In an advantageous embodiment, the thin-film element is additionally provided on its top opposite the support with an ink absorption layer. The ink absorption layer is preferably opaque white.
In the latter case, the thin-film element can be embedded, for example, in a security paper or another data carrier and form there a colored, watermark-like element. For this, the thin-film element is applied to a foil strip in at least some regions, especially in the form of a motif. In the case of a composite banknote, said foil strip is then adhered to the paper and printed on the top with a white ink absorption layer, such that the region having the thin-film element is practically not perceptible in top view. But when looked through, the thin-film element then nevertheless appears colored. Surprisingly, it proved that, in transmission, especially thin-film elements that appear green when looked through are also still clearly perceptible as colored through a paper layer of typical thickness, and due to the different visual impression in reflected light and transmitted light, form watermark-like and, moreover, colored elements.
Particularly advantageously, a further see-through security element for a window is located in another region on the same foil strip, such that the window element and the colored, watermark-like element can be manufactured in the same operations.
Further, the present invention includes, for a printing ink, optically variable color pigments that are formed by thin-film elements of the kind described.
Finally, the present invention also includes a data carrier having a thin-film element or a see-through security element of the kind described, the thin-film element or the see-through security element being arranged especially in or over a transparent window region or a through opening in the data carrier. The present invention also includes a data carrier having a thin-film element or a see-through security element of the kind described, in which the thin-film element or the see-through security element is embedded in the data carrier. The data carrier can especially include a paper substrate in which the thin-film element or the see-through security element is embedded.
The data carrier can especially be a value document, such as a banknote, especially a paper banknote, a polymer banknote or a foil composite banknote, or an identification card, such as a credit card, bank card, cash card, authorization card, personal identity card or a passport personalization page.
Further exemplary embodiments and advantages of the present invention are explained below by reference to the drawings, in which a depiction to scale and proportion was omitted in order to improve their clarity. The different exemplary embodiments are also not limited to the use in the form specifically described, but rather can also be combined with one another.
Shown are:
The invention will now be explained using the example of security elements for banknotes. For this,
The see-through security element 12 includes a motif 16 that, for illustration, is depicted in
If, in contrast, the see-through security element 12 is viewed in transmitted light (viewing position 24), for example in that the banknote 10 is held in front of a light source or up to daylight, then the motif 16 appears for the viewer 24 having vibrant, rich colors that, moreover, change with the tilt angle of the banknote 10. For example, the motif 16 appears, when looked through vertically, having a vibrant green hue that, when the banknote is tilted, changes into a rich blue when looked through obliquely.
The rich and vibrant color impression when looking through a security element that appears metallic and colorless in reflected light contradicts ordinary viewing habits and thus has a high attention and recognition value. This is further intensified by the color change when the banknote 10 is tilted, especially since the color change is very conspicuous due to the rich colors.
To produce the mentioned color effects, the see-through security element 12 includes, with reference to
The distinctive feature of the layer structure according to the present invention consists in that, for the two semitransparent absorber layers 34, 38, a material is used in whose complex refractive index N=n+ik the real part n and the imaginary part k differ significantly at least in a portion of the visible spectral range, namely by more than a factor of 5. In contrast, in the materials conventionally used for absorber layers of thin-film elements, such as chrome, nickel or palladium, the values for the real part n and the imaginary part k of the complex refractive index N are always on the same order of magnitude.
These different properties are illustrated in
The present inventors have now found that this large difference in the values of n and k when these materials are used as absorber layers of interference layer elements surprisingly produces an intense coloring of the transmission. At the same time, the reflection remains substantially colorless and thus appears color neutral to the viewer. This behavior is illustrated in
a) shows, first, the transmission of a conventional symmetrical chrome/dielectric/chrome structure when viewed vertically (curve 50, solid) and when viewed obliquely (curve 52, dotted). The layer thicknesses in the structure measure preferably 300 nm for the dielectric layer and 8 nm for the chrome layers. In both cases, the transmission spectra have a substantially flat curve, such that the transmitted light exhibits hardly any color saturation and thus appears grayish. Accordingly, see-through security elements on the basis of a chrome/dielectric/chrome thin-film element are optically little conspicuous.
In contrast, the transmission spectra of a symmetrical silver/dielectric/silver structure both when viewed vertically (curve 54, solid) and when viewed obliquely (curve 56, dotted) display clearly pronounced maxima 55 and 57, and thus a strong coloring of the transmitted light. The layer thicknesses in the structure are preferably 300 nm for the dielectric layer and 25 nm for the silver layers.
When viewed vertically (curve 54), the maximum 55 is about 560 nm at the boundary between yellow and green. If the viewer tilts the see-through security element, then the transmission maximum shifts to the short-wave range. When viewed vertically at 60° (curve 56), the maximum 57 is between 450 nm and 500 nm and displays a rich blue there. Due to the vibrant colors and the clear change in the hue, also the see-through color-shift effect is very conspicuous and memorable for the viewer.
The coloring of the transmission can be characterized more precisely in the CIELAB color space by specifying the chroma of the see-through color. In the CIELAB color space, every color is described by three coordinates L*, a* and b*, the variable L* corresponding to the brightness and being able to take on values from 0 to 100. The a* axis describes the green or red portion of a color, negative values of a* standing for green and positive values for red. The b* axis describes the blue or yellow portion of a color, negative values of b* standing for blue and positive values for yellow. The scales of the a* axis and the b* axis comprise a range of numbers from −150 to +100 or from −100 to +150, where, however, not all combinations correspond to a perceptible color.
To specify how vibrant or brilliant a color is, the chroma is used, which is given by
in other words, the distance of a color coordinate (a*, b*) from the origin (0, 0). The larger the chroma, the more vibrant or brilliant the respective color appears. For a chroma of 0, a black, gray or white color impression results, depending on the brightness.
The hue of a color can be specified by the color angle, which is given by
A pale and a vibrant color of a certain hue have the same color angle, but different chroma.
In the diagram in
As immediately evident from
Here, the chroma of silver/dielectric/silver layer systems according to the present invention is normally even many times greater than the chroma of conventional chrome/dielectric/chrome layer systems. For example, the chroma of a silver/dielectric/silver system in transmission is about C*ab=70 in green (−a* axis), while the chroma of a chrome/dielectric/chrome system is only about C*ab=10 in the same hue. In transmission in yellow (+b* axis), a chroma value C*ab=33 for the silver/dielectric/silver system stands opposite a chroma value of C*ab=4 for the chrome/dielectric/chrome system. The relationships are similar for red (+a* axis), blue (−b* axis) and the colors mixed from red, blue, yellow and green.
The total brightness L*, in other words the weighted average transmittance of the layer systems across the visible spectral range, is comparable for the chosen layer thicknesses for the silver layers (25 nm) and the chrome layers (8 nm), and is between about 20% and about 50% in each case.
The present inventors further surprisingly found that, through a suitable choice of the layer thickness of the dielectric layer, it is possible to produce both thin-film elements that display, in transmission, a high coloring and a strong color-shift effect, and thin-film elements that, in transmission, do display a high coloring but hardly change their color when tilted.
In the latter case, particularly easily understandable see-through security elements can be created that do display a conspicuous contrast between their appearance in top view (metallic and substantially colorless) and when looked through (strong, saturated colors), but that practically do not change their see-through color when the security element is tilted.
Both variants of the present invention are illustrated in
The first layer system exhibits two 25 nm thick silver layers between which a 340 nm thick SiO2 layer is arranged as the dielectric layer. In this variant, the color coordinates of the transmission of the layer system are in red when viewed vertically 82 and in yellow when viewed obliquely 84. As evident in
The second layer system exhibits two 25 nm thick silver layers between which a 200 nm thick SiO2 layer is arranged as the dielectric layer. In this variant, the color coordinates of the transmission of the layer system are in blue both when viewed vertically 92 and when viewed obliquely 94. The two color coordinates 92, 94 enclose only a very small color angle 96, such that the color impression of the second layer system, when tilted, remains nearly unchanged. In this variant of the present invention, the tilting of the layer system when looked through does not change the color coordinates, but changes only approximately along the line 90 the chroma of the perceived blue see-through color, which, however, will hardly attract the attention of the casual viewer “on the street.”
The exemplary embodiment in
For this, a transparent embossing lacquer layer 104 having the desired hologram embossing pattern was first applied to a transparent foil substrate 102. After the application of a primer layer, not depicted, a thin-film element having an interference layer structure, for example a thin-film element 30 of the kind described for
The described thin-film elements can also be used to manufacture printing inks having optically variable color pigments. Such a printing ink is depicted schematically in
Number | Date | Country | Kind |
---|---|---|---|
10 2009 041 583 | Sep 2009 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
---|---|---|---|---|
PCT/EP2010/005563 | 9/10/2010 | WO | 00 | 3/9/2012 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2011/032665 | 3/24/2011 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
3858977 | Baird et al. | Jan 1975 | A |
6031653 | Wang | Feb 2000 | A |
7667894 | Hoffmuller | Feb 2010 | B2 |
7699350 | Heim | Apr 2010 | B2 |
7728931 | Hoffmuller | Jun 2010 | B2 |
7808605 | Hoffmuller | Oct 2010 | B2 |
7986459 | Kaule | Jul 2011 | B2 |
8083894 | Gruszczynski | Dec 2011 | B2 |
8149511 | Kaule | Apr 2012 | B2 |
20010028921 | Shaw et al. | Oct 2001 | A1 |
20040240006 | Staub et al. | Dec 2004 | A1 |
20050151368 | Heim | Jul 2005 | A1 |
20070165182 | Hoffmuller | Jul 2007 | A1 |
20070211238 | Hoffmuller | Sep 2007 | A1 |
20070216518 | Hoffmuller | Sep 2007 | A1 |
20070229928 | Hoffmuller | Oct 2007 | A1 |
20070241553 | Heim | Oct 2007 | A1 |
20070246933 | Heim | Oct 2007 | A1 |
20070274559 | Depta | Nov 2007 | A1 |
20080014378 | Hoffmuller | Jan 2008 | A1 |
20080054621 | Burchard | Mar 2008 | A1 |
20080079257 | Fessl | Apr 2008 | A1 |
20080088859 | Depta | Apr 2008 | A1 |
20080160226 | Kaule | Jul 2008 | A1 |
20080163994 | Hoppe | Jul 2008 | A1 |
20080198468 | Kaule | Aug 2008 | A1 |
20080216976 | Ruck | Sep 2008 | A1 |
20080250954 | Depta | Oct 2008 | A1 |
20080258456 | Rahm | Oct 2008 | A1 |
20090001709 | Kretschmar | Jan 2009 | A1 |
20090008923 | Kaule | Jan 2009 | A1 |
20090008926 | Depta | Jan 2009 | A1 |
20090102605 | Kaule | Apr 2009 | A1 |
20090115185 | Hoffmuller | May 2009 | A1 |
20090236061 | Gruszczynski | Sep 2009 | A1 |
20090297805 | Dichtl | Dec 2009 | A1 |
20090322071 | Dichtl | Dec 2009 | A1 |
20100175843 | Gregarek | Jul 2010 | A1 |
20100177094 | Kaule | Jul 2010 | A1 |
20100182221 | Kaule | Jul 2010 | A1 |
20100194091 | Heim | Aug 2010 | A1 |
20100194532 | Kaule | Aug 2010 | A1 |
20100196587 | Keller | Aug 2010 | A1 |
20100207376 | Heim | Aug 2010 | A1 |
20100208036 | Kaule | Aug 2010 | A1 |
20100307705 | Rahm | Dec 2010 | A1 |
20100308570 | Heim | Dec 2010 | A1 |
20100320742 | Hoffmuller | Dec 2010 | A1 |
20110007374 | Heim | Jan 2011 | A1 |
20110012337 | Heim | Jan 2011 | A1 |
20110027538 | Hoffmann | Feb 2011 | A1 |
20110045248 | Hoffmuller | Feb 2011 | A1 |
20110069360 | Dichtl | Mar 2011 | A1 |
20110079997 | Heim | Apr 2011 | A1 |
20110091665 | Heim | Apr 2011 | A1 |
20110095518 | Hoffmuller | Apr 2011 | A1 |
20110101670 | Heim | May 2011 | A1 |
20110109078 | Hoffmuller | May 2011 | A1 |
20110114733 | Heim | May 2011 | A1 |
20110157183 | Kaule | Jun 2011 | A1 |
20120126525 | Dorfler | May 2012 | A1 |
20120168515 | Schutzmann | Jul 2012 | A1 |
20120170124 | Fuhse | Jul 2012 | A1 |
Number | Date | Country |
---|---|---|
1608217 | Apr 2005 | CN |
1628039 | Jun 2005 | CN |
1630587 | Jun 2005 | CN |
0395410 | Oct 1990 | EP |
0733919 | Sep 1996 | EP |
1189079 | Mar 2002 | EP |
WO 0200445 | Jan 2002 | WO |
WO 03068525 | Aug 2003 | WO |
Entry |
---|
Ordal et al., Optical properties of Au, Ni, and Pb at submillimeter wavelengths, Applied Optics vol. 26, No. 4, pp. 744-752 (Feb. 15, 1987). |
International Search Report, International Application No. PCT/EP2010/005563, 3 pages, Jan. 25, 2011. |
International Preliminary Report on Patentability, International Application No. PCT/EP2010/005563, 10 pages, May 10, 2012, English Translation. |
Chinese First Office Action, dated Dec. 10, 2013, in counterpart Chinese Patent Application No. 201080041164.9, 21 pp (with English translation). |
Disheng, Zhong, Vacuum Coating: Selection and Application of Optical Material, Liaoning University Press, Dec. 20, 2001, pp. 62 and 87 (in Chinese language); 3 pages. |
Number | Date | Country | |
---|---|---|---|
20120170124 A1 | Jul 2012 | US |