Claims
- 1. A thermoset adhesive composition, comprising:
- (a) a thermoplastic, substantially amine-terminated polyamide resin having an amine plus acid number greater than about 1 and less than about 50 and having an excess of free amine to acid groups, said polyamide resin comprising the reaction product of:
- a polymerized fatty acid,
- at least one acid selected from the group consisting of a linear dicarboxylic acid and a monocarboxylic acid; and
- at least one polyamine selected from the group consisting of linear, branched and cyclic polyamines;
- (b) a diluent, distinct from and not a part of the polymer structure of said polyamide resin, which is selected from the group consisting of dimer diamine, RNH.sub.2, RNHCH.sub.2 CH.sub.2 CH.sub.2 NH.sub.2 and R--X--R' wherein R and R' are any C.sub.14 -C.sub.24 aliphatic hydrocarbons, and X is selected from the group consisting of ##STR2## (c) an epoxy resin having at least two epoxy groups per molecule of epoxy resin;
- said adhesive composition comprising a ratio of epoxy groups to free amine groups of greater than 1:1 and less than about 10:1 and a weight ratio of said polyamide resin to said diluent of from about 100:1 to about 4:1.
- 2. The composition of claim 1 wherein the polyamide resin comprises the reaction product of 30-100 equivalent percent of said polymerized fatty acid, 0-70 equivalent percent of said 6 to 22 carbon atom linear dicarboxylic acid, 0-10 equivalent percent of said 2 to 22 carbon atom monocarboxylic acid, and 100-120 equivalent percent of 2 to 60 carbon atom polyamine selected from the group consisting of linear, branched, and cyclic polyamines.
- 3. The composition of claim 2 wherein the polymerized fatty acid has a dimeric fatty acid content greater than 65 percent by weight.
- 4. The composition of claim 3 wherein the linear dicarboxylic acid is selected from the group consisting of oxalic, malonic, succinic, suberic, adipic, azelaic, sebacic, and dodecanedioic acids.
- 5. The composition of claim 4 wherein the linear dicarboxylic acid is selected from the group consisting of adipic, azelaic, sebacic, and dodecanedioic acids.
- 6. The composition of claim 3 wherein the monocarboxylic acid is selected from the group consisting of stearic, tall oil fatty and oleic acids.
- 7. The composition of claim 3 wherein the polyamine is selected from the group consisting of diaminopropane, diaminobutane, diaminopentane, methylpentamethylenediamine, methylnonanediamine, diethylenetriamine, triethylenetetraamine, tetraethylenepentaamine, piperazine, dipiperazine, aminoethylpiperazine, bis(aminoethyl)piperazine, dimer diamine, polyetherdiamine, xylenediamine, bis(aminomethyl)benzene, bis(aminomethyl)cyclohexane, ethylenediamine, and hexamethylenediamine.
- 8. The composition of claim 7 wherein the polyamine is selected from the group consisting of ethylenediamine, hexamethylenediamine, piperazine, methylpentamethylenediamine, dimer diamine, and polyetherdiamine.
- 9. The composition of claim 1 wherein the epoxy resin has from about 2.2 to eight epoxy groups per molecule of epoxy resin.
- 10. The composition of claim 1 wherein the polyamide resin has an amine plus acid number greater than about 2 and less than about 30.
- 11. The composition of claim 1 wherein the polyamide resin has an amine plus acid number greater than about 2 and less than about 20.
- 12. The composition of claim 1 wherein the ratio of epoxy groups to free amine groups is greater than about 1.5:1 and less than about 5:1.
- 13. The composition of claim 1 wherein the weight ratio of polyamide resin to diluent is from about 35:1 to about 6:1.
- 14. The composition of claim 1 wherein the diluent has a molecular weight of from about 200 to 900.
- 15. The composition of claim 1 wherein the diluent is selected from the group consisting of tallowamine, ditallowamine, di(hydrogenatedtallow)amine, tallowaminopropylamine, dimer diamine, stearyl stearamide, ethylene bisstearamide, and stearyl stearate.
- 16. The composition of claim 1 wherein:
- said linear dicarboxylic acid is selected from the group consisting of oxalic, malonic, succinic, suberic, adipic, azelaic, sebacic, and dodecanedioic acids;
- said monocarboxylic acid is selected from the group consisting of stearic, tall oil fatty and oleic acids;
- said polyamine is selected from the group consisting of diaminopropane, diaminobutane, diaminopentane, methylpentamethylene-diamine, methylnonanediamine, diethylenetriamine, triethylenetetraamine, tetraethylenepentaamine, piperazine, dipiperazine, aminoethylpiperazine, bis(aminoethyl)piperazine, dimer diamine, polyetherdiamine, xylenediamine, bis(aminomethyl)benzene, bis(aminomethyl)cyclohexane, ethylenediamine, and hexamethylenediamine; and
- said polymerized fatty acid has a dimeric fatty acid content greater than 65 percent by weight.
- 17. The composition of claim 16 wherein the epoxy resin has from about 2.2 to eight epoxy groups per molecule of epoxy resin.
Parent Case Info
This is a continuation-in-part application of pending application Ser. No. 07/606,793, filed Oct. 30, 1990, now abandoned.
US Referenced Citations (5)
Continuation in Parts (1)
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606793 |
Oct 1990 |
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