In general, this invention relates to three way valves with a desirable configuration. In particular, this invention relates to three way valves that can directly couple with corresponding structures, such as a fuel cell manifold. Additionally, the present invention relates to methods of controlling and/or regulating the flow of a fluid through a fuel cell.
In general, a fuel cell is an electrochemical device that can convent energy stored in fuels such as hydrogen, methanol and the like, into electricity without combustion of the fuel. A fuel cell generally comprises a negative electrode, a positive electrode, and a separator within an appropriate container. Fuel cells operate by utilizing chemical reactions that occur at each electrode. In general, electrons are generated at one electrode and flow through an external circuit to the other electrode to balance the chemical reactions. This flow of electrons creates an over-voltage between the two electrodes that can be used to drive useful work in the external circuit. In commercial embodiments, several “fuel cells” are usually arranged in series, or stacked, in order to create larger over-potentials.
A fuel cell is similar to a battery in that both generally have a positive electrode, a negative electrode and electrolytes. However, a fuel cell is different from a battery in the sense that the fuel in a fuel cell can be replaced without disassembling the cell to keep the cell operating. Additionally, fuel cells have several advantages over other sources of power that make them attractive alternatives to traditional energy sources. Specifically, fuel cells are environmentally friendly, efficient and utilize convenient fuel sources, for example, hydrogen or methanol.
As noted above, the fuel in a fuel cell can be replaced without disassembling the cell. Generally, the fuel in a fuel cell is a fluid such as, for example, hydrogen gas, which is pumped or circulated to the anode, while an oxidizing agent, such as air (oxygen), is delivered to the cathode. Additionally, reaction products are generally removed from the system. The delivery of appropriate reactants to the anode and the cathode, as well as the removal of reaction products, introduce specific fluid flow issues.
Fuel cells have potential uses in a number of commercial applications and industries. For example, fuel cells are being developed that can provide sufficient power to meet the energy demands of a single family home. In addition, prototype cars have been developed that run off of energy derived from fuel cells. Furthermore, fuel cells can be used to power portable electronic devices such as computers, phones, video projection equipment and the like. With the increasing number of fuel cell applications, it would be desirable to provide a fuel cell that could address the aforementioned problems.
In a first aspect, the invention pertains to a three way valve comprising a central chamber having a selectively positionable seal and an opening to the exterior of the valve and a bypass chamber with a passage connecting the central chamber to the bypass chamber, wherein the bypass chamber has an opening to the exterior of the valve. In these embodiments, the three way valve further comprises a pass through chamber with a passage connecting the central chamber to the through chamber, wherein the through chamber has an opening to the exterior of the valve, and wherein the selectively positionable seal regulates fluid flow from the central chamber to the bypass chamber and to the through chamber. The openings respectively from the central chamber, the bypass chamber and the through chamber are roughly aligned in the same direction. Additionally, the three way valves can be used in methods of regulating the flow of a fluid through a fuel cell. In one embodiment, the method comprises providing a three way valve and adjusting the selectively positionable seal to regulate the fluid flow through the valve.
In second aspect, the invention pertains to a fuel cell comprising a cathode, an anode, an electrolyte and at least one three way valve for regulating fluid flow through the fuel cell comprising a valve body with three openings. In these embodiments, the fuel cell further comprises a rigid flow network, wherein the three way valve engages directly with the flow network.
In another aspect, the invention pertains to a fuel cell comprising a cathode, an anode and an electrolyte in contact with the anode and the cathode and at least one three way valve comprising a valve body having a central chamber, a bypass chamber, a through chamber, a first passage connecting the central chamber to the bypass chamber, a second passage connecting the central chamber to the through chamber, each chamber comprising a bore that forms an opening to the exterior of the valve body, and a selectively positionable seal that can seal the first passage or the second passage. In these embodiments, the fuel cell can further comprise a flow network comprising a fixed structure that has a fluid flow pathway to the anode or to the cathode, wherein the openings of the three way valve each engage directly with the fixed structure.
In a further aspect, the invention pertains to a three way valve comprising a valve body having a first chamber a second chamber and a third chamber, each chamber comprising a bore that forms an opening to the exterior of the valve body, the first chamber and the second chamber being connected by a first passage, the second chamber and the third chamber being connected by a second passage, wherein the openings form the first chamber, the second chamber and the third chamber are roughly aligned in the same direction. In these embodiments, the three way valve can further comprise a selectively positionable seal positioned within the second chamber having a sealing element which is adapted to engage the first passage or the second passage wherein the selectively positionable seal has a first position with the seal in contact with the first passage to seal the first passage and a second position with the seal in contact with the second passage to seal the second passage, and a control unit connected to the selectively positionable seal to control the position of the selectively positionable seal.
In still another aspect, the invention pertains to a method of regulating the flow of a fluid though a fuel cell, the fuel cell comprising a rigid flow network and a three way valve connected to the rigid flow network, the three way valve comprising a valve body having a central chamber, a bypass chamber having a first passage that connects the bypass chamber to the central chamber and a through chamber having a second passage that connects the central chamber to the through chamber, each chamber comprising a bore that forms an opening to the exterior of the valve body, and a selectively positionable seal that can regulate fluid flow through the three way valve. In these embodiments, the method can comprise adjusting the selectively positionable seal to regulate flow of a humidified fuel air mixture to an anode of the fuel cell.
Improved three way valves comprise three openings aligned to directly connect with a corresponding series of ports and a selectively positionable seal that regulates and/or directs the flow of a fluid within the valve. Improved fuel cells comprise a plurality of flow channels connected to at least one improved three way valve suitable for regulating fluid flow through the fuel cell. Generally, the flow channels comprise a series of ports, wherein the three way valve is configured to engage and disengage from the series of ports directly to form a manifold without the use of additional connectors, for example, tubes and/or hoses. Due to the fact that the three way valve can engage and disengage form the series of ports directly, potential leakage points in the fuel cell piping system can be reduced. In some embodiments, the three way valve comprises a central chamber having a selectively positionable seal, a bypass chamber and a through chamber. Generally, the selectively positionable seal can form a seal selectively at the port, or passage, connecting the central chamber with the bypass chamber or with the through chamber. The selectively positionable seal can regulate fluid flow from the central chamber to the bypass chamber and to the through chamber. In one embodiment, the selectively positionable seal can be actuated, for example, by a solenoid that is operably coupled to the selectively positionable seal.
The three way valves of the present disclosure are generally capable of directly connecting to a series of ports, without the need for adapters, such as tubes and/or hoses. In some embodiments, all three chambers of the three way valve are aligned with openings along a common plane. In other embodiments, the chambers are aligned with openings in different planes, however, in these embodiments the three way valve can still be directly connected to an appropriate series of ports to allow flow into both of the other chambers from central chamber. In one embodiment, a selectively positionable seal regulates the flow a fluid through the three way valve by obstructing the flow of fluid to one of the chambers. Specifically, the selectively positionable seal can be positioned to close off the bypass chamber from the central chamber, to close off the through chamber from the central chamber, or to allow flow into both of the other chambers from central chamber possibly with partial obstruction of the flow to either/or both sides.
As described above, the improved valves described herein comprise three aligned chambers each with a passage connecting the chamber with adjacent chambers and an opening to outside the valve. The shape of the chambers influences the character of the resulting flow through the valve. The orientation of the openings into the chambers provides for engagement of the valve with ports connected to appropriate flow channels. In general, the chambers are aligned in roughly the same orientation, and the openings into each chamber from outside the valve are similarly aligned in roughly the same orientation. While these rough relationships provide for the improved attachment of the valve, some variation can be tolerated without losing the improved aspect of the valve. In particular, it is the orientation of the three openings into the respective chambers that influences the attachment features of the valve.
In some embodiments, the openings into the respective chambers are coplanar. In other embodiments, the openings into the respective chambers are planar and along parallel planes, such that at least one of the openings extends below one or both of the other openings. More generally, while the openings are roughly oriented along the same direction, the outward normal to one of the openings can be at an angle relative to one or more of the other two openings. For convenience, the angles can be referenced to the outward normal of the plane along the central opening. The angle of the outward normal of the plane of the other two openings is generally less than about 75 degrees, in other embodiments less than about 50 degrees, in further embodiments less than about 30 degrees and in additional embodiments from about 5 degrees to about 25 degrees. A person of ordinary skill in the art will recognize that additional ranges of angles within these explicit ranges are contemplated and are within the present disclosure. In some embodiments, one or more openings may not be planar, such as undulating. For the nonplanar embodiments, the outward normal can be defined with a plane that passes approximately through the average of any undulations or the like. Roughly aligned, as used herein, with respect to the openings of the chambers, implies that the three way valve can be placed onto a fixed manifold with a single motion and fastened for use.
Referring to
In one embodiment, as shown in
Referring to
Additionally, in some embodiments, valve body 101 further comprises attachment sections 130 which are generally provided with fastener holes 132 for securing three way valve 100 to an appropriate series of ports via a mechanical fastener such as, for example, a screw or the like. Other fasteners can be substituted for fasteners and fastener holes 132 such as a clamp and suitable flanges or the like. As shown in
Three way valve 100 further comprises passage 114 between through chamber 106 and central chamber 102, and passage 116 between central chamber 102 and bypass chamber 104. Passages 114, 116 permit fluids that enter central chamber 102 though opening 108 to flow to either and/or both ports 104, 106. Referring to
Referring to
Generally, the first surface 140 and the second surface 142 of selectively positionable seal 118 can be composed of any material suitable for use in fluid transfer applications that is inert with respect to the fluid being transferred. Suitable materials include metals, metal alloys, polymers and combinations thereof. Suitable polymers include, for example, polyethylene, polypropylene, poly(tetrafluoroethylene), polyurethanes, poly(vinylidene fluoride) (PVDF) and blends and copolymers thereof. In one embodiment, first and second surfaces 140, 142 of selectively positional member 118 can be composed of a peroxide cured EPDM, while spacer 144 can be composed of PVDF. If a metal is used to form the selectively positionabie seal, then a separate sealing element, such as a polymeric coating described above, can generally be attached to the metal surface(s) to seal the passages. Suitable polymeric coatings that can be used for the sealing elements include, elastomers, natural rubbers, polyurethanes and the like and combinations thereof. In some embodiments, first surface 140 and second surface 142 are composed of the same material, while in other embodiments first surface 140 and second surface 142 may be composed of different materials.
In some embodiments, valve 100 can further comprise coupling structure 120 which can interface with solenoid 122.
In one embodiment, o-ring 184 can be used to attach connecting rod 182 with diaphragm stem 126. One of ordinary skill in the art will recognize that additional structures for connecting the connecting rod to the diaphragm stem are contemplated and are within the scope of the present disclosure. As shown in
As will be described in detail below, the solenoid system can actuate selectively positionable seal 118 such that selectively positionable seal 118 can be positioned to completely seal either passage 114 or passage 116. In one configuration, solenoid 122 can extend selectively positionable seal 118 to contact the inner edges and/or valve seat 121 of passage 114, which can seal passage 114. In another configuration, solenoid 122 can retract selectively positionable seal 118 such that selectively positionable seal 118 can contact that inner edge and/or valve seat 119 of passage 116, which can and seal passage 116. Alternatively, selectively positionable seal 118 can be positioned between passage 114 and 116, partially obstruct either passage 114 or passage 116, which permits a percentage of the total fluid to flow through both passage 114 and passage 116. During operation, in one configuration, as shown in
The chambers, coupling structure, solenoid housing, diaphragm stem, solenoid plunger and outer cap may be composed of any polymeric material suitable for use in fuel cell applications. Suitable polymers include, for example, polyethylene, ultra high molecular weight polyethylene (UHMWPE), poly(vinyl chloride), polycarbonates, poly(tetrafluoroethylene), polyurethanes, polypropylene, PVDF, and blends and copolymers thereof. The polymer should be selected such that it is chemically resistant to the fluids flowing through the valve and does not degrade under normal operating temperatures and pressures. Diaphragm 186 can be composed of any polymeric or elasotmeric composition with sufficient elasticity to permit the diaphragm to be converted from a convex position to a concave position. Suitable elastomers include, for example, natural rubbers, synthetic rubbers and the like and combinations thereof. In one embodiment, the diaphragm comprises a peroxide cured EPDM with a polyester fabric backing. In some embodiments, connecting rod can be composed of metal, such as steel, while in other embodiments connecting rod can be a polymeric material. In some embodiments, the o-rings can be composed of peroxide cured EPDM. In one embodiment, the compression spring can be composed of zinc coated music wire, however, other metal compression springs can also be employed. Various solenoids, and solenoid coils are commercially available. For example, one suitable commercially available solenoid coil is sold by Saia Burgess (Vandalia, Ohio). While solenoids are convenient, other motor types such as a stepper motor can be used to actuate seal 118. In general, the component pieces of the three way valve are produced and assembled to form the completed structure. As noted above, valve body can be integrally formed as a single structure by, for example, injection molding. The appropriate components of the solenoid system can be assembled and inserted into the valve body through the coupling structure. In one embodiment, the selectively positionable seal can be inserted through the opening in the central chamber and attached to the solenoid system. The outer cap can be connected to the coupling structure to secure solenoid system to the valve body.
In one embodiment, the three way valves of the present disclosure are suitable for use in fuel cell applications. As described above, a fuel cell generally comprises a anode, a cathode, a separator to electrically separate the anode and the cathode and an electrolyte, such as, for example, KOH, in an appropriate container. In a hydrogen fuel cell, hydrogen gas is supplied to the anode and air (oxygen) is supplied to the cathode. In these embodiments, hydrogen gas is ionized at the anode, which releases electrons and creates protons (H+ ions). The electrons are conducted through an external circuit anode to the cathode, where the electrons are involved in the reduction of molecular oxygen to form water. Thus, a hydrogen fuel cell generally requires a system capable of supplying the cathodes with oxygen (air) and the anodes with hydrogen. Example of fuel cells systems are disclosed in U.S. Pat. No. 6,451,467 to Peschke et al., entitled “Flow Control Subsystem for A Fuel Cell System,” and U.S. Pat. No. 5,648,182 to Hara et al., entitled “Fuel Cell Power Generation System,” which are hereby incorporated by reference.
In one embodiment, as shown in
Referring to
During use, an anode fuel such as, for example, humidified hydrogen gas, can be introduced into anode fuel supply inlet 236 and can flow into central chamber 102 of three way valve through line 238. Once the gas is in central chamber 102, selectively positionable seal 118 can direct the flow of fluid to either through chamber 106 or bypass chamber 104. Additionally, in some embodiments, selectively positionable seal 118 can regulate the flow of fuel, or other fluids, such that a portion of the flow goes into through chamber 106 and a portion of the flow goes into bypass chamber 104. Fuel or other fluids that are directed into through chamber 106 can flow through port 230 into supply line 240 and can be directed to, for example, the anodes of a fuel cell stack. Additionally, fuel directed into by-pass chamber 102 can flow through port 234 into bypass line 241 where the fuel can be directed to a by pass system. Additionally, an oxidant such as, for example, air (oxygen) can be introduced into flow network 220 through inlet 244 and can flow through supply line 246 to the cathodes of a fuel cell stack. In one embodiment, selectively positionable seal 118 can be positioned to block the flow of fuel into through chamber 106 during start up and/or during an emergency shutdown of a fuel cell, which can reduce or eliminate the flow of fuel to the anodes of the fuel cell stack. Additionally, during normal steady state operation of a fuel cell, selectively positionable seal 118 can be positioned to block flow to by-pass chamber 104.
The embodiments above are intended to be illustrative and not limiting. Additional embodiments are within the claims. Although the present invention has been described with reference to particular embodiments, workers skilled in the art will recognize that changes may be made in form and detail without departing from the spirit and scope of the invention.
The current application claims the benefit of priority from U.S. provisional patent application filed on Jul. 11, 2003, entitled “Three Way Valve Assembly” having Ser. No. 60/486,662, which is incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| 60486662 | Jul 2003 | US |