This application generally relates to a heating system for a water removal system for a fuel cell.
Vehicles may be powered by fuel cell systems. A fuel cell system generates electrical energy by chemical reactions caused by circulating hydrogen and oxygen through a fuel cell stack. A by-product of the chemical reactions is water. The fuel cell system must manage the accumulation of water by draining or recycling. In climates subject to freezing weather, additional challenges are present to prevent the water from freezing in the fuel cell system and causing blockages.
A vehicle includes a fuel cell system including a reservoir for water. The vehicle further includes a drain valve coupled to a drain channel defined by the reservoir and configured to drain water from the reservoir when opened. The vehicle further includes a cartridge heater positioned within the drain channel and proximate the drain valve. The vehicle further includes a controller configured to, in response to a fuel cell startup request, activate the cartridge heater for a duration that varies based on an ambient temperature.
The cartridge heater may be coupled to the reservoir at a surface of the reservoir opposite the drain channel. The cartridge heater may include a heated section proximate the drain valve that extends a distance from the drain valve based on an expected ice level in the reservoir during freezing conditions. The cartridge heater may be cylindrically shaped. A diameter of the cartridge heater may be such that an area of a channel opening defined by a cross-sectional area of the drain channel and a cross-sectional area of the cartridge heater within the drain channel is at least equivalent to an area defined by a two-millimeter diameter circular opening. The controller may be further configured to, in response to expiration of the duration, open the drain valve. The cartridge heater may be configured such that a tip of the cartridge heater that is proximate the drain valve is heated. The cartridge heater may be a split-sheath type.
A fuel cell system includes a reservoir configured to collect water, a drain valve coupled to a drain channel defined by the reservoir and configured to drain water from the reservoir when opened, a cartridge heater positioned within the drain channel and proximate the drain valve, and a controller configured to, in response to a fuel cell startup request, activate the cartridge heater for a duration that varies based on an ambient temperature.
The cartridge heater may be coupled to the reservoir at a surface of the reservoir opposite the drain channel. The cartridge heater may include an unheated section proximate the surface that extends a distance from the surface based on an expected ice level in the reservoir during freezing conditions. The cartridge heater may include a heated section proximate the drain valve that extends a distance from the drain valve based on an expected ice level in the reservoir during freezing conditions. A tip of the cartridge heater and a plunger of the drain valve may be separated by at least a predetermined gap. The controller may be further configured to activate the cartridge heater at a power level that varies based on the ambient temperature. A cross-sectional area of the cartridge heater may be such that a channel opening defined by the drain channel when the cartridge heater is inserted is at least equivalent to an area represented by a two-millimeter circular opening.
A water removal system for a fuel cell includes a reservoir for collecting water from the fuel cell and defining a drain channel. The water removal system further includes a drain valve coupled to the drain channel and configured to drain water from the reservoir when opened. The water removal system further includes a cartridge heater coupled to a surface of the reservoir opposite the drain channel and extending into the drain channel and proximate the drain valve.
The water removal system may further include a controller programmed to, in response to a fuel cell startup request, activate the cartridge heater for a duration that varies based on an ambient temperature. A tip of the cartridge heater that is proximate the drain valve may be a heated tip. A diameter of the cartridge heater may be such that an area of a channel opening defined by a cross-sectional area of the drain channel and a cross-sectional area of the cartridge heater within the drain channel is at least equivalent to an area defined by a two-millimeter diameter circular opening. The cartridge heater may include a heated section proximate the drain valve that extends a distance from the drain valve based on an expected ice level in the reservoir during freezing conditions.
Embodiments of the present disclosure are described herein. It is to be understood, however, that the disclosed embodiments are merely examples and other embodiments can take various and alternative forms. The figures are not necessarily to scale; some features could be exaggerated or minimized to show details of particular components. Therefore, specific structural and functional details disclosed herein are not to be interpreted as limiting, but merely as a representative basis for teaching one skilled in the art to variously employ the present invention. As those of ordinary skill in the art will understand, various features illustrated and described with reference to any one of the figures can be combined with features illustrated in one or more other figures to produce embodiments that are not explicitly illustrated or described. The combinations of features illustrated provide representative embodiments for typical applications. Various combinations and modifications of the features consistent with the teachings of this disclosure, however, could be desired for particular applications or implementations.
The fuel cell system 200 may provide electrical power to operate the electric machine 102 to propel the vehicle 100 or perform other vehicle functions. The fuel cell system 200 may generate electrical power that may be consumed by the components coupled to the high-voltage bus 120 (e.g., electrical loads 108). Electrical power generated by the fuel cell system 200 may also be stored by the traction battery 122. The electric machine 102 converts the electrical energy into rotational mechanical energy to drive the transmission 104. The transmission 104 may include gears and clutches that are configured to translate the rotational energy of the electric machine 102 into rotational energy at the drive wheels 106.
During operation of the fuel cell system 200, water, residual fuel such as hydrogen, and byproducts such as nitrogen, may accumulate at the anode side 214 of the fuel cell stack 212. The fuel cell system 200 may be configured to remove the liquid water and byproducts and to reuse the residual hydrogen and water vapor. One approach may be to collect those constituents in a separator 236 downstream of the fuel cell stack 212 that is configured to separate at least a portion of the liquid water and/or nitrogen and return the remaining constituents to the fuel cell stack 212 via a return passageway in a recirculation loop.
A primary fuel source 222 may be connected to the anode side 214 of the fuel cell stack 212, such as a primary hydrogen source. Non-limiting examples of the primary hydrogen source 222 may include a high-pressure hydrogen storage tank or a hydride storage device. The hydrogen source 222 may be connected to one or more ejectors 224. The ejector 224 may have a nozzle 226 supplying hydrogen into the converging section of a converging-diverging nozzle 228. The diverging section of the nozzle 228 may be connected to the input 230 of the anode side 214.
The output 232 of the anode side 214 may be connected to a passive recirculation loop 234. Typically, an excess of hydrogen gas is provided to the anode side 214 to ensure that there is sufficient hydrogen available to all the cells in the stack 212. In other words, hydrogen is provided to the fuel cell stack 212 above a stoichiometric ratio of one, i.e. at a fuel rich ratio relative to exact electrochemical needs. The recirculation loop 234 is provided such that excess hydrogen unused by the anode side 214 is returned to the input 230 so the excess may be used and not wasted.
Additionally, accumulated liquid and vapor phase water is an output of the anode side 214. The anode side 214 requires humidification for efficient chemical conversion and to extend membrane life. The recirculation loop 234 may be used to provide water to humidify the hydrogen gas before the input 230 of the anode side 214.
The recirculation loop 234 may include the separator 236, or water knock-out device. The separator 236 receives a stream or fluid mixture of hydrogen gas, nitrogen gas, and water from the output 232 of the anode side 214. The water may be mixed phase and contain both liquid and vapor phase water. The separator 236 may include a reservoir for holding a predetermined volume of water. The separator 236 removes at least a portion of the liquid phase water, which may exit the separator through drain line 238. At least a portion of the nitrogen gas, hydrogen gas, and vapor phase water may also exit the drain line 238, and pass through a control valve 239 (may also be referred to as a drain valve), for example, during a purge process of the fuel cell stack 212. The control valve 239 may be closely integrated with the separator 236. The remainder of the fluid in the separator 236 exits through passageway 240 in the recirculation loop 234, which is connected to the ejector 224. The fluid in passageway 240 is fed into the converging section of the converging-diverging nozzle 228 where it mixes with incoming hydrogen from the nozzle 226 and hydrogen source 222.
Liquid water may be removed from the anode side 214 by the separator 236 to prevent water blockages within the channels and cells of the anode side 214. Water blockages within the fuel cell stack 212 may lead to decreases in cell voltage and/or voltage instabilities within the fuel cell stack 212. Liquid water may also be removed by the separator 236 to prevent a blockage or partial blockage within the ejector 224. A liquid water droplet in the diverging section of the converging-diverging nozzle 228 would effectively create a second venturi section within the nozzle 228 and lead to pumping instabilities for the ejector 224.
The cathode side 216 of the stack 212 receives oxygen, for example, as a constituent in an air source 242. In one embodiment, a compressor 244 is driven by a motor 246 to pressurize the incoming oxygen. The pressurized air is then humidified by a humidifier 248 before entering the cathode side 216. Another separator 250 (shown in phantom) may be positioned downstream of the humidifier 248. The separator 250 may be used to remove liquid water from the humidified air flow before it enters the cathode side 216 of the stack 212 at input 252. Water droplets may be present downstream of the humidifier 248 due to liquid water being entrained by air high flow rates within the humidifier 248. Liquid water may be removed by the separator 250 to prevent water blockages within the cells of the cathode side 216, leading to decreases in cell voltage and/or instabilities within the fuel cell stack 212. The cathode stack outlet 254 of the cathode side 216 is connected to a valve 256. Drain line 238 from separator 236, and a drain line 258 from separator 250 may be connected to a line 260 downstream of the valve 256. In other embodiments, the drain lines may be plumbed to other locations in the fuel cell system 200.
Other system architectures may also be used for the fuel cell system 200. For example, a turbine may be used in addition to the compressor 244 to induce flow through the cathode side 216. In one example, a turbine is positioned downstream of the cathode stack outlet 254, with a separator interposed between the cathode side 216 and the turbine to remove liquid water before the fluid stream enters the turbine.
Based on the use of the ejector 224 to create flow through the anode side 214 and induce flow through the passive recirculation loop 234, the ejector 224 must overcome any pressure drops in the system, which includes a typically significant pressure drop across the fuel cell stack 212. The system 200 as shown does not include a pump or other device to induce flow in the recirculation loop 234, therefore all the compression work is accomplished by the ejector, otherwise described as a jet pump. To enable this function, the separator 236 may have a low pressure drop across it. The separator 236 may be configured to remove larger droplets of water from the fluid to prevent water blockages in the recirculating flow in the fuel cell stack 212 or ejector 224 caused by droplets. The separator 236 permits vapor phase water and smaller water droplets to remain in the recirculating flow in passageway 240 and return to the ejector 224 for humidification purposes. In one example, the separator 236 removes water droplets having a diameter on the order of one millimeter or larger.
Additionally, as the separator 236 receives fluid flow from the anode side 214, the separator 236 may be designed for use with hydrogen gas. Generally, hydrogen gas may cause material degradation or embrittlement issues and material used in the separator 236 may be hydrogen compatible. Additionally, hydrogen is a small molecule, and many conventional separator devices are not suitable for use with hydrogen because their design may permit leaks, for example, with a conventional threaded connection. Other conventional separators may contain rotating or moving parts, such as a rotating vane, or the like, which may not be compatible with hydrogen as the lubricant may poison the fuel cell stack, or the hydrogen may degrade or decompose the lubricant.
Separator 250 also needs to remove larger droplets of water from the fluid to prevent water blockages caused by droplets in the flow in the cathode side 216 of the fuel cell stack 212. The separator 250 permits vapor phase water, and smaller water droplets to remain in the flow for humidification. In one embodiment, the separator 250 removes water droplets that are the same size or larger than the cathode side 216 flow field channel widths. In one example, the cathode side flow field channels may be between 0.2 and 1.0 millimeters.
During fuel cell operation, water may collect in the separator 236. The fuel cell system may control a water level 306 within the separator 236 to a predetermined level. During fuel cell operation, there may be a preferred water level for operating the fuel cell system 200. Further, during shutdown, the fuel cell system 200 may be configured to purge water from the separator 236 to prepare for the next operating cycle. The purge of water may also reduce the risk of freezing in cold weather. During fuel cell operation, the drain valve 239 may be periodically actuated to allow water to flow out of the separator 236 to maintain the preferred water level.
Water that is collected in the separator 236 poses problems in freezing weather conditions. After some time in below-freezing temperatures, water within the fuel cell system 200 may freeze to form ice. Frozen water in the separator 236 can block the drain channel 316 and prevent water from exiting the separator 236. In addition, water may freeze around the plunger 310 and prevent movement of the plunger 310. Ice in the separator 236 can cause the water level to become too high and eventually impede optimal operation of the fuel cell system 200. As such, various systems may be employed to reduce the occurrence of ice in the fuel cell system 200.
Prior solutions include the use of a scavenged reservoir which is a smaller reservoir that the separator drains into. The drain valve is then attached to an outlet of the scavenged reservoir. In the scavenged reservoir configuration, the drain valve is at a higher level than the scavenged reservoir. Water may freeze in the scavenged reservoir and eventually exceed the volume capacity of the scavenged reservoir leading to a blockage. On inclined surfaces, water in the scavenged reservoir may freeze leading to blockages. In addition, moisture near the drain valve can cause freezing leading to the need for a heated drain valve. Other solutions include the use of a heated drain valve. A heated drain valve functions to permit movement of the valve, but does not necessarily melt ice to initiate drainage.
Referring again to
The length of the heated section 302 proximate the drain valve may extend a distance from the drain valve 239 based on an expected ice level in the reservoir during freezing conditions. The length of the heated section 302 may be configured such that the heated section 302 extends a distance from a tip of the heated section 302 proximate the drain valve 239 to a maximum expected ice or water surface thickness within the separator 236. That is, the heated section 302 should extend from the drain valve 239 through any formed ice to facilitate melting. The heated section 302 may be sized such that activating the heating element melts a channel that allows water that is added to the separator to flow through to the drain channel 316. Extension of the heated section 302 above the maximum expected ice/water level does not aid in melting the ice and may increase power usage.
The normal opening of the drain channel 316 may be desired to be between 2 millimeters and 5 millimeters. Insertion of the cartridge heater 300 may change an effective opening of the drain channel 316. As such, design parameters may be selected to ensure that the effective opening is satisfactory for fuel cell operation. A diameter of the cartridge heater 300 may be such that an area of a channel opening defined by a cross-sectional area of the drain channel 316 and a cross-sectional area of the cartridge heater 300 within the drain channel 316 is at least equivalent to an area defined by a two-millimeter diameter circular opening. For example, assume a circular drain channel having a diameter of 5 millimeters. A commercially available cartridge heater may have a diameter of ⅛ inch (3.175 millimeters). Inserting the ⅛-inch cartridge heater in the 5-millimeter opening leaves an opening equivalent to a 3.86-millimeter diameter circular opening. Similar analysis may be performed for other configurations. By proper selection of the diameters of the drain channel 316 and the cartridge heater 300, adequate flow through the drain channel 316 may be ensured. Note that other combinations are possible in addition to the example presented.
A tip of the heated section 302 may be adjacent the plunger 310. The cartridge heater 300 may be configured with a heated tip to facilitate melting ice that may impede movement of the plunger 310. A predetermined gap may be present between the tip and the plunger 310 such that the tip does not contact the plunger 310. Although no contact between the drain channel 316 and the cartridge heater 300 may be desired, contact is not necessary harmful as the expected temperatures are not anticipated to adversely affect any of the surfaces. However, the gap may be preferred to prevent impeding the motion of the plunger 310.
The cartridge heater 300 may be cylindrically shaped. In some configurations, the cartridge heater 300 may be a split-sheath type cartridge heater. The split-sheath cartridge heater includes two legs that may expand when the heater is activated. Additionally, when the heater is deactivated, the legs may contract back to their original position. This may aid in increasing the size of the drain passage melted into the ice.
The non-heated section 304 may function as a conduction barrier so that wires that lead outside of the separator 236 remain near the ambient temperature. This avoids heat cycles of the wiring and insulation that may lead to degradation.
The cartridge heater 300 may be electrically coupled to the controller 312. The controller 312 may activate the heating element within the heated section 302 to cause an increase in temperature. The controller 312 may be configured to vary the power supplied to the cartridge heater 300. For example, the controller 312 may include a solid-state driver circuit that can vary the current supplied to the cartridge heater 300. For example, a pulse-width modulated signal may be provided to modulate the current flowing through the cartridge heater 300.
The heating process may be repeated. For example, after a predetermined off-time, the cartridge heater 300 may be activated again. The predetermined off-time may be selected to ensure that the cartridge heater 300 is below a predetermined temperature. Repeating the process may also be triggered by other sensors. For example, a water level sensor in the separator 236 may indicate that the water level is not decreasing as expected. Other performance measures of the fuel cell operation may also indicate that the separator 236 is not draining properly. These conditions may trigger another heating cycle to try and remove any remaining ice that may be blocking the flow of water.
Actuation of the plunger 310 couples the drain channel 316 to the outlet port 308 as depicted in
Even assuming a starting temperature of 50° C. (122° F.), applying the heater at 20 Watts for 8.3 seconds results in a heater temperature of 171° C. It may be desired to prevent the heater from causing temperatures that may cause system degradation. The system may be designed to prevent high temperatures and/or utilize materials that can withstand high temperatures. One possible weak area in a cartridge heater system may be the connection point of the lead wires. If the lead wires are sheathed in Teflon, the temperature may be regulated to remain below 250° C. to prevent degradation of the sheathing. Another possible weak area is the face of the plunger 310. For example, the drain valve 239 may include a surface comprised of ethylene propylene diene monomer (EPDM) rubber. The EPDM rubber may provide the seal to prevent leakage when the valve is not activated. The EPDM rubber may degrade at temperatures above 150° C. However, as there is a gap between the heater tip and the plunger 310, the temperature at the face of the plunger 310 can be maintained within an acceptable range even under worst case conditions. For example, if the starting temperature is above a predetermined temperature level (e.g., 50° C.), then the heater may not be activated since freezing conditions are not suspected.
The cartridge heater 300 may be activated for a predetermined duration. The predetermined duration may be a function of the ambient air temperature at fuel cell startup. The vehicle 100 may include one or more temperature sensors. The temperature sensor may include an ambient air temperature sensor. The temperature sensors may be electrically coupled to the controller 312 or otherwise in communication with the controller 312.
An advantage of the heating system is that no additional sensors are required. For example, no temperature sensors monitoring the cartridge heater 300 are used. The cartridge heater 300 is operated for predetermined durations and power levels at which no degradation of the cartridge heater is expected. The durations are selected such that the cartridge heater 300 will not overheat or cause temperatures within the separator 236 to become excessive.
If heater operation is needed, operation 902 may be performed. At operation 902, a temperature associated with the vehicle may be measured. For example, an ambient air temperature sensor may be sampled to determine a temperature of the environment. In other configurations, a temperature sensor of the fuel cell system 200 may be sampled.
At operation 904, a heater duration may be computed. For example, the heater duration may be a function of the measured temperature. The heater duration may be selected as depicted in
The processes, methods, or algorithms disclosed herein can be deliverable to/implemented by a processing device, controller, or computer, which can include any existing programmable electronic control unit or dedicated electronic control unit. Similarly, the processes, methods, or algorithms can be stored as data and instructions executable by a controller or computer in many forms including, but not limited to, information permanently stored on non-writable storage media such as ROM devices and information alterably stored on writeable storage media such as floppy disks, magnetic tapes, CDs, RAM devices, and other magnetic and optical media. The processes, methods, or algorithms can also be implemented in a software executable object. Alternatively, the processes, methods, or algorithms can be embodied in whole or in part using suitable hardware components, such as Application Specific Integrated Circuits (ASICs), Field-Programmable Gate Arrays (FPGAs), state machines, controllers or other hardware components or devices, or a combination of hardware, software and firmware components.
While exemplary embodiments are described above, it is not intended that these embodiments describe all possible forms encompassed by the claims. The words used in the specification are words of description rather than limitation, and it is understood that various changes can be made without departing from the spirit and scope of the disclosure. As previously described, the features of various embodiments can be combined to form further embodiments of the invention that may not be explicitly described or illustrated. While various embodiments could have been described as providing advantages or being preferred over other embodiments or prior art implementations with respect to one or more desired characteristics, those of ordinary skill in the art recognize that one or more features or characteristics can be compromised to achieve desired overall system attributes, which depend on the specific application and implementation. These attributes may include, but are not limited to cost, strength, durability, life cycle cost, marketability, appearance, packaging, size, serviceability, weight, manufacturability, ease of assembly, etc. As such, embodiments described as less desirable than other embodiments or prior art implementations with respect to one or more characteristics are not outside the scope of the disclosure and can be desirable for particular applications.