This application claims priority to European Patent Application No. 18182663.7 filed on Jul. 10, 2018, the entire disclosure of which is hereby incorporated herein by reference.
The invention concerns a timepiece component comprising a shaft-like portion including at least one pivot about a pivot axis.
The invention also concerns a timepiece oscillator comprising at least one such component.
The invention also concerns a timepiece movement including at least one such oscillator and/or one at least one such component.
The invention also concerns a timepiece including at least one such movement and/or at least one such oscillator, and/or at least one such component.
The invention concerns the field of timepiece components and wheel sets, and more particularly the making of wheel sets comprised in oscillators or timepiece movements.
It is not conventional to make non-magnetic timepiece wheel sets. However, there is a need in various types of movements which rely on the laws of magnetism, in particular, to reduce or remove friction, especially in oscillators where it is sought to obviate the conventional lever/type stop mechanisms, which are highly detrimental to the power reserve.
The invention proposes to offer an alternative to conventional timepiece wheels sets that have steel arbors, which can be used in an environment in which magnetic type mechanisms must not be disturbed.
To this end, the invention concerns a timepiece component comprising a shaft-like portion including at least one pivot about a pivot axis, according to claim 1.
The invention also concerns a timepiece oscillator comprising at least one such component.
The invention also concerns a timepiece movement including at least one such oscillator and/or one at least one such component.
The invention also concerns a timepiece including at least one such movement and/or at least one such oscillator, and/or at least one such component.
Other features and advantages of the invention will appear upon reading the following detailed description, with reference to the annexed drawings, in which:
Unless otherwise specified, the compositions of the present description are mass percent compositions.
The invention concerns a timepiece component 1, notably a wheel set, which comprises a shaft-like portion 2, which includes at least one pivot 3 about a pivot axis D.
As regards the material of this shaft-like portion, it is preferable for it to have a Vickers hardness that is between that of a copper/beryllium alloy, 380 HV+/−20, and that of a 20AP steel or similar, 740 HV+/−30.
According to the invention, at least the material forming this shaft-like portion 2 is a non-magnetic alloy containing at least silver and palladium and having a Vickers hardness of more than 450 HV.
In a particular embodiment, component 1 is completely non-magnetic.
In a particular embodiment, shaft-like portion 2 runs through the entire length of component 1 in the direction of pivot axis D.
More particularly, shaft-like portion 2 carries at least one added element 4, 40, which is also non-magnetic. More particularly still, each added element 4, 40 is non-magnetic. More particularly still, the material forming each said added element 4, 40, is a non-magnetic alloy containing at least silver and palladium with a Vickers hardness of more than 450 HV.
In a particular embodiment, the material forming at least one, and more particularly each added element 4, 40, is the same as that which forms shaft-like portion 2.
In a variant, the material forming at least one added element 4, 40 is a ceramic.
In another variant, the material forming at least one added element 4, 40 is silicon and/or silicon dioxide, or a metallic glass or an amorphous or substantially amorphous metal, or suchlike, such as DLC (diamond-like-carbon) or otherwise.
In a particular composition, this non-magnetic alloy containing at least silver and palladium of shaft-like portion 2 contains, by mass, 50% to 60% palladium and 25% to 40% silver.
In another particular composition, this non-magnetic alloy containing at least silver and palladium of shaft-like portion 2 contains, by mass, 25% to 35% palladium and 65% to 75% silver, with a total by mass of at least silver and palladium less than or equal to 100%.
In another particular composition, this non-magnetic alloy containing at least silver and palladium of shaft portion 2 contains, by mass, at least 50% palladium or at least 80% silver, with a total by mass of the components of said alloy equal to 100%. The alloy can, in that case, be graded for fineness
In another particular composition, this non-magnetic alloy containing at least silver and palladium, of shaft-like portion 2, is a ternary alloy containing silver, palladium and copper, and contains, by mass, 20% to 50% palladium and 20% to 50% silver, and 20% to 40% copper, with a total by mass of silver, copper and palladium less than or equal to 100%. The copper has the effect of substantially increasing the hardness of the alloy.
In an advantageous variant, this non-magnetic ternary alloy contains, by mass, 36% to 40% palladium, 38% to 42% silver, 19% to 23% copper, with a total by mass of silver, palladium and copper less than or equal to 100%. It has a Vickers hardness of between 450 HV and 510 HV, and, more particularly, between 470 HV and 490 HV. This alloy therefore forms an advantageous material for any profile-turned timepiece component, since it has good machinability and its mechanical behaviour is close to that of steel. It is therefore more particularly suitable for non-magnetic wheel sets, or at least for non-magnetic wheel set arbors.
In a particular variant, the alloy containing at least silver and palladium is free of SVHC (Substances of Very High Concern), under annex 3 of the Swiss Chemicals Ordinance on Protection against Dangerous Substances and Preparations (ChemO), and annex 1.17 of the Ordinance on Reduction of Risks from Chemical Products (ORRChim) (substances listed in Annex XIV of REACH Regulation (EC) No 1907/2006).
In a particular variant, this non-magnetic alloy containing at least silver and palladium of shaft-like portion 2 has of modulus of elasticity of between 95 GPa and 105 GPa.
In a particular variant, this non-magnetic alloy containing at least silver and palladium of shaft-like portion 2 has a coefficient of expansion of between 14.10−6 and 17.10−6.
In a particular variant, this non-magnetic alloy containing at least silver and palladium of shaft-like portion 2 has a Poisson's ratio of between 0.35 and 0.39.
In a variant, this non-magnetic alloy containing at least silver and palladium contains, by mass, 0% to 2% indium, with a total by mass of the components of said alloy equal to 100%, to reinforce the alloy.
In a variant, this non-magnetic alloy containing at least silver and palladium contains, by mass, 0% to 2% tin, with a total by mass of the components of said alloy equal to 100%, to reinforce the alloy.
In a variant, this non-magnetic alloy containing at least silver and palladium contains, by mass, 0% to 2% platinum, more particularly 0% to 0.8% platinum, and more particularly still 0% to 0.5% platinum, with a total by mass of the components of said alloy equal to 100%,
In a variant only for uses inside the watch, this non-magnetic alloy containing at least silver and palladium contains, by mass, 0% to 1.0% nickel, with a total by mass of the components of said alloy equal to 100%.
In a variant, this non-magnetic alloy containing at least silver and palladium contains, by mass, 0% to 0.1% zinc, with a total by mass of the components of said alloy equal to 100%, to obtain greater strength and hardness.
In a variant, this non-magnetic alloy containing at least silver and palladium contains, by mass, 0.01% to 0.03% boron, with a total by mass of the components of said alloy equal to 100%, to obtain greater strength and hardness.
In a variant, this non-magnetic alloy containing at least silver and palladium contains, by mass, a total of less than or equal to 1% gold and/or platinum and/or ruthenium and/or rhenium, modifying agents, with a total by mass of the components of said alloy equal to 100%.
Thus, depending on the composition of the alloy, it is possible to obtain a hardness of close to 500 HV, or more than 500 HV.
In a particular case, as seen in
The choice of alloy makes it possible to produce a pivot-shank of very small diameter, notably less than 70 micrometres.
The invention also concerns a timepiece oscillator 100 comprising at least one such component 1.
The invention also concerns a timepiece movement 200 including at least one such oscillator 100, and/or at least one such component 1.
The invention also concerns a timepiece 1000 including at least one such movement 200, and/or at least one such oscillator 100, and/or at least one such component 1.
More particularly, this timepiece 1000 is a watch.
In short, the choice of a precious material, which may be graded for fineness, to make a timepiece wheel set arbor, goes against the prejudices related to the rapid wear of precious alloys. Choosing an alloy containing at least silver and palladium from among those described above, offers a surprising solution to the issue of wear, since these alloys show very little wear in normal conditions of use, while being non-magnetic as desired.
Naturally, although the above description mainly focused on embodiments of wheel sets with added elements, which reduces material cost, the use of these alloys containing at least silver and palladium for one-piece wheel sets is also entirely possible.
The invention provides a good solution to the still difficult problem of making non-magnetic wheel sets of small diameters, in particular for oscillator wheel sets, chronograph arbors, or otherwise.
Number | Date | Country | Kind |
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18182663 | Jul 2018 | EP | regional |
Number | Name | Date | Kind |
---|---|---|---|
20120112589 | Marechal et al. | May 2012 | A1 |
20140198624 | Von Gruenigen | Jul 2014 | A1 |
20150234361 | Marechal et al. | Aug 2015 | A1 |
20180024501 | Fussinger | Jan 2018 | A1 |
20180105902 | Kazama | Apr 2018 | A1 |
20180112292 | Vincent | Apr 2018 | A1 |
Number | Date | Country |
---|---|---|
712 762 | Jan 2018 | CH |
107632507 | Jan 2018 | CN |
107974570 | May 2018 | CN |
2 450 758 | May 2012 | EP |
2 757 424 | Aug 2014 | EP |
Entry |
---|
European Search Report dated Jan. 16, 2019 in European Application 1812663.7, filed on Jul. 10, 2018 (with English Translation of Categories of Documents). |
Combined Chinese Office Action and Search Report dated Oct. 13, 2020 in Patent Application No. 201910620260.1 (with English translation and English translation of Category of Documents), 12 pages. |
Number | Date | Country | |
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20200019122 A1 | Jan 2020 | US |