Claims
- 1. A contact lens colored over at least a portion of its surface, comprising a copolymeric hydrogel material to which at least one reactive dyestuff of the formula ##STR12## or ##STR13## wherein D is the radical of an organic dyestuff radical;
- R is a divalent organic electron attracting group capable of causing electron withdrawal of the C carbon atoms, thus activating the same;
- X is hydrogen or halo; and
- Y is leaving group; or mixtures thereof, is covalently bonded external to the polymer backbone by reaction at temperatures up to 60.degree. C. with hydroxyl, amino, amido or mercapto groups present in said polymer, over the colored portion of the lens.
- 2. A contact lens according to claim 1, wherein said reactive dyestuff is covalently bonded by nucleophilic addition to said hydroxyl, amino, amido or mercapto groups.
- 3. A contact lens according to claim 1, wherein said hydrogel material contains hydroxy groups in the polymer.
- 4. A contact lens according to claim 1, wherein D is the radical of an azo, phthalocyanine, azomethine, nitro or anthraquinone dye.
- 5. A contact lens according to claim 1, comprising a colored central portion and a clear annular edge.
- 6. A contact lens according to claim 1, wherein the colored portion thereof has a light transmission of 90% or less in a segment of the visible light range.
- 7. A contact lens according to claim 1 wherein the reactive dyestuff is bonded to the polymer backbone by reaction at temperatures up to 50.degree. C.
- 8. A process for preparing a contact lens colored over at least a portion of its surface, comprising reacting at temperatures up to 60.degree. C. at least one reactive dyestuff of the formula ##STR14## or ##STR15## wherein D is the radical of an organic dyestuff radical;
- R is a divalent organic electron attracting group capable of causing electron withdrawal of the C carbon atoms, thus activating the same;
- X is hydrogen or halo; and
- Y is a leaving group; or mixtures thereof with hydroxyl, amino, amido or mercapto groups present in the polymeric hydrogel contact lens material, and removing unreacted dyestuff from said lens material.
- 9. A process according to claim 8, wherein said lens material is in the form of a contact lens.
- 10. A process according to claim 9, wherein the reaction is conducted in an aqueous medium having a pH of at least 9 and at a temperature of up to 40.degree. C.
- 11. A process according to claim 9, wherein the reactive dyestuff is applied to only a portion of said lens.
- 12. A process according to claim 8, wherein said dyestuff reacts by nucleophilic addition to said hydroxyl, amino, amido or mercapto groups in the hydrogel material.
- 13. A process according to claim 8, wherein said hydrogel material contains hydroxy groups in the polymer.
- 14. The process according to claim 8 wherein the reactive dyestuff and the polymeric hydrogel contact lens material is reacted at temperatures up to 50.degree. C.
Parent Case Info
This application is a continuation-in-part of application Ser. No. 382,973 filed June 1, 1982, now U.S. Pat No. 4,468,229, which is a continuation-in-part of 292,325, filed Aug. 12, 1981, now abandoned.
US Referenced Citations (5)
Foreign Referenced Citations (4)
Number |
Date |
Country |
1004424 |
Sep 1965 |
GBX |
1163617 |
Sep 1969 |
GBX |
1547525 |
Jun 1979 |
GBX |
1583492 |
Jun 1981 |
GBX |
Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
382973 |
Jun 1982 |
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Parent |
292325 |
Aug 1981 |
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