Tire with silica-rich rubber tread for winter performance

Abstract

This invention relates to a tire having a tread intended for winter performance comprised cis 1,4-polybutadiene rubber (BR) and specialized solution polymerization prepared high vinyl styrene/butadiene rubber (HVS-SBR). Such tire tread is comprised of a compatible rubber blend of at least 40 phr of the BR in combination the HVS-SBR together with reinforcing filler composed of precipitated silica with a low BET nitrogen surface area and, optionally, rubber reinforcing carbon black. A disulfide silane based silica coupler is used to aid in coupling the precipitated silica to the elastomers. Compatibility of the combination of the BR with a relatively low glass transition temperature (Tg) of −100° C. or lower and the HVS-SBR with a relatively high Tg of at least 30° C. or higher, and therefore spaced apart Tg's of at least 70° C. is promoted by the high vinyl content of the HVS-SBR in a range of from about 40 to about 50 percent based upon its polybutadiene portion.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1, (FIG. 1), is presented to graphically illustrate Storage Modulus (G′) values as a function of temperature for Samples A through C.

FIG. 2, (FIG. 2), is presented to graphically illustrate tan delta values as a function of temperature for Samples A through C.

DETAILED DESCRIPTION OF THE DRAWINGS

For FIG. 1, a graphical presentation of Storage Modulus G′ versus Temperature, it is readily seen that the modulus increase at low temperature is higher (steeper curve) for Experimental Sample B but is lower (less steep curve) for Comparative Sample A.

This is considered herein to be significant in the sense of tire performance under winter conditions (e.g. snow and ice) being slightly worse for Experimental Sample B but better for Experimental Sample C.

For FIG. 2, a graphical presentation of tan delta versus Temperature, it is readily seen that the tan delta peak (maximum temperature) is similar for Comparative Sample A and Experimental Sample C but slightly higher for Experimental Sample B.

This is considered herein to be significant for tire performance in the sense that it is indicative of similar winter performance for Comparative Sample A and Experimental Sample C, but slightly inferior winter performance for Experimental Sample B, for a tire having a tread of the respective rubber compositions.

Further, it can be seen that the tan delta at lower temperatures, namely from about −95° C. to about −70° C., is relatively high for Experimental Samples B and C versus Comparative Sample A which is indicative of a relatively good resistance to tread wear potential for Experimental Samples B and C.

Further, it can be seen that the tan delta values at the higher temperatures, namely from about −30° C. to about 0° C., is relatively high for Experimental Samples B and C versus Comparative Sample A which is indicative of good wet performance (e.g. traction) for a tire having a tread of the respective rubber compositions.

Therefore, it is considered herein that an improved balance of wet traction and winter performance is provided for a tire having a tread of the Experimental Sample C rubber composition.

EXAMPLE II

A tires are individually prepared with a circumferential tread of the rubber composition of experimental Sample B and experimental Sample C and identified herein as Tire B and Tire C, respectively.

The tires were individually tested for wet traction and winter handling, the results of which are reported herein in Table 3, with the properties for Tire B being normalized to a value of 100 and the properties for Tire C reported on a comparison basis to normalized values for the Control Tire B.

	TABLE 3
	Property	Tire B	Tire C
	Wet traction	100	100
	Snow handling	100	106

From Table 3 it can be seen that while experimental Tire C exhibited wet traction similar to experimental Tire B, experimental Tire C exhibited significantly better snow handling than Tire B.

While various embodiments are disclosed herein for practicing the invention, it will be apparent to those skilled in this art that various changes and modifications may be made therein without departing from the spirit or scope of the invention.

Claims

1. A tire having a circumferential tread of a rubber composition which comprises, based on parts by weight per 100 parts by weight of rubber (phr): (A) 100 phr of elastomers comprised of (1) about 48 to about 60 phr of a specialized solution polymerization prepared styrene/butadiene copolymer rubber (HVS-SBR) having an onset Tg in a range of from about −28° C. to about −23° C., a bound styrene content in a range of about 23 to about 31 percent and a vinyl 1,2-content of from about 40 to about 50 percent,(2) about 60 to about 40 phr of cis 1,4-polybutadiene rubber (BR) having an onset Tg (ASTMD 3418) in a range of from about −100° C. to about −110° C. and a cis 1,4-isometric content in a range of from about 93 to about 100 percent, and, optionally,(3) from zero to about 20 phr of an additional rubber selected from polymers and copolymers of at least one of isoprene and 1,3-butadiene and copolymers of styrene and at least one of isoprene and 1,3-butadiene.(B) about 95 to about 110 phr of particulate reinforcing filler comprised of: (1) about 90 to about 105 phr of synthetic amorphous precipitated silica having a BET surface area in a range of from about 100 to about 135 m2/g, and(2) from 5 to about 15 phr of high structure rubber reinforcing carbon black having a DBP value in a range of from about 100 to about 140 cc/100 g in combination with an Iodine value in a range of from about 115 to about 185 g/kg; and(C) at least one silica coupling agent having a moiety reactive with hydroxyl groups on the surface of the said precipitated silica and an additional moiety interactive with the said rubbers.

2. The tire of claim 1 wherein said coupling agent is a bis(3-triethoxysilylpropyl) polysulfide containing an average of from about 2 to about 2.6 connecting sulfur atoms in its polysulfide bridge.

3. (canceled)

4. (canceled)

5. The tire of claim 1 wherein said additional rubbers are conjugated diene-based elastomers selected from at least one of cis 1,4-polyisoprene rubber, high vinyl polybutadiene having a vinyl 1,2 content in a range of about 30 to about 90 percent, styrene/butadiene copolymers (SBR) other than said HVS-SBR, styrene/isoprene/butadiene terpolymers, isoprene/butadiene copolymers, isoprene/styrene copolymers, acrylonitrile/butadiene copolymers and acrylonitrile/butadiene/styrene terpolymers.