The present invention relates to a titanium alloy part such as a titanium alloy spring, and a method for producing the same.
As compared to iron, titanium excels in physical properties which are important to any structural or functional part (or member) of a mechanical apparatus. Specifically, titanium has a lower density than that of iron, and has high strengths (e.g., tensile strength) relative to its specific gravity. Moreover, titanium has a Young's modulus which is about half of that of iron, and thus shows excellent elastic characteristics. Therefore, a structural or functional part which has a light weight, a high strength, and a good elasticity can be formed from titanium. A titanium alloy which is composed by adding various elements to titanium can have further improved characteristics.
In spite of such advantages, structural or functional parts composed of titanium or titanium alloys have only been used for specific applications such as aircraft or golf club shafts. The reason is that, conventionally, titanium and titanium alloys can only be produced at a higher cost than that of iron.
In recent years, however, methods for producing titanium alloys at lower costs have been developed, so that cost-related constraints on using titanium alloys as structural or functional parts are being relaxed. Therefore, studies have been directed to using titanium alloys in products in various fields by taking advantage of the aforementioned superior characteristics of titanium.
In particular, when a spring is composed of a titanium alloy (hereinafter, such a spring will be referred to as a “titanium alloy spring”), the weight per unit length of wire material composing the spring can be reduced due to the low density of titanium. The small Young's modulus makes it possible to reduce the number of turns made in the spring, and reduce the spring height and the total length of the wire material for the spring which are necessary for obtaining a given amount of contraction and expansion. Therefore, a titanium alloy spring can have a weight which is reduced by about 60% from that of a steel spring which has similar levels of functionalities. By using such light-weight springs for suspensions of a vehicle, the total weight of the vehicle can be reduced, and vibrations can be dampened quickly, whereby the vehicle running properties can be enhanced.
Conventionally, when producing a steel spring, objects (called “shot medium”) such as cut wires of steel or cast steel balls are shot against the surface of the spring to cause plastic deformation of the surface, thus creating a compressive stress in the interior of the spring near the surface, whereby the durability of the spring is improved. This treatment is called “shot peening”. In the case where a compressive stress has been created near the surface of the spring, even if a flaw is formed in the surface, the compressive stress will act in a direction which does not allow the flaw to expand. As a result, the flaw is prevented from expanding and causing destruction of the spring.
Also when producing a spring composed of a titanium alloy, shot peening is known to realize an improved durability, as is disclosed in Japanese Laid-Open Patent Publication No. 5-195175 and Japanese Laid-Open Patent Publication No. 5-112857.
However, a study conducted by the inventors of the present invention has shown that the shot peening conditions which are disclosed in the aforementioned publications do not actually guarantee that a spring having a sufficient durability, especially a sufficient fatigue strength, will be obtained.
In order to overcome the problems described above, preferred embodiments of the present invention provide a titanium alloy part having an excellent durability, and a method for producing the same.
A titanium alloy part according to a preferred embodiment of the present invention has a compressive stress of approximately 270 MPa or more within a depth of about 100 μm from a surface thereof. Herein, the compressive stress is a measurement result of residual stress by an X-ray technique using a V tube.
In a preferred embodiment, the titanium alloy part includes a surface region extending from the surface to a depth of about 100 μm, and an internal region located internal relative to the surface region, wherein the surface region includes a modified layer containing more a phase than does the internal region, the modified layer accounting for a proportion of about 10 vol % or less of the surface region.
In a preferred embodiment, the surface has a maximum surface roughness Rt of about 20 μm or less.
In a preferred embodiment, the titanium alloy part contains about 50 vol % or more of β phase at room temperature.
In a preferred embodiment, the titanium alloy part is a spring.
In a preferred embodiment, the titanium alloy part is a suspension spring for a vehicle.
In a preferred embodiment, the titanium alloy part is one selected from the group consisting of a valve spring for an engine, a connecting rod for an engine, and a structural part for an aircraft.
An engine according to the present invention includes a titanium alloy part having the aforementioned configuration.
A vehicle according to the present invention includes a titanium alloy part having the aforementioned configuration.
A method for producing a titanium alloy part according to another preferred embodiment of the present invention includes a step (A) of providing a shaped titanium alloy part, a step (B) of subjecting the shaped titanium alloy part to a shot peening using a first shot medium, and a step (C) of mechanically or physically removing at least a part of a modified layer created in a surface region of the shaped titanium alloy part as a result of step (B).
In a preferred embodiment, step (C) includes shooting a second shot medium against a surface of the shaped titanium alloy part, the second shot medium having a higher hardness than that of the first shot medium.
In a preferred embodiment, the second shot medium has a Vickers hardness of about 1,000 or more.
In a preferred embodiment, the second shot medium contains SiO2.
In a preferred embodiment, step (C) removes the shaped titanium alloy part at a depth of about 20 μm to about 40 μm from the surface.
In a preferred embodiment, the shaped titanium alloy part has a Vickers hardness of about 370 to about 470.
In a preferred embodiment, step (A) includes a step (A1) of winding around a wire material of a titanium alloy to obtain a shaped titanium alloy part having a coil shape, and a step (A2) of subjecting the shaped titanium alloy part to an aging treatment.
In a preferred embodiment, step (B) includes shooting the first shot medium against the shaped titanium alloy part via centrifugal force, compressed air, or hydraulic pressure.
A titanium alloy part according to the present invention hardly includes any modified layer in which defects which could serve as starting points of destruction exist, and a compressive stress exists in the area of the surface of the titanium alloy part. As a result, the titanium alloy part of the present invention exhibits a high fatigue strength.
Other features, elements, processes, steps, characteristics and advantages of the present invention will become more apparent from the following detailed description of preferred embodiments of the present invention with reference to the attached drawings.
In order to ascertain the reason why a sufficient fatigue strength cannot be obtained even if the conventionally-practiced shot peening is performed for a titanium alloy spring, the inventors have examined cross sections of titanium alloy springs.
As can be seen from a comparison between
A titanium alloy has a hexagonal close-packed (HCP) structure at room temperature. However, when the titanium alloy is placed within an environment that is at a temperature of 885° C. or more, or if the titanium alloy includes Mo, V, Nb, Ta, and the like as alloying elements, the titanium alloy has a body-centered cubic (BCC) structure. The HCP structure and the BCC structure are also referred to as the a phase and the β phase, respectively. An alloy which takes a BCC structure at room temperature is called a β alloy. Since the β phase generally offers good processibility, titanium alloy springs are generally composed of a β alloy.
In the case where a shot medium is shot against the surface of a titanium alloy spring, the kinetic energy of the shot medium is consumed when dents are formed on the spring surface, or consumed during heating of the spring surface. The inventors' analysis has shown that, due to the energy (deformation and heat) applied through the shot peening, the β phase has transitioned to the a phase in the modified layer 2, so that most of the resultant modified layer 2 is constituted by the a phase, i.e., the HCP structure. The modified layer 2 has a thickness of about 20 μm to about 40 μm. A region 1 which is located farther inward in the modified layer 2 is not affected by the heat, and therefore is constituted by the β phase or an alloy which abounds in the B phase. In other words, the modified layer 2 contains more α phase than does the region 1.
A fatigue test was performed for the titanium alloy spring shown in
The above-described information has led to the inventive concept that, by removing the modified layer 2, defects 3 that might serve as starting points of rupture can be removed, and yet a region 1 having a relatively large residual compressive stress can be provided in the area of the surface. As a result, the fatigue strength of the titanium alloy spring will be improved by taking advantage of the compressive stress of the area of the spring surface.
Hereinafter, a titanium alloy part according to preferred embodiments of the present invention and a method for producing the same will be specifically described.
Through detailed studies, the inventors have experimentally confirmed that the titanium alloy part 10 acquires an improved fatigue strength based on the presence of a compressive stress of approximately 270 MPa or more in a region at a depth no more than about 100 μm from the surface 11a of the titanium alloy part 10 (i.e., the surface region 11b). However, when taking the yield point of the titanium alloy part 10 into consideration, it is preferable that the compressive stress is about 1,100 MPa or less. As used herein, “stress” refers to a residual stress with respect to the β phase of the titanium alloy part 10, as measured by an X-ray technique using a V tube. However, a stress value as measured by an X-ray technique does not coincide with a value as measured by a strain gauge technique, which is a commonly-used stress measurement technique. Therefore, each stress value as measured by an X-ray technique is certified by using a strain gauge technique, and the stress value as measured by the X-ray technique is corrected based on the certification.
The profile of
It should be noted that the surface region 11b, which refers to the region at a depth no more than about 100 μm from the surface 11s of the titanium alloy part 10, is only distinguishable in the context of defining the compressive stress in the area of the surface. In other words, there is no actual distinction in composition or physical properties between the surface region 11b and the internal region 11a. In the example shown in
It is preferable that the entirety 11 (including the surface region 11b and the internal region 11a) of the titanium alloy part 10 contains approximately 50 vol % or more of the β phase. In fact, the entirety 11 of the titanium alloy part 10 may altogether be composed of the β phase. In other words, the titanium alloy part 10 may be composed of an α+β alloy containing approximately 50 vol % or more of the β phase, or composed of a β alloy. Such-an alloy preferably contains at least one or more element selected from among Al, Fe, Mo, Sn, V, Zr, Si, Cr, Nb, O, and the like. Typical exemplary compositions include: Ti-1.5Al-4.5Fe-6.8Mo-0.15O; Ti-13V-11Cr-3Al; Ti-8Mo-8V-2Fe-3Al; Ti-3Al-8V-6Cr-4Mo-4Zr; Ti-11.5Mo-6Zr-4.5Sn: Ti-15Mo-5Zr; and Ti-15Mo-5Zr-3Al.
As mentioned earlier, it is preferable that the modified layer emerging from the shot peening treatment is removed so that the surface region 11b contains no modified layer at all. Note however that, when a modified layer remains in the surface region 11a at a proportion of about 10 volt or less, the defects 3 which are a cause of stress concentration are almost entirely eliminated from the titanium alloy part 10, whereby the titanium alloy part 10 acquires a high fatigue strength.
It is preferable that the surface 11s of the titanium alloy part 10 has a maximum surface roughness Rt of about 20 μm or less. By making the surface 11s smooth, the stress concentration on the surface 11s can be alleviated, thus preventing the rupturing of the titanium alloy part 10 due to fatigue. In particular, if the surface 11s includes even a single rough portion, stress will concentrate in that portion. Therefore, by prescribing the aforementioned range of maximum surface roughness, a further prevention and minimization of stress concentration can be expected in addition to removing the modified layer.
Next, with reference to
First, a wire material for constructing a spring is prepared (step 21). In advance, the wire material is subjected to a cold wiredrawing process or the like so as to have a desired diameter. As the wire material, among those titanium alloy materials mentioned above, a β alloy or an α+β alloy having relatively a little a phase component is preferably used for good processibility. The prepared wire material is processed into a desired shape by a shaping method such as a coiling process (i.e., wound around), whereby a shaped titanium alloy part, which in this case is a shaped spring, is obtained (step 22). Thereafter, the shaped spring is subjected to an aging treatment (step 23).
Next, a shot peening treatment for generating a compressive stress in the area of the surface of the shaped spring is performed (step 24). As shown in
Next, the modified layer 30b is removed (step 25 in
In the case where the modified layer 30b is mechanically removed, it is preferable to remove the modified layer 30b by performing a shot peening using a shot medium which has a small grain size. Since a titanium alloy generally has a Vickers hardness of about 370 to about 470, it is preferable to use a shot medium which has a higher hardness than these values and provides good abrasive ability. For example, it is preferable to use an SiO2 shot medium having a specific gravity of about 2.5, a Vickers hardness of about 1,000, and an average grain size of about 50 μm or less. Due to the small grain size and the small specific gravity, such a shot medium does not apply a large energy at collision. Therefore, the shot medium will not form any new dents in the surface of the spring 30 by being shot, but is capable of applying a certain level of stress to the internal region 30a at collision. Moreover, an SiO2 shot medium is considered to have a high abrasive ability because of having a high hardness in spite of its spherical shape. On the other hand, the shot medium (e.g., cast steel) which is used in the first shot peening has a lower hardness than that of a shot medium composed of SiO2. Therefore, during the shot peening, the titanium alloy part only undergoes plastic deformation, and hardly any abrasion of the modified layer 30b and the internal region 30a occurs.
As shown in
From the titanium alloy spring produced in this manner, a modified layer containing defects which might serve as starting points of destruction has been removed, so that a compressive stress exists in the area of the spring surface. Since the spring surface has a small surface roughness, stress concentration is alleviated. As a result, the titanium alloy spring exhibits a high fatigue strength.
The above-described preferred embodiment illustrates the titanium alloy part of the present invention as a spring. A titanium alloy spring according to preferred embodiments of the present invention can be suitably used as a suspension spring for a vehicle, e.g., a two-wheeled vehicle or a four-wheeled vehicle. Moreover, the titanium alloy spring of preferred embodiments of the present invention is also suitable as a valve spring for an engine. Due to its excellent fatigue strength, a titanium alloy part according to preferred embodiments of the present invention is also suitably used for any elastic part or structural part, other than a spring, which is subjected to repetitive stress. For example, a titanium alloy part according to preferred embodiments of the present invention is also suitably used as a connecting rod for connecting a piston and a crankshaft of an engine, an engine valve, or a structural part for aircraft.
Hereinafter, some evaluation results of the characteristics of a titanium alloy part which was produced according to preferred embodiments of the present invention will be described. In the example below, a suspension spring (coil diameter: about 100 mm; height: about 150 mm) for a two-wheeled vehicle was produced from a wire (diameter: about 12 mm) which was composed of a titanium alloy whose composition was Ti-1.5Al-4.5Fe-6.8Mo-0.15O.
After subjecting this spring to an aging treatment at 520° C. for 3 hours, a shot peening treatment and a removal of the modified layer were performed under the following conditions. As a comparative example, a spring was produced through a similar procedure, but was only subjected to a shot peening treatment. In the present example of the invention, the shot peening treatment is performed twice, by using a different shot medium each time, in order to apply an internal stress in a more uniform manner.
As seen from
On the other hand, in Comparative Example, a gradually compressive stress occurs from the surface, such that a compressive stress of about 310 MPa exists at a depth of about 200 μm. At deeper positions, the compressive stress is gradually alleviated, and a constant value of approximately 260 MPa is maintained in any region deeper than about 400 μm.
As seen from
Thus, as compared to the spring of Comparative Example, the spring of preferred embodiments of the present invention is characterized in that the modified layer is substantially completely removed so that the surface is free of defects; the spring surface has a small surface roughness; and a compressive stress exists with a drastic profile beginning from the surface thereof. Such characteristics presumably contribute to the improved fatigue strength.
Table 2 shows results of durability evaluation tests which were performed while varying the maximum compressive stress within a depth of about 100 μm from the surface. As seen from Table 2, excellent durability is obtained by introducing a compressive stress of approximately 270 MPa or more within a depth of about 100 μm from the surface.
◯: good
X: bad
The motorcycle 100 includes a head pipe 102 attached to the front end of the body frame 101. To the head pipe 102, a front fork 103 is attached so as to be capable of swinging in the right-left direction of the vehicle. At the lower end of the front fork 103, a front wheel 104 is supported so as to be capable of rotating.
A seat rail 106 is attached at an upper portion of the rear end of the body frame 101 so as to extend in the rear direction. A seat 107 is provided on the seat rail 106.
At a central portion of the body frame 101, an engine (internal combustion engine) 109 is held. An exhaust pipe 110 is connected to an exhaust port of the engine 109, and a muffler 111 is attached to the rear end of the exhaust pipe 110.
A pair of rear arms 113 extending in the rear direction are attached to the rear end of the body frame 101. The rear arms 113 are pivoted by a seat pillar 114. At the rear end of the rear arms 113, a rear wheel 115 is supported so as to be capable of rotating.
The rear arm 113 which is provided on the left side of the motorcycle 100 and the rear arm (not shown) which is provided on the right side of the motorcycle 100 are connected to each other via a connection part 116 extending along the width direction of the vehicle.
The connection part 116 is linked to the seat rail 106 via a shock absorber 120, such that the rear arms 113 and the rear wheel 115 are suspended from the body via the shock absorber 120.
The motorcycle 100 can attain preferable performance because of incorporating a titanium alloy spring according to preferred embodiments of the present invention, which provides excellent fatigue strength, as the spring 122 of the shock absorber 120.
The illustrated motorcycle 100 incorporates a titanium alloy spring according to preferred embodiments of the present invention as a suspension spring. Alternatively, the titanium alloy spring according to preferred embodiments of the present invention can be implemented as a valve spring for an engine to also provide preferable performance. Alternatively, the titanium alloy part according to preferred embodiments of the present invention may be implemented as a connecting rod for an engine to also provide preferable performance. The suspension spring, the valve spring for an engine, the connecting rod, e.g., as such may be collectively referred to as “parts for an internal combustion engine”.
A titanium alloy part according to preferred embodiments of the present invention and a method for producing the same can be applied to various fields, such as elastic parts (e.g., springs) and structural parts in general. In particular, the titanium alloy part according to preferred embodiments of the present invention is light in weight and yet has a high strength and high durability, and therefore can be suitably used in fields such as transportation apparatuses (e.g., vehicles and aircraft), and architecture.
It should be understood that the foregoing description is only illustrative of the present invention. Various alternatives and modifications can be devised by those skilled in the art without departing from the present invention. Accordingly, the present invention is intended to embrace all such alternatives, modifications and variances which fall within the scope of the appended claims.
Number | Date | Country | Kind |
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2004-172183 | Jun 2004 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP05/10639 | 6/3/2005 | WO | 1/11/2006 |