Titanium slag-coke granules suitable for fluid bed chlorination

This invention relates to a process for producing a material suitable for manufacturing titanium pigment via chloride process. More particularly, this invention relates to a process whereby starting from relatively low TiO.sub.2 bearing materials, more specifically from slags containing relatively high amounts of undesirable alkali-earth elements, and which are rich in silica and alumina as well, a material is produced which is suitable for obtaining titanium pigment, by further processing.
Still further, this invention relates to a process for producing a material containing both TiO.sub.2 and carbon in unique granules suitable for fluid bed chlorination of these granules.
BACKGROUND OF THE INVENTION AND GENERAL DESCRIPTION OF PRIOR ART
In the well known electro-smelting process of ilmenite, metallic iron and a slag enriched in TiO.sub.2 is produced. Such slags are especially appreciated by the TiO.sub.2 pigment producers using the sulfate process route. A typical analysis of these slags is:
______________________________________ TiO.sub.2 71.0% FeO 11.8% SiO.sub.2 5.2% Al.sub.2 O.sub.3 5.5% CaO 0.8% MgO 5.1% V.sub.2 O.sub.5 0.58% Cr.sub.2 O.sub.3 0.18% MnO 0.24%______________________________________
However, because of the impurities contained in these slags, these slags are not generally accepted by the chloride process TiO.sub.2 pigment producers. To be suitable for the latter process, a slag must have essentially a low CaO and a low MgO content and secondarily a low Al.sub.2 O.sub.3 and SiO.sub.2 content. Typically, these constituents are found in the following ranges when suitable as a starting material in the chloride process:
______________________________________CaO from 0.0 to 0.2 in weight percentMgO from 0.0 to 1.0 in weight percentAl.sub.2 O.sub.3 from 0.0 to 1.0 in weight percentSiO.sub.2 from 0.0 to 1.5 in weight percent______________________________________
The undesirable impurities CaO and MgO are unwanted because these generate high boiling point chlorides in the process. These chlorides tend to accumulate in the fluidized bed used in the chloride process and, under operating conditions, remain in a molten form causing lower chlorination rate, bed sticking and defluidization.
The two other impurities mentioned above, namely Al.sub.2 O.sub.3 and SiO.sub.2, are essentially high chlorine gas consumers which increase the cost for producing TiO.sub.2 pigment and complicate the purification of TiCl.sub.4 as well as aggravate scrubbing problems of the TiCl.sub.4 distillation residues.
In other TiO.sub.2 source materials, including slags, depending on the origin of the ore, MnO could also be present. Manganese oxide is easier to distill from the reaction mixture than MgCl.sub.2 and CaCl.sub.2, however, it is also undesirable in large amounts.
The chloride process to produce titanium is based on the intermediate formation of titanium tetrachloride according to the following equation:
TiO.sub.2 +2C+2Cl.sub.2 .fwdarw.TiCl.sub.4 +2CO (or CO.sub.2)
The preferred raw material is natural or artificial rutile, the latter being manufactured from ilmenite by various processes.
Ilmenite is also widely used as a raw material for TiO.sub.2 pigment production. In the chlorination process, impurities associated with ilmenite, principally iron, cause the formation of large amounts of iron chlorides as either ferrous or ferric chlorides. The chlorides must be disposed of or processed for chlorine recycling.
Several processes for chlorination of high alkali-earth slags have been tried or proposed. The only one which heretofore has been effectively used involved the blending of a slag, such as Sorelslag, either with rutile or ilmenite with low CaO and MgO content. Such practice implies a source of these feeds and does not solve the problems mentioned above.
Another approach for avoiding the problem plagued use of slag consists of making briquets of slag and carbonaceous material. This is an impractical process because it necessitates batch operation. Still other processes have been operated at higher temperature in a fluid bed eventually with an excess of chlorine, such as disclosed in U.S. Pat. No. 2,974,009, and in presence of excess of carbon which must be continuously discharged, such as disclosed in U.S. Pat. No. 3,074,777, as well as where the starting material is washed before recycling including any unreacted material associated therewith (described in U.S. Pat. No. 2,701,180). Still another proposal has been to use a new reactor to produce flash chlorination of these slags such as disclosed in U.S. Pat. No. 3,787,556.
In absence of an oxygen acceptor, the chlorination rate of titanium dioxide is very low even at tempteratures as high as 1000.degree. C. In presence of an oxygen acceptor, e.g., carbon, the reaction proceeds already at temperatures as low as 500.degree. C. Two different mechanisms are involved in the temperature ranges of 500.degree.-800.degree. C. and above 900.degree. C. as further amplified. At low temperatures, good contact between TiO.sub.2 and carbon is necessary to get the reaction started while at high temperature a close contact is not imperative. Based on these facts, the briquetting process and also pelletizing and shaft furnace chlorination with continuous discharge of the unreacted material, such as disclosed in U.S. Pat. No. 3,359,065, does permit a low temperature reaction.
The reducing agent, so-called oxygen acceptor, generally employed in actual chlorinators is petroleum coke which is also a high cost material. In the present invention the carbon source is pyrolyzed bituminous coal which is less expensive than petroleum coke.

BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a graph showing the effect of particle size of fluidization.
FIG. 2 is a chlorination thermogravimetric curve of -28+48 mesh slag: coke granules.
FIG. 3 shows the temperature dependence of the rate of TiCl.sub.4 formation.

DESCRIPTION OF THE INVENTION AND DISCLOSURE OF EMBODIMENTS THEREOF
In accordance with this invention, the use of a slag for a starting material suitable for use in a chloride process and derived from a source such as ilmenite is an embodiment of this invention when these slags are processed to be suitable as intermediates. As there are upgraded ilmenites, but not as rich in titanium value as rutile, various degrees of upgrading are within the scope of the invention. However, the ilmenite feed to a smelter in which iron is extracted and a TiO.sub.2 slag is obtained should be at least low in CaO, MgO and MnO for the above mentioned reasons to be suitable for chlorination purposes.
A titanium slag commercially produced is known as "Sorelslag" and this slag contains high amounts of CaO, MgO, SiO.sub.2, and Al.sub.2 O.sub.3. Typically, these are 0.8; 5.1; 5.2 and 5.5 percent by weight, respectively. The purpose of this invention is to utilize this slag and to provide a process to use Sorelslag and similar titanium bearing materials as starting material for the chloride process route for making TiO.sub.2 pigment.
According to the present invention, however, it is possible to use the above described difference in the chlorination mechanisms to chlorinate titanium slags which are high in CaO and MgO contents in a fluid bed, and moreover, without a need for a continuous discharge at the bottom or on the side of the reactor while the reactor is operated under mild and not severe conditions for the reactor. By mild reactor conditions, it is meant temperature in the 600.degree.-800.degree. C. range compare to 950.degree.-1100.degree. C. in other reactors. No bed sticking occurs and the high chlorine consumers, i.e., Al.sub.2 O.sub.3 and SiO.sub.2, are only very slightly or not at all attacked. This results in significant chlorine savings.
According to the present invention, a titanium bearing compound and especially titania slag is to be ground to a very fine powder, then mixed in a proper ratio with a bituminous coking coal also in powdery form. A suitable binder can be added during the mixing. The slag-coal mixture is then pelletized into small grains, e.g., of a size from -28 to +100 mesh, the "green" grains are later heated up to 500.degree. C. at least for a few seconds in order to form a coke structure and these grains are further baked at 900.degree.-1000.degree. C. for 10 to 20 minutes to lower the hydrogen content as far as possible (initially at about 2.0% of the initial dry weight to 0.2% of the weight of the coked grain). The grains are cooled down in inert atmosphere or discharged in water. The removal of hydrogen is for the purpose of decreasing the chlorine consumption due to possible HCl formation.
The resulting grains having a suitable size (e.g., from -28 to +100 mesh) for fluidization are then chlorinated in a conventional fluid bed at about 700.degree. C. in a continuous system. A conventional fluid bed is disclosed in U.S. Pat. No. 3,957,757. The porous coke structure with high surface area retains the low volatility chlorides, i.e., CaCl.sub.2 and MgCl.sub.2, present in a molten state.
As the reaction proceeds, the grains become lighter and their fluidization property changes. At the same time, the surface of the grains abrades forming a TiO.sub.2 -free dry dust which is evacuated in the gas stream. As the pores are quite large, (of the order of 1 to 50 microns) the chlorine has no difficulty in diffusing into the core of the grains generating TiCl.sub.4 with the carbon evenly distributed within a grain. Finally, the carbon skeleton, reinforced by the unreacted silica and alumina, impregnated by CaCl.sub.2 and MgCl.sub.2 and almost free of titanium oxide is evacuated with the chloride vapors and CO.sub.2 generated in the process and is easily collected and separated. The excess carbon may be recovered after washing with water, the carbon skeleton including the trapped chlorides. The TiCl.sub.4 is later treated as usual.
A source material of titanium oxide having the above described high alkali-earth, alkali, silica, alumina or manganese content are such as: Sorelslag, brazilian anatase, rock ilmenites, perovskite, etc. A high content of alkali-earth, alkali, silica, alumina, or manganese in said source material is meant wherein individually these components are present in percent by weight of at least 1% alkali earth, 1% alkali, 3% silica, 3% alumina, 1% manganese, respectively.
The following example illustrates the practice of the invention; it is not intended to limit the invention, but merely illustrate the invention.
EXAMPLE
A titanium slag of the following composition (in percent by weight):
______________________________________TiO.sub.2 FeO SiO.sub.2 Al.sub.2 O.sub.3 Cr.sub.2 O.sub.3 V.sub.2 O.sub.5 CaO MgO______________________________________71.0 11.8 5.2 5.5 0.18 0.58 0.8 5.1______________________________________
was ground to 99 percent, -325 mesh.
A bituminous coal of the following analysis (in percent by weight).
______________________________________Moisture Ash Fixed Carbon Volatiles______________________________________0.24 5.70 62.00 32.30______________________________________
was 100 percent ball milled to -325 mesh.
A 2:1 ratio of slag:coal was mixed for 1 hour after mixing with a percent by weight of the dry solid of a solution of a binder chosen from the following compounds used as binders: ferrous chloride, sodium sulfite, starch, glue, molasses, sugar, bentonite, sulfuric acid, spent liquor from TiO.sub.2 pigment plant, or Lignosol (Lignosol is cellulose sulfonate). The amount of binder may vary from 0.25 to 1.00% by the dry weight of coal+slag.
The so obtained homogeneous mixture was pelletized in a 14" pelletizing disk running at 45 r.p.m. at a 42.degree. angle using a batch operation and a water spray. The disk was stopped when most of the granules or pellets seemed to have grown to the desired particle size. A desirable particle size is from 8 to 150 mesh, preferably from 28 to 100 mesh. The final moisture content was about 13 percent of weight of the pellets.
The pellets were partially dried in a pan on a hot plate and screened in order to separate the desired sizes. The fines were repelletized while the coarse particles were desaggregated before recycling.
The partially dried pellets (still containing about 5 percent by weight of water) were introduced in a hot tube furnace and baked for 20 minutes at 920.degree.-940.degree. C. in a nitrogen atmosphere, then cooled down to room temperature under nitrogen atmosphere. In general, the amount of TiO.sub.2 to carbon in the coked particles (pellets) are 40 to 60 percent by weight TiO.sub.2, and 15 to 20 percent by weight carbon.
The resulting coked pellets were separated from each other very easily when touched. The hydrogen content was less than 0.2 percent by weight.
The strength of the pellets after coking varied widely from one binder to the other and with the amount of binder, however, suitable strength after coking, should be maintained within a range from 100 to 2000, preferably from 300 to 600 g/mmD.
Table I illustrates the effect of binder on the particle strength and eventually abradability (percent by weight carry over per hour).
TABLE I______________________________________Effect of binder on strength and abradability ofcoked particles (in grams referred to 1 mm diameter sizegranules). % Binder StrengthTest Binder By Weight g/mmD* Abradability**______________________________________1 FeCl.sub.2 1.0 50 3.942 Na.sub.2 SO.sub.3 1.4 1600 Not determined3 Na.sub.2 SO.sub.3 0.6 1875 Not determined4 Na.sub.2 SO.sub.4 0.5 1135 Not determined5 Lignosol 1.0 608 0.846 Lignosol 0.5 378 0.277 Lignosol 0.25 308 0.13______________________________________ *D = diameter size of grains expressed as 1 mm for strength calculation. **Abradability is defined as percentage by weight carryover per hour from the fluid bed.
The strength of the granules followed the empirical formula
F=S.D.sup.1.155
where:
F is the force in grams necessary to break the granules
D is the diameter
S is the constant strength in grams per one mm of diameter.
From tests 5, 6, and 7 in the Table I, it is evident that the amount of binder has a reverse effect on strength versus abradability. Hence, generally a binder is used in proportions, based on slag and coal, taken as 1 (unit) from 0.002 to 0.010.
The effect of slag:coal ratio has been tested. Pellets with good strength were obtained with a ratio of 2:1, a broader proportional relationship is from 2.5:1 to 1.5:1.
The Table II shows the bulk densities of the coked pellets.
TABLE II__________________________________________________________________________Bulk Density of Coked PelletsParticle Size Distribution in % Bulk DensityTest -20+28 -28+48 -48+65 -65+100 -100 (mesh) g/cc lb/cu.ft.__________________________________________________________________________A 15.3 64.6 11.2 7.3 1.5 1.000 62.43B 11.7 62.5 13.7 10.3 1.8 0.915 57.12C 5.5 62.0 16.1 13.1 3.15 0.905 56.50__________________________________________________________________________
The fluidization characteristics of the same granules as in Table II are shown in Table III measured for a 2" diameter fluid bed.
TABLE III______________________________________Fluidization CharacteristicsCoked Pellets Min. Fluid Flow Temper- SCFH.sup.+ Gmf.sup.++ Gas Veloxity(N.sub.2)Test ature (Nitrogen) lb.ft.-2hr-1 ft.sec.-1______________________________________A Room 60 105.2 0.766 710.degree. C. 3.6 6.32 0.046* 0.159**B Room 50 87.8 0.649C Room 45 78.0 0.575______________________________________ *Referred to volume measured at room temperature. **With a temperature correction taking account of gas expansion at 710.degree. C. .sup.+ SCFH = Standard cubic foot per hour of nitrogen (at 72.degree. F.) .sup.++ GMF = Minimum fluidizing mass velocity, i. e., minimum mass of ga required per unit time to fluidize the grains.
From the above data and further data, a graph has been drawn as illustrated in FIG. 1, which shows the effect of particle size on fluidization at 710.degree. C. Further, a graph has been illustrated as shown in FIG. 2 which represents a thermogravimetric curve for chlorination of -28+48 mesh slag:coke (2:1 ratio) which shows that the reaction proceeds in several stages:
weight gain from 300.degree.-400.degree. C. due to non-volatile chloride formation mainly FeCl.sub.2.
strong reaction from 450.degree.-600.degree. C. mainly due to TiCl.sub.4 formation.
Al.sub.2 O.sub.3 and SiO.sub.2 chlorination from 800.degree.-900.degree. C.
MgCl.sub.2 distillation above 950.degree. C.
With reference to FIG. 3, it shows the temperature dependence of the rate of the main reaction (TiCl.sub.4 formation) which shows a relatively small change in terms of the low activation energy above 650.degree. C.
The effects of particle size on chlorination rate was found to obey an empirical formula as follows:
.DELTA.m/.DELTA.t=kD.sup.0.179
where the rate constant k=21.3 percent per minute for granules of 1 mm diameter at 695.degree. C.
.DELTA.m/.DELTA.t=expressed in mg per minute is weight loss per unit time.
D granule diameter in millimeters.
The chlorination rate increases slightly with change in diameter of a granule which is apparently due to a larger porosity, i.e., surface area.
Granules of the composition shown in Table IV have been chlorinated in an externally heated 2" fluid bed.
TABLE IV__________________________________________________________________________Typical analysis in percent by weight of slag:coke granulesfrom a ratio of slag:coal:Lignosol = 100:50:0.375 partsTiO.sub.2 C Fe.sub.T Al.sub.2 O.sub.3 SiO.sub.2 CaO MgO V.sub.2 O.sub.5 Cr.sub.2 O.sub.3 H L.O.I.__________________________________________________________________________52.5 24.4 7.7 4.9 4.7 0.8 3.9 0.4 0.1 0.17 23.3__________________________________________________________________________ Fe.sub.T = total iron expressed as elemental iron although partially present as FeO. L.O.I. = loss on ignition (essentially carbon less the oxygen fixed by lower valency oxides during calcination in air, such as FeO .fwdarw. Fe.sub.2 O.sub.3).
According to the invention, the articles of manufacture contain various components in various proportions therein as shown by the following analysis, in percent by weight:
______________________________________TiO.sub.2 C Fe.sub.T Al.sub.2 O.sub.3 SiO.sub.2 CaO MgO H50-55 20-30 5-10 3-5 3-5 0.6-1.0 3.0-5.0 0.1-0.3V.sub.2 O.sub.5 Cr.sub.2 O.sub.3 L.O.I.0.3-0.5 0.05-0.15 18-28______________________________________
With reference to the above data, in general, chlorination was carried out with a 50:50 mixture of chlorine and air (based on volume). A variation from 100:0.0 can also be used. The utilization of chlorine was about 98% for a bed high of 35-40 cm (14-16 inches) at a flow rate of 3.10 liters/minute of chlorine (standard temperature volume; temperature=20.degree. C.). The temperature range was 690.degree.-740.degree. C. The total running time was 133 minutes for treatment of 1036.8 g. of granules, the initial charge was 200 g. and 28.4 g. was generally added every 3 minutes up to a total of 836.8 g. until all available granules were fed. At the end of the test, the bed was fluid and 137.1 g. of solids were collected in the reactor which reduced to 110.0 g. after washing and drying corresponding to a 19.8 percent soluble chloride in the charge without any sticking.
450 g. of solids were collected as dry dust carry-over containing 41.5 percent of soluble chlorides. Total amount of TiCl.sub.4 collected was 996.8 g.
The solid composition in the bed was (in percent by weight):
______________________________________ WaterTiO.sub.2 C Fe.sub.T Al.sub.2 O.sub.3 SiO.sub.2 CaO MgO Solubles______________________________________39.45 15.72 1.29 12.42 6.45 0.47 3.77 19.77______________________________________
In the dust collector the composition of the solids after washing was (in percent by weight):
__________________________________________________________________________TiO.sub.2 + Fe.sub.2 O.sub.3 + SiO.sub.2 + Al.sub.2 O.sub.3 + CaO + MgOetc. Carbon Oxide/C ratio__________________________________________________________________________54.3 45.7 1.19__________________________________________________________________________
The conversion into chlorides of the various oxides were (in percent by weight):
______________________________________TiO.sub.2 SiO.sub.2 Al.sub.2 O.sub.3 CaO MgO______________________________________93 1.0 1.0 35 85______________________________________
In accordance to the above, it is readily evident that slags and titanium dioxide sources which heretofore could not have been utilized as starting materials are now amenable to processing and provide ready source material for eventual production of titanium dioxide via the chloride route or provide a ready source of TiCl.sub.4. Increasing scarcity of high grade raw materials can thus be economically met by turning to raw material sources in plentiful supply such as found on the North American continent.

Number	Name	Date
2253471	Muskat et al.	Aug 1941
2479904	Cole	Aug 1949
2723903	Cyr et al.	Nov 1955
2753243	Lyons	Jul 1956
2761760	Kamlet	Sep 1956
2805120	Plant	Sep 1957

Titanium slag-coke granules suitable for fluid bed chlorination

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