Patent Application
20240049767
The present invention relates to a tobacco sheet for a non-combustion heating-type flavor inhaler, a method for manufacturing the same, a non-combustion heating-type flavor inhaler, and a non-combustion heating-type flavor inhalation system.
In combustion-type flavor inhalers (cigarettes), tobacco fillers including leaf tobacco and tobacco sheets are burned to obtain the flavor. For example, Patent Literature 1 discloses a tobacco sheet used in a combustion-type flavor inhaler. As an alternative to combustion-type flavor inhalers, a non-combustion heating-type flavor inhaler configured to deliver flavor by heating a flavor source, such as a tobacco sheet, instead of combustion thereof, has been reported. The heating temperature of the non-combustion heating-type flavor inhaler is lower than the combustion temperature of the combustion-type flavor inhaler, and is, for example, about 400° C. or lower. As described above, the heating temperature of the non-combustion heating-type flavor inhaler is low; thus, an aerosol-generating agent can be added to the flavor source in the non-combustion heating-type flavor inhaler from the viewpoint of increasing the amount of smoke. The aerosol-generating agent is vaporized by heating to generate aerosol. The aerosol is supplied to a user along with a flavor component, such as a tobacco component, so that the user can obtain sufficient flavor.
The non-combustion heating-type flavor inhaler can include, for example, a tobacco-containing segment filled with a tobacco sheet or the like, a cooling segment, and a filter segment. The length of the tobacco-containing segment of the non-combustion heating-type flavor inhaler in the axial direction is usually shorter than the length of the tobacco-containing segment of the combustion-type flavor inhaler in the axial direction in relation to the heater. Thus, in the non-combustion heating-type flavor inhaler, a large amount of tobacco sheet is filled in the section of the short tobacco-containing segment in order to ensure the amount of aerosol generated during heating. To fill a large amount of tobacco sheet in a short section, in the non-combustion heating-type flavor inhaler, a tobacco sheet having a low filling capacity, that is, high density, is usually used. The filling capacity is a value indicating a volume when a shredded tobacco sheet having a predetermined mass is compressed at a predetermined pressure for a predetermined time.
However, the inventors have found that, when considering the heating method, the heating capacity of the heater, and the generation of aerosol, the total heat capacity of the tobacco-containing segment increases when a tobacco sheet having a low filling capacity (high density) is used, and thus the tobacco sheet filled in the tobacco-containing segment does not sufficiently contribute to the generation of aerosol depending on the heating method and the capacity of the heater. To solve the above-described problem, it is conceivable to reduce the total heat capacity of the tobacco-containing segment.
To reduce the total heat capacity of the tobacco-containing segment, the inventors have conducted studies on (1) a reduction in the specific heat of the tobacco raw material contained in the tobacco sheet, and (2) the use of a tobacco sheet having a high filling capacity (low density). However, with respect to (1), it is difficult to reduce the specific heat of the tobacco raw material itself; thus, it was considered effective to reduce the total heat capacity of the tobacco-containing segment by (2). Therefore, it is desired to develop a high-filling-capacity (low-density) tobacco sheet suitable for a non-combustion heating-type flavor inhaler.
The present invention aims to provide a high-filling-capacity tobacco sheet for a non-combustion heating-type flavor inhaler, a non-combustion heating-type flavor inhaler containing the tobacco sheet, and a non-combustion heating-type flavor inhalation system.
The present invention includes the following embodiments.
A tobacco sheet for a non-combustion heating-type flavor inhaler contains a tobacco raw material, in which a cross-section of the tobacco sheet in the thickness direction has a corrugated shape.
The tobacco sheet for the non-combustion heating-type flavor inhaler described in the first aspect further contains a fructan.
In the tobacco sheet for the non-combustion heating-type flavor inhaler described in the first or second aspect, the fructan is selected from the group consisting of inulin-type fructans, levan-type fructans, branched fructans, fructo-oligosaccharides, and mixtures thereof.
The tobacco sheet for the non-combustion heating-type flavor inhaler described in any one of the first to third aspects further contains:
In the tobacco sheet for the non-combustion heating-type flavor inhaler described in the fourth aspect, each of the saturated fatty acid and the ester of the saturated fatty acid is a single compound.
A tobacco-containing segment contains, as fillers:
A tobacco-containing segment contains, as fillers:
A non-combustion heating-type flavor inhaler includes:
A non-combustion heating-type flavor inhalation system includes:
A method for manufacturing the tobacco sheet for the non-combustion heating-type flavor inhaler described in any one of the first to third aspects includes the steps of:
A method for manufacturing the tobacco sheet for the non-combustion heating-type flavor inhaler described in the fourth or fifth aspect includes the steps of:
According to the present invention, it is possible to provide a high-filling-capacity tobacco sheet for a non-combustion heating-type flavor inhaler, a non-combustion heating-type flavor inhaler containing the tobacco sheet, and a non-combustion heating-type flavor inhalation system.
[Tobacco Sheet for Non-Combustion Heating-Type Flavor Inhaler]
A tobacco sheet for a non-combustion heating-type flavor inhaler according to the present embodiment (hereinafter, also referred to as a “tobacco sheet”) contains a tobacco raw material, in which a cross section of the tobacco sheet in the thickness direction has a corrugated shape. The tobacco sheet according to the present embodiment has a corrugated shape in its cross section in the thickness direction and thus is bulky and has a high filling capacity. The use of the tobacco sheet according to the present embodiment can reduce the total heat capacity of the tobacco-containing segment to allow the tobacco sheet filled in the tobacco-containing segment to contribute sufficiently to aerosol generation. The tobacco sheet according to the present embodiment preferably further contains an aerosol-generating agent and one or two or more types of forming agents. When the mixing ratio of these components is within a predetermined range, the filling capacity of the tobacco sheet is further improved.
(Shape of Tobacco Sheet)
The tobacco sheet according to the present embodiment has a corrugated shape in its cross section in the thickness direction. That is, when the tobacco sheet according to the present embodiment is cut in the thickness direction in one direction of the planar directions, the cross section has a corrugated shape. The one direction of the planar directions may be, for example, the longitudinal direction or the lateral direction of the tobacco sheet. The term “corrugated shape” used here is not particularly limited as long as it has a shape that undulates vertically, and the crests of the waves may be straight or curved. The waves may be regular or irregular.
(Tobacco Raw Material)
A tobacco raw material contained in the tobacco sheet according to the present embodiment is not particularly limited as long as it contains a tobacco component, and examples thereof include a tobacco powder and a tobacco extract. Examples of the tobacco powder include leaf tobacco, midribs, and residual stems. These may be used alone or in combination of two or more. These can be used as the tobacco powder by shredding them into a predetermined size. Regarding the size of the tobacco powder, the 90% cumulative particle size (D90) in the volume-based particle size distribution measured by dry laser diffractometry is preferably 200 μm or more from the viewpoint of further improving the filling capacity. When the tobacco raw material is tobacco powder, the proportion of the tobacco powder contained in 100% by mass of the tobacco sheet is preferably 45% to 95% by mass, more preferably 50% to 93% by mass, still more preferably 60% to 85% by mass. Examples of the tobacco extract include a tobacco extract obtained by roughly crushing leaf tobacco, mixing the crushed leaf tobacco with a solvent, such as water, under stirring to extract a water-soluble component from the leaf tobacco, and drying and concentrating the obtained water extract under reduced pressure.
(Aerosol-Generating Agent)
The tobacco sheet according to the present embodiment preferably further contains an aerosol-generating agent from the viewpoint of increasing the amount of smoke during heating. Examples of the aerosol-generating agent include glycerine, propylene glycol, and 1,3-butanediol. These may be used alone or in combination of two or more.
When the tobacco sheet contains the aerosol-generating agent, the proportion of the aerosol-generating agent contained in 100% by mass of the tobacco sheet is preferably 4% to 50% by mass. When the proportion of the aerosol-generating agent is 4% or more by mass, aerosol can be generated in sufficient quantity during heating. When the proportion of the aerosol-generating agent is 50% or less by mass, a sufficient amount of aerosol can be generated during heating from the viewpoint of heat capacity. The proportion of the aerosol-generating agent is more preferably 6% to 40% by mass, still more preferably 8% to 30% by mass, particularly preferably 10% to 20% by mass.
(Forming Agent)
The tobacco sheet according to the present embodiment preferably further contains a forming agent from the viewpoint of ensuring the shape. In particular, the tobacco sheet of the present embodiment preferably further contains a first forming agent and a second forming agent from the viewpoint that the performance of the tobacco sheet to retain the aerosol-generating agent and to maintain the corrugated shape can be sufficiently achieved. Here, the first forming agent and the second forming agent may be different from each other in the type of forming agent, or may be the same in the type of the forming agent but different in the form. Examples of the first forming agent include polysaccharides, proteins, and synthetic polymers. Examples of the polysaccharides include cellulose derivatives and naturally occurring polysaccharides.
Examples of the cellulose derivatives include cellulose ethers, such as methyl cellulose, ethyl cellulose, hydroxyethyl cellulose, hydroxymethylethyl cellulose, hydroxypropyl cellulose, hydroxypropylmethyl cellulose, benzyl cellulose, trityl cellulose, cyanoethyl cellulose, carboxymethyl cellulose, carboxyethyl cellulose, and aminoethyl cellulose; organic acid esters, such as cellulose acetate, cellulose formate, cellulose propionate, cellulose butyrate, cellulose benzoate, cellulose phthalate, and tosyl cellulose; and esters of inorganic acids, such as cellulose nitrate, cellulose sulfate, cellulose phosphate, and cellulose xanthate.
Examples of the naturally occurring polysaccharides include plant-derived polysaccharides, such as guar gum, tara gum, locust bean gum, tamarind seed gum, pectin, arabic gum, tragacanth gum, karaya gum, ghatti gum, arabinogalactan, flax seed gum, cassia gum, psyllium seed gum, and artemisia seed gum; algae-derived polysaccharides, such as carrageenan, agar, alginic acid, propylene glycol alginate, furcellaran, and oyster thief extracts; microorganism-derived polysaccharides, such as xanthan gum, gellan gums, curdlan, pullulan, Agrobacterium succinoglycan, welan gum, macrophomopsis gum, and rhamsan gum; crustacean-derived polysaccharides, such as chitin, chitosan, and glucosamine; and starches, such as starches, sodium starch glycolate, pregelatinized starch, and dextrin.
Examples of the proteins include cereal proteins, such as wheat gluten and rye gluten. Examples of the synthetic polymers include polyphosphoric acid, sodium polyacrylate, and polyvinylpyrrolidone. As the second forming agent, although the second forming agent is different from the first forming agent, the polysaccharides, the proteins, the synthetic polymers, and so forth similar to the first forming agent can be used.
When the first forming agent is contained in the tobacco sheet, the proportion of the first forming agent contained in 100% by mass of the tobacco sheet is preferably 0.1% to 15% by mass. When the proportion of the first forming agent is 0.1% or more by mass, the mixture of raw materials can be easily formed into a sheet shape. When the proportion of the first forming agent is 15% or less by mass, other raw materials can be sufficiently used for ensuring a function required for the tobacco-containing segment of the non-combustion heating-type flavor inhaler. The proportion of the first forming agent is more preferably 0.1% to 12% by mass, still more preferably 0.1% to 10% by mass, particularly preferably 0.1% to 7% by mass.
When the second forming agent is contained in the tobacco sheet, the proportion of the second forming agent contained in 100% by mass of the tobacco sheet is preferably 0.1% to 15% by mass. When the proportion of the second forming agent is 0.1% or more by mass, the mixture of raw materials can be easily formed into a sheet shape. When the proportion of the second forming agent is 15% or less by mass, other raw materials can be sufficiently used for ensuring a function required for the tobacco-containing segment of the non-combustion heating-type flavor inhaler. The proportion of the second forming agent is more preferably 0.1% to 12% by mass, still more preferably 0.1% to 10% by mass, particularly preferably 0.1% to 7% by mass.
When the first forming agent and the second forming agent are the same in type but different in form, for example, the first forming agent may be in the form of a powder, and the second forming agent may be in the form of a solution or slurry. For example, in a method for manufacturing a tobacco sheet described below, a forming agent as the first forming agent may be directly mixed in the form of a powder, and the forming agent as the second forming agent may be dispersed or swollen in a solvent, such as water, and then mixed. Such a method can also provide the same effect as when two forming agents of different types are used.
(Reinforcing Agent)
The tobacco sheet according to the present embodiment can further contain a reinforcing agent from the viewpoint of further improving physical properties. Examples of the reinforcing agent include fibrous materials, such as fibrous pulp and fibrous synthetic cellulose, and liquid materials having a surface coating function of forming a film when dried, such as an aqueous suspension of pectin. These may be used alone or in combination of two or more.
When the tobacco sheet contains a reinforcing agent, the proportion of the reinforcing agent contained in 100% by mass of the tobacco sheet is preferably 4% to 40% by mass. Within this range, other raw materials can be sufficiently used for ensuring the functions required for the tobacco-containing segment of the non-combustion heating-type flavor inhaler. The proportion of the reinforcing agent is more preferably 4.5% to 35% by mass, still more preferably 5% to 30% by mass.
(Humectant)
The tobacco sheet according to the present embodiment can further contain a humectant from the viewpoint of quality retention. Examples of the humectant include sugar alcohols, such as sorbitol, erythritol, xylitol, maltitol, lactitol, mannitol, and reduced maltose syrup. These may be used alone or in combination of two or more.
When the humectant is contained in the tobacco sheet, the proportion of the humectant contained in 100% by mass of the tobacco sheet is preferably 1% to 15% by mass. Within this range, other raw materials can be sufficiently used for ensuring the functions required for the tobacco-containing segment of the non-combustion heating-type flavor inhaler. The proportion of the humectant is more preferably 2% to 12% by mass, still more preferably 3% to 10% by mass.
(Other Components)
The tobacco sheet according to the present embodiment can contain, in addition to the tobacco raw material, the aerosol-generating agent, the forming agents (first and second forming agents), the reinforcing agent, and the humectant, a flavor agent, such as a flavoring agent or a taste enhancer, a coloring agent, a wetting agent, a preservative, a diluent, such as an inorganic substance, and so forth, as needed.
(Filling Capacity)
The tobacco sheet according to the present embodiment preferably has a filling capacity of 190 cc/100 g or more. When the filling capacity is 190 cc/100 g or more, the total heat capacity of the tobacco-containing segment of the non-combustion heating-type flavor inhaler can be sufficiently reduced, and the tobacco sheet filled in the tobacco-containing segment can further contribute to aerosol generation. The filling capacity is more preferably 210 cc/100 g or more, more preferably 230 cc/100 g or more. The upper limit of the filling capacity range is not particularly limited, but can be, for example, 800 cc/100 g or less. The filling capacity is a value measured with DD-60A (trade name, available from Borgward) after a tobacco sheet is shredded into a size of 0.8 mm×20 mm and left in a conditioning room at 22° C. and 60% for 48 hours. The measurement is performed by placing 15 g of the shredded tobacco sheet in a cylindrical container having an inside diameter of 60 mm and determining the volume when the shredded tobacco sheet is compressed for 30 seconds with a load of 3 kg.
[Method for Manufacturing Tobacco Sheet]
The method for manufacturing tobacco sheet according to the present embodiment can include, for example, a step of preparing a mixture containing a tobacco raw material, an aerosol-generating agent, a first forming agent, and a second forming agent, a step of rolling the mixture to form a rolled article, and a step of imparting a corrugated shape to the rolled article while cutting the rolled article into strips by pressing a rotary roller cutter against the rolled article. The process of imparting a corrugated shape is also referred to as a rippling process. For example, the tobacco sheet according to the present embodiment can be manufactured by the following method.
The sheet cut into strips by the rotary roller cutter is subjected to a resistance force as it is peeled from the roll, giving it the corrugated shape and serrated shape as illustrated in
[Non-Combustion Heating-Type Flavor Inhaler]
The non-combustion heating-type flavor inhaler according to the present embodiment includes a tobacco-containing segment containing the tobacco sheet according to the present embodiment and so forth. The non-combustion heating-type flavor inhaler according to the present embodiment includes the tobacco-containing segment filled with the high-filling-capacity tobacco sheet according to the present embodiment and so forth. Thus, the total heat capacity of the tobacco-containing segment can be sufficiently reduced, and the tobacco sheet filled in the tobacco-containing segment can further contribute to aerosol generation.
The length of the non-combustion heating-type flavor inhaler according to the present embodiment in the axial direction is preferably, but not particularly limited to, 40 mm or more and 90 mm or less, more preferably 50 mm or more and 75 mm or less, still more preferably 50 mm or more and 60 mm or less. The circumference of the non-combustion heating-type flavor inhaler is preferably 16 mm or more and 25 mm or less, more preferably 20 mm or more and 24 mm or less, still more preferably 21 mm or more and 23 mm or less. In an embodiment, for example, the tobacco-containing segment has a length of 20 mm, the cooling segment has a length of 20 mm, the center-hole segment has a length of 8 mm, and the filter segment has a length of 7 mm. The length of the filter segment can be selected in the range of 4 mm to 10 mm. In this case, the airflow resistance of the filter segment is selected so as to be 15 mmH2O/segment or more and 60 mmH2O/segment or less. The lengths of these individual segments can be appropriately changed in accordance with manufacturing suitability, required quality, and so forth. Even if the filter segment alone is disposed downstream of the cooling segment without using the center-hole segment, the flavor inhaler can function as a non-combustion heating-type flavor inhaler.
(Tobacco-Containing Segment)
In the tobacco-containing segment 5, a wrapping paper (hereinafter, also referred to as a “wrapper”) is filled with the tobacco sheet according to the present embodiment. A method for filling the tobacco sheet into the wrapping paper is not particularly limited. For example, the tobacco sheet may be wrapped in a wrapper, or the tobacco sheet may be filled in a tubular wrapper. When the tobacco sheet has a shape, such as a rectangular shape, having a longitudinal direction, the tobacco sheet may be packed in such a manner that its longitudinal direction is an unspecified direction in the wrapper, or may be packed so as to be aligned in the axial direction of the tobacco-containing segment 5 or in a direction perpendicular to the axial direction.
(Cooling Segment)
In an embodiment, as illustrated in
The tubular member 10 and mouthpiece lining paper 15 described below are provided with perforations 11 penetrating therethrough. The presence of the perforations 11 allows outside air to be introduced into the cooling segment 6 during inhalation. Thus, the vaporized aerosol component produced by heating the tobacco-containing segment 5 comes into contact with the outside air to reduce its temperature, thus liquefying to form an aerosol. The diameter of (length across) each perforation 11 is not particularly limited, and may be, for example, 0.5 mm or more and 1.5 mm or less. The number of the perforations 11 is not particularly limited. One perforation or two or more perforations may be used. For example, the multiple perforations 11 may be provided on the circumference of the cooling segment 6.
The amount of outside air introduced through the perforations 11 is preferably 85% or less by volume, more preferably 80% or less by volume, based on the volume of the entire gas inhaled by a user. When the proportion of the amount of outside air is 85% or less by volume, a decrease in flavor due to dilution with outside air can be sufficiently inhibited. In other words, this is also referred to as a ventilation ratio. The lower limit of the range of the ventilation ratio is preferably 55% or more by volume, more preferably 60% or more by volume, from the viewpoint of cooling performance.
The cooling segment may also be a segment including a crimped, pleated, gathered, or folded sheet of a suitable component material. The cross-sectional profile of such an element may exhibit randomly oriented channels. The cooling segment may also include a bundle of longitudinally extending tubes. Such a cooling segment can be formed, for example, by wrapping a pleated, gathered, or folded sheet material with wrapping paper.
The length of the cooling segment in the axial direction can be, for example, 7 mm or more and 28 mm or less, and can be, for example, 18 mm. The cooling segment can be substantially circular in its axial cross-sectional shape. The diameter can be, for example, 5 mm or more and 10 mm or less, and can be, for example, about 7 mm.
(Center-Hole Segment)
The center-hole segment includes a filling layer having one or multiple hollow portions and an inner plug wrapper (inner wrapping paper) covering the filling layer. For example, as illustrated in
(Filter Segment)
The configuration of the filter segment 8 is not particularly limited, and the filter segment 8 may be formed of a single filling layer or multiple filling layers. The outside of the filling layer may be wrapped with one or more sheets of wrapping paper. The flow resistance per segment of the filter segment 8 can be appropriately changed in accordance with, for example, the amount of filler and the material of the filler filled in the filter segment 8. For example, when the filler is formed of cellulose acetate fibers, the flow resistance can be increased by increasing the amount of cellulose acetate fibers filled in the filter segment 8. When the filler is formed of cellulose acetate fibers, the filling density of the cellulose acetate fibers can be 0.13 to 0.18 g/cm3. The airflow resistance is a value measured by an airflow resistance measuring device (trade name: SODIMAX, available from SODIM).
The circumference of the filter segment 8 is not particularly limited, but is preferably 16 to 25 mm, more preferably 20 to 24 mm, still more preferably 21 to 23 mm. The length of the filter segment 8 in the axial direction can be selected from 4 to 10 mm, and is selected in such a manner that the airflow resistance is 15 to 60 mmH2O/segment. The length of the filter segment 8 in the axial direction is preferably 5 to 9 mm, more preferably 6 to 8 mm. The cross-sectional shape of the filter segment 8 is not particularly limited, and may be, for example, circular, elliptical, polygonal, or the like. To the filter segment 8, flavoring agent-containing breakable capsules or flavoring agent beads may be added, or a flavoring agent may be directly added.
As illustrated in
[Non-Combustion Heating-Type Flavor Inhalation System]
A non-combustion heating-type flavor inhalation system according to the present embodiment includes the non-combustion heating-type flavor inhaler according to the present embodiment and a heating device configured to heat the tobacco-containing segment of the non-combustion heating-type flavor inhaler. The non-combustion heating-type flavor inhalation system according to the present embodiment may have another configuration other than the non-combustion heating-type flavor inhaler according to the present embodiment and the heating device.
In
The heating temperature by the heating device is not particularly limited, but is preferably 400° C. or lower, more preferably 150° C. or higher and 400° C. or lower, still more preferably 200° C. or higher and 350° C. or lower. The heating temperature refers to the temperature of the heater of the heating device.
The non-combustion heating-type flavor inhaler is required to reduce smoke flavor inhibition (stimulation) or discomfort. The smoke flavor inhibition refers to stimulation to the oral cavity or throat upon inhalation. Hereinafter, a tobacco sheet for a non-combustion heating-type flavor inhaler in which smoke flavor inhibition or discomfort is reduced will be described.
In this embodiment, the tobacco sheet for a non-combustion heating-type flavor inhaler contains fructan. When the tobacco sheet is used for smoking, fructan is thermally decomposed to continuously generate a sweet aroma. The generated sustained sweet aroma can continuously inhibit the smoke flavor inhibition from the early stage to the late stage of the smoking behavior.
The fructan is not particularly limited, and an inulin-type fructan, a levan-type fructan, a branched fructan, a fructo-oligosaccharide, or a combination of two or more thereof can be used. Among these, the inulin-type fructan is preferred from the viewpoint of cost reduction.
Without being bound by theory, it is presumed that when the fructan of the present embodiment generates a sweet aroma by a caramelization reaction, there are the following features.
Fructan is composed of multiple monosaccharides bonded, and has a molecular structure larger than monosaccharides and disaccharides. For this reason, when fructan undergoes a caramelization reaction, it is considered that fructan undergoes a multi-stage decomposition process in which fructan is decomposed into sugars having relatively small molecules such as monosaccharides and disaccharides, and then these monosaccharides and disaccharides undergo a caramelization reaction to generate a sweet aroma. When monosaccharides and disaccharides undergo a caramelization reaction, these sugars are considered to undergo a caramelization reaction to directly generate a sweet aroma. Thus, fructan is considered to be able to generate a sweet aroma at a slower rate and for a longer period of time than monosaccharides and disaccharides because of a larger number of decomposition steps. In the present embodiment, it is considered that these features relating to the caramelization reaction of fructan can continuously inhibit the smoke flavor inhibition from the early stage to the late stage of the smoking behavior.
In some embodiments, the fructan content based on 100% by mass of the tobacco sheet can be, but is not particularly limited to, 0.1% to 5% by mass, 0.3% to 3.5% by mass, or 0.5% to 3% by mass. A higher fructan content is more preferred from the viewpoint of suppression of the smoke flavor inhibition and the viewpoint of the persistence of the inhibition of the smoke flavor inhibition. An excessively higher fructan content may reduce flavor. Thus, the fructan content is preferably 0.5% to 3% by mass from the viewpoint of achieving the inhibition of the smoke flavor inhibition and the persistence thereof and providing flavor.
In this embodiment, the tobacco raw material may further contain tobacco leaves, aged tobacco leaves, processed tobacco leaves, tobacco fillers, non-tobacco materials, or a combination of two or more thereof.
<Tobacco Leaves, Aged Tobacco Leaves, and Processed Tobacco Leaves>
The term “tobacco leaves” is used as a generic term for harvested tobacco leaves before they are subjected to aging as described below. In an embodiment, aging includes curing. Tobacco leaves that have undergone aging and have not yet been processed into various forms used in tobacco products (such as shredded tobacco, tobacco sheets, and tobacco granules, described below) are referred to as “aged tobacco leaves”. The aged tobacco leaves processed into various forms used in tobacco products are referred to as “processed tobacco leaves”.
Examples of the form of processed tobacco leaves used in tobacco products include “shredded tobacco” obtained by shredding aged tobacco leaves into a predetermined size. Further examples thereof may include “tobacco sheets” and “tobacco granules”. A composition containing aged tobacco leaves that have been ground to a predetermined particle size (hereinafter also referred to as a “fine tobacco powder”) is formed into sheets to obtain the “tobacco sheets” and into granules to obtain the “tobacco granules”. The “fine tobacco powder” is also one form of processed tobacco leaves.
Examples of the non-tobacco materials can include roots (including scaly roots (scaly bulbs), tuberous roots (potatoes), bulbs, and so forth), stems, tubers, skins (including stem bark, tree bark, and so forth), leaves, and flowers (including petals, pistils, stamens, and so forth), seeds, and fruits of plants; and tree trunks and branches.
A method for manufacturing a fructan-containing tobacco sheet is not limited. In some embodiments of the present application, the tobacco sheet can be manufactured by preparing the above-described tobacco sheet and supplying fructan from the outside. Specifically, fructan is preferably supplied to the rolled article. The rolled article may be used before or after the corrugated shape is imparted.
In this embodiment, the tobacco sheet for the non-combustion heating-type flavor inhaler contains a saturated fatty acid-based additive.
In this embodiment, the tobacco sheet may contain a material derived from an Oriental variety. In this case, the amount of material derived from the Oriental variety is preferably 10% or less by mass based on the tobacco raw material. When the amount of material derived from the Oriental variety is within this range, a smoke taste with a further reduced discomfort can be provided. From this viewpoint, the upper limit of the amount is preferably 8% or less by mass, more preferably 5% or less by mass. The lower limit thereof is preferably 0.1% or more by mass, more preferably 2% or more by mass, still more preferably 3% or more by mass.
The saturated fatty acid-based additive is selected from the group consisting of a saturated fatty acid having a molar mass of 200 to 350 g/mol, an ester of the saturated fatty acid, and a combination thereof. The saturated fatty acid reduces discomfort during smoking. The ester of the saturated fatty acid is prepared from an alcohol and a saturated fatty acid having a molar mass of 200 to 350 g/mol; thus, the molar mass of the ester varies in accordance with the molar mass of the alcohol. In one embodiment, the molar mass of the ester is 210 to 1,300 g/mol. The ester of a saturated fatty acid typically has a lower vapor pressure than the fatty acid; thus, the effect of reducing discomfort during smoking lasts throughout smoking. Hereinafter, the discomfort reduction effect during smoking is also referred to simply as a discomfort reduction effect.
From the viewpoint of achieving the above effect, the lower limit of the molar mass of the ester of the saturated fatty acid is preferably 240 g/mol or more, more preferably 270 g/mol or more. The upper limit is preferably 1,140 g/mol or less, 1,112 g/mol or less, 300 g/mol or less, or 290 g/mol or less.
The saturated fatty acid-based additive content is 0.01% to 3% by mass based on the total dry matter mass of the tobacco raw material (assuming that the dry matter mass is 100% by mass). When the content is less than the lower limit, the discomfort reduction effect is not sufficient. When the content is more than the upper limit, the sense of offensive odor increases. From this viewpoint, the lower limit of the content is preferably 1% or more by mass, and the upper limit thereof is preferably 2% or less by mass. The dry matter mass is the mass excluding a medium described below, and is preferably the mass of the residue when the composition is dried at 100° C. for 5 hours.
Each of the saturated fatty acid and the fatty acid moiety in the ester preferably has 12 to 20 carbon atoms, more preferably 15 to 19 carbon atoms. When the number of carbon atoms is within this range, the discomfort reduction effect is more noticeable.
In the saturated fatty acid-based additive, the solubility of the saturated fatty acid in water is preferably 0.15 mg/g or less, more preferably 0.12 mg/g or less. The lower limit thereof is not limited and may be 0 mg/g, but is preferably 0.05 mg/g or more.
Specific preferred examples of the saturated fatty acid include octanoic acid, decanoic acid, myristic acid, palmitic acid, stearic acid, and nonadecanoic acid. Among these, palmitic acid, stearic acid, or nonadecanoic acid is preferred from the viewpoint of easy availability and providing the discomfort reduction effect. The saturated fatty acid may be a mixture, but is preferably a single substance that is not a mixture. In this embodiment, the term “single substance (single compound)” includes a case where the compound is a pure substance and a case where the compound contains incidental impurities. Thus, in one embodiment, the saturated fatty acid consists only of palmitic acid. If the saturated fatty acid is a single substance, when the tobacco composition of the present invention is formed into a formed product such as a sheet, the dispersibility of the saturated fatty acid in the formed product is improved.
Preferred specific examples of the ester of the saturated fatty acid (hereinafter, also referred to simply as “ester”) include the alkyl ester and sugar ester of the saturated fatty acid described above. An alkyl moiety is preferably derived from a linear, branched, or cyclic alkyl group having 1 to 10 carbon atoms, such as a methyl group. The sugar moiety is preferably derived from a disaccharide such as sucrose. Preferred examples of the ester include sucrose palmitate and methyl palmitate. The saturated fatty acid moiety in the ester is preferably derived from a single saturated fatty acid for the reasons described above. The alcohol moiety in the ester need not be a single moiety, but is preferably a single moiety for the reasons described above. The ester also functions as an emulsifier.
In one embodiment, the saturated fatty acid-based additive contains the saturated fatty acid and the ester. In this case, the discomfort reduction effect can be advantageously maintained longer. In addition, the type of saturated fatty acid-based additive can be appropriately selected, in accordance with, for example, the tobacco raw material used. Thus, this embodiment also has an advantage of being versatile.
The whole or part of the saturated fatty acid-based additive is preferably in the form of a powder. When the saturated fatty acid-based additive is in the form of a powder, the dispersibility of the saturated fatty acid-based additive in a formed article such as a sheet is improved as described below. The size thereof is not limited. However, for example, the D50 is preferably 30 to 120 μm, more preferably 50 to 100 μm. In addition, from the viewpoint of the dispersibility, the saturated fatty acid-based additive preferably has a higher degree of crystallinity than waxes and natural fats and oils.
The tobacco sheet may contain liquid sugar. The liquid sugar is sugar in liquid form. When the tobacco sheet contains the liquid sugar, the sweet taste is improved in addition to the reduction of discomfort during smoking. From this viewpoint, the liquid sugar content is preferably 3% to 10% by mass, more preferably 5% to 8% by mass, based on the dry matter mass in the tobacco composition.
The tobacco sheet may contain a natural botanical flavoring agent. When the tobacco sheet contains the natural botanical flavoring agent, the sweet taste is improved in addition to the discomfort reduction effect. From this viewpoint, the content of the natural botanical flavoring agent is preferably 0.5% to 3% by mass, more preferably 2% to 3% by mass, based on the dry matter mass in the tobacco composition. As the natural botanical flavoring agent, those known in the tobacco field can be used, and licorice is preferred in the present invention. Licorice is a sweetener derived from Spanish licorice, which belongs to the genus Glycyrrhiza of the legume family.
The amount of nicotine contained in the tobacco sheet according to the present embodiment is not limited, but can be 2% or more by mass based on the dry matter mass of the tobacco sheet in one embodiment. Typically, the discomfort during smoking tends to increase as the amount of nicotine increases. In the present embodiment, however, the discomfort reduction effect is provided as described above. Thus, when the amount of nicotine is within the above range, the effect of the present embodiment becomes more pronounced. The upper limit of the amount of nicotine is practically, but not limited to, 3% or less by mass.
In another embodiment, the amount of nicotine may be 1.5% or less by mass. When the amount of nicotine is within the above range, a milder smoke flavor can be imparted. The lower limit of the amount of nicotine is practically, but not limited to, 0.1% or more by mass. Nicotine contained in the tobacco sheet may be derived from the tobacco raw material, or may be derived from other components.
The tobacco sheet in the present embodiment can contain the above-described aerosol-generating agent. The amount of aerosol-generating agent is preferably 12% or less by mass, more preferably 11% or less by mass, based on the dry matter mass of the tobacco sheet. The lower limit thereof is not limited and may be 0% by mass, and is preferably 1% or more by mass. An amount of aerosol-generating agent of more than the upper limit may result in a difficulty in producing the sheet. An amount of less than the lower limit may result in a reduction in smoke sensation.
When the tobacco sheet contains a binder, the strength of the sheet is improved. The binder is an adhesive for binding fibers together. As the binder, those known in the art can be used. Examples of the binder include thickening polysaccharides, such as gums, modified celluloses, and modified starches. The amount of binder is appropriately adjusted in accordance with the intended use, and can be, for example, about 1% to 10% by mass based on the dry matter mass of the tobacco sheet.
The tobacco sheet in the present embodiment is manufactured by a freely-selected method. For example, when the mixture is prepared, a saturated fatty acid-based additive is mixed to prepare a mixture containing the additive, and a sheet can be manufactured by the above-described method using the mixture. In this case, it is preferable to use a saturated fatty acid-based additive in powder form and to perform mixing so as to maintain the powder form. The tobacco sheet manufactured in this manner has good dispersibility of the aerosol-generating agent. Good dispersibility indicates that the saturated fatty acid-based additive is uniformly dispersed. The mixing step is preferably performed at a temperature equal to or lower than the melting point of the saturated fatty acid-based additive. For example, this step can be performed at 10° C. to 50° C.
The mixture (also referred to as “slurry”) containing the saturated fatty acid-based additive is preferably prepared by a method including the following step.
A step of mixing the tobacco raw material or the fibrous tobacco material, a saturated fatty acid-based additive that is partially or entirely in the form of a powder, and a medium in such a manner that the powder is maintained in a powder state, to form a slurry.
In this method, the slurry is prepared while the saturated fatty acid-based additive is maintained in a powder state. Thereby, the dispersibility of component (B) is improved when a formed article is formed. The size of the powder is as described above. The phrase “the saturated fatty acid-based additive is maintained in a powder state” indicates that the whole or part of the saturated fatty acid-based additive is maintained in a powder state.
Examples of the medium include water and hydrophilic organic solvents. The most preferable medium is water in view of handling.
In this method, first, solid materials at room temperature are each formed into a powder by pulverization or the like. The resulting powders are mixed to prepare a powder mixture. Liquid or pasty materials at room temperature, such as a medium, are mixed to prepare a liquid mixture. A step of mixing the powder mixture and the liquid mixture is preferably included.
From the viewpoint of satisfactorily dispersing the powdery saturated fatty acid-based additive in the medium, the viscosity of the slurry at 25° C. is preferably 100,000 to 200,000 (mPa·s). The viscosity is measured with a Brookfield type viscometer (DV-I prime available from Brookfield) using a spindle No. LV4 at a rotational speed of 1.0 rpm.
In this embodiment, the tobacco-containing segment (hereinafter, also referred to simply as “tobacco segment”) contains paper or paper containing an aerosol-generating agent. The outline of the tobacco segment in this embodiment is illustrated in
In Embodiment 3-1, a tobacco segment contains, as fillers, a tobacco sheet, and paper in which the total amount of lignin and hemicellulose is 0.1% to 10% by mass. The fillers are fillers for tobacco segments. Lignin is a high-molecular-weight phenol compound contained in, for example, wood. Hemicellulose is an insoluble polysaccharide contained in the cell wall. When the total amount is within this range, an offensive odor (such as a fiber odor) during smoking can be reduced. That is, in this embodiment, the effect of diluting the smoke flavor can be provided without significantly impairing the original smoke flavor. From this viewpoint, the upper limit of the total amount of lignin and hemicellulose contained is preferably 9.0% or less by mass.
Although lignin and hemicellulose are measured by known methods, they are preferably measured by the following method in the present invention.
In Step 1), for example, a Thermo Scientific™ Dionex™ ASE™ Accelerated Solvent Extractor System (Model: ASE-350) can be used.
Step 2) can be specifically performed as described below.
In a screw bottle, 50 mg of the sample A is placed, followed by the addition of 8.5 ml of ultrapure water (ML-Q water) and 0.5 ml of a pancreatin solution. The mixture is shaken at 40° C. and 125 rpm for 16 hours. The pancreatin solution is the supernatant obtained by adding 8 g of pancreatin to 100 ml of 0.1 M phosphate buffer with a pH of 6.4, stirring the mixture for 1 hour, and centrifuging the mixture at 8,000 rpm for 30 minutes. The sample liquid is then transferred to a 15-ml centrifuge tube using ML-Q water and centrifuged at 8,000 rpm for 15 minutes to remove the supernatant. This washing is repeated three times. After washing, 10 ml of an aqueous solution of 5% sulfuric acid is added thereto, and hydrolysis is performed at 100° C. for 2.5 hours. After the completion of the hydrolysis reaction, the sample is allowed to cool to room temperature. The precipitate is then filtered off, and the filtrate is collected in a 250-ml volumetric flask. After thoroughly washing the residue on the filter paper with ML-Q water, the volume is adjusted to 250 ml. This solution is used as a sample for hemicellulose measurement. Then 500 μl of the sample is transferred to a 20-ml test tube, and 500 μl of an aqueous solution of 5% phenol and 2.5 ml of concentrated sulfuric acid are added thereto. The mixture is vigorously stirred for 10 seconds. The sample is allowed to stand at room temperature for 20 minutes or more. The absorbance is measured at a wavelength of 490 nm with a spectrophotometer to quantify hemicellulose.
[Quantification of Lignin]
Steps ii) and iii) can be specifically performed as described below.
In a screw bottle, 100 mg of the sample A is placed, followed by the addition of 4 ml of 72% sulfuric acid. The sample is completely immersed in sulfuric acid and then shaken at 30° C. and 200 rpm for 4 hours. Next, 157.2 ml of ultrapure water (ML-Q water) is added in such a manner that the sulfuric acid concentration after dilution is 4%. The mixture is transferred to a recovery flask and heated to reflux in an oil bath at 110° C. for 2 hours. After cooling to room temperature, filtration is performed. The resulting sample is dried with a rotary dryer and weighed.
The density of the paper used in this embodiment is preferably 0.05 to 0.8 (g/cm3), more preferably 0.1 to 0.6 (g/cm3). The density is measured by a known method and is preferably determined from the following formula.
Density (g/cm3)=weight (g)/area (cm2)/thickness (cm)
The amount of paper used in this embodiment is preferably 5% to 70% by mass, more preferably 10% to 50% by mass, still more preferably 15% to 40% by mass, based on the dry matter mass of the tobacco sheet. When the amount of paper contained is within this range, the smoke flavor can be diluted to an appropriate level without impairing the original smoke flavor. The dry matter mass is the mass of the residue when the tobacco sheet is dried at 100° C. for 5 hours in one embodiment.
The paper used in the present embodiment is not limited as long as the total amount of lignin and hemicellulose contained is within the above range, and for example, tobacco paper such as a wrapper, and printing paper such as high-quality printing paper and medium-quality printing paper can be used. However, from the viewpoint of inhibiting the generation of an offensive odor, non-coated paper or slightly coated paper is preferred. The paper used in the present embodiment may contain or need not contain an aerosol-generating agent described below. The amount may be in the range described in Embodiment 3-2, or may be in a range other than this.
As Embodiment 3-2, the tobacco segment includes, as fillers, a tobacco sheet, and paper containing an aerosol-generating agent. The aerosol-generating agent is a material that is vaporized by heating and cooled to generate an aerosol or generates an aerosol by atomization. In this embodiment, the use of the paper containing the aerosol-generating agent can provide the effect of diluting the smoke flavor without reducing the amount of smoke. As the aerosol-generating agent, those described above can be used. The amount thereof is preferably 3% to 20% by mass, more preferably 5% to 15% by mass, based on the dry matter mass of the paper. An amount of aerosol-generating agent of more than the upper limit may result in, for example, staining on the tobacco segment. An amount of less than the lower limit may result in a reduction in smoke sensation. The aerosol-generating agent can be added to the paper by, for example, impregnation or spraying.
The amount of paper containing aerosol-generating agent is preferably 5% to 75% by mass, more preferably 10% to 50% by mass, still more preferably 15% to 40% by mass, based on the dry matter mass of the tobacco sheet.
The paper used in this embodiment is not limited, and may be the paper described in Embodiment 3-1. The density of the paper before addition of the aerosol-generating agent used in the present embodiment may be in the range described in Embodiment 3-1, or may be in a range other than this. The amount of lignin and hemicellulose contained in the paper used in the present embodiment is not limited, and may be in the range described in Embodiment 3-1, or may be in a range other than this.
In any of the embodiments, the shape of the paper is not limited as long as the paper is easily mixed with the tobacco sheet. In one embodiment, the paper is in the form of a sheet, shred, or strand. In a preferred embodiment, the paper and the tobacco sheet have the same shape. In a most preferred embodiment, shredded paper and shredded tobacco sheet are used.
In addition, the paper may contain a flavoring agent, such as menthol, which is commonly used in the art.
While specific examples of the present embodiment will be described below, the present invention is not limited thereto.
Tobacco lamina (leaf tobacco) was dry-ground with a Hosokawa Micron ACM machine to obtain a tobacco powder. With regard to the tobacco powder, the 90% cumulative particle size (D90) in the volume-based particle size distribution measured by a dry laser diffractometry using a Mastersizer (trade name, available from Malvern Panalytical of Spectris Co., Ltd.) was 200 μm.
A tobacco sheet was manufactured using the tobacco powder as a tobacco raw material. Specifically, 70 parts by mass of the tobacco raw material, 12 parts by mass of glycerine as an aerosol-generating agent, 4 parts by mass of powdered carboxymethyl cellulose as a first forming agent, 1 part by mass of carboxymethyl cellulose swollen with water as a second forming agent, 5 parts by mass of fibrous pulp as a reinforcing agent, and 8 parts by mass of cocoa powder as a flavoring agent were mixed and kneaded by an extruder. The kneaded product was formed into a sheet shape with two pairs of metal rollers to form a rolled article. A rotary roller cutter for noodle making was pressed against the rolled article, and a corrugated shape was imparted while cutting the rolled article into strips. The sheet was cut into a length of 20 mm and dried to provide a tobacco sheet having a length of 20 mm and a width of 0.8 mm. The cross-section of the tobacco sheet in the thickness direction had a cross-sectional shape as illustrated in
The filling capacity of the resulting tobacco sheet was measured. Specifically, the tobacco sheet was allowed to stand in a conditioning room at 22° C. and 60% RH for 48 hours, and then the filling capacity was measured with DD 60A (trade name, available from Borgward). The measurement was performed by placing 15 g of the tobacco sheet in a cylindrical container having an inside diameter of 60 mm, and determining the volume when the tobacco sheet was compressed for 30 seconds with a load of 3 kg. Table 1 presents the results. In Table 1, the filling capacity is indicated by the rate of increase in filling capacity (%) with respect to a reference value of the filling capacity of Comparative example 1 described below.
A rolled article was produced in the same manner as in Example 1. Thereafter, the rolled article was shredded into strips with multiple ring-shaped rotary blades. The sheet was cut so as to have a length of 20 mm to provide a non-corrugated tobacco sheet having a length of 20 mm and a width of 0.8 mm. The filling capacity of the resulting tobacco sheet was measured in the same manner as in Example 1. Table 1 presents the results.
As presented in Table 1, the tobacco sheet of Example 1, which is the tobacco sheet according to the present embodiment, had improved filling capacity as compared with the non-corrugated tobacco sheet of Comparative example 1.
A tobacco sheet (smoking composition sheet) produced by a known papermaking method was prepared. The tobacco sheet was filled in a wrapper to form a smoking segment, and a non-combustion heating-type flavor inhaler illustrated in
First, 10 g of inulin-type fructan (available from Fuji Nihon Seito Corporation, product name: Fuji FF) was mixed with 90 g of a mixture of propylene glycol and water (propylene glycol:water=1:9 (ratio by mass)), thereby preparing a solution of inulin-type fructan. The same tobacco sheet as in 1. was prepared. The solution of inulin-type fructan was added using a syringe so as to spread throughout the entire tobacco sheet, thereby providing sheets each having an inulin-type fructan content of 0.5%, 1.0%, 2.0%, 3.0%, or 3.5% by mass based on the entire smoking composition sheet (containing inulin-type fructan) after the addition.
In addition, 10 g of fructose (available from Happo Shokusan Co., Ltd., product name: fructose) was mixed with 90 g of a mixture of propylene glycol and water (propylene glycol:water=1:9 (ratio by mass)), thereby preparing a fructose solution. The same tobacco sheet as in 1. was prepared. The solution of fructose was added using a syringe so as to spread throughout the entire tobacco sheet, thereby providing sheets each having a fructose content of 0.5%, 1.0%, 2.0%, 3.0%, or 3.5% by mass based on the entire smoking composition sheet (containing fructose) after the addition.
The fructan-containing smoking composition sheet or the fructose-containing smoking composition sheet produced as described above was filled in a wrapper to form a smoking segment to prepare a non-combustion heating-type flavor inhaler illustrated in
The inulin-type fructan is a type of fructan. The smoking composition sheet containing the inulin-type fructan corresponds to the example of the present application. Fructose is a type of monosaccharide. The smoking composition sheet containing fructose corresponds to the comparative example of the present application.
Each of the non-combustion heating-type flavor inhalers prepared as described in 1 or 2 above was installed in a non-combustion external heating-type smoking system illustrated in
Each of the thus-prepared flavor inhalers was evaluated for flavor and smoke flavor inhibition by 10 well-trained panelists. In the example and the comparative example, the “flavor” means a flavor obtained by combining a tobacco-derived flavor and a sweet flavor derived from inulin-type fructan or fructose.
The evaluation of the flavor and smoke flavor inhibition of each smoking test rod was performed by each panelist's evaluation based on the five-point scale in Table 1a below and calculating the average value of the 10 panelists. In the criteria in Table 1a below, a sheet equivalent to a sheet that does not contain the inulin-type fructan or fructose is rated 3. When the average value had a value of two decimal places, the average value was rounded to the nearest tenth to calculate the score. Tables 2a and 3a and
As described above, the smoking composition sheets containing inulin-type fructan correspond to the example of the present application, whereas the smoking composition sheets containing fructose correspond to the comparative example of the present application.
The results presented in Table 2a and
The results presented in Table 3a and
Regarding fructose, the panelists commented that the smoke flavor inhibition increased in the latter half of smoking (the effect of inhibiting the smoke flavor inhibition did not last for a long time). For this reason, as described in Reference Example 2a below, a comparative experiment was conducted on inulin-type fructan and fructose in terms of the persistence of an inhibitory effect on smoke flavor inhibition.
A non-combustion heating-type flavor inhaler prepared in the same manner as in “2. Preparation of Fructan- or Fructose-Containing Smoking Composition Sheet” in Reference example 1a was installed in a non-combustion external heating-type smoking system illustrated in
Each of the thus-prepared flavor inhalers was evaluated for the persistence of an inhibitory effect on smoke flavor inhibition by 10 well-trained panelists. The persistence of the inhibitory effect on the smoke flavor inhibition of each smoking test rod was evaluated as follows: The inhibitory effect on the flavor and taste until the latter half of smoking and the absence of the inhibitory effect on the smoke flavor inhibition after smoking were evaluated by each panelist according to the five-point scale presented in Table 4a below, and the average value of 10 panelists was calculated. When the average value had a value of two decimal places, the average value was rounded to the nearest tenth to calculate the score.
According to the criteria in the following Table 4a, when the persistence of the inhibitory effect on the smoke flavor inhibition in accordance with the difference in inulin-type fructan content is evaluated, a sheet equivalent to a sheet containing 2.0% by mass of fructose is rated 3. When the persistence of the inhibitory effect on the smoke flavor inhibition in accordance with the difference in fructose content is evaluated, a sheet equivalent to a sheet containing 2.0% by mass of inulin-type fructan is rated 3.
Tables 5a and 6a and
The results presented in Table 5a and
The results presented in Table 6a and
The above results indicated that the inulin-type fructan was superior to fructose in terms of the persistence of the inhibitory effect on the smoke flavor inhibition.
From the above, it was found that the tobacco material of this example continuously inhibited the smoke flavor inhibition from the early stage to the late stage of smoking behavior (excellent in the persistence of the inhibitory effect on the smoke flavor inhibition).
A tobacco sheet produced by papermaking was provided as component (A). The sheet contained a tobacco material and 15% by mass of vegetable glycerine as an aerosol-generating agent. A saturated fatty acid presented in Table 1b was provided as component (B) and sprayed onto the sheet. The amount of component (B) added based on the dry matter mass of the tobacco composition (the total of the tobacco sheet produced by papermaking and the component (B)) is presented in Table 1b. For example, in Example A1, the amount of octanoic acid added was 1.0% by mass based on the dry matter mass of the tobacco composition.
After drying the sheet, multiple slits were made therein. The resulting sheet was wrapped to provide a tobacco rod. At this time, the longitudinal direction of the slit was parallel to the longitudinal direction of the tobacco segment. The tobacco rod was used to produce a non-combustion heating-type tobacco flavor inhaler having the structure illustrated in
A smoking test was conducted by heating the non-combustion heating-type tobacco flavor inhaler under the following conditions using a hollow cylindrical heater having an outside diameter of 3.2 mm and an inside diameter of 1.3 mm.
A test was conducted by 10 well-trained panelists by the visual analog scale (category scale) method using a non-combustion heating-type tobacco flavor inhaler produced without adding the component (B) (see a reference comparative example below) as a comparative subject. Table 1b presents the results. A lower value of the score difference indicates less discomfort.
A non-combustion heating-type tobacco flavor inhaler was produced in the same manner as in Reference Example 1b, except that the component (B) was not used.
The following materials were provided.
Others: licorice, liquid sugar, softwood pulp, glycerine, and binder (guar gum)
A non-combustion heating-type tobacco flavor inhaler was produced and evaluated by the following procedure.
A non-combustion heating-type tobacco flavor inhaler was produced and evaluated in the same manner as in Reference example 2b, except that the amounts of respective components were changed as given in Table 2b.
It is clear from the above that the tobacco formulation of this example reduces discomfort during smoking.
A tobacco sheet produced by a known papermaking method was provided. The tobacco sheet was filled in a wrapper to form a tobacco segment, and a non-combustion heating-type flavor inhaler illustrated in
Paper in which the total amount of lignin and hemicellulose contained was 0.1% to 10% by mass (materials 1 to 7) and paper in which the total amount thereof was more than 10% by mass (materials 8 to 10) were provided. The same tobacco sheet and paper as provided in Reference comparative example 1c were shredded into pieces having a width of 0.3 to 2.0 mm and a length of 3 to 50 mm. The shredded pieces of paper and the shredded pieces of tobacco sheet were mixed in a ratio by mass of 80:20. A non-combustion heating-type flavor inhaler was prepared in the same manner as in Reference comparative example 1c and subjected to a smoking test. Based on the results of Reference comparative example 1c, the smoke flavor and the amount of smoke were evaluated according to the following criteria.
The fiber odor was evaluated according to the following criteria.
A non-combustion heating-type flavor inhaler was prepared and subjected to a smoking test in the same manner as in Reference example 1c, except that the tobacco sheet and the material 5 were blended in the amounts given in Table 2c.
The tobacco sheet and material 5 were blended in the amounts given in Table 3c. However, 10% by mass of glycerine serving as an aerosol-generating agent was added to the material 5 based on the dry matter mass. A non-combustion heating-type flavor inhaler was prepared in the same manner as in Reference example 1c, except that the blend was used. Then a smoking test was conducted.
[Quantification of Hemicellulose]
1) The paper was subjected to a solvent extraction (solvent: water) with a Thermo Scientific™ Dionex™ ASE™ Accelerated Solvent Extractor System (Model: ASE-350), thereby separating the residue. The residue was subjected to cryogenic grinding with, for example, liquid nitrogen, thereby preparing sample A.
2) In a screw bottle, 50 mg of the sample A was placed, followed by the addition of 8.5 ml of ultrapure water (ML-Q water) and 0.5 ml of a pancreatin solution. The mixture was shaken at 40° C. and 125 rpm for 16 hours. The sample liquid was then transferred to a 15-ml centrifuge tube using ML-Q water and centrifuged at 8,000 rpm for 15 minutes to remove the supernatant. This washing is repeated three times. After washing, 10 ml of an aqueous solution of 5% sulfuric acid was added thereto, and hydrolysis is performed at 100° C. for 2.5 hours. After the completion of the hydrolysis reaction, the sample was allowed to cool to room temperature. The precipitate was then filtered off, and the filtrate was collected in a 250-ml volumetric flask. After thoroughly washing the residue on the filter paper with ML-Q water, the volume was adjusted to 250 ml. This solution was used as a sample for hemicellulose measurement.
3) Then 500 μl of the sample was transferred to a 20-ml test tube, and 500 μl of an aqueous solution of 5% phenol and 2.5 ml of concentrated sulfuric acid were added thereto. The mixture was vigorously stirred for 10 seconds. The sample was allowed to stand at room temperature for 20 minutes or more. The absorbance was measured at a wavelength of 490 nm with a spectrophotometer to quantify hemicellulose.
[Quantification of Lignin]
i) The sample A was prepared.
ii) In a screw bottle, 100 mg of the sample A was placed, followed by the addition of 4 ml of 72% sulfuric acid. The sample was completely immersed in sulfuric acid and then shaken at 30° C. and 200 rpm for 4 hours. Next, 157.2 ml of ultrapure water (ML-Q water) was added in such a manner that the sulfuric acid concentration after dilution was 4%. The mixture was transferred to a recovery flask and heated to reflux in an oil bath at 110° C. for 2 hours.
iii) After the mixture that had been subjected to reflux treatment was allowed to cool to room temperature, filtration was performed. The resulting sample was dried with a rotary dryer and weighed to determine the amount of lignin.
It is clear that the tobacco segment of the present example can moderately dilute the smoke flavor.
Embodiments are described below.
[1] A tobacco sheet for a non-combustion heating-type flavor inhaler contains a tobacco raw material, in which the tobacco sheet has a corrugated shape in cross section in the thickness direction.
[2] In the tobacco sheet for the non-combustion heating-type flavor inhaler described in [1], the tobacco sheet further contains an aerosol-generating agent.
[3] In the tobacco sheet for the non-combustion heating-type flavor inhaler described in [2], the aerosol-generating agent is at least one selected from the group consisting of glycerine, propylene glycol, and 1,3-butanediol.
[4] In the tobacco sheet for the non-combustion heating-type flavor inhaler described in [2] or [3], the proportion of the aerosol-generating agent contained in 100% by mass of the tobacco sheet is 4% to 50% by mass.
[5] In the tobacco sheet for the non-combustion heating-type flavor inhaler described in any one of [1] to [4], the tobacco sheet further contains a first forming agent and a second forming agent.
[6] In the tobacco sheet for the non-combustion heating-type flavor inhaler described in [5], the first forming agent is at least one selected from the group consisting of polysaccharides, proteins, and synthetic polymers.
[7] In the tobacco sheet for the non-combustion heating-type flavor inhaler described in [5] or [6], the second forming agent is different from the first forming agent and is at least one selected from the group consisting of polysaccharides, proteins, and synthetic polymers.
[8] In the tobacco sheet for the non-combustion heating-type flavor inhaler described in any one of [5] to [7], the proportion of the first forming agent contained in 100% by mass of the tobacco sheet is 0.1% to 15% by mass.
[9] In the tobacco sheet for the non-combustion heating-type flavor inhaler described in any one of [5] to [8], the proportion of the second forming agent contained in 100% by mass of the tobacco sheet is 0.1% to 15% by mass.
[10] A non-combustion heating-type flavor inhaler includes a tobacco-containing segment containing the tobacco sheet for the non-combustion heating flavor inhaler described in any one of [1] to [9].
[11] A non-combustion heating-type flavor inhalation system includes:
[12] A method for manufacturing the tobacco sheet for the non-combustion heating-type flavor inhaler described in any one of [1] to [9] includes the steps of:
[1a] A tobacco material contains a fructan.
[2a] In the tobacco material described in [1a], the fructan is selected from the group consisting of inulin-type fructans, levan-type fructans, branched fructans, fructo-oligosaccharides, and mixtures thereof.
[3a] In the tobacco material described in [1a] or [2a], the amount of the fructan contained in the entire tobacco material is 0.5% to 3% by mass.
[4a] The tobacco material described in any one of [1a] to [3a] further contains a tobacco sheet or shredded tobacco.
[5a] A heating-type smoking article contains the tobacco material described in any one of [1a] to [4a].
[1b] A tobacco composition contains:
[2b] In the composition described in [1b], each of the saturated fatty acid and the ester of the saturated fatty acid in the component (B) is a single compound.
[3b] In the composition described in [1b] or [2b], the fatty acid moiety in each of the saturated fatty acid and the ester, which are the component (B), has 12 to 20 carbon atoms.
[4b] The composition described in any one of [1b] to [3b] further contains 1% to 10% by mass of liquid sugar based on the dry matter mass in the composition.
[5b] In the composition described in any one of [1b] to [4b], the component (A) contains 10% or less by mass of a material derived from an Oriental variety.
[6b] The composition described in any one of [1b] to [5b] further contains 0.5% to 3% by mass of a natural botanical flavoring agent based on the dry matter mass in the composition.
[7b] In the composition described in any one of [1b] to [6b], nicotine is contained in an amount of 2% or more by mass based on the dry matter mass in the composition.
[8b] In the composition described in any one of [1b] to [6b], nicotine is contained in an amount of 1.5% or less by mass based on the dry matter mass in the composition.
[9b] The composition described in any one of [1b] to [8b] further contains 12% or less by mass of an aerosol-generating agent based on the dry matter mass in the composition.
[10b] A sheet is composed of the tobacco composition described in any one of [1b] to [9b].
[11b] A method for producing the tobacco composition described in any one of [1b] to [10b] includes:
[12b] The production method described in [11b] further includes setting the viscosity of the slurry to 100,000 to 200,000 (mPa·s).
[1c] A tobacco segment for heating contains, as fillers:
[2c] A tobacco segment for heating contains, as fillers:
[3c] In the tobacco segment described in [1c], the total amount of lignin and hemicellulose contained is 9.0% or less by mass.
[4c] In the tobacco segment described in [1c] or [3c], the amount of paper contained is 5% to 70% by mass based on the dry matter mass of the tobacco material.
[5c] In the tobacco segment described in [4c],
[6c] In the tobacco segment described in any one of [1c] to [5c], the paper has a density of 0.05 to 0.8 [g/cm3].
[7c] In the tobacco segment described in [2c] or [6c], the amount of paper contained is 5% to 75% by mass based on the dry matter mass of the tobacco material.
[8c] In the tobacco segment described in any one of [1c] and [3c] to [6c], the paper contains an aerosol-generating agent.
[9c] A non-combustion heating-type flavor inhaler includes the tobacco segment described in any one of [1c] to [8c].
[10c] A method for producing the tobacco segment described in any one of [1c] to [8c] includes mixing the paper with the tobacco material.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2021-074180 | Apr 2021 | JP | national |
| 2021-113314 | Jul 2021 | JP | national |
| 2021-170059 | Oct 2021 | JP | national |
| 2021-208018 | Dec 2021 | JP | national |
The present application is a continuation application of International Application No. PCT/JP2022/018913, filed on Apr. 26, 2022.
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP2022/018913 | Apr 2022 | US |
| Child | 18493162 | US |
