Patent Application
20140348545
1. Field of the Invention
The present invention relates to a toner housing container and an image forming apparatus.
2. Description of the Related Art
In electrophotographic image forming apparatuses, a powder conveying device supplies (or replenishes) a toner serving as a developer from a toner container, which is a powder housing container housing the developer in the powder form, into a developing device.
For example, there is proposed a toner housing container that includes a rotatable tubular powder housing member, a conveying pipe receiving member fixed to the powder housing member, an opening provided in the conveying pipe receiving member, and an uplifting portion configured to uplift the toner upward in the container along with rotation of the container body (e.g., see Japanese Patent Application Laid-Open (JP-A) No. 2012-133349). According to this proposed technique, the toner is uplifted by the uplifting portion along with rotation of the container body, and the toner falls from the uplifting portion during the rotation and is supplied into the conveying pipe.
However, in the system employing the mechanism of uplifting the toner by the uplifting portion and supplying the toner into the conveying pipe, there is a problem that when the amount of toner remaining in the toner bottle becomes low, it is difficult for the toner to be replenished into the developing device.
Therefore, it is currently requested to provide a toner housing container that can replenish a toner into a developing device even when the amount of toner remaining in the toner housing container becomes low.
The present invention aims to solve the conventional problems described above and achieve the following object. That is, an object of the present invention is to provide a toner housing container that can replenish a toner into a developing device even when the amount of toner remaining in the toner housing container becomes low.
Means for solving the problems is as follows.
A toner housing container of the present invention includes:
a container body mountable on a toner conveying device and housing a toner to be supplied into the toner conveying device;
a conveying portion provided in the container body and configured to convey the toner from one end of the container body in a longer direction thereof to the other end thereof at which a container opening portion is provided;
a pipe receiving port provided at the container opening portion and capable of receiving a conveying pipe fixed to the toner conveying device; and
an uplifting portion configured to uplift the toner conveyed by the conveying portion from a lower side of the container body to an upper side thereof and move the toner toward a toner receiving port of the conveying pipe,
wherein a flow rate index of the toner measured by a powder rheometer and represented by the following formula (1) is in a range represented by the following formula (2),
wherein the container body includes a protruding portion protruding from a container body interior side of the container opening portion toward the one end,
wherein the uplifting portion includes an uplifting wall surface extending from an internal wall surface of the container body toward the protruding portion, and a curving portion curving so as to conform to the protruding portion, and
wherein the protruding portion is provided such that when the toner housing container is mounted on the toner conveying device, the protruding portion is present between the curving portion and the toner receiving port of the conveying pipe being inserted.
Flow rate index=(total energy at a rotation speed of 10 mm/s)/(total energy at a rotation speed of 100 mm/s) (1)
1.8≦flow rate index≦6.5 (2)
The present invention can provide a toner housing container that can solve the conventional problems described above and replenish a toner into a developing device even when an amount of toner remaining in the toner housing container becomes low.
A toner housing container of the present invention includes at least a toner, a container body, a conveying portion, a pipe receiving port, and an uplifting portion, and further includes other members according to necessity.
A flow rate index of the toner measured by a powder rheometer and represented by the following formula (1) is in a range represented by the following formula (2), preferably in a range represented by the following formula (3), and more preferably in a range represented by the following formula (4).
Flow rate index=(total energy at a rotation speed of 10 mm/s)/(total energy at a rotation speed of 100 mm/s) (1)
1.8≦flow rate index≦6.5 (2)
2.8≦flow rate index≦6.5 (3)
2.8≦flow rate index≦4.0 (4)
The container body is mountable on a toner conveying device, and houses the toner, which is to be supplied into the toner conveying device.
The conveying portion is provided in the container body, and conveys the toner from one end of the container body in a longer direction thereof to the other end thereof at which a container opening portion is provided.
The pipe receiving port is provided at the container opening portion, and capable of receiving a conveying pipe fixed to the toner conveying device.
The uplifting portion (also referred to as toner transporting portion) uplifts the toner conveyed by the conveying portion from a lower side of the container body to an upper side thereof and moves the toner into a toner receiving port of the conveying pipe.
The container body includes a protruding portion protruding from a container body interior side of the container opening portion toward the one end.
The uplifting portion includes an uplifting wall surface extending from an internal wall surface of the container body toward the protruding portion, and a curving portion curving so as to conform to the protruding portion.
The protruding portion is provided such that when the toner housing container is mounted on the toner conveying device, the protruding portion is present between the curving portion and the toner receiving port of the conveying pipe being inserted.
The protruding portion is preferably a plate-shaped member and provided such that a flat side surface of the plate-shaped member is present between the curving portion and the toner receiving port of the toner conveying pipe being inserted. This makes it easier for the flat side surface of the plate-shaped member to receive the toner, and facilitates passing of the toner from the uplifting portion into the toner conveying pipe.
The flat side surface is a side surface intersecting approximately perpendicularly with such a surface of the plate-shaped member as facing the uplifting portion.
The uplifting portion includes a rising portion rising from an internal wall surface of the container body toward the protruding portion. The rising portion includes a curving portion curving so as to conform to the protruding portion.
The protruding portion is provided such that when the toner housing container is mounted on the toner conveying device, the protruding portion is present between the curving portion and the toner receiving port of the conveying pipe being inserted.
It is preferable that the toner housing container include two uplifting portions, and that when the toner housing container is mounted on the toner conveying device, the protruding portion be present between the curving portions of the respective ones of the two uplifting portions and the toner receiving port of the conveying pipe being inserted. This leads to efficient uplifting of the toner, and facilitates passing of the toner from the uplifting portions into the toner conveying pipe.
Two protruding portions may or may not be provided to face each other by sandwiching therebetween a longer direction center axis of the toner housing container.
In an image forming apparatus of the present invention, the toner housing container is demountably set in the body of the image forming apparatus.
An embodiment of the present invention will be explained below with reference to the drawings.
Four toner housing containers 32 (Y, M, C, and K) corresponding to respective colors (yellow, magenta, cyan, and black) are demountably (replaceably) set in a toner housing container accommodating section 70 provided in an upper portion of the printer section 100. An intermediate transfer unit 85 is provided below the toner housing container accommodating section 70.
The intermediate transfer unit 85 includes an intermediate transfer belt 48 as an intermediate transfer member, four first transfer bias rollers 49 (Y, M, C, and K), a second transfer backup roller 82, a plurality of tension rollers, an unillustrated intermediate transfer cleaning device, and the like. The intermediate transfer belt 48 is tensed and supported by a plurality of roller members, and endlessly moves in the arrow direction of
In the printer section 100, four image forming units (Y, M, C, and K) corresponding to the respective colors are provided side by side so as to face the intermediate transfer belt 48. Four toner replenishing devices 60 (Y, M, C, and K) as toner conveying devices corresponding to the toner housing containers of the respective colors are provided below the four toner housing containers 32 (Y, M, C, and K). Toners, which are powder developers housed in the toner housing containers 32 (Y, M, C, and K), are supplied (replenished) by corresponding ones of the toner replenishing devices 60 (Y, M, C, and K) into developing devices of the image forming units 46 (Y, M, C, and K) corresponding to the respective colors.
As shown in
In the present embodiment, a laser beam scanner system using a laser diode is employed as the exposing device 47. However, other systems such as one using a LED array may be used as an exposing unit.
The image forming unit 46Y includes a drum-shaped photoconductor 41Y as an image bearing member. The image forming unit 46Y is configured such that a charging roller 44Y as a charging unit, a developing device 50Y as a developing unit, a photoconductor cleaning device 42Y, an unillustrated charge eliminating device, and the like are provided around the photoconductor 41Y. Through an image forming process (a charging step, an exposing step, a developing step, a transfer step, and a cleaning step) performed on the photoconductor 41Y, a yellow toner image is formed on the photoconductor 41Y.
The other three image forming units 46 (M, C, and K) have substantially the same configuration as the image forming unit 46Y corresponding to yellow, except for using different colors of toners. Toner images corresponding to the respective colors of toners are formed on the photoconductors 41 (M, C, and K). In the following, the image forming unit 46Y corresponding to yellow will only be explained, by appropriately skipping explanation of the other three image forming units 46 (M, C, and K).
The photoconductor 41Y is driven to rotate in the clockwise direction of
Each of the four first transfer bias rollers 49 (Y, M, C, and K) of the intermediate transfer unit 85 forms a first transfer nip by sandwiching the intermediate transfer belt 48 between itself and the photoconductor 41 (Y, M, C, and K). A transfer bias inverse to the polarity of the toner is applied to the first transfer bias rollers 49 (Y, M, C, and K).
The surface of the photoconductor 41Y on which a toner image is formed through the developing step reaches the first transfer nip facing the first transfer bias roller 49Y across the intermediate transfer belt 48, and has the toner image on the photoconductor 41Y transferred onto the intermediate transfer belt 48 by this first transfer nip (first transfer step). At this time, although slightly, the toner remains un-transferred on the photoconductor 41Y. The surface of the photoconductor 41Y having transferred the toner image onto the intermediate transfer belt 48 by the first transfer nip reaches a position facing the photoconductor cleaning device 42Y. The un-transferred toner remained on the photoconductor 41Y is mechanically collected by a cleaning blade 42a of the photoconductor cleaning device 42Y at this facing position (cleaning step). Finally, the surface of the photoconductor 41Y reaches a position facing the unillustrated charge eliminating device, and has a residual potential on the photoconductor 41Y eliminated at this position. In this way, the series of image forming process performed on the photoconductor 41Y is completed.
Such an image forming process is performed in the other image forming units 46 (M, C, and K) in the same manner as in the yellow image forming unit 46Y. That is, the exposing device 47 provided below the image forming units 46 (M, C, and K) emits laser light L based on image information to the photoconductors 41 (M, C, and K) of the image forming units 46 (M, C, and K). Specifically, the exposing device 47 emits laser light L from a light source, and irradiates the photoconductors 41 (M, C, and K) with the laser light through a plurality of optical elements while scanning the laser light L with a polygon mirror being driven to rotate. After this, toner images of the respective colors formed on the photoconductors 41 (M, C, and K) through the developing step are transferred onto the intermediate transfer belt 48.
At this time, the intermediate transfer belt 48 passes through the first transfer nips of the respective first transfer bias rollers 49 (Y, M, C, and K) sequentially by running in the arrow direction of
The intermediate transfer belt 48 on which the color toner image is formed with the toner images of the respective colors transferred and overlaid reaches a position facing the second transfer roller 89. At this position, the second transfer backup roller 82 forms a second transfer nip by sandwiching the intermediate transfer belt 48 between itself and the second transfer roller 89. Then, the color toner image formed on the intermediate transfer belt 48 is transferred by the effect oft for example, a transfer bias applied to the second transfer backup roller 82 onto a recording medium P such as a transfer sheet transferred to the position of the second transfer nip. At this time, un-transferred toner that has not been transferred onto the recording medium P remains on the intermediate transfer belt 48. The intermediate transfer belt 48 having passed through the second transfer nip reaches the position of the unillustrated intermediate transfer cleaning device, and has the un-transferred toner on the surface thereof collected. In this way, the series of transfer process performed on the intermediate transfer belt 48 is completed.
Next, the behavior of the recording medium P will be explained.
The recording medium P conveyed to the second transfer nip described above is transferred thereto via a sheet feeding roller 27, a registration roller pair 28, etc., from a sheet feeding tray 26 provided in the sheet feeding section 200 provided below the printer section 100. Specifically, a plurality of sheets of recording media P are overlaid and stocked in the sheet feeding tray 26. When the sheet feeding roller 27 is driven to rotate in the counterclockwise direction in
The recording medium P conveyed to the registration roller pair 28 stops once at the position of the roller nip of the registration roller pair 28 stopped from being driven to rotate. Then, by the registration roller pair 28 being started to rotate so as to be in time for the color toner image on the intermediate transfer belt 48 to arrive at the second transfer nip, the recording medium P is conveyed to the second transfer nip. In this way, a desired color toner image is transferred onto the recording medium P.
The recording medium P onto which the color toner image is transferred at the second transfer nip is conveyed to the position of a fixing device 86. Through the fixing device 86, the color toner image transferred onto the surface is fixed on the recording medium P with heat and pressure applied by a fixing belt and a pressurizing roller. The recording medium P passed through the fixing device 86 is discharged to the outside of the apparatus through the gap between the rollers of a sheet discharging roller pair 29. The recording medium P discharged to the outside of the apparatus by the sheet discharging roller pair 29 is stacked sequentially on a stacking section 30 as an output image. In this way, the series of image forming process in the copier 500 is completed.
Next, the configuration and operation of the developing device 50 in the image forming unit 46 will be explained in greater detail. The explanation will be given by taking the image forming unit 46Y corresponding to yellow for example. However, the image forming units 46 (M, C, and K) corresponding to the other colors have also the same configuration and operation.
As shown in
The developer G in the developing device 50 circulates to and from the first developer receptacle 53Y and the second developer receptacle 54Y while being stirred by the two developer conveying screws 55Y. The developer G in the first developer receptacle 53Y is conveyed by one of the developer conveying screws 55Y, and supplied onto and borne by the surface of the sleeve of the developing roller 51Y by the effect of a magnetic field formed by the magnet roller in the developing roller 51Y. The sleeve of the developing roller 51Y is driven to rotate in the counterclockwise direction as indicated by an arrow in
The developer G borne on the developing roller 51Y is conveyed in the arrow direction of
The toner concentration of the developer G in the developing device 50Y is adjusted to a certain range. Specifically, the toner housed in a toner housing container 32Y is replenished into the second developer receptacle 54Y through the toner replenishing device 60Y according to the amount of consumption of the toner contained in the developer G in the developing device 50Y along with development. The toner replenished into the second developer receptacle 54Y is mixed and stirred with the developer G by the two developer conveying screws 55Y, and circulates to and from the first developer receptacle 53Y and the second developer receptacle 54Y.
Next, the toner replenishing device 60 (Y, M, C, and K) will be explained.
The toners in the toner housing containers 32 (Y, M, C, and K) mounted in the toner housing container accommodating section 70 of the printer section 100 are appropriately replenished into the developing devices 50 (Y, M, C, and K) according to the consumption of the toners in the developing devices 50 (Y, M, C, and K) for the respective colors, as shown in
The toner replenishing device 60 (Y, M, C, and K) is constituted by the toner housing container accommodating section 70, a conveying nozzle 611 (Y, M, C, and K) as a conveying pipe, a conveying screw 614 (Y, M, C, and K) as a conveying member, a toner fall-down conveying path 64 (Y, M, C, and K), a container rotation driving unit 91 (Y, M, C, and K), etc.
For the expediency of explanation, a later-described container opening portion 33a side of a container body 33 of the toner housing container 32Y is defined as the container leading end side, and the side opposite to the container opening portion 33a (i.e., a later-described gripping portion 303 side) is defined as a container rear end side, based on the direction in which the toner housing container 32Y is mounted onto the toner replenishing device 60Y. When the toner housing container 32Y is moved in the direction of an arrow Q in
As for the form of the toner housing container, the toner housing container 32Y is an approximately cylindrical toner bottle. The toner housing container 32Y is mainly constituted by a container leading end side cover 34Y held non-rotatably on the toner housing container accommodating section 70, and a container body 33Y as a toner housing member with which a container gear 301Y is formed integrally. The container body 33Y is held rotatably relative to the container leading end side cover 34Y.
As shown in
The container receiving section 72 is formed such that the length thereof in the longer direction is substantially the same as the length of the container body 33Y in the longer direction. The container cover receiving section 73 is provided at the container leading end side of the container receiving section 72 in the longer direction (mounting/demounting direction) thereof, and the insertion port forming section 71 is provided at one end side of the container receiving section 72 in the longer direction thereof. In
Hence, along with the operation of mounting the toner housing container 32Y, the container leading end side cover 34Y slides over the container receiving section 72 for a while after passing through the insertion port forming section 71, and after this, gets mounted on the container cover receiving section 73.
As shown in
In the state that the container leading end side cover 34Y is mounted on the container cover receiving section 73, rotation driving is input to the container gear 301Y (
A conveying screw 614Y is provided in the conveying nozzle 611Y. The conveying screw 614Y rotates upon input of rotation driving into a conveying screw gear 605Y from the container rotation driving unit 91Y, and conveys the toner supplied into the conveying nozzle 611Y. The conveying direction downstream end of the conveying nozzle 611Y is connected to the toner fall-down conveying path 64Y. The toner conveyed by the conveying screw 614Y falls through the toner fall-down conveying path 64Y by its own weight and is replenished into the developing device 50Y (the second developer receptacle 54Y).
When the toner housing containers 32 (Y, M, C, and K) have expired (i.e., when the containers have become empty with almost all of the housed toner consumed), they are replaced with new ones respectively. The toner housing container 32 is provided with the gripping portion 303 at a longer-direction one end thereof that is opposite to the container leading end side cover 34. For the replacement, the replacement personnel can remove the mounted toner housing container 32 by gripping the gripping portion 303 and withdrawing the container.
The toner replenishing device 60Y controls the amount of toner to be supplied into the developing device 50Y based on the rotation speed of the conveying screw 614Y. Hence, the toner having passed through the conveying nozzle 611Y is directly conveyed into the developing device 50Y through the toner fall-down conveying path 64Y with the amount of supply into the developing device 50 uncontrolled. Even the toner replenishing device 60Y, of which conveying nozzle 611Y is inserted into the toner housing container 32Y as in the present embodiment, may be provided with a first toner reservoir such as a toner hopper.
The toner replenishing device 60Y of the present embodiment is configured to convey the toner supplied into the conveying nozzle 611Y by the conveying screw 614Y. However, the conveying member for conveying the toner supplied into the conveying nozzle 611Y is not limited to a screw member. For example, a mechanism for imparting a conveying force by means of a member other than a screw member may also be employed, such as a mechanism for generating a negative pressure at the opening of the conveying nozzle 611Y by means of a well-known powder pump.
Next, the toner housing containers 32 (Y, M, C, and K) and the toner replenishing devices 60 (Y, M, C, and K) of the present embodiment will be explained in greater detail. As described above, the toner housing containers 32 (Y, M, C, and K) and the toner replenishing devices 60 (Y, M, C, and K) have substantially the same configuration, except for using different colors of toners. Hence, the following explanation will be given by omitting the suffixes Y, M, C, and K representing the colors of the toners.
The toner replenishing device 60 includes the conveying nozzle 611 in which the conveying screw 614 is provided, and a nozzle shutter 612. The nozzle shutter 612 closes a nozzle opening 610 formed in the conveying nozzle 611 while in a non-mounted state (the state of
First, the toner housing container 32 will be explained.
As described above, the toner housing container 32 is mainly constituted by the container body 33 and the container leading end side cover 34.
As shown in
An uplifting portion 304 is formed on the internal wall of the container body 33 at the container leading end side. When the toner is conveyed to the container leading end side by the spiral projection 302 along with rotation of the container body 33 in the direction of the arrow A of
The boss 304h is a portion (rising portion) that rises inward in the container body 33 toward the center of rotation of the container body 33 while forming a spiral like a ridge line of a mountain. The uplifting wall surface 304f is a wall surface that connects the boss 304h with the internal circumferential wall of the container body 33 and that is on the container-rotation-direction downstream side of the boss 304h. When the toner comes into an internal space facing the uplifting portion 304 by the conveying force of the spiral projection 302 while the uplifting wall surface 304f is located at the lower side, the uplifting wall surface 304f uplifts the toner upward along with rotation of the container body 33. This enables the toner to be uplifted above the inserted conveying nozzle 611. That is, the toner is uplifted from the lower side to the upper side.
When the rotation advances further, the toner uplifted by the uplifting wall surface 304f slips off from the uplifting wall surface due to the gravity force, or collapses and falls down.
The conveying nozzle 611, which is a later-described conveying pipe on the apparatus body, is present at where the toner slips off to. Therefore, the toner is moved into a nozzle opening of the conveying pipe.
In
Because of a further necessity of conveying the toner in the direction toward the container opening portion 33a, the uplifting wall surface 304f is inclined so as to be farther from the longer direction axial line (i.e., the dashed-dotted line in
The container gear 301 is formed at a more container leading end side of the container body 33 than the uplifting portion 304. The container leading end side cover 34 is provided with a gear exposing opening 34a from which a portion (at a deeper side of
The container opening portion 33a having a cylindrical shape is formed at a more container leading end side of the container body 33 than the container gear 301. By press-fitting a receiving member fixing portion 337 of the nozzle receiving member 330 into the container opening portion 33a, it is possible to fix the nozzle receiving member 330 into the container body 33. The method for fixing the nozzle receiving member 330 is not limited to press fitting, but may be fixing with an adhesive and fixing by screwing.
The toner housing container 32 is configured such that a toner is filled into the container body 33 thereof from the opening of the container opening portion 33a, and after this, the nozzle receiving member 330 is fixed into the container opening portion 33a of the container body 33.
A cover claw hooking portion 306 is formed at the container gear 301 side end of the container opening portion 33a of the container body 33. The container leading end side cover 34 is mounted on the toner housing container 32 (container body 33) being in the state shown in
The container body 33 is formed by biaxial stretching blow molding process. This biaxial stretching blow molding process is typically a two-stage process including a pre-form molding step and a stretching blow molding step. In the pre-form molding step, a resin is injection-molded into a pre-form having a test tube shape. By this injection molding, the container opening portion 33a, the cover claw hooking portion 306, and the container gear 301 are formed at the mouth portion of the test tube shape. In the stretching blow molding step, the pre-form that has been cooled after the pre-form molding step and released from the molding die is heated and softened, and after this, blow-molded and stretched.
The portions of the container body 33 that are on the container rear end side of the container gear 301 are molded in the stretching blow molding step. That is, the uplifting portion 304, the portion where the spiral projection 302 is formed, and the gripping portion 303 are molded in the stretching blow molding step.
The portions of the container body 33 that are on the container leading end side of the container gear 301, such as the container gear 301, the container opening portion 33a, the cover claw hooking portion 306, etc. remain as their shapes on the pre-form obtained by the injection molding, which ensures them a molding precision. On the other hand, the uplifting portion 304, the portion where the spiral projection 302 is formed, and the gripping portion 303 are stretched and molded in the stretching blow molding step after injection-molded, which results in a poorer molding precision than the portions obtained by the pre-form molding.
Next, the nozzle receiving member 330 fixed into the container body 33 will be explained.
The nozzle receiving member 330 is constituted by a container shutter support member 340 as a support member, a container shutter 332, a container seal 333 as a sealing member, a container shutter spring 336 as a biasing member, and a receiving member fixing portion 337. The container shutter support member 340 is constituted by a shutter rear end support portion 335 as a rear end portion, shutter side surface support portions 335a (protruding portions) as side surface portions having a flat plate shape, shutter support opening portions 335b as side surface opening portions, and the receiving member fixing portion 337. The container shutter spring 336 is constituted by a coil spring.
A shutter side surface support portion 335a (protruding portion) serving as a protruding portion, and a shutter support opening portion 336b, which are provided on the container shutter support member 340, are provided side by side with each other in the rotation direction of the toner housing container. Two shutter side surface support portions 335a (protruding portions) facing each other form part of a cylindrical shape. The cylindrical shape is largely cut out at the positions of the shutter support opening portions 335b (two positions). With this configuration, a circular-columnar space S1 (
To sum up, the container body includes the protruding portions that protrude from the container body interior side of the container opening portion toward the container rear end side.
The nozzle receiving member 330 fixed into the container body 33 rotates together with the container body 33 when the container body 33 rotates. At this time, the shutter side surface support portions 335a (protruding portions) of the nozzle receiving member 330 rotate around the conveying nozzle 611 of the toner replenishing device 60. Therefore, the shutter side surface support portions 335a (protruding portions) and the shutter support opening portions 335b that are rotating alternately pass the region immediately above the nozzle opening 610 formed at the top portion of the conveying nozzle 611. Therefore, even if a toner deposition occurred above the nozzle opening 610 for an instant, the shutter side surface support portion 335a (protruding portion) would go across and collapse the toner deposition. This would prevent aggregation of toner deposition while in an idle state, and hence prevent a toner conveying failure upon resume. On the other hand, at the timing at which the shutter side surface support portions 335a (protruding portions) are located on the lateral sides of the conveying nozzle 611, and the shutter support opening portion 335b faces the nozzle opening 610, the toner will pass through the shutter support opening portion 335b as indicated by an arrow β in
The container shutter 332 is constituted by a leading end cylindrical portion 332c as a closing portion, a sliding portion 332d, a guide rod 332e, and shutter slip-off preventing claws 332a. The leading end cylindrical portion 332c is a portion that is on the container leading end side and hermetically contacts a cylindrical opening (the nozzle receiving port 331) of the container seal 333. The sliding portion 332d is a cylindrical portion that is on a more container rear end side than the leading end cylindrical portion 332c, has a greater external diameter than the leading end cylindrical portion 332c, and slides on the internal circumferential surfaces of the pair of shutter side surface support portions 335a (protruding portions).
The guide rod 332e is a rod member that rises from the cylinder interior of the leading end cylindrical portion 332c toward the container rear end side, and is a rod portion that, by being inserted into the coil of the container shutter spring 336, restricts the container shutter spring 336 so as not to allow the spring to buckle.
A guide rod sliding portion 332g is a pair of planer surfaces formed on both sides of the center axis of the guide rod 332e from a middle portion of the circular-columnar guide rod 332e. The container rear end side of the guide rod sliding portion 332g branches into two and forms a pair of cantilevers 332f.
The shutter slip-off preventing claws 332a are a pair of claws that are provided at an end of the guide rod 332e opposite from the base end thereof from which the guide rod rises, and at the end of the cantilevers 332f, and prevent the container shutter 332 from slipping off from the container shutter support member 340.
As shown in
Positioning is effected by this hooking of the shutter slip-off preventing claws 332a on the shutter rear end support portion 335, and by the biasing force of the container shutter spring 336. Specifically, the leading end cylindrical portion 332c and the container seal 333, which exert the toner leakage preventing function of the container shutter 332, are positioned with respect to the container shutter support member 340 in the axial direction. They are positioned so as to hermetically contact each other, to thereby make it possible to prevent leakage of the toner.
The receiving member fixing portion 337 has a tubular shape, of which diameters on the external circumferential surface and the internal circumferential surface decrease stepwise toward the container rear end side. The diameters gradually decrease from the container leading end side to the container rear end side. As shown in
As shown in
As shown in
The function of the seal member roll-in preventing space 337b will be described. When the container shutter 332 is moved from a state of closing the nozzle receiving port 331 toward the container rear end, the internal circumferential surface of the container seal 333 slides relative to the leading end cylindrical portion 332c of the container shutter 332. Hence, the internal circumferential surface of the container seal 333 is dragged by the container shutter 332 and elastically deformed so as to move toward the container rear end.
At this time, if there is no seal member roll-in preventing space 337b, and the vertical surface (the adhesive surface of the container seal 333) connecting with the third internal circumferential surface connects with the fifth internal circumferential surface GG orthogonally, there is a risk of the following state. Specifically, the elastically deformed portion of the container seal 333 is tucked in and rolled in between the internal circumferential surface of the receiving member fixing portion 337 sliding relative to the container shutter 332 and the external circumferential surface of the container shutter 332. If the container seal 333 is rolled in between the sliding portions of the receiving member fixing portion 337 and container shutter 332, i.e., between the internal circumferential surface GG and the leading end cylindrical portion 332c, the container shutter 332 is locked to the receiving member fixing portion 337 and cannot open or close the nozzle receiving port 331.
Compared with this, the nozzle receiving member 330 of the present embodiment has the seal member roll-in preventing space 337b formed at the internal circumference thereof. The internal diameters of the seal member roll-in preventing space 337b (i.e., the internal diameters of the internal circumferential surface EE and of the taper surface extending from this surface) are smaller than the external diameter of the container seal 333. Therefore, the container seal 333 as a whole would not enter the seal member roll-in preventing space 337b. Further, there is a limit to a range of the container seal 333 that may be dragged by the container shutter 332 and elastically deformed, and the container seal will return by its own elasticity before reaching the internal circumferential surface GG and getting rolled in. With this effect, it is possible to prevent making it impossible to perform opening or closing of the nozzle receiving port 331 due to the container shutter 332 being locked to the receiving member fixing portion 337.
As shown in
When the toner housing container 32 is mounted on the toner replenishing device 60 as shown in
The rotational axis direction position of the nozzle shutter 612 relative to the toner housing container 32 is determined by the nozzle shutter striking ribs 337a being struck by such a surface of the nozzle shutter flange 612a biased by the nozzle shutter spring 613 as is opposite to a nozzle shutter spring receiving surface 612f thereof. As a result, a rotational axis direction positional relationship among the container leading end side end surface of the container seal 333, the container leading end side end surface of a leading end opening 305 (a later-described internal space of the cylindrical receiving member fixing portion 337 provided in the container opening portion 33a), and the nozzle shutter 612 is determined.
Next, the operation of the container shutter 332 and the conveying nozzle 611 will be explained with reference to
After this, when the container body 33 rotates, the toner uplifted above the conveying nozzle 611 by the uplifting portion 304 falls into and is introduced into the conveying nozzle 611 from the nozzle opening 610. The toner introduced into the conveying nozzle 611 is conveyed through the conveying nozzle 611 toward the toner fall-down conveying path 64 along with rotation of the conveying screw 614, and falls through the toner fall-down conveying path 64 to be supplied into the developing device 50.
In the region of the cross-section along the line E-E of
Further, at the region where the shutter side surface support portion 335a and the boss face each other, the boss 304h curves outward in the radial direction of the container so as to conform to the contour of the shutter side surface support portion 335a (a curving portion 304i). In other words, the boss dents from the internal side toward the external side in the radial direction.
This denting portion of the boss is referred to as curving portion 304i.
The curving portion 304i is gentler than other portions of the boss 304h and conforms to the shutter side surface support portion 335a also in the longer direction.
In
Likewise, the uplifting wall surface 304f also faces the shutter side surface support portion 335a. When seen from the container rotation direction downstream side, there are the uplifting wall surface 304f, a rotation direction downstream side end surface 335c (a flat side surface) of the shutter side surface support portion 335a (protruding portion), and a rotation direction upstream side lateral edge portion 611s of the nozzle opening 610. When the conveying nozzle 611 is inserted, the shutter side surface support portions 335a as the protruding portions extend along the conveying nozzle 611.
Also by means of the uplifting portion 304 formed by the uplifting wall surfaces 304f of the container body 33 shown in
At this time, the external circumferential surface and rotation direction downstream side end surface 335c (flat side surface) of the shutter side surface support portion 335a (protruding portion) function as a toner pass-down portion for passing the toner from the uplifting portion 304 into the nozzle opening 610.
Along with the rotation of the container body 33 in the direction of the arrow A in the drawing, the toner uplifted by the uplifting wall surface 304f along the circumferential direction of the container body flows toward the direction of the nozzle opening 610 due to the gravity force (the arrow T1 in the drawing). In the configuration shown in
The presence of the curving portion 304i of the boss 304h enables the boss 304h and the uplifting wall surface 304f to conform even more to the shutter side surface support portion 335a to thereby make the shutter side surface support portion 335a effectively function in passing the toner from the uplifting wall surface into the nozzle opening.
With this arrangement, the uplifted toner efficiently enters the nozzle opening 610. Further, when a toner satisfying the formula (2) described above is used, the amount of toner to remain in the container body 33 when replacing the toner housing container 32 can be reduced. Further, when a toner satisfying the formulae (3) and (4) described above is used, the amount of toner to be replenished will be stable. This stable amount of replenishment will be maintained even when the amount of toner in the container body 33 becomes low. Further, since the amount of toner to remain in the container body 33 at the time of replacement can be reduced, economic efficiency can be improved by saving the running cost, and at the same time, environmental impacts can be reduced by reducing residual toner to be disposed of.
It is better to make the shutter side surface support portion 335a (protruding portion) and the boss 304h closely contact each other. However, to save the manufacturing costs, the boss 304h, the uplifting wall surface 304f, and the curving portion 304i are often manufactured with blow molding, which cannot be as dimensionally precise as injection molding. With blow molding, it is difficult to form a complete close contact with the shutter side surface support portion, and it is preferable to manufacture them with a slight gap in terms of mass productivity. In the present embodiment, the distance between the curving portion and the shutter side surface support portion facing the curving portion is from about 0.3 mm to 1 mm.
To sum up, the present embodiment includes the following useful features:
However, as described above, the boss 304h and the uplifting wall surface 304f are often manufactured with blow molding, which cannot be as dimensionally precise as injection molding. Therefore, it is difficult to make them completely closely contact the shutter side surface support portion 335a. Then, when they are configured as described above, it may be impossible for the toner to be conveyed well toward the conveying nozzle. Furthermore, even when the shape of the uplifting wall surface is configured so as to improve the toner conveying function, it has been sometimes impossible for the toner to be conveyed well toward the conveying nozzle.
This problem is remarkable in case of blow molding. Even by means of other than blow molding, it is difficult to realize high dimensional precision of the boss and the shutter side surface support portion. Therefore, the container body of the present invention is not limited to a product obtained by blow molding.
The present inventors consider it due to the following factors to be impossible for the toner to be conveyed well toward the conveying nozzle as described above.
For the first factor, when the toner has a high flowability, it is considered that the toner may flow down from between the shutter side surface support portion 335a and the rising portion (boss 304h) (the portion indicated by A in
For the second factor, when seen in the longer direction, the uplifting wall surface 304f is provided so as to incline toward the opening portion (so as to incline outward from the direction of the axial line of the container body), so as to be gradually away from the boss 304h, which is the closest to the conveying nozzle 611 (the portion indicated by B in
For the third factor, when seen in the longer direction likewise, the toner moves from the container rear end side of the uplifting wall surface 304f toward the leading end side thereof (the portion indicated by C in
For the fourth factor, when the toner has a low flowability, it is considered inherently impossible for the toner to be discharged.
It is possible to raise such factors as described above, and it is considered that these factors combine with each other and cause difference in the dischargeability of the toner to be discharged from inside the container to outside the container.
The toner dischargeability is a remarkable problem when the remaining amount of toner has become low.
When the remaining amount of toner is high, the toner is discharged by the momentum of the conveying force of the spiral conveying portion in the toner housing container. When the remaining amount of toner is low, it may be impossible for the toner to be poured into the nozzle opening 610, depending on the configuration of the uplifting portion and the pass-down portion.
Here, when the toner satisfying the formula (2) described above is used, for the first and second factors, it is considered that the toner particles have an appropriate aggregating force, which produces an effect of making them less susceptible to fall into a gap and making them get across a gap of a certain expanse. This allows the toner agent to be supplied into the nozzle even when there is a gap. Further, even if toner particles fall in a gap, they may not drop off and pass through the gap depending on the degree of aggregation, and it can be considered that the fallen toner particles may form an aggregate in the very region where they have fallen to thereby perform the function of filling the gap.
For the third factor, it is considered that an appropriate aggregating force of the toner particles makes the toner less likely to fall off to thereby improve the uplifting efficiency.
For the fourth factor, it is considered that increased fiowability will make the toner smooth for conveying.
When the toner housing container 32 is in the set position shown in
Here, if it is assumed that the container shutter end surface 332h and the conveying nozzle end surface 611a are flat surfaces, the container shutter end surface 332h and the conveying nozzle end surface 611a contact each other by surface slide, and they are heavily loaded as a result. It is difficult for them to have an ideally perfect interfacial slide due to errors in assembly and variations in parts, and they have a slight gap between them. Therefore, the toner may enter this gap, and be frictioned along with the surface slide.
Further, assume a case where the toner floating up in the toner housing container deposits between the container shutter 332 and the container shutter support member 340. In the state that the toner housing container 32 is mounted on the toner replenishing device 60, a braking force is applied to the container shutter because the leading end cylindrical portion 332c of the container shutter 332 is pushed onto the conveying nozzle end surface 611a by the container shutter spring 336. Consequently, it is considered that the container shutter 332 does not rotate in conjunction with the container shutter support member 340 that is fixed on the container body 33 and is rotating synchronously with the spiral projection 302. In this case, it is predicted that the toner between the container shutter 332 and the container shutter support member 340 may be frictioned by the container shutter 332.
In this case, the toner that is frictioned and applied a load as a result may form an aggregate that is larger than the particle diameter of a toner that is not applied a load. If the aggregate is conveyed into the developing device 50 through the toner replenishing device 60, abnormal images such as undesired black spots may be produced. This phenomenon of forming an aggregate is more often the case with, particularly, a low melting point toner that can form an image at a low fixing temperature, among toners.
Hence, in the present invention, it is preferable to provide an aggregation suppressing unit configured to suppress aggregation of a toner that may occur along with rotation of the container body 33, as will be explained below.
As the aggregation suppressing unit, the container shutter 332 is let to rotate in conjunction with the container shutter support member 340 even when the leading end cylindrical portion 332c of the container shutter 332 is pushed onto the conveying nozzle 611 by being pushed in the longer direction thereof by the container shutter spring 336 and is applied a braking force as the result of being pushed. This preventing effect reduces the sliding load to be applied to the toner between the container shutter 332 and the container shutter support member 340. As a conjunctive rotation, a rotation of the container shutter 332 about the axis of the guide rod 332e is assumed. A state that the container shutter 332 rotates in conjunction with the container shutter support member 340 means a state that both of them rotate simultaneously, in other words, a state that the container shutter 332 does not rotate relative to the container shutter support member 340. As the region between the container shutter 332 and the container shutter support member 340, the region between the external circumferential surface of the sliding portion 332d and the internal circumferential surface of the shutter support opening portion 335b, and the region between the guide rod sliding portion 332g and a rear end opening 335d are assumed.
The sliding load to the toner is much larger in a rotation operation about the axis than in an opening/closing operation of the container shutter 332 in the axial direction, because an opening/closing operation occurs only when the toner housing container 32 is mounted or demounted, whereas a rotation operation occurs every time a replenishing operation is performed.
The guide rod 332e is constituted by a cylindrical portion 332i, the guide rod sliding portion 332g, the cantilevers 332f, and the shutter slip-off preventing claws 332a. As shown in
When assembling the container shutter 332 on the container shutter support member 340, the guide rod 332e is inserted through the container shutter spring 336, and the pair of cantilevers 332f of the guide rod 332e are warped toward the axial center of the guide rod 332e to let the shutter slip-off preventing claws 332a pass through the rear end opening 335d. As a result, the guide rod 332e is assembled on the nozzle receiving member 330 as shown in
When the toner housing container 32 is set in the set position, the guide rod sliding portion 332g passes through the rear end opening 335d, and comes to a position at which the flat portions of the guide rod sliding portion 332g as a driving force receiving portion and the sides of the rear end opening 335d as a driving force transmitting portion face and contact each other as shown in
Accordingly, even though the container shutter end surface 332h is pushed onto the conveying nozzle end surface 611a by being pushed by the container shutter spring 336, the container shutter 332 is fixed to the rotating container shutter support member 340 in the direction of rotation about the longer axis thereof (i.e., the center axis of the guide rod 332e, and at the same time, the axis of rotation of the container body 33), by means of the surface contact between the flat portions of the guide rod sliding portion 332g and the sides of the rear end opening 335d. As a result, a rotational force is transmitted to the guide rod 332e of the container shutter 332 from the container shutter support member 340 that is rotating. Because this rotational force is greater than the braking force described above, the container shutter 332 rotates along with the rotation of the container shutter support member 340. In other words, the container shutter 332 is in conjunction with the rotation of the container shutter support member 340 (at this time, both of them are restricted from relative rotation). That is, the guide rod sliding portion 332g and the rear end opening 335d function as a driving transmitting unit that transmits a rotational force from the container shutter support member 340 to the container shutter 332. At the same time, they can be described as the aggregation suppressing unit. This aggregation suppressing unit suppresses sliding friction of the toner between the container shutter 332 and the container shutter support member 340 in the direction of rotation about the axis of the guide rod 332e. This makes it possible to suppress toner aggregation between the container shutter 332 and the container shutter support member 340 along with the rotation of the container body 33.
The aggregation suppressing unit is not limited to the guide rod sliding portion 332g, but may be the cantilevers 332f. In this case, the length and position of the cantilevers 332f may be determined such that they are positioned at the rear end opening 335d when the toner housing container 32 is in the set position.
Another aggregation suppressing unit will be explained. First, the problem to be solved by this aggregation suppressing unit will be described. When the container shutter 332 rotates simultaneously with the toner housing container 32 (container body 33), the container shutter end surface 332h rotates relative to the conveying nozzle end surface 661a. The leading end cylindrical portion 332c of the container shutter 332 is pushed onto the conveying nozzle 611 in the longer direction thereof by being pushed by the container shutter spring 336. When this relative rotation occurs in this state, the container shutter end surface 332h applies an extremely heavy sliding load to the conveying nozzle end surface 661a, which may be the cause of occurrence of a toner aggregate.
Hence, there is proposed a second aggregation suppressing unit, which suppresses toner aggregation that may be caused along with rotation of the container shutter 332 as an opening/closing member, and which aims to suppress occurrence of a toner aggregate in a region different from the region in the embodiment described above. The aggregation suppressing unit described below reduces a sliding load on the toner in a region where the conveying nozzle end surface 611a and the facing leading end cylindrical portion 332c abut on each other.
As shown in
The material of the abutment part 342 may be the same as the container shutter 332, e.g., polystyrene resin, when formed integrally with the container shutter 332. Since the container shutter 332 is a component assembled on the toner housing container 32, it is replaced together with the toner housing container 32. Therefore, on the premise that it may be replaced, the material of the abutment part 342 that is to rotate by keeping in contact with the conveying nozzle end surface 611a is, in terms of durability, preferably a material softer than the material of the conveying nozzle 611 (end surface 611a) that is set in the printer section 100 and is not to be replaced in principle.
As shown in
Next, an interfacial gap between the container shutter end surface 332h and the conveying nozzle end surface 611a formed by the abutment part 342 will be explained. As shown in
The present inventors have studied the relationship between the amount X of projection and occurrence of black spots in the images, i.e., the relationship between a sliding area of the abutment region and occurrence of black spots in the images, and found the tendency shown in
As shown in
The aggregation suppressing unit is not limited to the one obtained by integrally molding the abutment part 342 and the container shutter 332 as shown in
Also with this configuration, the sliding load to be applied to the toner that enters the interfacial gap between the container shutter end surface 332h and the conveying nozzle end surface 611a is suppressed. Therefore, it is less likely for an aggregate to occur. In this way, a load to the toner is suppressed, because the sliding load when the toner enters the interfacial gap between the container shutter end surface 332h and the conveying nozzle end surface 611a is suppressed. This makes it possible to minimize the load to the toner, and to thereby suppress occurrence of an aggregate and abnormal images.
The conveying nozzle end surface 611a is a flat planar end surface. However, as shown in
Another aggregation suppressing unit will be explained.
The aggregation suppressing unit described above is provided between the container shutter end surface 332h and the conveying nozzle end surface 611a, and is therefore particularly effective for suppressing generation of a toner aggregate. However, it is predicted that when the toner housing container 32 is demounted from the toner replenishing device 60, the toner deposited between the surfaces may fall into the image forming apparatus or onto the floor to thereby contaminate them.
Hence, the present aggregation suppressing unit includes a seal member 350 that is provided on a non-abutment region R of the container shutter end surface 332h that is not to abut on the conveying nozzle end surface 611a. This makes it possible to prevent the toner from remaining in the interfacial gap between the container shutter end surface 332h and the conveying nozzle end surface 611a.
The seal member 350 is made of an elastic material such as polyurethane foam. As shown in
Providing the seal member 350 in this way makes it difficult for the toner to enter the interfacial gap, because the facing surface 350a of the seal member 350 contacts the conveying nozzle end surface 611a before the conveying nozzle end surface 611a and the abutment part 342 abut on each other, as shown in
As shown in
By providing the seal member 350, it is possible to suppress the toner from entering the interfacial gap, which makes it possible to suppress occurrence of an aggregate due to the rotation of the container body 33 more securely.
As shown in
The present invention is also feasible when the protruding portions are, as shown in
The conveying nozzle pushes away the overlaid portions of the thin film members and is inserted into the container opening portion. In this case, there is no shutter of the above-described embodiment that is biased by the biasing member.
However, there are a pair of flat plate-shaped members that protrude from the container opening portion toward the container rear end side and function as toner pass-down portions for passing the toner from the uplifting portion into the nozzle opening, like the shutter side surface support portions 335a of the above-described embodiment.
The other members than those described above are the same as the embodiment described above.
Like this, the shape and configuration of the protruding portions may be anything as long as the effect of the present invention can be obtained.
Next, an example manufacturing step of filling the toner housing container 32 with a toner will be explained with reference to
First, a hole 33d2 (through-hole) to lead into the container body 33 is formed at the gripping portion 303 of an empty toner housing container 32 (a machining step).
After this, a cleaning nozzle is inserted from the hole 33d2 to clean the interior of the container body 33.
After this, the toner housing container 32 in which the hole 33d2 is formed is set on a filling machine 200 as shown in
Specifically, a constricted portion 33d1 of the gripping portion 303 as a hooking portion is engaged with a support portion 210 of the filling machine 200, and the toner housing container 32 is suspended such that the gripping portion 303 comes to the top.
Then, a nozzle 220 of the filling machine 200 is inserted into the hole 33d2 of the toner housing container 32, and the filling machine 200 fills the toner housing container 32 with the toner (a filling step).
Then, with reference to
This ensures sealedness of the toner housing container 32 after filled with the toner.
In the present embodiment, a cap 90 to be placed over the gripping portion 303 is used as the sealing member. However, a plug to be inserted into the hole 33d2 may be used as a sealing member, or a seal member such as polyurethane foam to be placed over the hole 33d2 for cover may be used as a sealing member. That is, the toner housing container of the present embodiment is completed as a toner housing container having a hole opened in the container body and having this hole sealed with a sealing member.
As described above, in the present embodiment, when filling the toner housing container 32 with a toner, it is unnecessary to disassemble the nozzle receiving member 330 from the container body 33 to fill the toner housing container 32 with the toner.
This improves the work efficiency in the manufacturing process.
The toner housed in the toner housing container of the present invention will be explained.
A flow rate index of the toner measured by a powder rheometer and represented by the following formula (1) is in a range represented by the following formula (2), preferably in a range represented by the following formula (3), and more preferably in a range represented by the following formula (4).
Flow rate index=(total energy at a rotation speed of 10 mm/s)/(total energy at a rotation speed of 100 mm/s) (1)
1.8≦flow rate index≦6.5 (2)
2.8≦flow rate index≦6.5 (3)
2.8≦flow rate index≦4.0 (4)
When the toner satisfies the formula (2) above, it can satisfy both of dischargeability and toner replenishing efficiency at the same time. This makes it possible to provide a toner housing container that can perform toner replenishment even when the amount of toner remaining in the toner housing container becomes low.
When the toner satisfies the formula (3) or the formula (4) above, the replenishing speed will be stable. This stable replenishing speed will be maintained even when the amount of toner in the container body 33 becomes low.
A method for adjusting the flow rate index of the toner is not particularly limited, and may be appropriately selected according to the purpose. For example, the flow rate index may be adjusted based on the types of external additives and the content of the external additives in the toner.
The flow rate index of the toner can be measured with, for example, a powder rheometer FT-4 manufactured by Sysmex Corporation, and in combination, a cylindrical split vessel having a diameter of 25 mm and a cubic capacity of 25 mL dedicated for the measurement with FT-4 and a 23.5 mm propeller-shaped blade (hereinafter, referred to as blade) dedicated for the measurement with FT-4.
The shape of the propeller-shaped blade is, for example, as shown in
The split vessel has, for example, a diameter of 26 mm, a cubic capacity of 25 mL, and a height of 52 mm from the bottom of the vessel to the splitting position. A powder layer is formed in the split vessel by charging the vessel with a toner up to the height of 55 mm.
Next, conditioning before the measurement will be explained. Conditioning is for forming a uniform powder layer by stirring the powder layer and deaerating it of excess air before the measurement. The blade is lifted down from the height of 60 mm to the height of 5 mm through the powder layer at a blade incident angle (i.e., an angle formed between the locus of the outermost edge of the moving blade and the surface of the powder layer) of 5°, while being rotated clockwise at a blade rotation speed of 40 mm/s to thereby stir the powder layer. After this, the blade lifted down from the height of 5 mm to the height of 2 mm at a blade incident angle of 2° while being rotated clockwise at a rotation speed of 40 mm/s, to thereby prevent generation of a non-uniform layer due to compression of the toner at the bottom of the vessel. Then, the blade is lifted up from the height of 2 mm to the height of 60 mm at a blade incident angle of 5° while being rotated clockwise at a rotation speed of 100 mm/s. Then, at the height of 60 mm, the blade is rotated clockwise and counterclockwise alternately, to thereby shake off the toner deposited on the blade. The process up to this is one cycle. This process is repeated for 18 cycles, to thereby complete the conditioning.
After the conditioning, any toner above the level-full height of the split vessel (a height of 52 mm from the bottom) is leveled off, and the mass of 25 mL of toner is measured. After this, the toner is measured at the rotation speeds of 100 mm/s, 70 mm/s, 40 mm/s, and 10 mm/s continuously. The measurement is at a blade incident angle of 5°.
After the measurement, total energy, which is the sum of a rotation torque and a vertical load, is displayed. The total energy at the rotation speed of 10 mm/s and the total energy at the rotation speed of 100 mm/s are extracted, and the flow rate index is calculated based on the following formula (1).
Flow rate index=(total energy at the rotation speed of 10 mm/s)/(total energy at the rotation speed of 100 mm/s) (1)
The measurement is performed after humidity conditioning of the toner at 23° C., at 53% RH, for 24 hours.
The toner contains at least, for example, toner base particles containing a binder resin and a colorant, and an external additive, and further contains other components according to necessity. The toner may be charged positively or negatively, and is not particularly limited in this regard.
The external additive is not particularly limited and may be appropriately selected according to the purpose. Examples thereof include silica particles, hydrophobized silica particles, metal salt of fatty acid (e.g., zinc stearate and aluminum stearate), metal oxide particles (e.g., titania, alumina, tin oxide, and antimony oxide) or hydrophobized product thereof, and fluoropolymer. Among these, hydrophobized silica particles, titania particles, and hydrophobized titania particles are preferable.
Examples of the hydrophobized silica particles include: R-972, R-974, RX-200, RY-200, R-202, R-805, R-812, RX-50, NAX-50, NX-90G, R-8200, and RX-300 (all manufactured by Nippon Aerosil Co., Ltd.); H2000/4, H2000T, H05TM, H13TM, H20TM, and H30TM (all manufactured by Clariant K.K.); X-24-9163A (manufactured by Shin-Etsu Chemical Co., Ltd.); and UFP-30 and UFP-35 (both manufactured by Denki Kagaku Kogyo Kabushiki Kaisha).
Examples of the titania particles include: P-25 (manufactured by Nippon Aerosil Co., Ltd.); STT-30 and STT-65C-S (both manufactured by Titan Kogyo, Ltd.); TAF-140 (manufactured by Fuji Titanium Industry Co., Ltd.); and MT-150W, MT-500B, MT-600B, and MT-150A (all manufactured by Tayca Corp.).
Examples of the hydrophobized titania particles include: T-805 (manufactured by Nippon Aerosil Co., Ltd.); STT-30A and STT-65S-S (both manufactured by Titan Kogyo, Ltd.); TAF-500T and TAF-1500T (both manufactured by Fuji Titanium Industry Co., Ltd.); JMT-1501B, JMT-150ANO, JMT-150AO, MTY-02, MT-100S, and MT-100T (all manufactured by Tayca Corp.); and IT-S(manufactured by Ishihara Sangyo Kaisha Ltd.).
Particle diameter and shape of the external additive are not particularly limited and may be appropriately selected according to the purpose.
Flowability of the toner can be controlled based on the shape and particle diameter of the external additive.
For example, in terms of particle diameter, an external additive having a larger particle diameter imparts a poorer flowability to the toner, because it is more easily immobilized on the toner base particles when mixed therewith, than an external additive having a smaller particle diameter. Conversely, an external additive having a smaller particle diameter imparts a better flowability to the toner, because it is not immobilized on the toner base particles but tends to remain flowable.
In terms of shape, an external additive having a shape closer to a true circle is more flowable and imparts a better flowability to the toner. Titanium oxide used as an external additive is acicular, whereas a spherical product and an atypically-shaped product are known as silica external additives. Among these, spherical silica is the most flowable and imparts a good flowability to the toner. Silica having a small particle diameter imparts a particularly good flowability.
The content of the external additive in the toner is not particularly limited and may be appropriately selected according to the purpose.
It is possible to control the flowability of the toner by varying the content of the external additive in the toner relative to the toner base particles. Typically, it is possible to increase the flowability of the toner by increasing the amount of the external additive in the toner, because this increases the amount of the external additive to cover the surface of the toner base particles, whereas it is possible to reduce the flowability by reducing the amount thereof. Particularly, it is possible to control the flowability of the toner effectively, by increasing or reducing the amount of spherical silica having a small particle diameter.
On the other hand, when the rate of coverage of the toner base particles with the external additive is excessively high, the area over which the surface is covered with an inorganic substance is excessively large, which makes it difficult to fix the toner. Conversely, when the rate of coverage with the external additive is excessively low, the flowability of the toner is poor, which makes it impossible to replenish the toner or makes it likely for toner particles to aggregate and produce abnormal images.
The toner base particles contain at least a binder resin and a colorant, and further contain a releasing agent, a charge controlling agent, etc. according to necessity.
The binder resin is not particularly limited and may be appropriately selected according to the purpose. Examples thereof include polyester resin, silicone resin, styrene/acrylic resin, styrene resin, acrylic resin, epoxy resin, diene-based resin, phenol resin, terpene resin, coumarin resin, amideimide resin, butyral resin, urethane resin, and ethylene/vinyl acetate resin. One of these may be used alone or two or more of these may be used in combination. Among these, polyester resin, and a combination of polyester resin and any other of the above binder resins are preferable because they have excellent low temperature fixability and can realize a smooth surface on the image, and because they have sufficient flexibility even when they have a low molecular weight.
The polyester resin is not particularly limited and may be appropriately selected according to the purpose. The polyester resin may be a modified polyester resin having any type of reactive functional group incorporated in the side chain of the polyester, or may be an unmodified polyester resin having no such group incorporated. One of these may be used alone or two or more of these may be used in combination.
The polyester resin may be a crystalline polyester resin or a non-crystalline polyester resin.
The modified polyester resin is not particularly limited and may be appropriately selected according to the purpose. Examples thereof include a resin obtained from an elongation reaction, a cross-linking reaction, or both thereof of an active hydrogen group-containing compound and polyester reactive with the active hydrogen group-containing compound (hereinafter, this polyester may be referred to as “prepolymer”). According to necessity, the elongation reaction, the cross-linking reaction, or both thereof may be terminated with a reaction terminator (e.g., a product obtained by blocking monoamine, such as diethyl amine, dibutyl amine, butyl amine, lauryl amine, and ketimine compound).
The colorant is not particularly limited and may be appropriately selected according to the purpose. Examples thereof include black pigment, yellow pigment, magenta pigment, and cyan pigment. Among these, it is preferable to add any of yellow pigment, magenta pigment, and cyan pigment.
The black pigment is used for, for example, a black toner. Examples of the black pigment include carbon black, copper oxide, manganese dioxide, aniline black, active charcoal, non-magnetic ferrite, magnetite, nigrosine dye, and iron black.
The yellow pigment is used for, for example, a yellow toner. Examples of the yellow pigment include: C.I. Pigment Yellow 74, 93, 97, 109, 128, 151, 154, 155, 166, 168, 180, and 185; naphtol yellow S; Hansa yellow (10G, 5G, and G); cadmium yellow, yellow iron oxide; yellow ocher; chrome yellow; titanium yellow; and polyazo yellow.
The magenta pigment is used for, for example, a magenta toner. Examples of the magenta pigment include: quinacridone-based pigment; and monoazo pigment such as C.I. Pigment Red 48:2, 57:1, 58:2, 5, 31, 146, 147, 150, 176, 184, and 269. The monoazo pigment may be used in combination with the quinacridone-based pigment.
The cyan pigment is used for, for example, a cyan toner. Examples of the cyan pigment include Cu-phthalocyanine pigment, Zn-phthalocyanine pigment, and Al-phthalocyanine pigment.
The content of the colorant in the toner is not particularly limited and may be appropriately selected according to the purpose. However, it is preferably from 1 part by mass to 15 parts by mass, and more preferably from 3 parts by mass to 10 parts by mass, relative to 100 parts by mass of the toner.
The colorant may be used as a master batch in which it is combined with a resin. Such a resin is not particularly limited. However, in terms of compatibility with the binder resin, the resin is preferably the binder resin or a resin having a similar structure to the binder resin.
The releasing agent is not particularly limited and may be appropriately selected according to the purpose. Examples thereof include brazing material and wax.
Examples of the brazing material and wax include plant wax, mineral wax, and petroleum wax. Examples of the plant wax include carnauba wax, cotton wax, tallow, and rice wax. Examples of animal wax include bees wax and lanolin. Examples of the mineral wax include ozocerite and cersine. Examples of the petroleum wax include paraffin, microcrystalline, and petrolatum.
The melting point of the releasing agent is not particularly limited and may be appropriately selected according to the purpose. However, it is preferably from 50° C. to 120° C., and more preferably from 60° C. to 90° C. When the melting point is lower than 50° C., the wax may adversely affect the storage stability. When the melting point is higher than 120° C., cold offset may be likely to occur upon low temperature fixing. The melting point of the releasing agent is obtained by measuring a maximum endothermic peak with a differential scanning calorimeter (TG-DSC system, TAS-100 manufactured by Rigaku Corporation).
The releasing agent is preferably present in the toner base particles dispersedly. For this purpose, the releasing agent is preferably incompatible with the binder resin. A method for minutely dispersing the releasing agent in the toner base particles is not particularly limited and may be appropriately selected according to the purpose. Examples thereof include a method of dispersing the releasing agent by applying a kneading shear thereto when manufacturing a toner.
The dispersed state of the releasing agent can be confirmed by observing a thin film piece of the toner particles with a transmission electron microscope (TEM). The dispersion diameter of the releasing agent is preferably small. However, when it is excessively small, the releasing agent may not exude sufficiently in fixing. The releasing agent is present dispersedly when the releasing agent can be confirmed at a magnification of ×10,000. When the releasing agent cannot be confirmed at the magnification of ×10,000, the releasing agent is minutely dispersed successfully, but would not exude sufficiently in fixing.
The content of the releasing agent in the toner is not particularly limited and may be appropriately selected according to the purpose. However, it is preferably from 1% by mass to 20% by mass, and more preferably from 3% by mass to 10% by mass. When the content is less than 1% by mass, the releasability will be poor, resulting in poor hot offset resistance, which makes it necessary to take measures such as oil-coating fixing. When the content is greater than 20% by mass, a great amount of the releasing agent would be deposited on the surface of the toner base particles, which is not favorable because the releasing agent is soft and has poor stress resistance, which would lead to troubles such as degradation of heat resistant storage stability due to buried external additive, filming over the photoconductor, etc.
To impart an appropriate chargeability to the toner, it is possible to add a charge controlling agent to the toner according to necessity.
The charge controlling agent may be any publicly-known charge to controlling agent. When a colored material is used, the color tone may be changed. Therefore, a colorless or nearly white material is preferable. Examples of such preferable materials include triphenylmethane dyes, molybdic acid chelate pigments, rhodamine dyes, alkoxy amines, quaternary ammonium salts (including fluorine-modified quaternary ammonium salts), alkylamides, phosphorus, phosphorus compounds, tungsten, tungsten compounds, fluorine active agents, metal salts of salicylic acid, and metal salts of salicylic acid derivatives. One of these may be used alone, or two or more of these may be used in combination.
The content of the charge controlling agent in the toner is not determined flatly, because it is determined based on the type of the binder resin and the toner producing method including a dispersing method. However, it is preferably from 0.01% by mass to 5% by mass, and more preferably from 0.02% by mass to 2% by mass relative to the binder resin. When the content is greater than 5% by mass, the toner becomes excessively chargeable, to thereby reduce the effect of the charge controlling agent and have a greater electrostatic force of attracting a developing roller, leading to degradation of flowability of the developer, or degradation of the image density. When the content is less than 0.01% by mass, charge rising property and charge buildup may be poor, which may influence toner images.
The method for producing the toner is not particularly limited and may be appropriately selected according to the purpose. Examples thereof include pulverizing method and chemical method. Toner base particles can be obtained with these methods.
Examples of the chemical method include suspension polymerization method, emulsion polymerization aggregation method, seed polymerization method, dissolution suspension method, dissolution suspension polymerization method, and phase-transfer emulsification method, which produce a toner by using a monomer as a starting material, and aggregation method for aggregating resin particles obtained by these methods while they are dispersed in an aqueous medium, and granulating them to particles of a desired size by heating and melting, etc.
The dissolution suspension method is a method of dissolving a resin or a resin precursor in an organic solvent or the like and dispersing or emulsifying it in an aqueous medium.
The dissolution suspension polymerization method is a method of, according to the dissolution suspension method, emulsifying or dispersing in an aqueous medium containing fine resin particles, an oil phase composition containing a binder resin precursor containing a functional group reactive with an active hydrogen group (this binder resin precursor is referred to as reactive group-containing prepolymer), and reacting the reactive group-containing prepolymer with an active hydrogen group-containing compound in the aqueous medium.
The phase-transfer emulsification method is a method of adding water to a solution of a resin or a resin precursor and an appropriate emulsifying agent, to thereby transfer the phase.
These producing methods will be explained below in detail.
The pulverizing method is a method of for example, melt-kneading toner materials containing at least a colorant, a binder resin, and a releasing agent, and pulverizing and classifying the melt-kneaded product, to thereby produce toner base particles.
In the melt-kneading, the toner materials are mixed, and the obtained mixture is subjected to a melt kneader to be melt-kneaded. Examples of the melt kneader include a uniaxial or biaxial continuous kneader, and a batch type kneader using a roll mill.
In the pulverizing, the kneaded product obtained by the kneading is pulverized. In this pulverizing, it is preferable to pulverize the kneaded product coarsely first, and finely next. At this time, a method of pulverizing the kneaded product by making it collide on an impact board in a jet stream, a method of pulverizing the kneaded product by making the particles collide on themselves in a jet stream, and a method of pulverizing the kneaded product in a narrow gap between a mechanically rotating rotor and a stator are preferably used.
In the classifying, the pulverized product obtained by the pulverizing is classified and adjusted to particles of a predetermined particle diameter. The classifying can be performed by removing fine particles with a cyclone, a decanter, a centrifuge, or the like.
After the pulverizing and the classifying are completed, the pulverized product may be classified in an air stream with a centrifugal force or the like, to thereby produce toner base particles having a predetermined particle diameter.
The dissolution suspension method is a method of, for example, dispersing or emulsifying in an aqueous medium, an oil phase composition obtained by dissolving or dispersing in an organic solvent, a toner composition containing at least a binder resin or a binder resin precursor, a colorant, and a releasing agent, to thereby produce toner base particles.
The organic solvent used for dissolving or dispersing the toner composition is preferably a volatile organic solvent having a boiling point of lower than 100° C., because such an organic solvent will be easily removed afterwards.
In the dissolution suspension method, it is possible to use an emulsifying agent or a dispersant according to necessity, when dispersing or emulsifying the oil phase composition in an aqueous medium.
In the dissolution suspension polymerization method, it is preferable to obtain toner base particles by, according to the dissolution suspension method, dispersing or emulsifying in an aqueous medium containing fine resin particles, an oil phase composition containing at least a binder resin, a binder resin precursor containing a functional group reactive with an active hydrogen group (this binder resin precursor is referred to as reactive-group containing prepolymer), a colorant, and a releasing agent, and reacting an active hydrogen group-containing compound contained in the oil phase composition, the aqueous medium, or both thereof with the reactive group-containing prepolymer, to thereby granulate the materials.
It is possible to produce the fine resin particles by a publicly-known polymerization method. It is preferable to obtain the fine resin particles in the form of an aqueous dispersion liquid of fine resin particles.
The volume average particle diameter of the fine resin particles is preferably from 10 nm to 300 nm, and more preferably from 30 nm to 120 nm. When the volume average particle diameter of the fine resin particles is less than 10 nm and greater than 300 nm, the particle size distribution of the toner may be poor.
The solid content concentration of the oil phase composition is preferably from 40% by mass to 80% by mass. When the solid content concentration is excessively high, it is difficult to dissolve or disperse the oil phase composition or to handle the oil phase composition because of high viscosity thereof. When the solid content concentration is excessively low, the productivity of the toner may be poor.
Toner compositions other than the binder resin, such as the colorant and the releasing agent, and a master batch or the like thereof may be individually dissolved or dispersed in an organic solvent, and after this, mixed with the binder resin dissolved or dispersed liquid.
The aqueous medium may be water alone, but a solvent miscible with water may be used in combination with water. Examples of solvent miscible with water include alcohol (e.g., methanol, isopropanol, and ethylene glycol), dimethylformamide, tetrahydrofuran, cellosolves (e.g., methyl cellosolve), and lower ketones (e.g., acetone and methyl ethyl ketone).
The method of dispersion or emulsification in the aqueous medium is not particularly limited. Publicly-known equipment such as a low speed shearing system, a high speed shearing system, a friction system, a high pressure jet system, and an ultrasonic system can be employed. Among these, a high speed shearing system is preferable in terms of making the particle diameter small. When a high speed shearing disperser is used, the rotation speed is not particularly limited, but is typically from 1,000 rpm to 30,000 rpm, and preferably from 5,000 rpm to 20,000 rpm. The temperature during the dispersing is typically from 0° C. to 150° C. (under pressure), and preferably from 20° C. to 80° C.
Method for removing the organic solvent from the obtained emulsified dispersion is not particularly limited and may be appropriately selected according to the purpose. For example, it is possible to employ a method of gradually raising the temperature while stirring the whole system under normal pressure or reduced pressure to thereby evaporate and remove the organic solvent in the liquid drops completely.
Method for washing and drying the toner base particles dispersed in the aqueous medium may be a publicly-known technique. That is, a process of solid-liquid-separating them with a centrifuge, a filter press, or the like, dispersing the obtained toner cake again in ion-exchanged water of from normal temperature to about 40° C., adjusting their pH with acid or alkali according to necessity, and then solid-liquid-separating them again is repeated a few times, to thereby remove impurities, surfactant, and the like, and after this the resultant is dried with an air flow drier, a circulating drier, a reduced pressure drier, a vibro-fluidizing drier, or the like, to thereby obtain toner particles. Fine particle components included in the toner may be removed with centrifugation or the like, or the obtained toner may be adjusted to a desired particle size distribution with a publicly-known classifier according to necessity after the drying.
The toner base particles may be mixed with particles of the external additive, the charge controlling agent, etc. At this time, a mechanical impact may be applied to suppress the particles of the external additive, etc. from being detached from the surface of the toner base particles.
The method for applying the mechanical impact is not particularly limited and may be appropriately selected according to the purpose. Examples thereof include a method of applying a mechanical impact to the mixture with a blade rotating at a high speed, and a method of subjecting the mixture into a high speed air flow, and accelerating the air flow to thereby make the particles collide on themselves or on an appropriate impact board.
The equipment used for the method is not particularly limited and may be appropriately selected according to the purpose. Examples thereof include ANGMILL (manufactured by Hosokawa Micron Corporation), an apparatus made by modifying I-TYPE MILL (manufactured by Nippon Pneumatic Mfg. Co., Ltd.) to reduce the pulverizing air pressure, a hybridization system (manufactured by Nara Machinery Co., Ltd.), a kryptron system (manufactured by Kawasaki Heavy Industries, Ltd.) and an automatic mortar.
Examples of the present invention will be explained below. The present invention is not limited to the Examples below by any means. “Part” represents “part by mass” unless otherwise expressly specified. “%” represents “% by mass” unless otherwise expressly specified.
Flow rate index of the toner was measured with a powder rheometer FT-4 manufactured by Sysmex Corporation, and in combination, a cylindrical split vessel having a diameter of 25 mm and a cubic capacity of 25 mL dedicated for the measurement with FT-4 and a 23.5 mm propeller-shaped blade (hereinafter, referred to as blade) dedicated for the measurement with FT-4.
The shape of the propeller-shaped blade was as shown in
The split vessel had a diameter of 25 mm, a cubic capacity of 25 mL, and a height of 52 mm from the bottom of the vessel to the splitting position. A powder layer was formed in the split vessel by charging the vessel with a toner up to the height of 55 mm.
Next, conditioning before the measurement will be explained. Conditioning is for forming a uniform powder layer by stirring the powder layer and deaerating it of excess air before the measurement. The blade was lifted down from the height of 60 mm to the height of 5 mm through the powder layer at a blade incident angle (i.e., an angle formed between the locus of the outermost edge of the moving blade and the surface of the powder layer) of 5°, while being rotated clockwise at a blade rotation speed of 40 mm/s to thereby stir the powder layer. After this, the blade was lifted down from the height of 5 mm to the height of 2 mm at a blade incident angle of 2° while being rotated clockwise at a rotation speed of 40 mm/s, to thereby prevent generation of a non-uniform layer due to compression of the toner at the bottom of the vessel. Then, the blade was lifted up from the height of 2 mm to the height of 60 mm at a blade incident angle of 5° while being rotated clockwise at a rotation speed of 100 mm/s. Then, at the height of 60 mm, the blade was rotated clockwise and counterclockwise alternately, to thereby shake off the toner deposited on the blade. The process up to this was one cycle. This process was repeated for 18 cycles, to thereby complete the conditioning.
After the conditioning, any toner above the level-full height of the split vessel (a height of 52 mm from the bottom) was leveled off, and the mass of 25 mL of toner was measured. After this, the toner was measured at the rotation speeds of 100 mm/s, 70 mm/s, 40 mm/s, and 10 mm/s continuously. The measurement was at a blade incident angle of 5°.
After the measurement, total energy, which was the sum of a rotation torque and a vertical load, was displayed. The total energy at the rotation speed of 10 mm/s and the total energy at the rotation speed of 100 mm/s were extracted, and the flow rate index was calculated based on the following formula (1).
Flow rate index=(total energy at the rotation speed of 10 mm/s)/(total energy at the rotation speed of 100 mm/s) (1)
The measurement was performed after humidity conditioning of the toner at 23° C., at 53% RH, for 24 hours.
A reaction tank equipped with a cooling pipe, a stirrer, and a nitrogen introducing pipe was charged with sebacic acid (202 parts) (1.00 mol), 1,6-hexanediol (154 parts) (1.30 mol), and tetrabutoxy titanate as a condensation catalyst (0.5 parts), and they were reacted under nitrogen stream at 180° C. for 8 hours while distilling away water to be produced. Next, while raising the temperature gradually to 220° C., they were reacted under nitrogen stream for 4 hours while distilling away water to be produced and 1,6-hexanediol, and further reacted at reduced pressure of from 5 mmHg to 20 mmHg until Mw reached about 15,000, to thereby obtain [Crystalline Polyester Resin 1]. The obtained [Crystalline Polyester Resin 1] had Mw of 14,000, and a melting point of 66° C.
A reaction vessel equipped with a stirrer, a thermometer, a capacitor, and a nitrogen gas introducing pipe was charged with 1,8-octanedicarboxylic acid (4.9 mol), sodium dimethyl 5-sulfoisophthalate (0.1 mol), 1,6-hexanediol (4.8 mol), and ethylene glycol (0.22 mol). After this, the interior of the vessel was turned to an inert atmosphere with nitrogen gas, and the vessel was charged with dibutyltin oxide (0.04 mol). The materials were stirred and reacted under nitrogen gas stream at about 180° C. for about 5 hours. After this, titanium tetrabutoxide (0.02 mol) was added, and the materials were additionally reacted for 4 hours at a temperature of 230° C. at reduced pressure of 10.0 mmHg in the reaction vessel to thereby obtain [Crystalline Polyester Resin 2]. The obtained [Crystalline Polyester Resin 2] had Mw of 16,000 and a melting point of 64° C.
A reaction tank equipped with a cooling pipe, a stirrer, and a nitrogen introducing pipe was charged with bisphenol A-EO 2 mol adduct (222 parts), bisphenol A-PO 2 mol adduct (129 parts), terephthalic acid (150 parts), adipic acid (15 parts), and tetrabutoxy titanate (0.5 parts), and they were reacted under nitrogen stream at 230° C. at normal pressure for 8 hours while distilling away water to be produced. Next, they were reacted at reduced pressure of from 5 mmHg to 20 mmHg, and cooled to 180° C. when the acid value became 2 mgKOH/g. Trimellitic anhydride (35 parts) was added thereto, and they were reacted at normal pressure for 3 hours, to thereby obtain [Non-Crystalline Polyester Resin 1]. The obtained [Non-Crystalline Polyester Resin 1] had Mw of 6,000 and Tg of 54° C.
A reaction tank equipped with a cooling pipe, a stirrer, and a nitrogen introducing pipe was charged with bisphenol A-EO 2 mol adduct (212 parts), bisphenol A-PO 2 mol adduct (116 parts), terephthalic acid (166 parts), and tetrabutoxy titanate (0.5 parts), and they were reacted under nitrogen stream at 230° C. at normal pressure for 8 hours while distilling away water to be produced. Next, they were reacted at reduced pressure of from 5 mmHg to 20 mmHg until Mw reached about 15,000, to thereby obtain [Non-Crystalline Polyester Resin 2]. The obtained [Non-Crystalline Polyester Resin 2] had Mw of 14,000 and Tg of 60° C.
A reaction tank equipped with a cooling pipe, a stirrer, and a nitrogen introducing pipe was charged with bisphenol A-EO 2 mol adduct (204 parts), bisphenol A-PO 2 mol adduct (106 parts), terephthalic acid (166 parts), and tetrabutoxy titanate (0.5 parts), and they were reacted under nitrogen stream at 230° C. at normal pressure for 8 hours while distilling away water to be reduced. Next, they were reacted at reduced pressure of from 5 mmHg to 20 mmHg until Mw reached about 40,000, to thereby obtain [Non-Crystalline Polyester Resin 3]. The obtained [Non-Crystalline Polyester Resin 3] had Mw of 38,000 and Tg of 62° C.
A four-necked flask equipped with a nitrogen introducing pipe, a dehydrating pipe, a stirrer, and a thermocouple was charged with bisphenol A-ethylene oxide 2 mol adduct (360 parts), bisphenol A-propylene oxide 2 mol adduct (130 parts), isophthalic acid (140 parts), adipic acid (52 parts), and titanium tetraisopropoxide (400 ppm). The materials were reacted at normal pressure at 230° C. for 8 hours, and further reacted at reduced pressure of from 10 mmHg to 15 mmHg for 4 hours. After this, trimellitic anhydride was added to the reaction vessel in an amount of 1 mol % relative to the whole resin content, and the materials were reacted at 180° C. at normal pressure for 3 hours, to thereby obtain [Non-Crystalline Polyester Resin 4]. The obtained [Non-Crystalline Polyester Resin 4] had Mw of 5,100 and Tg of 42° C.
A reaction vessel equipped with a stirrer, a thermometer, a capacitor, and a nitrogen gas introducing pipe was charged with bisphenol A-ethylene oxide 2 mol adduct (1.5 mol), bisphenol A-trimethylene oxide 2 mol adduct (1.8 mol), cyclohexanedimethanol (1.1 mol), ethylene glycol (0.62 mol), terephthalic acid (4.0 mol), and isophthalic acid (1.0 mol), and the interior of the reaction vessel was purged with dry nitrogen gas. After this, dibutyltin oxide (0.04 mol) was added to the reaction vessel, and the materials were stirred and reacted under nitrogen gas stream at about 195° C. for about 6 hours, and further stirred and reacted at an elevated temperature of about 240° C. for about 6.0 hours. After this, the pressure in the reaction vessel was reduced to 10.0 mmHg, and the materials were stirred and reacted at the reduced pressure for about 0.5 hours, to thereby obtain a pale yellow transparent [Non-Crystalline Polyester Resin 5]. The obtained [Non-Crystalline Polyester Resin 5] had Mw of 11.300 and Tg of 56° C.
A reaction tank equipped with a cooling pipe, a stirrer, and a nitrogen introducing pipe was charged with bisphenol A-EO 2 mol adduct (720 parts), bisphenol A-PO 2 mol adduct (90 parts), terephthalic acid (290 parts), and tetrabutoxy titanate (1 part), and they were reacted under nitrogen stream at 230° C. at normal pressure for 8 hours while distilling away water to be produced. Next, they were reacted at reduced pressure of from 10 mmHg to 15 mmHg for 7 hours, to thereby obtain [Intermediate Polyester 1]. [Intermediate Polyester 1] had Mn of 3,200 and Mw of 9,300.
Next, a reaction tank equipped with a cooling pipe, a stirrer, and a nitrogen introducing pipe was charged with the obtained [Intermediate Polyester 1] (400 parts), isophorone diisocyanate (95 parts), and ethyl acetate (500 parts), and they were reacted under nitrogen stream at 80° C. for 8 hours, to thereby obtain a 50% ethyl acetate solution of [Polyester Prepolymer 1] having an isocyanate group at a terminal. The content of free isocyanate in [Polyester Prepolymer 1] was 1.47% by mass.
A reaction vessel equipped with a stirring bar and a thermometer was charged with xylene (480 parts), and low molecular weight polyethylene (SANWAX LEL-400 manufactured by Sanyo Chemical Industries, Ltd.: softening point of 128° C.) (100 parts), and they were dissolved well. Then, after the reaction vessel was purged with nitrogen, a mixture solution of styrene (740 parts), acrylonitrile (100 parts), butyl acrylate (60 parts), di-t-butylperoxyhexahydroterephthalate (36 parts), and xylene (100 parts) was dropped down into the vessel at 170° C. for 3 hours, to promote polymerization. The resultant was retained at that temperature for 30 minutes. Next, the resultant was desolventized, to thereby synthesize [Graft Polymer]. The obtained [Graft Polymer] had Mw of 24,000 and Tg of 67° C.
A vessel equipped with a stirring bar and a thermometer was charged with paraffin wax (HNP-9 manufactured by Nippon Seiro Co., Ltd.: melting point of 75° C.) (50 parts), [Graft Polymer] (30 parts), and ethyl acetate (420 parts). While being stirred, the materials were warmed to 80° C., retained at 80° C. for 5 hours, then cooled to 30° C. in 1 hour, and subjected to dispersion with a beads mill (ULTRA VISCOMILL manufactured by Imex Co., Ltd.) at a liquid delivering speed of 1 kg/hr, at a disk peripheral velocity of 6 m/second, with zirconia beads having a diameter of 0.5 mm packed to 80% by volume, for 3 passes, to thereby obtain [Releasing Agent Dispersion Liquid 1].
A vessel equipped with a stirring bar and a thermometer was charged with [Crystalline Polyester Resin 1] (100 parts) and ethyl acetate (400 parts). While being stirred, the materials were heated and dissolved at 75° C., then cooled to 10° C. or lower in 1 hour, and subjected to dispersion with a beads bill (ULTRA VISCOMILL manufactured by Imex Co., Ltd.) at a liquid delivering speed of 1 kg/hr, at a disk peripheral velocity of 6 m/second, with zirconia beads having a diameter of 0.5 mm packed to 80% by volume, for 5 hours, to thereby obtain [Crystalline Polyester Resin Dispersion Liquid 1].
The materials described above were mixed with a Henschel mixer (manufactured by Nippon Coke and Engineering. Co., Ltd.). The obtained mixture was kneaded with two rolls. The kneading was started from 90° C., and after this, the temperature was gradually lowered to 50° C. The obtained kneaded product was pulverized with a pulverizer (manufactured by Hosokawa Micron Corporation) to thereby produce [Master Batch 1].
A vessel equipped with a thermometer and a stirrer was charged with [Non-Crystalline Polyester Resin 1] (93 parts), [Crystalline Polyester Resin Dispersion Liquid 1] (68 parts), [Releasing Agent Dispersion Liquid 1] (75 parts), [Master Batch 1] (18 parts), and ethyl acetate (19 parts), and they were pre-dispersed with the stirrer. After this, they were stirred with a TK homomixer (manufactured by Primix Corporation) at a rotation speed of 5,000 rpm, to be dissolved and dispersed uniformly, to thereby obtain [Oil Phase 1].
A reaction vessel equipped with a stirring bar and a thermometer was charged with water (600 parts), styrene (120 parts), methacrylic acid (100 parts), butyl acrylate (45 parts), alkylallylsulfosuccinic acid sodium salt (ELEMINOL JS-2 manufactured by Sanyo Chemical Industries, Ltd.) (10 parts), and ammonium persulfate (1 part), and they were stirred at 400 rpm for 20 minutes, which resulted in a white emulsion. The emulsion was heated until the internal temperature of the system was raised to 75° C., and then reacted for 6 hours. A 1% ammonium persulfate aqueous solution (30 parts) was further added to the vessel, and the materials were aged at 75° C. for 6 hours, to thereby obtain [Fine Resin Particle Water Dispersion]. The volume average particle diameter of the particles contained in this [Fine Resin Particle Water Dispersion] was 60 nm, and the resin content had a weight average molecular weight of 140,000, and Tg of 73° C.
Water (990 parts), [Fine Resin Particle Water Dispersion] (83 parts), a 48.5% sodium dodecyldiphenyletherdisulfonate aqueous solution (ELEMINOL MON-7 manufactured by Sanyo Chemical Industries, Ltd.) (37 parts), and ethyl acetate (90 parts) were mixed and stirred, to thereby obtain [Aqueous Phase 1].
A 50% ethyl acetate solution of [Polyester Prepolymer 1] (45 parts), and a 50% ethyl acetate solution of isophorone diamine (3 parts) were added to [Oil Phase 1] (273 parts), and they were stirred with a TK homomixer (manufactured by Primix Corporation) at a rotation speed of 5,000 rpm to be dissolved and dispersed uniformly, to thereby obtain [Oil Phase 1′]. Next, another vessel equipped with a stirrer and a thermometer was charged with [Aqueous Phase 1] (400 parts), and it was stirred with a TK homomixer (manufactured by Primix Corporation) at 13,000 rpm while adding thereto [Oil Phase 1′] to emulsify the materials for 1 minute, to thereby obtain [Emulsified Slurry 1].
A vessel equipped with a stirrer and a thermometer was charged with [Emulsified Slurry 1], and it was desolventized at 30° C. for 8 hours, to thereby obtain [Slurry 1]. The obtained [Slurry 1] was filtered at reduced pressure, and after this, subjected to the following washing process.
(1) Ion-exchanged water (100 parts) was added to the obtained filtration cake, and they were mixed with a TK homomixer (at a rotation speed of 6,000 rpm for 5 minutes), and after this, filtered.
(2) A 10% sodium hydroxide aqueous solution (100 parts) was added to the filtration cake obtained in (1), and they were mixed with a TK homomixer (at a rotation speed of 6,000 rpm for 10 minutes), and after this, filtered at reduced pressure.
(3) 10% hydrochloric acid (100 parts) was added to the filtration cake obtained in (2), and they were mixed with a TK homomixer (at a rotation speed of 6,000 rpm for 5 minutes), and after this, filtered.
(4) An operation of adding ion-exchanged water (300 parts) to the filtration cake obtained in (3), mixing them with a TK homomixer (at a rotation speed of 6,000 rpm for 5 minutes), and after this, filtering them was repeated twice, to thereby obtain a filtration cake 1.
The obtained filtration cake 1 was dried with an air-circulating drier at 45° C. for 48 hours, and after this, sieved through a mesh having a mesh size of 75 μm, to thereby produce toner base particles 1. The particle diameter of the toner base particles 1 was measured, and the volume average particle diameter (Dv) thereof was 5.6 μm.
Toner base particles 2 were obtained in the same manner as the production of the toner base particles 1, except that [Non-Crystalline Polyester Resin 4] was used instead of [Non-Crystalline Polyester Resin 1] in the production of [Oil Phase 1] in the production example 5-1. The particle diameter of the obtained toner base particles 2 was measured, and the volume average particle diameter (Dv) thereof was 5.6 μm.
[Oil Phase 2] was obtained in the same manner as the production of [Oil Phase 1], except that [Non-Crystalline Polyester Resin 1] (161 parts) was used instead of [Non-Crystalline Polyester Resin 1] (93 parts) and [Crystalline Polyester Resin Dispersion Liquid 1] (68 parts) in the production of [Oil Phase 1] in the production Example 5-1.
Toner base particles 3 were obtained in the same manner as the production of the toner base particles 1, except that [Oil Phase 1] was changed to [Oil Phase 2] in the production of the toner base particles 1 in the production example 5-1. The particle diameter of the obtained toner base particles 3 was measured, and the volume average particle diameter (Dv) thereof was 5.6 μm.
Toner base particles 4 were obtained in the same manner as the production of the toner base particles 3, except that [Releasing Agent Dispersion Liquid 1] (75 parts) was changed to 50 parts in the production of [Oil Phase 2] in the production example 5-3. The particle diameter of the obtained toner base particles 4 was measured, and the volume average particle diameter (Dv) thereof was 5.6 μm.
Toner base particles 5 were obtained in the same manner as the production of the toner base particles 4, except that in the washing step (3) in the production of the toner base particles 4 in the production example 5-4, a filtration cake was obtained by adding 10% hydrochloric acid (100 parts) to the filtration cake, mixing them with a TK homomixer (at a rotation speed of 6,000 rpm for 5 minutes), subjecting the obtained slurry to a step of heating at 55° C. for 10 minutes and smoothing the surface to reduce the surface area, and after this, filtering the resultant. The particle diameter of the obtained toner base particles 5 was measured, and the volume average particle diameter (Dv) thereof was 5.6 μm.
Toner base particles 6 were obtained in the same manner as the production of the toner base particles 3, except that [Releasing Agent Dispersion Liquid 1] (75 parts) was changed to 0 part in the production of [Oil Phase 2] in the production example 5-3. The particle diameter of the obtained toner base particles 6 was measured, and the volume average particle diameter (Dv) thereof was 5.6 μm.
The materials described above were mixed with a Henschel mixer (manufactured by Nippon Coke and Engineering. Co., Ltd.). The obtained mixture was kneaded with two rolls. The kneading was started from 90° C., and after this, the temperature was gradually lowered to 50° C. The obtained kneaded product was pulverized with a pulverizer (manufactured by Hosokawa Micron Corporation) to thereby produce [Master Batch 2].
[Non-Crystalline Polyester Resin 2] (54 parts), [Non-Crystalline Polyester Resin 3] (27 parts), [Crystalline Polyester Resin 1] (8 parts), paraffin wax (HNP-9 manufactured by Nippon Seiro Co., Ltd.: melting point of 75° C.) (6 parts), and [Master Batch 2] (12 parts) were previously mixed with a Henschel mixer (HENSCHEL 20B manufactured by Nippon Coke and Engineering. Co., Ltd.) at 1,500 rpm for 3 minutes, and after this, melted and kneaded with a uniaxial kneader (small-sized BUSS CO-KNEADER manufactured by Buss AG) at setting temperatures of 90° C. at the entrance and 60° C. at the exit and at a feeding amount of 10 kg/hr. The obtained kneaded product was rolled and cooled, and coarsely pulverized with a pulverizer (manufactured by Hosokawa Micron Corporation). Next, the resultant was finely pulverized with an I type mill (IDS-2 type, manufactured by Nippon Pneumatic Mfg. Co., Ltd.) with a flat planar impact board at an air pressure of (6.0 atm/cm2) at a feeding amount of 0.5 kg/hr, and further classified with a classifier (132 MP manufactured by Alpine AG), to thereby obtain [Toner Base Particles 7]. The particle diameter of the toner base particles 7 was measured, and the volume average particle diameter (Dv) thereof was 7.0 μm.
Styrene (91 parts) and n-butyl acrylate (29 parts) as monovinyl monomers (calculated Tg of a copolymer obtained by copolymerizing these monomers was 60° C.), carbon black (product name: #25B manufactured by Mitsubishi Chemical Corporation) (7 parts) as a colorant, a charge controlling resin (product name: FCA-1001-NS manufactured by Fujikura Kasei Co., Ltd., styrene/acrylic resin) (1 part) as a charge controlling agent, divinyl benzene (0.6 parts) as a cross-linkable polymerizable monomer, t-dodecylmercaptan (1.2 parts) as a molecular weight modifier, and polymethacrylic acid eater macromonomer (product name: AA6 manufactured by Toagosei Co., Ltd., Tg=94° C.) (0.6 parts) as a macromonomer were stirred and mixed with a stirrer, and after this, dispersed uniformly with a medium type disperser. Paraffin wax (HNP-9 manufactured by Nippon Seiro Co., Ltd.) (12 parts) as a releasing agent was added thereto, and they were mixed and dissolved, to thereby obtain a polymerizable monomer composition.
Meanwhile, an aqueous solution obtained by dissolving sodium hydroxide (hydroxide of alkali metal) (4.8 parts) in ion-exchanged water (50 parts) was gradually added to an aqueous solution obtained by dissolving magnesium chloride (water-soluble multivalent metal salt) (8.6 parts) in ion-exchanged water (250 parts) at room temperature while being stirred, to thereby prepare a magnesium hydroxide colloid (sparingly water-soluble metal hydroxide colloid) dispersion liquid.
The above polymerizable monomer composition was added to the magnesium hydroxide colloid dispersion liquid obtained as above, and they were stirred. T-butylperoxyisobutyrate (product name: PERBUTYL IB manufactured by NOF Corporation) (6 parts) as a polymerization initiator was added thereto, and they were subjected to dispersion with a high-speed emulsifier/disperser (product name: T.K. HOMOMIXER manufactured by Primix Corporation) at a rotation speed of 12,000 rpm, to thereby form liquid droplets of the polymerizable monomer composition.
Next, a water dispersion liquid of the polymerizable monomer composition formed in the liquid droplet form was added into a reaction vessel from the top thereof, and warmed to 95° C. to undergo a polymerization reaction. When the polymer inversion rate reached 95%, the temperature in the reaction vessel was changed to 90° C., and methyl methacrylate (1 part) as a polymerizable monomer for a shell, and 2,2′-azobis(2-methyl-N-(2-hydroxyethyl)-propionamide) (product name: VA-086 manufactured by Wako Pure Chemical Industries, Ltd., watersoluble) (0.1 parts) as a water-soluble polymerization initiator dissolved in ion-exchanged water (10 parts) were added. The polymerization of the materials was further continued for 3 hours with the temperature maintained at 90° C., and the materials were water-cooled to terminate the reaction, to thereby obtain a water dispersion of colorant resin particles.
While being stirred, the above water dispersion of colorant resin particles was acid-washed by dropping thereto sulfuric acid until pH became 6.5 or lower. Next, the water dispersion of colorant resin particles was filtered to separate the water, and ion-exchanged water (500 parts) was added thereto to slurry the colorant resin particles again. The slurry was subjected to a water washing process (washing, filtering, and dehydrating) a few times at room temperature (25° C.), and the obtained solid content was filtered and separated, put in a chamber of a vacuum drier, and vacuum-dried at a pressure of 30 torr at a temperature of 50° C. for 72 hours, to thereby obtain [Toner Base Particles 8]. The particle diameter of the obtained toner base particles 8 was measured, and the volume average particle diameter (Dv) thereof was 5.6 μm.
Emulsion polymerization aggregation method was performed by individually preparing a resin particle dispersion liquid, a colorant particle dispersion liquid, and a releasing agent particle dispersion liquid described below, and while stirring and mixing them at a predetermined ratio, adding a metal salt aggregating agent thereto to neutralize them ionically to thereby form aggregated particles.
Next, an inorganic hydroxide was added thereto to adjust the pH of the system from a mild acidic level to a neutral level. After this, the materials were heated to a temperature equal to or higher than the glass transition point of the resin particles, to thereby fuse and merge the materials together.
After the reaction was completed, the resultant was subjected to enough of washing and solid-liquid separation drying steps, to thereby obtain desired toner particles.
A cyan pigment (ECB-301 manufactured by Dainichiseika Color & Chemicals Mfg. Co., Ltd.) (20 parts), an anionic surfactant (NEOGEN SC manufactured by Dai-Ichi Kogyo Seiyaku Co., Ltd., effective component of 10% relative to the colorant) (2 parts), and ion-exchanged water (78 parts) were added into a stainless vessel, of which size was such that the height of a liquid surface when the above components were all added therein was at about ⅓ of the height of the vessel), dispersed with a homogenizer (ULTRA TURRAX T50 manufactured by IKA Inc.) at 5,000 rpm for 5 minutes, after this, stirred with a stirrer for one daytime and nighttime, and defoamed.
Continuously, the dispersion liquid was dispersed with a high-pressure shock disperser ULTIMIZER (HJP30006 manufactured by Sugino Machine Ltd.) at a pressure of 240 MPa.
The dispersion was performed for equivalently 25 passes, as reduced from the total amount of materials added and the processing performance.
After this, ion-exchanged water was added to adjust the solid content concentration to 16.5%.
The volume average particle diameter of the obtained colorant particle dispersion liquid was measured with a micro track UPA, and it was 115 nm.
Paraffin wax (HNP-9 manufactured by Nippon Seiro Co., Ltd.) (280 parts), an anionic surfactant (NEOGEN RK manufactured by Dai-Ichi Kogyo Seiyaku Co., Ltd., effective component of 3.0% relative to the releasing agent) (8.4 parts), an ion-exchanged water (720 parts) were dispersed sufficiently with a homogenizer (ULTRA TURRAX T50 manufactured by IKA Inc.) while being heated to 95° C., and after this, dispersed with a pressure jetting homogenizer (GAULIN HOMOGENIZER manufactured by Gaulin Inc.) at a dispersion pressure of 500 kg/cm2, for a time equivalent to 10 passes as reduced from the amount of materials added and the dispersion performance, to thereby obtain a releasing agent particle dispersion liquid.
The volume average particle diameter of the releasing agent particles was 225 nm.
After this, ion-exchanged water was added to adjust the solid content concentration to 25.8%.
[Non-Crystalline Polyester Resin 5] was dispersed with a disperser obtained by modifying CAVITRON CD1010 (manufactured by Eurotec, Ltd.) to a high-temperature high-pressure type.
Ion-exchanged water (79%), an anionic surfactant (NEOGEN RK manufactured by Dai-Ichi Kogyo Seiyaku Co., Ltd.) (1% as an effective component), and [Non-Crystalline Polyester Resin 5] (20%) were used at this concentration (composition) ratio. Their pH was adjusted to 8.5 with ammonia, and they were subjected to CAVITRON at a rotor rotation speed of 60 Hz, at a pressure of 5 kg/cm2, and with heating by a heat exchanger to 140° C., to thereby obtain a non-crystalline polyester resin dispersion liquid (1) having a volume average particle diameter of 290 nm.
[Crystalline Polyester Resin 2] (200 parts) (solid content concentration of 100%) was added to distilled water (800 parts), and they were heated to 85° C. After this, their pH was adjusted to 9.0 with ammonia, and an anionic surfactant (NEOGEN RK manufactured by Dai-Ichi Kogyo Seiyaku Co. Ltd.) (0.4 parts as an effective component) was added thereto. While being heated to 85° C., they were dispersed with a homogenizer (ULTRA TURRAX T50 manufactured by IKA Japan Inc.) at 8,000 rpm for 7 hours, to thereby obtain a crystalline polyester resin dispersion liquid (1).
The volume average particle diameter thereof was 260 nm.
[Non-Crystalline Polyester Resin Dispersion Liquid 1](non-crystalline polyester resin concentration of 20%) (150 parts) and an anionic surfactant (NEOGEN RK manufactured by Dai-Ichi Kogyo Seiyaku Co., Ltd., amount of effective component of 60%) (1.5 parts) were mixed. After this, a 1.0% nitric acid aqueous solution was added thereto, to adjust their pH to 4.0, to thereby prepare additional particles (1).
A 3-liter reaction vessel equipped with a thermometer, a pH meter, and a stirrer was charged with ion-exchanged water (410 parts), the crystalline polyester resin dispersion liquid (1) (160 parts) (crystalline polyester resin concentration of 20%), the non-crystalline polyester resin dispersion liquid (1) (340 parts) (non-crystalline polyester resin concentration of 20%), and an anionic surfactant (NEOGEN RK manufactured by Dai-Ichi Kogyo Seiyaku Co., Ltd., an amount of effective component of 60%) (2.5 parts) (effective component of 1.5 parts). While being temperature-controlled from the outside with a mantle heater, the materials were retained at a temperature of 30° C. at a stirring rotation speed of 150 rpm for 30 minutes.
After this, the colorant particle dispersion liquid (50 parts) (colorant concentration of 15%), and the releasing agent particle dispersion liquid (60 parts) (releasing agent concentration of 25%) were added thereto, and the materials were retained for 5 minutes.
While they were maintained at that state, a 1.0% nitric acid aqueous water was added thereto to adjust their pH to 2.7.
The stirrer and the mantle heater were removed, and while the materials were dispersed with a homogenizer (ULTRA TURRAX T50 manufactured by IKA Japan Inc.) at 3,000 rpm, a mixture solution of polyaluminum chloride (0.33 parts) and a 0.1% nitric acid aqueous solution (37.5 parts) was added thereto by half the amount thereof. After this, the materials were dispersed at a dispersing rotation speed of 5,000 rpm while adding thereto the remaining half of the mixture solution in 1 minute, and then dispersed at a dispersing rotation speed of 6,500 rpm for 6 minutes.
The reaction vessel was mounted with the stirrer and the mantle heater, and the materials were warmed to 42° C. at a rate of 0.5° C./minute while appropriately adjusting the rotation speed of the stirrer so as for the slurry to be stirred sufficiently, and retained at 42° C. for 15 minutes. After this, while raising the temperature at a rate of 0.05° C./minute, the particle diameter of the materials was measured every 10 minutes with COULTER MULTISIZER II (manufactured by Coulter Inc., with an aperture diameter of 50 μm) at a measurement concentration of 10% obtained by ISOTON as a diluent. When the volume average particle diameter became 5.0 μm, the additional particles (1) (150 parts) was added thereto in 3 minutes.
After the materials were retained for 30 minutes after the addition of the additional particles, a 5% sodium hydroxide aqueous solution was used to adjust pH to 9.0.
After this, the materials were warmed to 95° C. at a temperature raising rate of 1° C./minute while adjusting pH to 9.0 every 5° C., and after this, retained at that state. When 2 hours passed, the materials were confirmed to have become substantially spherical, and cooled to 20° C. at a rate of 1° C./minute, to thereby solidify the particles
After this, the reaction product was filtered, and passed through ion-exchanged water to be washed. When the electrical conductivity of the filtrate became 50 mS or lower, the particles in a cake form were extracted, and added to ion-exchanged water of an amount of 10 times as large as the mass of the particles. They were stirred with a three-one motor. When the particles were broken apart sufficiently, pH was adjusted to 3.8 with a 1.0% nitric acid aqueous solution, and the materials were retained for 10 minutes.
After this, the materials were again filtered, and passed through water to be washed. When the electrical conductivity of the filtrate became 10 mS or lower, the passing water was stopped to allow the materials to undergo solid-liquid separation.
The particles obtained in a cake form were broken apart with OSTER and dried with an oven set to 25° C. for 24 hours, to thereby obtain [Toner Base Particles 9]. The particle diameter of the toner base particles 9 was measured, and the volume average particle diameter (Dv) thereof was 5.7 μm.
According to Table 1, predetermined external additives were added in a predetermined amount to the obtained [Toner Base Particles 1] to [Toner Base Particles 9] (100 parts). As a mixing order, silica A was firstly added and mixed, titanium oxide (product name “JMT-150IB” manufactured by Tayca Corp.) (0.6 parts) was secondly added and mixed, and silica B was thirdly added and mixed. After the mixing, the mixture was passed through a sieve with a mesh size of 500, to thereby obtain toners 1 to 17.
The toner housing container shown in
The container body of the toner housing container shown in
The uplifting portion had an uplifting wall surface that extended from the internal wall surface of the container body toward the protruding portion, and a curving portion that curved so as to conform to the protruding portion.
The uplifting portion also had a rising portion that rose from the internal wall surface of the container body toward the protruding portion. The rising portion had the curving portion that curved so as to conform to the protruding portion.
The protruding portion was provided such that when the toner housing container was mounted on a toner conveying device, the protruding portion may be present between the curving portion and a toner receiving port of a conveying pipe being inserted.
Furthermore, in the toner housing container shown in
Moreover, the toner housing container shown in
In the toner housing container shown in
The toner housing container was evaluated according to the following evaluation method.
At this time, dischargeability of the toner from the container body was evaluated based on the following evaluation criteria. The results are shown in Table 1.
The toner housing container was filled with 120 g of toner (the cubic capacity of the toner housing container was 1,200 mL). The toner housing container was shaken to stir the toner sufficiently. The toner housing container was mounted on the replenishing device including the conveying nozzle described in the embodiment (see
Condition: rotation speed of the toner housing container: 100 rpm
Pitch of the conveying screw in the conveying nozzle of the replenishing device: 12.5 mm
Outer diameter of the conveying screw: 10 mm
Shaft diameter of the conveying screw: 4 mm
Rotation speed of the conveying screw: 500 rpm
B: Toner was discharged even when the amount of toner remaining in the housing container became 70 g.
D: Toner became undischargeable before the amount of toner remaining in the housing container became 70 g.
In this experiment, based on the assumption that the amount of toner filled before used (the amount of toner filled when shipping the product) was 200 g or more, the evaluation criterion for examining the dischargeability was set to an amount of remaining toner of 70 g as above.
B was a pass level, and D was a failure level.
The toner housing container described above was evaluated according to the same evaluation method as the method for evaluating the diachargeability.
At this time, replenishing stability of the toner from the container body was evaluated based on the following evaluation criteria. The results are shown in Table 1.
A: Very favorable (in an operation to drive the device until the toner could no longer be discharged, when the amount of toner remaining in the toner housing container was in the range of 10 g or more but less than 70 g, the amount of toner replenished was maintained stably at 0.4 g/sec or more (at a constant amount), “a” in
B: Favorable (in an operation to drive the device until the toner could no longer be discharged, when the amount of toner remaining in the toner housing container was in the range of 10 g or more but less than 70 g, the amount of toner replenished was maintained constant at less than 0.4 g/sec, “b” in
C: Acceptable level (in an operation to drive the device until the toner could no longer be discharged, when the amount of toner remaining in the toner housing container became less than 70 g, the toner was discharged for sure, but the amount of toner replenished was not constant, and decreased with inclination, “c” in
D: Practically unusable level (in an operation to drive the device until the toner could no longer be discharged, the toner was discharged for sure, but became undischargeable when the amount of remaining toner was 70 g or more)
DD: Practically unusable level (the toner could not be discharged)
A, B, and C were pass levels, and D and DD were failure levels.
Further, in this experiment, the amount of fluctuation of the amount of replenishment of the toners evaluated as A and B was 0.06 g/sec or less in the range of the remaining amount of from 10 g to 70 g.
In Table 1, the kinds of silica are as follows.
X-24 (product name): manufactured by Shin-Etsu Chemical Co., Ltd.
UFP35 (product name): manufactured by Denki Kagaku Kogyo Kabushiki Kaisha
UFP50 (product name): manufactured by Denki Kagaku Kogyo Kabushiki Kaisha
NX90G (product name): manufactured by Nippon Aerosil Co., Ltd.
H2000 (product name): manufactured by Clariant K.K.
Aspects of the present invention are as follows, for example.
<1> A toner housing container, including:
a container body mountable on a toner conveying device and housing a toner to be supplied into the toner conveying device;
a conveying portion provided in the container body and configured to convey the toner from one end of the container body in a longer direction thereof to the other end thereof at which a container opening portion is provided;
a pipe receiving port provided at the container opening portion and capable of receiving a conveying pipe fixed to the toner conveying device; and
an uplifting portion configured to uplift the toner conveyed by the conveying portion from a lower side of the container body to an upper side thereof and move the toner toward a toner receiving port of the conveying pipe,
wherein a flow rate index of the toner measured by a powder rheometer and represented by the following formula (1) is in a range represented by the following formula (2),
wherein the container body includes a protruding portion protruding from a container body interior side of the container opening portion toward the one end,
wherein the uplifting portion includes an uplifting wall surface extending from an internal wall surface of the container body toward the protruding portion, and a curving portion curving so as to conform to the protruding portion, and
wherein the protruding portion is provided such that when the toner housing container is mounted on the toner conveying device, the protruding portion is present between the curving portion and the toner receiving port of the conveying pipe being inserted,
Flow rate index=(total energy at a rotation speed of 10 mm/s)/(total energy at a rotation speed of 100 mm/s) (1)
1.8≦flow rate index≦6.5 (2).
In the toner housing container according to <1>, the toner housed in the container body is conveyed by the conveying portion toward the other end at which the container opening portion is provided. When the toner is moved toward the toner receiving port of the conveying pipe by the uplifting portion, as long as the protruding portion of the container body is present between the curving portion of the uplifting portion and the toner receiving port of the conveying pipe being inserted, and as long as the flow rate index of the toner satisfies the formula (2), the toner will be replenished stably into the developing device and can be replenished into the developing device even when the amount of toner remaining in the toner housing container becomes low.
<2> A toner housing container, including:
a container body mountable on a toner conveying device and housing a toner to be supplied into the toner conveying device;
a conveying portion provided in the container body and configured to convey the toner from one end of the container body in a longer direction thereof to the other end thereof at which a container opening portion is provided;
a pipe receiving port provided at the container opening portion and capable of receiving a conveying pipe fixed to the toner conveying device; and
an uplifting portion configured to uplift the toner conveyed by the conveying portion from a lower side of the container body to an upper side thereof and move the toner toward a toner receiving port of the conveying pipe,
wherein a flow rate index of the toner measured by a powder rheometer and represented by the following formula (1) is in a range represented by the following formula (2),
wherein the container body includes a protruding portion protruding from a container body interior side of the container opening portion toward the one end,
wherein the uplifting portion includes a rising portion rising from an internal wall surface of the container body toward the protruding portion,
wherein the rising portion includes a curving portion curving so as to conform to the protruding portion, and
wherein the protruding portion is provided such that when the toner housing container is mounted on the toner conveying device, the protruding portion is present between the curving portion and the toner receiving port of the conveying pipe being inserted,
Flow rate index=(total energy at a rotation speed of 10 mm/s)/(total energy at a rotation speed of 100 mm/s) (1)
1.8≦flow rate index≦6.5 (2).
In the toner housing container according to <2>, the toner housed in the container body is conveyed by the conveying portion toward the other end at which the container opening portion is provided. When the toner is moved toward the toner receiving port of the conveying pipe by the uplifting portion, as long as the protruding portion of the container body is present between the curving portion of the uplifting portion and the toner receiving port of the conveying pipe being inserted, and as long as the flow rate index of the toner satisfies the formula (2), the toner will be replenished stably into the developing device and can be replenished into the developing device even when the amount of toner remaining in the toner housing container becomes low.
<3> The toner housing container according to <1> or <2>,
wherein the flow rate index of the toner is in a range represented by the following formula (3),
2.8≦flow rate index≦6.5 (3).
<4> The toner housing container according to any one of <1> to <3>,
wherein the flow rate index of the toner is in a range represented by the following formula (4),
2.8≦flow rate index≦4.0 (4).
<5> The toner housing container according to any one of <1> to <4>,
wherein the protruding portion is a plate-shaped member, and
wherein a flat side surface of the plate-shaped member is provided so as to be present between the curving portion and the toner receiving port of the conveying pipe being inserted.
<6> The toner housing container according to any one of <1> to <5>,
wherein the toner housing container includes two uplifting portions, and
wherein when the toner housing container is mounted on the toner conveying device, the protruding portion is present between the curving portions of respective ones of the two uplifting portions and the toner receiving port of the conveying pipe being inserted.
<7> The toner housing container according to any one of <1> to <6>,
wherein the uplifting portion and the protruding portion are fixed to the container body or formed integrally with the container body, and
wherein the uplifting portion uplifts the toner from the lower side to the upper side by rotation of the container body.
<8> The toner housing container according to any one of <1> to <7>,
wherein the toner housing container includes a shutter member capable of moving between a closing position to close the container opening portion and an opening position to open the container opening portion,
wherein the shutter member moves from the closing position to the opening position by being pushed by the conveying pipe, and
wherein the protruding portion is provided so as to extend along a region in which the shutter member moves.
<9> An image forming apparatus, including:
an image forming apparatus body in which the toner housing container according to any one of <1> to <8> is set demountably.
This application claims priority to Japanese application No. 2013-107053, filed on May 21, 2013 and incorporated herein by reference, and Japanese application No. 2014-096927, filed on May 8, 2014 and incorporated herein by reference.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2013-107053 | May 2013 | JP | national |
| 2014-096927 | May 2014 | JP | national |
