Patent Grant
10663876
This application claims priority under 35 U.S.C. § 119(b) to Japanese Application No. 2017-229772, filed Nov. 30, 2017 and Japanese Application No. 2018-136292, filed Jul. 20, 2018, the disclosures of which are incorporated herein by reference in their entirety.
1. Field of the Invention
The present invention relates to a toner as a developing agent, and a toner cartridge, a development device and an image forming apparatus containing the toner.
2. Description of the Related Art
In order to improve the quality of a print image (toner image) formed on a sheet by an image forming apparatus employing an electrophotographic process, there has been a proposal specifying melt viscosity and a ratio of a toner to be used. See Japanese Patent Application Publication No. 2015-68889 (in particular, claims 1 to 3), for example.
However, it is sometimes impossible to maintain the quality of print images at a high level just by specifying the melt viscosity and the ratio of the toner. For example, even when the color tone of a print image just after the printing is excellent, colors of the print image can fade away due to chronological change (i.e., light resistance is insufficient). Further, when the printing is performed in consideration of the chronological change in the color tone of the print image, there are cases where the color tone of the print image just after the printing is inappropriate. Incidentally, the color tone means a detailed tone of color, such as subtle gradation of color, subtle deviation in color, and so forth.
The object of the present invention is to provide a toner that makes it possible to form a print image having an excellent color tone and excelling in the light resistance, and a toner cartridge, a development device and an image forming apparatus containing the toner.
A toner according to the present invention includes binder resin; and a coloring agent provided in the hinder resin. The coloring agent is configured so that hue of a hue measurement print image printed on a print medium with the toner satisfies
−8.6≤a*(Y)≤−7.9 and 93.4≤b*(Y)≤95.4
where a*(Y) and b*(Y) respectively represent an a* value and a b* value of the hue measurement print image in an L*a*b* color model,
light resistance F of a light resistance measurement print image printed on a print medium with the toner, after an irradiation test in which the light resistance measurement print image is irradiated with light having 0.36 W/m2 spectral irradiance at a wavelength of 340 nm for 663 hours satisfies
F≥70%, and
the light resistance F is obtained as
F (%)=(D(E)/D(S))×100(%)
where D(E) represents optical density of a 100% density image with the toner after the irradiation test and D(S) represents optical density of the 100% density image with the toner before the irradiation test. Furthermore, the toner is configured so that melt viscosity η of the toner at 120° C. satisfies
1400 (Pa·s)≤η≤1600 (Pa·s).
According to the present invention, a print image having an excellent color tone and excelling in the light resistance can be formed.
In the accompanying drawings:
A toner, a toner cartridge, a development device and an image forming apparatus according to embodiments of the present invention will be described below with reference to the accompanying drawings. In a first embodiment, a description will be given of an image forming apparatus using a toner according to the embodiment, a development device as a development means constituting a part of the image forming apparatus, and a toner cartridge that can be attached to the development device. In second and third embodiments, a description will be given of toners as developing agents employing the present invention. However, the following embodiments are just examples for illustration and a variety of modifications are possible within the scope of the present invention.
(1) First Embodiment
The image forming apparatus 1 includes image forming sections 10W, 10Y, 10M, 10C and 10K as image forming means arranged in series in a moving direction D1 in a part over the intermediate transfer belt 9. The image forming sections 10W, 10Y, 10M, 10C and 10K respectively form toner images according to image data by using a white (W) toner, a yellow (Y) toner, a magenta (M) toner, a cyan (C) toner and a black (K) toner. Each image forming section 10W, 10Y, 10M, 10C, 10K can be provided as an exchangeable unit structure to be detachably mounted on a main body of the apparatus. The yellow toner contained in a development device 11Y of the image forming section 10Y or contained in a toner cartridge attached to the development device 11Y is a toner according to the second or third embodiment of the present invention. Incidentally, the white toner, the magenta toner, the cyan toner and the black toner contained in development devices 11W, 11M, 11C and 11K of the image forming sections 10W, 10M, 10C and 10K or contained in toner cartridges attached to the development devices 11W, 11M, 11C and 11K are genuine toners of an ordinary (commercially available) type.
Each image forming section 10W, 10Y, 10M, 10C, 10K includes a photosensitive drum 12W, 12Y, 12M, 12C, 12K as an image bearing body on whose surface an electrostatic latent image is formed and a charging roller 13W, 13Y, 13M, 13C, 13K as a charging device or charging means for uniformly charging the surface of the photosensitive drum 12W, 12Y, 12M, 12C, 12K. Further, each image forming section 10W, 10Y, 10M, 10C, 10K includes an LED (Light-Emitting Diode) array head 14W, 14Y, 14M, 14C, 14K, as an exposure device or exposure means for forming the electrostatic latent image according to image data by applying light to the uniformly charged surface of the photosensitive drum 12W, 12Y, 12M, 12C, 12K, and a cleaning blade 5W, 5Y, 5M, 5C, 5K. Incidentally, it is also possible to provide each LED array head 14W, 14Y, 14M, 14C, 14K not as a part of the image forming section 10W, 10Y, 10M, 10C, 10K provided as an exchangeable unit structure but as a component fixed to the main body of the apparatus.
Each photosensitive drum 12W, 12Y, 12M, 12C, 12K includes an electrically conductive support body in a cylindrical shape and a photosensitive layer part made of a photosensitive layer applied on a surface of the electrically conductive support body. The photosensitive layer part includes a blocking layer, a charge generation layer and a charge transport layer that are stacked in layers. The charge transport layer has been applied up to a thickness of approximately 18 μm, for example. The film thickness is measured by using an eddy current film thickness meter “LH-200J” produced by Kett Electric Laboratory, for example.
Each image forming section 10W, 10Y, 10M, 10C, 10K includes the development device 11W, 11Y, 11M, 11C, 11K as the development means for supplying the white toner, the yellow toner, the magenta toner, the cyan toner or the black toner to the surface of the photosensitive drum 12W, 12Y, 12M, 12C, 12K. Each development device 11W, 11Y, 11M, 11C, 11K includes a development roller 15W, 15Y, 15M, 15C, 15K as a developing agent bearing body, a supply roller 17W, 17Y, 17M, 17C, 17K, a development blade 16W, 16Y, 16M, 16C, 16K for regulating a thickness of the toner on the development roller 15W, 15Y, 15M, 15C, 15K, and a toner storage part 18W, 18Y, 18M, 18C, 18K as a container for storing the white toner, the yellow toner, the magenta toner, the cyan toner or the black toner. Each toner storage part 18W, 18Y, 18M, 18C, 18K includes a toner cartridge that can be attached to the development device 11W, 11Y, 11M, 11C, 11K.
Each development roller 15W, 15Y, 15M, 15C, 15K includes a shaft made of metal and an elastic body provided on the periphery of the shaft. The elastic body is semiconductive urethane rubber at rubber hardness of 70° (ASKER C), for example. Each supply roller 17W, 17Y, 17M, 17C, 17K includes a shaft made of metal and a foam body provided on the periphery of the shaft. The foam body is silicone foam at hardness of 50° (ASKER F), for example.
The image forming apparatus 1 includes a sheet cassette 20 in which unused sheets 23 are stacked up, a sheet feed roller 21 for extracting the sheets 23 from the sheet cassette 20 sheet by sheet by rotating in a direction of an arrow D2, and conveyance rollers 22 for conveying the sheet 23 in a direction of an arrow D3. Further, the image forming apparatus 1 includes the intermediate transfer belt 9 in an endless shape moving in a direction of an arrow D1, drive rollers 25a and 25b for driving the intermediate transfer belt 9, a driven roller 25c for supporting the intermediate transfer belt 9, and a cleaning blade 4 for removing the toners remaining on the surface of the intermediate transfer belt 9. Furthermore, the image forming apparatus 1 includes transfer rollers 19W, 19Y, 19M, 19C and 19K for transferring the toner image of the white toner, the toner image of the yellow toner, the toner image of the magenta toner, the toner image of the cyan toner and the toner image of the black toner respectively formed on the surfaces of the photosensitive drums 12W, 12Y, 12M, 12C and 12K onto the intermediate transfer belt 9 (primary transfer) and a transfer roller 27, as a transfer unit or transfer means for transferring the toner images formed on the intermediate transfer belt 9 onto the sheet 23 as the print medium (secondary transfer). Moreover, the image forming apparatus 1 includes a fixing unit 24, as a fixing means including a heating roller 28 having a heating element such as a halogen lamp and a pressure roller 29, and an ejection roller unit 26 for ejecting the sheet 23 after passing through the fixing unit 24 to the outside of the apparatus.
Further, the image forming apparatus 1 includes various types of sensors 38 for detecting a position of the sheet 23, temperature, humidity, and so forth, a CPU (Central Processing Unit) 37, a process control section 40 for controlling a voltage of each section such as the image forming sections 10W, 10Y, 10M, 10C and 10K, a development voltage control section 41, a layer formation/supply voltage control section 42, a charging voltage control section 43, an exposure control section 44, a transfer voltage control section 46, and a motor control section 47. The development voltage control section 41 controls voltages of the development rollers 15W, 15Y, 15M, 15C and 15K. The layer formation/supply voltage control section 42 controls voltages of the supply rollers 17W, 17Y, 17M, 17C and 17K and the development blades 16W, 16Y, 16M, 16C and 16K. The charging voltage control section 43 controls voltages of the charging rollers 13W, 13Y, 13M, 13C and 13K. The transfer voltage control section 46 controls voltages of the transfer rollers 19W, 19Y, 19M, 19C and 19K and the transfer roller 27. The exposure control section 44 controls lighting and extinction of LEDs of the LED array heads 14W, 14Y, 14M, 14C and 14K.
The motor control section 47 includes a photosensitive drum motor control section (not shown) for controlling a photosensitive drum motor 112. The motor control section 47 rotates the photosensitive drums 12W, 12Y, 12M, 12C and 12K in a predetermined direction by controlling the photosensitive drum motor 112 via the photosensitive drum motor control section. In each image forming section, the photosensitive drum 12W, 12Y, 12M, 12C, 12K, the development roller 15W, 15Y, 15M, 15C, 15K and the supply roller 17W, 17Y, 17M, 17C, 17K are connected together by a drive force transmission mechanism such as one or more gears, and the development roller 15W, 15Y, 15M, 15C, 15K and the supply roller 17W, 17Y, 17M, 17C, 17K rotate in conjunction with the rotation of the photosensitive drum 12W, 12Y, 12M, 12C, 12K. Further, the motor control section 47 rotates the drive rollers 25a and 25b for the intermediate transfer belt 9 by controlling a transfer belt drive motor (not shown). Furthermore, the motor control section 47 rotates the sheet feed roller 21 by controlling a sheet feed motor (not shown).
Further, the image forming apparatus 1 includes a separation/contact means 48 as a separation/contact mechanism, a separation/contact condition judgment section 52, an up-and-down motor 122, a revolution number detection section 50, and a lifetime calculation section 51. The separation/contact means 48 makes each image forming section 10W, 10Y, 10M, 10C, 10K separate from or contact the intermediate transfer belt 9 by driving the up-and-down motor 122 to move an up-and-down link lever. The revolution number detection section 50 detects a cumulative number of revolutions of each photosensitive drum 12W, 121, 12M, 12C, 12K. The lifetime calculation section 51 calculates a remaining number of revolutions of each photosensitive drum 12W, 12Y, 12M, 12C, 12K before expiration of the lifetime of the photosensitive drum 12W, 12Y, 12M, 12C, 12K.
The separation/contact condition judgment section 52 judges a separation/contact condition of each image forming section 10W, 10Y, 10M, 10C, 10K based on a rotational condition of the photosensitive drum 12W, 12Y, 12M, 12C, 12K. When the image forming section 10W has no image data of an electrostatic latent image for the white toner, the image forming section 10W remains separate from the intermediate transfer belt 9 and no rotational drive force is transmitted to the photosensitive drum 12W.
Furthermore, the image forming apparatus 1 includes a unit order storage section 53 and a data presence/absence judgment section 54. The unit order storage section 53 stores the order of arrangement of the image forming sections 10W, 10Y, 10M, 10C and 10K. The data presence/absence judgment section 54 judges whether image data to be printed by each image forming section 10W, 10Y, 10M, 10C, 10K exists or not by analyzing print data transmitted from the host device 31 and received by the interface section 32.
The print control section 30 commands the motor control section 47 to rotate the photosensitive drums 12W, 12Y, 12M, 12C and 12K as the image bearing bodies by using the photosensitive drum motor 112 via the photosensitive drum motor control section. At the same time, the development rollers 15W, 15Y, 15M, 15C and 15K and the supply rollers 17W, 17Y, 17M, 17C and 17K are rotated.
The print control section 30 commands the development voltage control section 41 to apply voltages to the development rollers 15W, 15Y, 15M, 15C and 15K, commands the layer formation/supply voltage control section 42 to apply voltages to the supply rollers 17W, 17Y, 17M, 17C and 17K and the development blades 16W, 16Y, 16M, 16C and 16K, and commands the charging voltage control section 43 to apply voltages to the charging rollers 13W, 13Y, 13M, 13C and 13K. When each photosensitive drum 12W, 12Y, 12M, 12C, 12K rotates, the charging roller 13W, 13Y, 13M, 13C, 13K rotates accompanying the rotation of the photosensitive drum 12W, 12Y, 12M, 12C, 12K and the surface of the photosensitive drum 12W, 12Y, 12M, 12C, 12K is charged.
After the surfaces of the photosensitive drums 12W, 12Y, 12M, 12C and 12K have been charged uniformly, the print control section 30 commands the exposure control section 44 to form electrostatic latent images according to image data on the surfaces of the photosensitive drums 12W, 12Y, 12M, 12C and 12K with the LED array heads 14W, 14Y, 14M, 14C and 14K.
After the electrostatic latent image has been formed on the surface of each photosensitive drum 12W, 12Y, 12M, 12C, 12K, the electrostatic latent image on the surface of the photosensitive drum 12W, 12Y, 12M, 12C, 12K is developed with the toner on the surface of the development roller 15W, 15Y, 15M, 15C, 15K.
Meanwhile, the print control section 30 commands the motor control section 47 to rotate the drive rollers 25a and 25b for the intermediate transfer belt 9 in a direction of an arrow D4 and a direction of an arrow D5 by using the transfer belt drive motor. The rotation of the drive rollers 25a and 25b causes the intermediate transfer belt 9 to move and rotate. Then, the print control section 30 commands the motor control section 47 to feed a sheet 23 with the sheet feed roller 21 by using the sheet feed motor. The sheet 23 after being fed by the sheet feed roller 21 rotating in the direction of the arrow D2 is pressed between the conveyance rollers 22 and conveyed in the direction of the arrow D3.
The sheet 23 onto which the toner images have been transferred is heated and pressed by the fixing unit 24, by which the toner images are fixed on the sheet 23. The sheet 23 is ejected by the ejection roller unit 26 to the outside of the apparatus through an ejection port.
The image forming apparatus 1, the development device 11Y and the toner cartridge according to the first embodiment include the toner according to the second or third embodiment as the yellow toner. In cases where the image forming apparatus 1 according to the first embodiment includes the toner according to the second embodiment, a print image having an excellent color tone and excelling in the light resistance can be formed. In cases where the image forming apparatus 1 according to the first embodiment includes the toner according to the third embodiment, a print image having an excellent color tone, excelling in the light resistance, and excelling in sublimation resistance can be formed.
(2) Second Embodiment
(2-1) Toner According to Second Embodiment
The coloring agent 102 includes one or more types of yellow pigment. The coloring agent 102 in the toner according to the second embodiment is configured so that the print hue of a hue measurement print image (yellow 100% density image shown in
−8.6≤a*(Y)≤−7.9 (1)
93.4≤b*(Y)≤95.4 (2)
where a*(Y) and b*(Y) represent the a* value and the b* value of the hue measurement print image in the CIE1976 (L*, a*, b*) color space, that is, the L*a*b* color model.
Further, the toner according to the second embodiment is configured so that the melt viscosity η (Pa·s (pascal second)) of the toner at 120° C. satisfies the following condition (3): In other words, for the toner according to the second embodiment, the type and molecular weight of the resin used as the binder resin 101 and the types, amounts, compounding ratios, etc. of other components are determined to satisfy the following condition (3):
1400 (Pa·s)≤η≤1600 (Pa·s) (3)
Furthermore, the coloring agent 102 of the toner according to the second embodiment is desired to be configured so that the light resistance F (%) of a light resistance measurement print image as a toner image printed on a sheet as the print medium by the image forming apparatus 1 according to the first embodiment, after being irradiated with light having 0.36 W/m2 spectral irradiance at a wavelength of 340 nm for 663 hours (i.e., after an irradiation test), satisfies the following condition (4): In other words, the type, amount, compounding ratio, etc. of the pigment constituting a part of the coloring agent 102 are desired to be determined to satisfy the following condition (4):
F≥70% (4)
The light resistance F (%) is calculated by use of the following expression using a survival rate of the optical density (O.D.):
F (%)=(D(E)/D(S))×100(%)
where D(E) represents the O.D. of the yellow 100% density image after the irradiation test and D(S) represents the O.D. of the yellow 100% density image before the irradiation test.
Namely, the light resistance F (%) is percentage representation of a value obtained by dividing second optical density as the optical density of the light resistance measurement print image with the toner after the irradiation test by first optical density as the optical density of the light resistance measurement print image with the toner before the irradiation test.
The basis of upper limits and lower limits in the above conditions (1) to (4) in regard to the toner (yellow toner) according to the second embodiment will be described later with reference to Table 1,
Further, evaluation of a red image (compound color image) in a case where the red image is printed by using the toner (yellow toner) according to the second embodiment and a conventional magenta toner will be described later with reference to Table 2 and
Print images formed by use of the toner according to the second embodiment have excellent color tones and excel in the light resistance.
(2-2) Manufacturing Process of Toner According to Second Embodiment
The toner according to the second embodiment is manufactured by the following manufacturing process using emulsion polymerization, for example:
(Preparation Step)
Styrene-acrylic copolymer resin as binder resin (101 in
The styrene-acrylic copolymer resin can be produced from styrene, acrylic acid and methyl methacrylate.
The coloring agent is a mixture of C.I. Pigment Yellow 155 and C.I. Pigment Yellow 185 as yellow pigments at a ratio of 4:1. C.I. is an abbreviation of Color Index International.
The wax is paraffin wax.
The external additive is silica, including hydrophobic silica fine powder whose average particle diameter is 8 nm to 20 nm (hereinafter also referred to as “small silica”), hydrophobic silica fine powder whose average particle diameter is 20 nm to 80 nm (hereinafter also referred to as “large silica”), and colloidal silica fine powder whose average particle diameter is 80 nm to 140 nm (hereinafter also referred to as “colloidal silica”), for example. The small silica is “Aerosil 8972” or “Aerosil R974” produced by Nippon Aerosil Co., Ltd., for example. The large silica is “Aerosil RX50” or “Aerosil VP RX 40S” produced by Nippon Aerosil Co., Ltd., for example. The colloidal silica is sol-gel spherical silica particles “X-24-9163A” or “X-24-9600A-80” produced by Shin-Etsu Chemical Co., Ltd., for example.
(Coloring Resin Particle Formation Step)
Subsequently, the styrene-acrylic copolymer resin and the coloring agent, together with the wax and the charge control agent as needed, are mixed together by using emulsion polymerization, and the coloring resin particles are generated by cohesion.
In the emulsion polymerization, primary particles are made by dispersing a resin monomer in a solvent including an emulsifier, a polymerization initiator and water, the coloring agent emulsified by an emulsifier (surfactant) is mixed into the solvent including the primary particles, while also adding the wax, the charge control agent, etc. into the solvent as needed, and the coloring resin particles are generated in the solvent by cohesion of these materials. The coloring resin particles are extracted from the solvent, unnecessary solvent components and by-product components are removed by rinsing and drying, by which the coloring resin particles are obtained.
(External Additive Adhesion Step)
Subsequently, the silica as the external additive is mixed into the coloring resin particles by using a mixer, by which a nonmagnetic monocomponent toner like the one shown in
(2-3) Evaluation Test of Toner According to Second Embodiment
(2-3-1) Outline of Evaluation Test of Yellow Toner
The yellow toners T1 to T3 in the examples E1 to E3 were manufactured as the toners according to the second embodiment. Further, the yellow toners T4 to T6 in the comparative examples C1 to C3 were manufactured.
The evaluation test was performed on these yellow toners T1 to T6. In the evaluation test, the yellow 100% density images of the yellow toners T1 to T6 were printed on a white paper medium (sheet), the L* value, the a* value and the b* value in the L*a*b* color model were measured as the print hue, the optical density (O.D.) in the aforementioned calculation formula of the light resistance F (%) was measured, and the light resistance F (%) was calculated from the D.D.
Further, in the evaluation test, the melt viscosity η (Pa·s) of each of the yellow toners T1 to T6 was measured.
(2-3-2) Measurement of Hue (Print Hue) of Yellow Toner Print Image
(Measuring Instrument)
For the measurement of the L* value, the a* value and the b* value representing the print hue in the L*a*b* color model, a measuring instrument “X-Rite528” (produced by X-Rite Inc.) as a colorimeter/densitometer was used.
(Underlay for Print Medium)
In the measurement of print hue by use of the measuring instrument “X-Rite528”, a white paper medium (i.e., white paper) was used as an underlay (black packing) for the print medium. Specifically, an underlay made by stacking five sheets of white paper satisfying the following conditions was used as the underlay for the print medium:
96.3≤L*(W)≤96.8,
1.7≤a*(W)≤2.0, and
−5.6≤b*(W)≤−5.2
where L*(W), a*(W) and b*(W) respectively represent the L* value, the a* value and the b* value in the L*a*b* color model. As the white paper, paper “Excellent White A4 (70 kg paper)” (produced by Oki Data Corporation) was used.
(Setting of Measuring Instrument)
For the measurement of print hue of the print images with the yellow toners T1 to T6, measurement conditions in the measuring instrument “X-Rite528” were set as follows:
A measurement mode was set at “measurement mode by L*a*b* color model”, an observation light source (illuminant) was set at “D50” (light source at color temperature of approximately 5000 K), and a viewing angle (observation field) was set at “2°”.
(Measurement)
The hue of the print obtained on the print medium by using each of the yellow toners T1 to T6 was measured by use of the measuring instrument “X-Rite528” with the above-described settings.
(2-3-3) Measurement of Optical Density in Measurement of Hue of Yellow Toner
(Measuring Instrument)
The optical density was employed as a parameter indicating the density of the toner print image. As a measuring instrument for measuring the optical density, the measuring instrument “X-Rite528” was used.
(Underlay for Print Medium)
In the measurement of optical density of the print images by use of the measuring instrument “X-Rite528”, a black paper medium (i.e., black paper) was used as the underlay for the print medium. Specifically, black paper satisfying the following conditions was used as the underlay for the print medium:
25.1≤L*(B)≤25.9,
0.2≤a*(B)≤0.3, and
0.5≤b*(B)≤0.7
where L*(B), a*(B) and b*(B) respectively represent the L* value, the a* value and the b* value in the L*a*b* color model. As the black paper, “Colored Fine Quality Paper: Black” (produced by Hokuetsu Kishu Paper Co., Ltd.) was used.
(Setting of Measuring Instrument)
For the measurement of optical density of the print images with the yellow toners T1 to T6, measurement conditions in the measuring instrument “X-Rite528” were set as follows:
The measurement mode was set at “density measurement mode”, a status setting was set at “status I”, a white reference setting was set at “absolute white reference”, and a filer setting was set at “no polarizing filter”. The “status I” is a setting in regard to a wavelength range to be evaluated, which is stipulated in ISO5-3 “Photography and graphic technology—Density measurements”—Part 3: Spectral conditions.
(Measurement)
The optical density of each print was measured by use of the measuring instrument “X-Rite528” with the above-described settings. In the measuring instrument “X-Rite528”, the optical density is obtained as four numerical values: a V value (Visual Value), a C value (Cyan Value), an M value (Magenta Value) and a Y value (Yellow Value). The Y value was used as the optical density of the yellow toners T1 to T6, the M value was used as the optical density of the magenta toner, and the C value was used as the optical density of the cyan toner.
(2-3-4) Measurement of Melt Viscosity of Yellow Toner
As a parameter indicating the melt viscosity of the toner, melt viscosity η (Pa·s) at 120° C. obtained from viscoelasticity measurement by use of a rotary rheometer was employed.
For the measurement of the melt viscosity η, a viscosity/viscoelasticity measurement device “HAAKE MARS III” produced by Thermo Fisher Scientific K.K. was used. In the measurement by use of “HAAKE MARS III”, a temperature rise rate was set at 5° C./min, a frequency was set at 1 Hz, a gap was set at 1 mm, the yellow toners T1 to T6 were first melted sufficiently at a temperature of 140° C. by using a parallel plate having a ϕ20 mm diameter, thereafter the yellow toners T1 to T6 were heated from 50° C. to 230° C., and the melt viscosity η (Pa·s) when the yellow toners T1 to T6 were at 120° C. was obtained.
(2-3-5) Measurement of Optical Density for Calculating Light Resistance of Yellow Toner Print Image
(Irradiation Test)
For the measurement of the light resistance F (%) of each yellow toner T1-T6, the survival rate (%) of the optical density (O.D.) of the toner image on the print, in a case where a light resistance test using a xenon arc lamp was performed on the print with the yellow toner T1-T6, was employed.
For the light resistance test using the xenon arc lamp, a xenon weather resistance test device (Weather-Ometer) “Ci4000” produced by ATLAS was used. In the measurement by use of “Ci4000”, the spectral irradiance at 340 nm was set at 0.36 W/m2, black panel temperature was set at 63° C., and an irradiation test for 663 hours was performed on a toner image at an optical density (O.D.) of 1.0 (yellow monochrome solid image) printed on Excellent White Paper produced by Oki Data Corporation, the optical density of the toner image after the irradiation test was measured, and the light resistance F (%) was obtained from the aforementioned calculation formula of the light resistance F (%).
(Measuring Instrument)
For the measurement of the optical density of the toner image in the measurement of light resistance, the measuring instrument “X-Rite528” (produced by X-Rite Inc.) was used.
(Underlay for Print Medium)
In the measurement of optical density by use of the measuring instrument “X-Rite528”, the white paper medium (i.e., white paper) was used as the underlay for the print medium. Specifically, the underlay made by stacking five sheets of white paper satisfying the following conditions was used as the underlay for the print medium:
96.3≤L*(W)≤96.8,
1.7≤a*(W)≤2.0, and
−5.6≤b*(W)≤−5.2
where L*(W), a*(W) and b*(W) respectively represent the L* value, the a* value and the b* value in the L*a*b* color model. As the white paper, the paper “Excellent White A4 (70 kg paper)” (produced by Oki Data Corporation) was used.
(Setting of Measuring Instrument)
For the measurement of optical density of the print images with the yellow toners T1 to T6, measurement conditions in the measuring instrument “X-Rite528” were set as follows: The measurement mode was set at “density measurement mode”, the status setting was set at “status I”, the white reference setting was set at “absolute white reference”, and the filer setting was set at “no polarizing filter”.
With the above-described settings, the optical density of the print obtained on the print medium by using each of the yellow toners T1 to T6 was measured by use of the measuring instrument “X-Rite528” at a plurality of time points in the irradiation test. In the measuring instrument “X-Rite528”, the optical density is obtained as the four numerical values: the V value (Visual Value), the C value (Cyan Value), the M value (Magenta Value) and the Y value (Yellow Value), in which the Y value was used as the optical density of the yellow toners T1 to T6.
(Measurement)
The optical density of the print obtained on the print medium by using each of the yellow toners T1 to T6 was measured by use of the measuring instrument “X-Rite528” with the above-described settings.
(2-3-6) Result of Evaluation Test of Yellow Toner
Table 1 shows a result of the measurement of the print hue, the light resistance F (%), and the melt viscosity η (Pa·s) at 120° C. of the yellow toners T1 to T3 in the examples E1 to E3 as the toners according to the second embodiment and the yellow toners T4 to T6 in the comparative examples C1 to C3.
The yellow toner T1 in the example E1 is an example of the toner according to the second embodiment. In the yellow toner T1, the coloring agent includes C.I. Pigment Yellow 155 and C.I. Pigment Yellow 185 at the ratio of 4:1. In the yellow toner T1, the melt viscosity η (Pa·s) at 120° C. is adjusted to 1600 (Pa·s) by lowering the molecular weight of the binder resin compared to that in an ordinary (commercially available) yellow toner (yellow toner T4 in the comparative example C1).
The yellow toner T2 in the example E2 is an example of the toner according to the second embodiment. In the yellow toner T2, the coloring agent includes C.I. Pigment Yellow 155 and C.I. Pigment Yellow 185 at the ratio of 4:1. In the yellow toner T2, the melt viscosity η (Pa·s) at 120° C. is adjusted to 1400 (Pa·s) by using binder resin differing in the molecular weight from the binder resin of the yellow toner T1.
The yellow toner T3 in the example E3 is an example of the toner according to the second embodiment. In the yellow toner T3, the coloring agent includes C.I. Pigment Yellow 155 and C.I. Pigment Yellow 185 at the ratio of 4:1. In the yellow toner T3, the melt viscosity η (Pa·s) at 120° C. is adjusted to 1600 (Pa·s) while using binder resin differing in the molecular weight from the binder resin of the yellow toner T1.
The yellow toner T4 in the comparative example C1 is an ordinary (commercially available) yellow toner. The yellow toner T4 is a yellow toner of a genuine yellow toner cartridge used for a color LED printer “C911dn” produced by Oki Data Corporation. The melt viscosity η of this yellow toner T4 at 120° C. is 1800 (Pa·s).
In the yellow toner T5 in the comparative example C2, the coloring agent is C.I. Pigment Yellow 155. In the yellow toner T5, the molecular weight of the binder resin is set equal to that in the yellow toner T4 in the comparative example C1. The melt viscosity η at 120° C. of the yellow toner T5 in the comparative example C2 configured as above is 2160 (Pa·s).
In the yellow toner T6 in the comparative example C3, the coloring agent is C.I. Pigment Yellow 155. In the yellow toner T6, the molecular weight of the binder resin is set equal to that in the yellow toner T4 in the comparative example C1. The melt viscosity η at 120° C. of the yellow toner. T6 in the comparative example C3 configured as above is 2100 (Pa·s).
In the yellow toners T1 to T3 in the examples E1 to E3, the pigments are selected so that the print hue satisfies both of the conditions (1) and (2).
The toner images with the yellow toners T1 to T3 in the examples E1 to E3 have excellent color tones equivalent to the color tone of the toner image with the conventional yellow toner T4 represented by the comparative example C1. Even these toner images (prints) having print hues different from each other look like they have color tones equivalent to each other, which can be attributed to the human eye lacking the ability to perceive a slight difference between yellow colors and recognizing such images as images of the same color tone.
Further, it has been known that the light resistance F (%) generally decreases as a pigment achieving a yellow print hue with a higher b* value in the yellow color is used in a yellow toner. Namely, the light resistance F (%) decreases with the increase in the b* value of the yellow toner. In the yellow toners T1 to T3 as the toners according to the second embodiment, the upper limit “95.4” of the b* value in the aforementioned condition (2) is a value for letting the toner have better light resistance than the conventional yellow toner T4 represented by the comparative example C1.
The yellow color print hue of the yellow toners T1 to T6 in the examples E1 to E3 and the comparative examples C1 to C3 was measured as indicated by the graph G2 shown in
Further, it has been known that the tendency of the toner to be consolidated when subjected to a high-pressure and high-humidity environment (e.g., temperature: 50° C., humidity: 55%) increases with the decrease in the melt viscosity at 120° C. The aforementioned high-pressure and high-humidity environment presumes the severest environment to which the toner can be subjected during transportation. If components of the yellow toners T1 to T3 in the examples E1 to E3 are changed to make a toner whose melt viscosity η at 120° C. is lower than 1400 (Pa·s), the toner cannot maintain sufficiently high viscosity due to the consolidation of the toner in the aforementioned severest environment. The lower limit 1400 (Pa·s) of the melt viscosity η in the aforementioned condition (3) is a lower limit for preventing the toner from falling into a state prone to consolidation.
As seen in Table 1 and
Further, as seen in
As above, from the evaluation test using the yellow 100% density images with the yellow toners T1 to T6, the yellow toners T1 to T3 and T6 can be judged to be excellent in the print hue and the light resistance.
(2-4) Evaluation Test of Toner According to Second Embodiment in Cases of Compound Color
(2-4-1) Procedure of Evaluation Test of Toner in Cases of Compound Color
Next, a description will be given of an evaluation test for judging the hue of the yellow toners T1 to T6 in the examples E1 to E3 and the comparative examples C1 to C3 in cases of compound color.
The evaluation test of toners in cases of compound color was performed by using a color LED printer “C941dn” produced by Oki Data Corporation, loading the image forming section 10Y with each of the yellow toners T1 to T6 in the examples E1 to E3 and the comparative examples C1 to C3, and using toners of genuine white, magenta, cyan and black toner cartridges, used for the color LED printer “C941dn” produced by Oki Data Corporation, for the image forming sections 10W, 10M, 10C and 10K. As the print medium used in this test, the paper “Excellent White A4 (70 kg paper)” produced by Oki Data Corporation was used.
With the above-described configuration, a test for hue evaluation was carried out according to the following procedure:
The print medium used in this test is the same as the print medium used in this second embodiment.
The print hue measurement print pattern shown in
In the judgment on the hue of the red 200% density image, the hue is judged to be excellent as an overall judgment when a judgment by a visual check and a judgment by the print hue of the red color are both excellent. The judgment by a visual check was made by using the red 200% density image in the print obtained by the test, in which the hue was judged to be excellent when the red 200% density image looks equivalent in hue to the red 200% density image obtained by using the yellow toner T4 in the comparative example C1.
(2-4-2) Result of Evaluation Test of Toner in Cases of Compound Color
The hue judgment lower limit (thin dotted line) in
y=−0.6701x+87.938
y=−5.6289x+390.87
These straight lines represent the quality judgment border line and the print hue is excellent outside the quality judgment border line (thick dotted lines). The reason is as follows: When the print hue of a red color lies outside the quality judgment border line, it seems to be possible to reproduce the lower limit value of the red color hue by modifying the way of forming the composite color with a yellow color and a magenta color, e.g., by forming the composite color with a 95% yellow color and a 97% magenta color.
The result of the evaluation test performed by using the yellow toners T1 to T6 in the examples E1 to E3 and the comparative examples C1 to C3 to check the effect of the toners according to the second embodiment will be shown below as Table 2.
As seen in Table 2, the hue of the red 200% density images formed by using the yellow toners T1 to T3 in the examples E1, E2 and E3 as the toners according to the second embodiment and the yellow toner T4 in the comparative example C1 was judged to be excellent as the result of the visual check judgment. In contrast, as seen in Table 2, the hue of the red 200% density images formed by using the yellow toners T5 and T6 in the comparative examples C2 and C3 was judged to be inferior as the result of the visual check judgment.
As seen in
It can be considered that the reason why the hue of the red 200% density images formed by using the yellow toners T5 and T6 in the comparative examples C2 and C3 was inferior is that the melt viscosity η was high (Table 1) and it was difficult to form an image in a condition in which the yellow toner and the magenta toner were more desirably molten and mixed together.
As shown in Table 2 as overall judgment, EXCELLENT was obtained as the overall judgment on the hue in the cases where the red 200% density images were formed by using the yellow toners T1 to T3 in the examples E1 to E3 as the toners according to the second embodiment and the yellow toner T4 in the comparative example C1. In the cases where the red 200% density images were formed by using the yellow toners T5 and T6 in the comparative examples C2 and C3, the overall judgment on the hue was inferior.
(2-5) Effect of Second Embodiment
According to the evaluation result of the print images with the yellow toners T1 to T6 shown in Table 1 and the evaluation result of the red 200% density images by using the yellow toners T1 to T6 shown in Table 2, both of the judgment on the yellow print image and the judgment on the red 200% density image resulted in excellent in the cases of using the yellow toners T1 to T3 in the examples E1 to E3.
Therefore, it becomes possible to form a print image having an excellent color tone and excelling in the light resistance by configuring the toner according to the second embodiment to satisfy both of the aforementioned conditions (1) and (2) and to satisfy the aforementioned condition (3).
(3) Third Embodiment
(3-1) Outline of Third Embodiment
In the above second embodiment, the description has been given of toners that make it possible to form a print image having an excellent color tone and excelling in the light resistance. However, there are cases where printing of a toner image (also referred to as “iron printing”) is carried out by means of thermocompression bonding of transfer paper, as a special-purpose transfer medium having the toner image thereon, to a final medium such as fabric (e.g., T-shirt). The transfer paper is the print medium 23 in the image forming apparatus 1 according to the first embodiment.
In such cases of transferring and thermocompression-bonding a toner image on transfer paper to a final medium such as fabric, color degradation can occur in the print image obtained by the thermocompression bonding process. This can be attributed to sublimation of part of the pigments included in the toners due to heat.
In the third embodiment, a description will be given of a toner capable of forming an excellent print image excelling in the sublimation resistance, having an excellent color tone, and excelling in the light resistance. The toner according to the third embodiment is usable as a yellow toner as a developing agent in the image forming apparatus 1 and the toner cartridge described in the above first embodiment. Incidentally, the sublimation resistance is an index representing the degree of how unlikely an object substance (in the third embodiment, the pigment included in the toner) is to be sublimated. With the increase in the sublimation resistance, the object substance is less likely to be sublimated, that is, the pigment is less likely to disappear from the toner image due to sublimation.
The toner according to the third embodiment is a nonmagnetic monocomponent yellow toner. The configuration of each particle of the toner according to the third embodiment is the same as that shown in
The coloring agent 102 includes one or more types of yellow pigment. The coloring agent 102 in the toner according to the third embodiment is configured so that the print hue of the hue measurement print image (yellow 100% density image shown in
−8.6≤a*(Y)≤−7.9 (1)
93.4≤b*(Y)≤95.4 (2)
Further, the toner according to the third embodiment is configured so that the melt viscosity η (Pa·s) of the toner at 120° C. satisfies the condition (3) similarly to the case of the second embodiment.
1400(Pa·s)≤η≤1600(Pa·s) (3)
Furthermore, the coloring agent 102 of the toner according to the third embodiment is desired to be configured so that the light resistance F (%) of the light resistance measurement print image as a toner image printed on a sheet as the print medium by the image forming apparatus 1 according to the first embodiment, after being irradiated with light having 0.36 W/m2 spectral irradiance at the 340 nm wavelength for 663 hours (i.e., after the irradiation test), satisfies the condition (4) similarly to the case of the second embodiment.
F≥70% (4)
Moreover, the coloring agent 102 of the toner according to the third embodiment is desired to be configured so that the sublimation resistance Sr (%) of a sublimation resistance measurement print image as a toner image (i.e., yellow 100% density image) printed on a sheet as the print medium (transfer paper in the third embodiment) by the image forming apparatus 1 according to the first embodiment, after being heated at 180° C. for 10 minutes (i.e., after a heating test), satisfies the following condition (5):
Sr (%)≥98(%)
Sr (%)=(b*(E)/b*(S))×100(%) (5)
where b*(E) represents the b* value of the yellow 100% density image after the heating test and b*(S) represents the b* value of the yellow 100% density image before the heating test.
In addition, the coloring agent 102 of the toner according to the third embodiment is desired to be configured so that the b* value of a thermocompression bonding transferability measurement print image as a toner image printed on transfer paper for the thermocompression bonding transfer by the image forming apparatus 1 according to the first embodiment, after being pressed at 180° C. and 60 psi for 10 seconds (i.e., after a thermocompression bonding transfer test), satisfies the following condition (6):
b*(P)≤2.9 (6)
where b*(P) represents the b* value of the yellow 100% density image (i.e., thermocompression bonding transferability measurement print image) after the thermocompression bonding transfer test.
The basis of the upper limits and the lower limits in the above conditions (1) to (6) in regard to the toner (i.e., yellow toner) according to the third embodiment will be described later with reference to Table 3 in
Further, evaluation of a red image (compound color image) in a case where the red image is printed by using the toner (yellow toner) according to the third embodiment and a conventional magenta toner will be described later with reference to Table 4 in
Print images formed by use of the toner according to the third embodiment have excellent color tones, excel in the light resistance, excel in the sublimation resistance, and excel in the thermocompression bonding transferability.
(3-2) Manufacturing Process of Toner According to Third Embodiment
The toner according to the third embodiment is manufactured by the following manufacturing process using emulsion polymerization, for example:
(Preparation Step)
Styrene-acrylic copolymer resin as binder resin (101 in
The styrene-acrylic copolymer resin can be produced from styrene, acrylic acid and methyl methacrylate.
The coloring agent is a mixture of C.I. Pigment Yellow (PY) 155 and C.I. Pigment Yellow (PY) 185 as yellow pigments at a ratio within a range from 73:27 to 80:20. However, the pigment of the coloring agent in the comparative example C11 includes C.I. Pigment Yellow 74 at the ratio of 100%.
The reason why the pigment mixture ratio is set higher than or equal to 73:27 is that it was impossible to produce the coloring resin particles by mixing coloring agents by means of emulsion polymerization when the mixture ratio was less than 73:27. Namely, the reason is that production of the coloring resin particles by emulsion polymerization became impossible as a mixture ratio of PY 155 was gradually increased.
The reason why the pigment mixture ratio is set lower than or equal to 80:20 is that the print hue of the yellow 100% density image deteriorates and the yellow color becomes pale to a visually recognizable level when the mixture ratio is higher than 80:20. Incidentally, this was confirmed by a drop in the b* value representing the print hue in regard to the comparative example C12 shown in Table 3 in
The wax is paraffin wax.
The external additive is the same silica as that described in the second embodiment, including hydrophobic silica fine powder whose average particle diameter is 8 nm to 20 nm, hydrophobic silica fine powder whose average particle diameter is 20 nm to 80 nm, and colloidal silica fine powder whose average particle diameter is 80 nm to 140 nm, for example.
(Coloring Resin Particle Formation Step)
Subsequently, the styrene-acrylic copolymer resin, and the coloring agent, together with the wax and the charge control agent as needed, are mixed together by using emulsion polymerization, and the coloring resin particles are generated by cohesion. The coloring resin particle formation step in the third embodiment is the same as that described in the second embodiment.
(External Additive Adhesion Step)
Subsequently, the silica as the external additive is mixed into the coloring resin particles by using a mixer, by which a nonmagnetic monocomponent toner like the one shown in
(3-3) Evaluation Test of Toner According to Third Embodiment
(3-3-1) Outline of Evaluation Test of Yellow Toner
The yellow toners T11 to T15 in the examples E11 to E15 were manufactured as the toners according to the third embodiment. Further, the yellow toners T16 to T18 in the comparative examples C11 to C13 were manufactured.
The evaluation test was performed on these yellow toners T11 to T18. In the evaluation test, the yellow 100% density images of the yellow toners T11 to T18 were printed on a white paper medium (sheet), the L* value, the a* value and the b* value in the L*a*b* color model were measured as the print hue, the optical density (O.D.) in the aforementioned calculation formula of the light resistance F (%) was measured, and the light resistance F (%) was calculated from the O.D.
Further, in the evaluation test, the melt viscosity η (Pa·s) of each of the yellow toners T11 to T18 was measured.
(3-3-2) Measurement of Hue (Print Hue) of Yellow Toner Print Image
(Measuring Instrument)
For the measurement of the L* value, the a* value and the b* value representing the print hue in the L*a*b* color model, the measuring instrument “X-Rite528” (produced by X-Rite Inc.) as a colorimeter/densitometer was used.
(Underlay for Print Medium)
In the measurement in the third embodiment, the same underlay as that used in the measurement in the second embodiment was used as the underlay for the print medium.
(Setting of Measuring Instrument)
For the measurement of print hue of the print images with the yellow toners T11 to T18, measurement conditions in the measuring instrument “X-Rite528” were set as follows:
The measurement mode was set at “measurement mode by L*a*b* color model”, the observation light source (illuminant) was set at “D50”, and the viewing angle (observation field) was set at “2°”.
(Measurement)
The hue of the print obtained on the print medium by using each of the yellow toners T11 to T18 was measured by use of the measuring instrument “X-Rite528” with the above-described settings.
(3-3-3) Measurement of Optical Density in Measurement of Hue of Yellow Toner
(Measuring Instrument)
The optical density was employed as the parameter indicating the density of the toner print image. As the measuring instrument for measuring the optical density, the measuring instrument “X-Rite528” was used.
(Underlay for Print Medium)
In the measurement of optical density of the print images by use of the measuring instrument “X-Rite528”, a black paper medium (i.e., black paper) was used as the underlay for the print medium. In the measurement in the third embodiment, the same underlay as that used in the measurement in the second embodiment was used as the underlay for the print medium.
(Setting of Measuring Instrument)
For the measurement of optical density of the print images with the yellow toners T11 to T18, measurement conditions in the measuring instrument “X-Rite528” were set as follows:
In the third embodiment, similarly to the case of the second embodiment, the measurement mode was set at “density measurement mode”, the status setting was set at “status I”, the white reference setting was set at “absolute white reference”, and the filer setting was set at “no polarizing filter”. The “status I” is stipulated in ISO as mentioned in the second embodiment.
(Measurement)
The optical density of each print was measured by use of the measuring instrument “X-Rite528” with the above-described settings. In the measuring instrument “X-Rite528”, the optical density is obtained as the four numerical values: the V value, the C value, the M value and the Y value. The Y value was used as the optical density of the yellow toners T11 to T18, the M value was used as the optical density of the magenta toner, and the C value was used as the optical density of the cyan toner.
(3-3-4) Measurement of Melt Viscosity of Yellow Toner
As the parameter indicating the melt viscosity of the toner, the melt viscosity η (Pa·s) at 120° C. obtained from viscoelasticity measurement by use of the rotary rheometer was employed.
The melt viscosity η measurement method is the same as the measurement method in the second embodiment. Namely, the temperature rise rate was set at 5° C./min, the frequency was set at 1 Hz, the gap was set at 1 mm, the yellow toners T11 to T18 were first melted sufficiently at the temperature of 140° C. by using the parallel plate having the ϕ20 mm diameter, thereafter the yellow toners T11 to T18 were heated from 50° C. to 230° C., and the melt viscosity η (Pa·s) when the yellow toners T11 to T18 were at 120° C. was obtained.
(3-3-5) Measurement of Optical Density for Calculating Light Resistance of Yellow Toner Print Image
(Irradiation Test)
For the measurement of the light resistance F (%) of each yellow toner T11-T18, a survival rate (%) of the O.D. of the toner image on the print, in the case where the light resistance test using the xenon arc lamp was performed on the print with the yellow toner T11-T18, was employed.
The light resistance test using the xenon arc lamp is the same as the light resistance test in the second embodiment, and the light resistance F (%) was obtained from the expression (5).
(Measuring Instrument)
For the measurement of the optical density of the toner image in the measurement of light resistance, the measuring instrument “X-Rite528” (produced by X-Rite Inc.) was used.
(Underlay for Print Medium)
The underlay for the print medium used in the measurement of optical density by use of “X-Rite528” in the third embodiment is the same as the underlay in the second embodiment.
(Setting of Measuring Instrument)
For the measurement of optical density of the print images with the yellow toners T11 to T18, measurement conditions in the measuring instrument “X-Rite528” were set as follows: The measurement mode was set at “density measurement mode”, the status setting was set at “status I”, the white reference setting was set at “absolute white reference”, and the filer setting was set at “no polarizing filter”.
With the above-described settings, the optical density of the print obtained on the print medium by using each of the yellow toners T11 to T18 was measured by use of the measuring instrument “X-Rite528” at a plurality of time points in the irradiation test. In the measuring instrument “X-Rite528”, the optical density is obtained as the four numerical values: the V value, the C value, the M value and the Y value, in which the Y value was used as the optical density of the yellow toners T11 to T18.
(Measurement)
The optical density of the print obtained on the print medium by using each of the yellow toners T11 to T18 was measured by use of the measuring instrument “X-Rite528” with the above-described settings.
(3-3-6) Measurement of Sublimation Resistance of Yellow Toner Print Image
(Test)
For the measurement of the sublimation resistance Sr (%) of each yellow toner T11-T18, the survival rate (%) of the b* value of the toner image on the print, after performing a heating test with a hot plate on the print with the yellow toner T11-T18, was employed.
For the heating test, “DIGITAL HOT PLATE/STIRRER DP-1M” as a hot plate (301 in
Subsequently, the b* value of the yellow 100% density image in the sublimation resistance measurement print image is measured. This b* value is described also as b*(S). Subsequently, the set temperature of the hot plate is set at 180° C., and the hot plate is left untouched until the surface temperature of the hot plate reaches 180° C. The surface temperature of the hot plate is measured by using a radiation thermometer or the like, for example.
Subsequently, as shown in
After heating the print for 10 minutes, the b* value of the yellow 100% density image 303 in the sublimation resistance measurement print image is measured. This b* value is described also as b*(E).
The sublimation resistance Sr (%) was calculated from b*(S) and b*(E) obtained as above and the following calculation formula (7) of the sublimation resistance Sr (%):
Sr (%)=(b*(E)/b*(S))×100(%) (7)
The optical density and hue measurement method in the measurement of sublimation resistance is performed in the same way as the method in the measurement of light resistance.
(3-3-7) Measurement of Thermocompression Bonding Transferability of Yellow Toner Print Image
As the heat pressing machine 310, an iron pressing machine “Model HTP234PS1” produced by BIOTECH Co., Ltd. was used. As the thermocompression bonding transfer paper 311, “TCC3.1” produced by BIOTECH Co., Ltd. was used. As the fabric (T-shirt), “United Athle 5806-01 4.0 oz. white” of C.A.B. CLOTHING INC. was used.
In the measurement, a thermocompression bonding print 311 as a yellow 100% density image at an O.D. of 1.4 printed on thermocompression bonding transfer paper is generated first.
Subsequently, the set temperature of the heat pressing machine 310 is set at 180° C. and the heat pressing machine 310 is left untouched until a thermometer (not shown) of the machine indicates 180° C. Then, as shown in
The pressing pressure of the heat pressing machine 310 in the press was adjusted to 60 psi. When the iron pressing machine “Model HTP234PS1” is used as the heat pressing machine 310, the pressing pressure can be adjusted to 60 psi by setting a pressure regulation dial at “Dial 8”.
After the elapse of five seconds since the start of the heat press by the heat pressing machine 310, the thermocompression bonding print 311 is peeled from the fabric (T-shirt) 313. Then, the b* value of the yellow 100% density image on the thermocompression bonded print 311 after undergoing the heat press is measured. The optical density measurement method and the hue measurement method in the measurement of thermocompression bonding transferability are the same as those in the measurement of light resistance.
(3-3-8) Result of Evaluation Test of Yellow Toner
Table 3 in
The yellow toner T11 in the example E11 is an example of the toner according to the third embodiment. In the yellow toner T11, the coloring agent includes C.I. Pigment Yellow 155 and C.I. Pigment Yellow 185 at the ratio of 80:20. In the yellow toner T11, the melt viscosity η (Pa·s) at 120° C. is adjusted to 1600 (Pa·s) by lowering the molecular weight of the binder resin compared to that in an ordinary (commercially available) yellow toner (yellow toner T16 in the comparative example C11).
The yellow toner T12 in the example E12 is an example of the toner according to the third embodiment. In the yellow toner T12, the coloring agent includes C.I. Pigment Yellow 155 and C.I. Pigment Yellow 185 at the ratio of 80:20. In the yellow toner T12, the melt viscosity η (Pa·s) at 120° C. is adjusted to 1400 (Pa·s) by using binder resin differing in the molecular weight from the binder resin of the yellow toner T11.
The yellow toner T13 in the example E13 is an example of the toner according to the third embodiment. In the yellow toner T13, the coloring agent includes C.I. Pigment Yellow 155 and C.I. Pigment Yellow 185 at the ratio of 80:20. In the yellow toner T13, the melt viscosity η (Pa·s) at 120° C. is adjusted to 1600 (Pa·s) while using binder resin differing in the molecular weight from the binder resin of the yellow toner T11.
The yellow toner T14 in the example E14 is an example of the toner according to the third embodiment. In the yellow toner T14, the coloring agent includes C.I. Pigment Yellow 155 and C.I. Pigment Yellow 185 at the ratio of 76.5:23.5. In the yellow toner T14, binder resin equal in the molecular weight to the binder resin of the yellow toner T11 is used as the binder resin. The melt viscosity η at 120° C. of the yellow toner T14 in the example E14 configured as above is 1400 (Pa·s).
The yellow toner T15 in the example E15 is an example of the toner according to the third embodiment. In the yellow toner T15, the coloring agent includes C.I. Pigment Yellow 155 and C.I. Pigment Yellow 185 at the ratio of 73:27. In the yellow toner T15, binder resin equal in the molecular weight to the binder resin of the yellow toner. T11 is used as the binder resin. The melt viscosity η at 120° C. of the yellow toner T15 in the example E15 configured as above is 1600 (Pa·s).
The yellow toner T16 in the comparative example C11 is an ordinary (commercially available) yellow toner. The yellow toner T16 is the yellow toner of the genuine yellow toner cartridge used for the color LED printer “C911dn” produced by Oki Data Corporation. In the yellow toner T16 in the comparative example C11, the coloring agent includes C.I. Pigment Yellow 74 at the ratio of 100%. The melt viscosity η of this yellow toner T16 at 120° C. is 1800 (Pa·s).
In the yellow toner T17 in the comparative example C12, the coloring agent is C.I. Pigment Yellow 155. In the yellow toner T17, the molecular weight of the binder resin is set equivalent to that in the yellow toner T16 in the comparative example C11. The melt viscosity η at 120° C. of the yellow toner T17 in the comparative example C12 configured as above is 2160 (Pa·s).
In the yellow toner T18 in the comparative example C13, the coloring agent includes C.I. Pigment Yellow 155 and C.I. Pigment Yellow 185 at the ratio of 80:20. In the yellow toner T18, the molecular weight of the binder resin is set equivalent to that in the yellow toner T16 in the comparative example C11. The melt viscosity η at 120° C. of the yellow toner T18 in the comparative example C13 configured as above is 2100 (Pa·s).
In the yellow toners T11 to T15 in the examples E11 to E15, the pigments are selected so that the print hue satisfies both of the conditions (1) and (2). In regard to the coloring agents C.I. Pigment Yellow 155 and C.I. Pigment Yellow 185, the reason why there is no toner with the C.I. Pigment Yellow 185 ratio over 27% in the examples E11 to E15 and the comparative examples C11 to C13 is that it was impossible to produce a toner with a still increased ratio of C.I. Pigment Yellow 185 due to a problem in production.
The toner images with the yellow toners T11 to T15 in the examples E11 to E15 have excellent color tones equivalent to the color tone of the toner image with the conventional yellow toner T16 represented by the comparative example C11.
Even these toner images (prints) having print hues different from each other look like they have color tones equivalent to each other, which can be attributed to the human eye lacking the ability to perceive a slight difference between yellow colors and recognizing such images as images of the same color tone.
Further, it has been known that the light resistance F (%) generally decreases as a pigment achieving a yellow print hue with a higher b* value in the yellow color is used in a yellow toner. Namely, the light resistance F (%) decreases with the increase in the b* value of the yellow toner.
In the yellow toners T11 to T15 as the toners according to the third embodiment, the upper limit “95.4” of the b* value in the aforementioned condition (2) is a value for letting the toner have better light resistance than the conventional yellow toner T16 represented by the comparative example C11.
As described above, the yellow color print hue of the yellow toners T11 to T18 in the examples E11 to E15 and the comparative examples C11 to C13 was measured as indicated by the graph G9 shown in
As is clear from
Further, it has been known that the tendency of the toner to be consolidated when subjected to a high-pressure and high-humidity environment (e.g., temperature: 50° C., humidity: 55%) increases with the decrease in the melt viscosity at 120° C. Such high-pressure and high-humidity environment presumes the severest environment to which the toner can be subjected during transportation. If components of the yellow toners T11 to T15 in the examples E11 to E15 are changed to make a toner whose melt viscosity η at 120° C. is lower than 1400 (Pa·s), the toner cannot maintain sufficiently high viscosity due to the consolidation of the toner in the aforementioned severest environment.
The lower limit 1400 (Pa·s) of the melt viscosity η in the aforementioned condition (3) is a lower limit for preventing the toner from falling into a state prone to consolidation.
As seen in Table 3 in
Further, the sublimation resistance Sr (%) of the yellow toner T16 in the comparative example C11 is under 98% as the permissible value, whereas the sublimation resistance Sr (%) of the other yellow toners T11 to T15, T17 and T18 is higher than or equal to the permissible value 98%.
The sublimation resistance Sr (%) being higher than or equal to 98% can be regarded as a result obtained when sublimation hardly occurs to the toner, and thus the yellow toners T11 to T15, T17 and T18 can be regarded as excellent toners causing no problem due to sublimation.
Furthermore, as seen in
Moreover, as seen in
In other words, as the b* value exceeds 2.9, the color of the image on the fabric (e.g., T-shirt) becomes pale. Namely, the difference between the density of the image on the transfer paper and the density of the image after being transferred onto the fabric increases. As a result, when a person who purchased the transfer paper with the print image sees the fabric (e.g., T-shirt) onto which the image has been transferred from the transfer paper, the person is highly likely to feel that the result of the print on the fabric differs from expectation (color is pale).
As above, from the evaluation tests using the yellow 100% density images with the yellow toners T11 to T18, the yellow toners T11 to T15 and T18 can be judged to be excellent in the print hue, the light resistance, the sublimation resistance and the thermocompression bonding transferability.
(3-4) Evaluation Test of Toner According to Third Embodiment in Cases of Compound Color
(3-4-1) Procedure of Evaluation Test of Toner in Cases of Compound Color
Next, a description will be given of an evaluation test for judging the hue of the yellow toners T11 to T18 in the examples E11 to E15 and the comparative examples C11 to C13 in cases of compound color. In the evaluation test, a sheet that has undergone blank printing as shown in
The evaluation test of toners in cases of compound color was performed similarly to the case of the second embodiment by using the color LED printer “C941dn” produced by Oki Data Corporation and loading the image forming section 10Y with each of the yellow toners T11 to T18 in the examples E11 to E15 and the comparative examples C11 to C13.
The evaluation of the hue was performed similarly to the case of the second embodiment.
The print medium used in this test was fine quality paper as white paper weighing 80 g/m2 and satisfying the following conditions:
96.3≤L*(W)≤96.8,
1.7≤a*(W)≤2.0,
−5.6≤b*(W)≤−5.2, and
78.0 (sec)≤Beck smoothness≤129.3 (sec)
where L*(W), a* (W) and b* (W) respectively represent the L* value, the a* value and the b* value in the L*a*b* color model.
Specifically, the paper “Excellent White A4 (70 kg paper)” (produced by Oki Data Corporation) was used as the print medium. Incidentally, the Bekk smoothness was measured by using “DIGI-BEKK DB-2” (produced by Toyo Seiki Seisaku-sho, Ltd.) in conditions stipulated in “JIS P 8119”.
The print pattern for the measurement of print hue is the same as that in the second embodiment (print pattern shown in
In the judgment on the hue of the red 200% density image, the hue is judged to be excellent as the overall judgment when the judgment by a visual check and the judgment by the print hue of the red color are both excellent. The judgment by a visual check was made by using the red 200% density image in the print obtained by the test, in which the hue was judged to be excellent when the red 200% density image looks equivalent in hue to the red 200% density image obtained by using the yellow toner T16 in the comparative example C11.
(3-4-2) Result of Evaluation Test of Toner in Cases of Compound Color
The comparative example C1 in the second embodiment and the comparative example C11 in the third embodiment represent the same toner. Thus, the graph G3 in
The result of the evaluation test performed by using the yellow toners T11 to T18 in the examples E11 to E15 and the comparative examples C11 to C13 to check the effect of the toners according to the third embodiment is shown in
As seen in Table 4 in
As seen in
It can be considered that the reason why the hue of the red 200% density images formed by using the yellow toners T17 and T18 in the comparative examples C12 and C13 was inferior is that the melt viscosity η was high (Table 3 in
As shown in Table 4 in
(3-5) Effect of Third Embodiment
According to the evaluation result of the print images with the yellow toners T11 to T18 shown in Table 3 in
Therefore, it becomes possible to form a print image having an excellent color tone, excelling in the light resistance, excelling in the sublimation resistance, and excelling in the thermocompression bonding transferability by configuring the toner according to the third embodiment to satisfy the aforementioned conditions (1), (2) and (3) and to satisfy the aforementioned conditions (4), (5) and (6).
(4) Modifications
While the image forming apparatus 1 according to the first embodiment is a printer of the intermediate transfer type secondarily transferring toner images primarily transferred onto the intermediate transfer belt 9 onto the sheet 23 by using the transfer roller 27, the present invention is applicable also to printers, facsimile machines and multifunction peripherals directly transferring toner images from the image forming sections 10W, 10Y, 10M, 10C and 10K to the sheet 23.
While examples using emulsion polymerization for the manufacturing of the toner were described in the second and third embodiments, the manufacturing method of base particles of the toner is not limited to emulsion polymerization. The manufacturing method of the toner base particles can also be a different method such as pulverization, suspension polymerization or dissolution suspension, for example.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2017-229772 | Nov 2017 | JP | national |
| 2018-136292 | Jul 2018 | JP | national |
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| 6432598 | Alexandrovich et al. | Aug 2002 | B1 |
| 20090291377 | Hirose et al. | Nov 2009 | A1 |
| 20120251939 | Tani et al. | Oct 2012 | A1 |
| Number | Date | Country |
|---|---|---|
| 2011-197032 | Oct 2011 | JP |
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| Number | Date | Country | |
|---|---|---|---|
| 20190163080 A1 | May 2019 | US |
