The present invention relates to an electrophoretic light shutter display, more specifically, to a multi-stable transmissive electrophoretic light shutter display employing symmetric electrode patterning. The basic unit consists of four pixels with four identical square transparent electrodes connected with a quadruple thin film transistor core on the first substrate, an overlapped circular electrode on the second substrate, and a cell of electrophoretic particles dispersed in a transparent liquid fluid sandwiched between the first and second substrates. When an electric pulse with predetermined polarity is applied to any one of the pixels, the colored charged particles will be able to move fan-in or fan-out radially with linear grayscales. Therefore, the total transmission of the incident light through the shutter can be electrically modulated and maintained for good in zero-field conditions.
The electrophoretic effect is well known, and the prior art is replete with a number of patents and articles which describe the effect. As will be recognized by a person skilled in the art, the electrophoretic effect operates on the principle that certain particles, when suspended in a medium, can be electrically charged and thereby caused to migrate through the medium to an electrode of opposite charge. Electrophoretic displays (EPDs) utilize the electrophoretic effect to produce desired images.
EPDs generally comprise a suspension of colored charged pigment particles dispersed in a dyed solvent of contrasting color, which is injected into a cell consisting of two parallel and transparent conducting electrode panels. The charged particles are transported and packed against one electrode under the influence of an electric field, so that the viewer may see the color of the pigment. When the polarity of the field is reversed, the pigment particles are transported and packed on the opposite electrode. If the optical density of the dyed solvent is high enough to absorb the light scattered by the particles residing on the rear electrode, the observer will perceive the color of the dyed solvent. The performance of the resulting display is strongly dependent upon the suspension stability.
In non-aqueous dispersions, colloid particles generally owe their stability to the fact that their surfaces are charged and, hence, repel each other. When the particles are uncharged, the dispersion is unstable. The fact that a colloidal particle bears a net surface charge is not a sufficient condition for stability because electroneutrality demands that the particle plus its immediate surroundings bear no net charge. In other words, the surface charge must be compensated by an equal but opposite counter charge, so that the surface charge and countercharge together form an electrical double layer. P. Murau and B Singer, in an article appearing in Vol. 49, No. 9 of the Journal of Applied Physics (1978) and entitled “The Understanding and Elimination of Some Suspension Instabilities in an Electrophoretic Display”, indicate that when the double layer is compressed, the particles can approach each other to within a few hundred angstroms before repulsion is felt whereupon the van der Waals attraction becomes so strong that aggregation occurs.
The interactions of particle surfaces and charge control agents in colloidal suspensions had been the subject of considerable research. Reference is made to an article entitled “Mechanism of Electric Charging of Particles in Nonaqueous Liquids” appearing in Vol. 15 of the Journal of the American Chemical Society (1982), wherein F. M. Fowkes et al discuss the mechanism of electrostatic charging of suspended acidic particles by basic dispersants in solvents of low dielectric constant. Reference is also made to an article entitled “Steric and Electrostatic Contributions to the Colloidal Properties of Nonaqueous Dispersions” appearing in Vol. 21 of the Journal of the American Chemical Society (1984) wherein F. M. Fowkes and R. J. Pugh discuss the importance of anchoring sites for steric stabilizers in minimizing particle flocculation. The essential point developed by these references is that particle surface interactions are acid-base in character. Acidic pigment surface sites and basic charge control agents yield negative pigment surface charge. On the other hand, basic pigment surface sites and acidic charge control agents yield positive pigment surface charge.
Since electrophoretic devices utilize low polarity liquids in which ionization of ordinary organic acids and salts is negligible (approximately 10−10 moles per liter), the charge of the particle is governed by trace impurities unless otherwise controlled by adsorbing on the pigment surface a suitable charge control agent. This amount of charge, although sufficient for electrophoretic activity may still be inadequate for electrostatic stabilization of the suspension. if the charge control agent is also polymeric, or a polymeric dispersant is present in addition, the colloid stability can be further enhanced.
As will be recognized by a person skilled in the art, the selection of the electrophoretic particles used in the EPD is very important in determining the performance of the EPD and the quality of the viewed image produced. Ideally, electrophoretic particles should have an optimum charge/mass ratio, Which is dependent upon the particle size and surface charge, to obtain good electrostatic deposition at high velocity as well as rapid reversal of particle motion when voltages change. Additionally, it is desirable to utilize electrophoretic particles that have essentially the same density as the fluid medium in which they are suspended. By using electrophoretic particles of essentially the same density as the suspension medium, the migration of the electrophoretic particles through the medium remains independent of both the orientation of the EPD and the forces of gravity. The light-colored particles are commonly inorganic pigments. Titanium dioxide, for example, has been used in EPDs to produce good optical contrast between the white particles and the colored suspension medium. However, it has a density of about 4 g/cm3, which is too high to match with any organic liquid to prevent the sedimentation problem. In the past decades, great effort has been made to solve the density problem of titanium dioxide. However, very little work has succeeded without trading off the quality of the images, especially regarding the whiteness. Coating titanium dioxide particles with a polymeric material to reduce the density of titanium dioxide is an example.
U.S. Pat. No. 4,655,897 to DiSanto et al., U.S. Pat. No. 4,093,534 to Carter et al., U.S. Pat. No. 4,298,448 to Muller et al., and U.S. Pat. No. 4,285,801 to Chaing teach a different means to utilize the light-colored titanium dioxide particles in EPDs to produce good optical contrast between the white particles and the colored suspension medium.
Useful electrophoretic displays are bistable: their state persists even after the activating electric field is removed. This is generally achieved via a residual charge on the electrodes and van der Waals interactions between the particles and the walls of the electrophoretic cell. Unfortunately, the stability of the prior art electrophoretic displays is limited. Although flocculation or settling of particles can be avoided by matching the density of the particles with that of the liquid medium, long-term particle agglomeration remains a problem. That is, cohesive forces among particles may eventually overcome dispersive forces degrading the appearance and function of the display. For example, particle agglomerations respond less efficiently to an applied field (increasing switching time) and are also more vulnerable to the action of gravity (limiting usefulness in arbitrary orientations); thus, if the display is oriented vertically, gravity can overcome adhesion to the cell wall and cause agglomerations to settle.
U.S. Pat. Nos. 5,930,026 and 5,961,804 to Jacobson et al introduce an E-ink technology, microencapsulating individual elements of an electrophoretic display. This approach eliminates the effects of agglomeration on a scale larger than the size of the capsule, which is sufficiently small to be individually unnoticeable. The E-ink is positioned between the transparent common electrode and the pixel electrodes and typically comprises multiple microcapsules having a diameter between about 10 and 50 microns. In one example of a black-and-white display, each microcapsule comprises positively charged white particles and negatively charged black particles suspended in a fluid. When a negative electric field is applied from the pixel electrode to the transparent common electrode, the negatively charged black particles move towards the common electrode and the pixel becomes darker to a viewer. Simultaneously, the positively charged white particles move towards the pixel electrode on the backplane, away from the viewer's sight. The basic function of the current e-ink device is a reflective bistable display.
It is a primary objective of the present invention to create a transmissive electrophoretic light shutter.
It is another objective of the present invention to achieve a bistable smart window.
It is a further objective of the present invention to fabricate a multi-stable light modulator.
It is another objective of the present invention to take the advantage of the symmetric electrode structure for the TFT addressing the suspended particles in a way of fan-in and fan-out within a pixel.
It is again another objective of the present invention to create a zero-field haze-free transparent optical ON state.
It is still a further objective of the present invention to create a zero-field Lambertian opaque optical OFF state.
It is another objective of the present invention to obtain a zero-field black optical OFF state.
It is still another objective of the present invention to obtain a color image.
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The white particle 422 has a double-layer structure with a size in the range of 1˜5 microns, more preferably 2 microns. A thermoplastic polyethylene wax material is coated on the cores of the white particle as a top layer in order to match the density to each other and the dielectric liquid fluid. Meanwhile, a suitable electric charge control agent with a predetermined polarity will be embedded into the polymeric layer to build up the charge density for those particles. Generally, the charge control agent tenders a zeta potential equal to 50˜100 elementary charges on the surface of a particle 1 micron in radius; this produces sufficient electrophoretic mobility on the order of 10−4 to 10−5 cm2/V-sec. One of the embodiments of the present invention is to prepare precisely controlled uniform charged particles. Intensive research has been focused on making polyethylene micro balls as a starting material for electrophoretic charged particles. Two categories of dry powders are available now: the first polyethylene micro ball with an average size of 5 microns and a melting point of 110° C. and the second polyethylene ball with an average size of 6 microns and a melting point of 120° C. The following examples illustrate the process of making positive charged white particles.
The working medium used to make electrophoretic particles according to the present invention was a commercial aliphatic solvent consisting of hydrocarbons of isoparaffinic structure as the commercial name ISOPAR G from Brenntag, CAS No 90622-57-4. The solvent has a distillation range from 161° to 173° C., with a density of 0.748 g/cm3.
In 1000 ml of this solvent, the following were suspended at room temperature with agitation:
The mixture was heated to 105° C. with continued agitation, the surfactant and the CCA were dissolved completely and the polyethylene micro ball and TiO2 particle were dispersed very uniformly. And then the temperature was increased slowly up to 109-110° C. It was discovered that as the temperature is close to the melting point of the polyethylene wax, the micro ball starts attaching to the TiO2 particles and forming a cluster of combinations to minimize the systematic energy. At the melting temperature of 110°, or just above it, the micro ball dissolves rapidly and encapsulates TiO2 particles completely. At this moment, a strong agitation is needed to control the dimension of the resulting microcapsule around 2 microns. Clouding and precipitation of the microcapsules from the clear solution occurred when the mixture was cooled below the melting point of polyethylene wax. The mixture when cooled down to room temperature was filtered, and the residue remaining on the filter, i.e. the encapsulated pigment particles, was washed with cold hexane to remove adhering solvent.
The positively charged white particles were uniformly distributed. A sharp maximum in the particle size distribution was found at a particle diameter of about 2 microns.
In 1000 ml of ISOPAR solvent, the following were suspended at room temperature with agitation:
The wax-encapsulation process of the white particles was basically the same as that of example 1. The positively charged white particles were uniformly distributed. A sharp maximum in the particle size distribution was found at a particle diameter of about 2 microns.
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The black particle 522 has a double-layer structure with a size in the range of 1˜5 microns, more preferably 2 microns. A thermoplastic polyethylene wax material is coated on the cores of the black particle as a top layer in order to match the density to each other and the dielectric liquid fluid. Meanwhile, a suitable electric charge control agent with a predetermined polarity will be embedded into the polymeric layer to build up the charge density for those particles. Generally, the charge control agent tenders a zeta potential equal to 50˜100 elementary charges on the surface of a particle 1 micron in radius; this produces sufficient electrophoretic mobility on the order of 10−4 to 10−5 cm2/V-sec. One of the embodiments of the present invention is to prepare precisely controlled uniform charged particles. Intensive research has been focused on making polyethylene micro ball as a starting material for electrophoretic charged particles. Two categories of dry powders are available now: the first polyethylene micro ball with an average size of 5 microns and a melting point of 110° C. and the second polyethylene ball with an average size of 6 microns and a melting point of 120° C. The following examples illustrate the process of making positive charged white particles and negative charged black particles.
In 1000 ml of ISOPAR solvent, the following were suspended at room temperature with agitation:
The wax-encapsulation process of the black particles was basically the same as that of example 1. The negatively charged black particles were uniformly distributed. A sharp maximum in the particle size distribution was found at a particle diameter of about 2 microns.
3 g of the polyethylene encapsulated positive particles and 3 g negative particles thus obtained were stirred into a mixture (dielectric liquid fluid) consisting of 55 ml liquid paraffin (“perliquidum”, DAB 6, density 0.83 to 0.87 g/cm3, maximum viscosity about 65 cP) and 45 ml of Tetrachloroethylene (density 1.622 g/cm3, viscosity 0.89 cP). In order to produce the EPID suspension, the resulting mixture was homogenized for about 10 seconds using ultrasound before application.
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Where d is the distance between electrodes, η is the viscosity of the liquid medium, ∈ is the dielectric constant, V is the potential difference between the electrodes, and is the zeta potential of the particles. The quantity t represents the time required for charged particles to migrate from one of the electrodes to the other. According to the symmetrical pixel design of the present invention, the relationship between the switching time and the grayscale level can be derived as follows. The black area A is governed by formula 2.
A=πd2 (2)
Suppose the cell gap is sufficiently small compared with the side length of the square pixel cell and the particles migrate from the square center, one can combine formula 1 and formula 2 into formula 3:
One may realize immediately that the switching time t has a linear relationship with the grayscale A=ƒ(d). In the case of a constant applied voltage and all other parameters remaining the same, the grayscale is directly proportional to the switching time. In the case of square wave pulses, the grayscale is directly proportional to the number of pulses. Therefore, a multi-stable clear-and-black electrophoretic light shutter is achieved. This is the theoretical background of the present invention. Practically, the shutter can be used as a smart window, a displayable window.
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Turning now to 8, illustrated is a schematic structure of a sunlight readable PC computer. The computer is substantially similar to a conventional PC except for a transparent electrophoretic light shutter display 530 opening on the back lid. An internal backlight unit and a TFT LCD panel within the housing 520 are of approximately the same area as the electrophoretic display 530. The substantially transparent display panel 530 can be embedded on the back lid.
During the daytime in an outdoor application, a beam of sunlight 511 passing through the electronic window 530 becomes light beam 512. It proceeds to pass through a built-in backlight structure and a LCD panel as a fun-color image 513 to a viewer 540. Meanwhile, the built-in backlight structure will generate an artificial color imaging light 521 to the viewer 540. The color image 513 illuminated by the sunlight may be much brighter than that of the 521 so that the internal backlit can be automatically attenuated or even completely turned off.
In indoor applications or a dimmed outdoor environment, the electrophoretic light shutter 530 is set in an optical OFF state. There will be no internal backlight leaking out of the light shutter. The PC is back to the normal working mode and the built-in backlight is fully responsible for the generation of the color image 521.
Whenever it is needed the electrophoretic light shutter can be turned to a reflective display mode or an E-book mode so that a viewer 850 will discern a black-and-white image 814 from the back lid of the computer. The dual display mode can be also set up when two views 840, and 850 opposite to the device watch their content simultaneously, in a convertible display mode, the back lid of the PC may be also flipped back to the keyboard 860 and the device becomes a tablet E-reader.
In the U.S. Pat. No. 7,853,288, the applicant discloses a sunlight illuminated and sunlight readable mobile phone, which is incorporated herein by reference. The display panel opens a transparent window to the ambient light, which allows the sunlight to illuminate the display in both indoor and outdoor applications.
In the U.S. Pat. App. No. 20140043565, the applicant discloses a sunlight readable full-color active-matrix liquid crystal display device by means of light guiding films, which is incorporated herein by reference.
In the U.S. Pat. App. No. 20150002781, the applicant discloses a sunlight readable full-color active-matrix liquid crystal display device by means of an electric controllable light shutter, Which is incorporated herein by reference.