The invention relates to heating films, particularly to transparent heating films which can be applied to windshields of vehicles for defogging.
Moisture will condense on a windshield of vehicle because of temperature difference. This will obstruct a driver's vision to risk driving safety. Thus windshields of all vehicles are provided with a defogger to eliminate fog on a windshield. Current vehicle defoggers usually attach metallic grid lines on a rear windshield and the grid lines are connected in parallel. When powered, the grid lines are heated by their own resistance to heat up the rear windshield so as to dissipate mist attached on the windshield. While such a conventional defogger is working, however, the heated areas concentrate near the grid lines, and the areas which are located apart from the grid lines have to be heated by thermal conduction. This not only makes defogging time extended, but also causes internal stress in the windshield because of uneven heat distribution to make the windshield rupture after long term use. Further, conventional defogger grid lines are made of opaque metallic material, such grid lines attached on a windshield not only affect the appearance but also impede a driver's vision to be adverse to driving safety.
To improve the problems of vision obstruction and poor appearance of conventional defogger, some manufacturers have replace metallic defoggers with ITO conductive strips. However, the ITO conductive strips as a heat source can overcome the problem of vision obstruction, but the drawbacks of uneven heating distribution and long defogging time have not been solved. In addition, ITO film material possesses fragility and poor ductility, so its bending portions are easy to fracture to cause an open circuit and fail.
An object of the invention is to provide a transparent heating film, which can completely planarly and rapidly heat up
To accomplish the above object, the transparent heating film of the invention includes: a base layer being a transparent film with a dielectric property; a resistance layer, being a transparent conductive film with a surface resistivity between 60 and 150 Ω/sq, and disposed on the base layer; an electrode layer, having an electrode circuit pattern which is formed by a mesh crossed with conductive wires, a mesh density of the electrode circuit pattern being between 1 and 25 mesh/mm2, and the electrode circuit pattern electrically connecting with at least one local area of the resistance layer; and a protection layer, being a transparent film with a dielectric property, and completely covering the electrode layer and the resistance layer.
In the invention, the base layer and the protection layer are made of glass, polypropylene (PP), polyethylene (PE), polystyrene (PS), polymethyl methacrylate (PMMA), polycarbonate (PC), polyethylene terephthalate (PET), polyvinyl chloride PVC), polyimide (PI) or polyurethane (PU), but not limited to these. Other soft, hard or flexible materials are available.
In the invention, the resistance layer is a metal oxide film which is made of indium tin oxide (ITO), indium zinc oxide (IZO), aluminum zinc oxide (AZO), antimony tin oxide (ATO) or polyethylene dioxythiophene (PEDOT), but not limited to these.
In the invention, the conductive wires are made of graphene or an alloy containing silver, copper, gold, aluminum or molybdenum. Preferably, the conductive wire is below 8 μm in width. More preferably, the conductive wire is below 5 μm in width.
According to the invention, the electrode circuit pattern is electrically connected to the resistance layer via mesh conductive wires, so multiple electric contacts are formed between the electrode circuit pattern and the resistance layer. When the electrode circuit pattern is powered, the electric contacts and their adjacent areas on the resistance layer will be heated up by the electrothermal conversion. Because the electric contacts P are evenly distributed on the resistance layer 20, the heat therefrom will be evenly distributed to the whole region to avoid overheating at local areas. Also, the thermal conducting time can be shortened to improve the defogging efficiency. Accordingly, the invention can solve the problem of uneven electrothermal conversion on a large-size heating film. In addition, the electrode circuit pattern is electrically connected to the resistance layer. The electrode circuit pattern is formed by a mesh crossed with metallic wires with ductility and malleability, so the transparent heating film of the invention can used under bent conditions, such as being attached on a curved surface. Even if the film material of the resistance layer is fractured, the conductive wires on the electrode circuit pattern still can make electric conduction to implement defogging.
In a preferred embodiment, the invention further includes an auxiliary electrode layer. The auxiliary electrode layer has an auxiliary electrode circuit pattern formed by a micron mesh crossed with conductive wires. The auxiliary electrode circuit pattern is electrically connecting with both the electrode layer and at least one local area of the resistance layer. Meshes of the auxiliary electrode circuit pattern are staggered with meshes of the electrode circuit pattern. A mesh density of the auxiliary electrode circuit pattern is between 1 and 25 mesh/mm2. The conductive wires are made of graphene or an alloy containing silver, copper, gold, aluminum or molybdenum. Preferably, the conductive wire is below 8 μm in width. More preferably, the conductive wire is below 5 μm in width. In some embodiments of the invention, mesh densities in local areas can be increased by adding auxiliary electrode circuit patterns in the local areas to decrease equivalent impedance of the resistance layer in the local areas. The reduced equivalent impedance can reduce heat by electrothermal conversion. On the other hand, the invention may add more electric contacts on the resistance layer to make heat distributed more evenly on the whole region. This cam shorten thermal conducting time and improve defogging efficiency. According to the invention, heat generated in local areas of the resistance layer can be adjusted by electrically connecting local areas with electrode circuit patterns with different mesh densities and/or auxiliary electrode circuit patterns. As a result, the invention provides an approach which can adjust local heat of a heating film.
In an embodiment of the invention, the electrode layer has multiple electrode circuit patterns with different mesh densities, the multiple electrode circuit patterns are formed by meshes crossed with micron conductive wires. The mesh densities are between 1 and 25 mesh/mm2. Adjacent ones of the electrode circuit patterns are electrically connected to each other. The multiple electrode circuit patterns are electrically connected with at least one local area of the resistance layer. In a preferred embodiment, local areas with different equivalent impedances are formed on the resistance layer by disposing multiple electrode circuit patterns with different mesh densities on the electrode layer and connecting to the resistance layer to generate different heat in the local areas.
The summary of the invention introduces specific concepts in a concise manner. The following description will further describe the details. The summary of the invention does not recognize critical or basic features and does not intent to limit the scope of the invention.
Preferred embodiments are depicted in the drawings. To make the invention more understandable, some elements in the drawings are not drawn in an accurate scale and sizes of some elements are enlarged with respect to other elements. For the sake of clearness, irrelative details are not drawn.
The transparent heating film of the invention can be obtained by superposing the abovementioned layers. As shown in
The transparent heating film of the invention can be obtained by superposing the abovementioned layers. As shown in
The transparent heating film of the invention can be obtained by superposing the base layer 10, the resistance layer 20, the electrode layer 30 and the protection layer 40. As shown in
It will be appreciated by persons skilled in the art that the above embodiments have been described by way of example only and not in any limitative sense, and that various alterations and modifications are possible without departure from the scope of the invention as defined by the appended claims.