Transparent soap formulations and methods of making same

Abstract

Formulations for transparent soaps and methods of preparation are disclosed. The transparent soaps are prepared by combining high and low molecular weight fatty acids in the presence of polyhydric alcohols. Citric acid is added to adjust pH. The formulations do not require volatile, short-chain monohydric alcohols to achieve transparency and the end products are able to retain transparent qualities when exposed to hot water conditions. Suitable formulations can be remelted to reduce waste.

Description

FIELD OF THE INVENTION

The present invention relates to transparent soap formulations and corresponding methods of manufacture. More particularly, the invention is a transparent soap formulation prepared by combining high and low molecular weight fatty acids in the presence of polyhydric alcohols. Adjustments to pH are accomplished with citric acid.

BACKGROUND OF THE INVENTION

As used in this specification, the term "transparent soap" refers to a one-quarter inch soap section through which a person having 20/20 vision can read 14 point boldface type. This term is not restricted to those soaps which are clear or colorless because it is often desirable to add color to transparent soap. The present invention contemplates both colored and clear transparent soaps.

For commercial acceptance, transparent soaps must retain all the quality characteristics of conventional, opaque soap (such as good lather, hardness, mildness, minimum sluffing and the like). These products must remain transparent under normal use for extended periods of time. U.S. Pat. Nos. 3,793,214 and 3,926,828 describe known, but inferior, formulations made by neutralizing a mixture of saturated fatty acids and aliphatic monocarboxylic acid with a pH adjusting agent containing alkanolamines.

The present invention includes, inter alia, the production of transparent soaps comprised of sodium tallowate, sodium cocoate and non-volatile polyhydric alcohols, in which the pH is adjusted with citric acid. Transparent products made from the presently disclosed soap formulations have all of the desired qualities of conventional, opaque soap and additional features which permit economic and safe production.

Currently known soap formulations do not retain transparency when remelted, making it impractical to economically recycle excess waste. Conventional techniques also require aging, a process which evaporates volatile, short-chain monohydric alcohols. This aging process is time-consuming, expensive and potentially hazardous to production personnel.

The ability of soap to be remelted and retain all of its original qualities is critical for reducing costs. During production, a large reserve of scrap soap accumulates. This scrap is frequently discarded because it cannot be remelted to form a product which exhibits the original features. Lages U.S. Pat. No. 3,969,259; Verite U.S. Pat. No. 4,980,078 and Lindberg U.S. Pat. No. 4,468,338 disclose state-of-the-art transparent soap preparations which are subject to these deficiencies. These and other references demonstrate the need for a remeltable formulation to dramatically reduce production costs.

The traditional method for making transparent soap involves forming a solution of ingredients in a volatile solvent (commonly ethanol), casting the pourable mixture into large mold frames and allowing the volatile solvent to evaporate. Solidified soap is semi-opaque when initially cast. Solvent evaporation creates the transparent qualities of each formulation. But, evaporation is time-consuming and commonly causes a weight loss in excess of 15 percent.

For example, soap bars produced according to Chambers U.S. Pat. No. 4,988,453 must initially contain 6 to 15 percent volatile, low molecular weight alcohols (such as methylated spirits, ethanol and isopropanol) which require an aging period of several days to achieve transparency. In addition, the aging-evaporation procedure releases alcohol vapors which require expensive measures to reduce the hazards of exposure.

Other problems are known to the art. Typical casting methods cause shrink deformation resulting from the evaporation of alcohol and moisture. Transparent bars frequently have inferior end-use properties, despite higher retail prices when compared to opaque counterparts. Known transparent soaps frequently develop a sticky, opaque surface layer when placed in contact with water. And, high alkaline content can cause skin dryness. Soap bars which typically display these problems are produced according to the disclosures of Fromont U.S. Pat. No. 2,820,768; Poper U.S. Pat. No. 4,290,904 and Jungermann U.S. Pat. No. 4,758,370. They are sold commercially under the trade name "Neutrogena."

The present disclosure provides, inter alia, formulations which include sodium soap and polyhydric alcohols in critical weight percent ranges. These ingredients are mixed with specific acids to adjust the pH condition. Disclosed formulations produce soap products that do not require aging to obtain transparency, can be remelted and have the ability to accept color. This invention also provides a mild formulation which exhibits all the qualities of a conventional, high quality soap.

It is an object of the present invention to provide formulations and methods for making transparent soaps which do not require lengthy aging procedures or the use of hazardous, volatile, low molecular weight alcohols to achieve transparency.

Another object is to provide a transparent soap which can be remelted to achieve acceptable transparency using recycled production scrap.

A further object is to provide formulations for making transparent soaps which do not form undesirable opaque sluff-residues during or after end use application.

Yet another object is to provide transparent soap bars with exceptional gloss-like clarity and enhanced stability to light, heat and oxygen.

Still another object is to provide transparent soaps having excellent odor profiles with or without incorporation of a fragrance.

SUMMARY OF THE INVENTION

The present invention includes formulations and methods for making a transparent soap composition which contains polyethylene glycol, propylene glycol, glycerin, triethanolamine lauryl sulfate, alkoxylated cetyl alcohol, sodium hydroxide, sodium alkyl polyether sulfonate, sucrose, sodium cocoyl isethionate, unreacted free fatty acids, sodium tallowate, sodium cocoate and other minor ingredients such as fragrance, antioxidants, chelating agents, foam stabilizers, colorants and germicides.

Maintaining the correct balance of organic solvents and free fatty acids will produce an exceptional transparent product under the correct pH conditions. Organic solvents are preferably chosen from polyols having 2 to 6 carbon atoms. The term "polyol" generally defines a non-volatile, dihydric or higher, polyhydric alcohol such as polyethylene glycol, propylene glycol and glycerin.

The process for making the present transparent soaps essentially begins with heating a composite mixture of selected polyols with other ingredients such as foam boosters and agents for providing mildness. A separate blend of selected tallow and vegetable fatty acids is heated to match the temperature of the polyol mixture. The blend is then added to the polyol mixture. A new composite is formed and heated to a higher temperature.

An aqueous solution of sodium hydroxide is slowly added to the mixture with careful monitoring and control of the reaction temperature. Other ingredients in the form of sodium salts can be added during this step for convenience. The composite is continuously mixed.

A heated, aqueous sodium chloride solution is added to the agitated composite, followed by addition of other ingredients such as solidifying agents which are effective when the mixture is cooled. Heat is maintained and the composite is mixed vigorously until all ingredients are totally solubilized.

After the ingredients are solubilized, the temperature is reduced. During cooling, the pH of the composite is carefully adjusted with a solution of citric acid to achieve the correct pH value and free fatty acid content. The composite is then poured into molds and allowed to solidify.

As the description below further illustrates, the transparent soaps of the present formulation are made without lengthy processing and aging procedures. The method of the present invention does not require the use of volatile, low molecular weight alcohols to achieve transparency. Present formulations also provide a product that is compatible with hot water wash conditions without formation of the undesirable, opaque residues that develop with known transparent products.

The soap bar of this invention has exceptional gloss-like clarity, enhanced stability to light, heat and oxygen, as well as excellent odor characteristics with or without incorporation of a fragrance. Further, the unique formulation provides the delivery of other cosmetic materials and benefits, such as emolliency and deodorancy, while maintaining clarity and superior after-feel. These and other advantageous of the present invention are further described in this specification.

DETAILED DESCRIPTION OF THE INVENTION

The preferred formulations for the present transparent soaps contain the ingredients and ranges outlined in the following chart. All values are expressed in weight percents.

______________________________________ RANGE OPTI- MINI- MUM MAXI- MUM W/W MUMINGREDIENT W/W % % W/W %______________________________________Polyethylene Glycol 0.1 9.60 15.0Propylene Glycol 0.1 10.90 20.0Glycerin 0.1 12.76 20.0Triethanolamine Lauryl Sulfate 0.1 10.45 20.0Alkoxylated Cetyl Alcohol 0.1 0.67 3.0Tetrasodium Edta 0.1 0.14 0.5Distyrl Biphenyl Derivative 0.0 0.01 0.1Tallow/Coconut Fatty Acid 17.0 19.00 21.0Sodium Hydroxide (50%) 6.0 7.60 9.0Sodium Alkyl Polyether Sulfonate 0.1 3.61 8.0Sucrose 3.0 7.84 12.0Sodium Cocoyl Isethionate 1.0 3.80 10.0Sodium Chloride 0.1 0.71 2.0Pentasodium Pentatate 0.0 0.05 0.2Tetrasodium Etidronate 0.0 0.05 0.2Citric Acid 0.1 0.77 1.5Water 5.0 11.04 15.0Fragrance 0.0 1.0 3.0______________________________________

A broad range of molecular weight fatty acids could be substituted to achieve similar results. For instance, soaps prepared from fatty acids having a distribution of coconut or other tropical nut oils may provide a lower end of the broad molecular weight spectrum (i.e., fatty acids with 6 to 14 carbon atoms); while soaps prepared from fatty acids having the molecular weight distribution of peanut oil, grapeseed oil or tallow may provide the upper end. In the preferred embodiment, the starting formulations have fatty acid components with 70 to 85% tallow and 15 to 30% coconut fatty acids.

The amount of fatty acid to be neutralized with a stoichio-metric amount of a polyol or polyol blend is preferably in range ratio of about 1:1 to 1:3, and more preferably within the range of 1:1.9 to 1:2.5, with the optimum ratio being about 1:2.2. In addition to the neutralizing role, the presence of non-volatile polyols enhances the clarity of the end product and prevents shrinkage of the bar during storage and use. The sodium hydroxide in the indicated ranges provides further neutralizing activity for production of optimum transparency.

A correct pH range and the use of an adjusting agent are critical for achieving transparent soap bars from starting formulations. It has been unexpectedly discovered that adjusting the pH within a range of 9.1 to 9.5 will result in the desired end products. The optimum pH is approximately 9.2. Obtaining a pH outside the preferred range will opacify the product. Excess free alkalinity will also produce an opaque soap bar. A free fatty acid content in the range of 0.1 to 5.0% will provide transparent products. The preferred free fatty acid range is between 2.0 to 4.0%.

Water is an important ingredient because the hardness and clarity of the finished bar are strongly dependent on its total moisture content. There are several sources of water in this formulation such as the caustic soda solution and the water generated during the formation of sodium tallowate and sodium cocoate produced by the neutralization reaction. Water is also introduced with the addition of triethanolamine lauryl sulfate, alkoxylated cetyl alcohol and the like. The addition of free water to the bar formulation will also influence the final product. Generally, water addition of less than 5% total (not formed in situ or introduced by other ingredients) will usually result in a bar that is too hard and tends to form crystals with associated loss of clarity. Free water addition in excess of about 15% will usually result in a bar that is too soft.

Ingredients to improve mildness are also contemplated by the present formula. These ingredients may include the sodium salt of alkyl polyether sulfonate, sodium cocoyl isethionate and alkoxylated cetyl alcohol.

Foam boosters are also included in the formula to ensure sufficient lather characteristics. These compositions include triethanolamine lauryl sulfate and sodium cocoyl isethionate. But, the primary foam characteristics are provided by the reaction of fatty acid with sodium hydroxide. The following, non-limiting example demonstrates the preferred embodiment of this invention.

EXAMPLE 1

Transparent Soap Bars

Table 1 lists the ingredients and weight percents for a formula which was used to prepare test soap bars of the present invention. Additional examples demonstrate various properties of soap bars prepared according to this invention.

TABLE 1______________________________________FORMULAINGREDIENTS PERCENTAGE______________________________________Polyethylene Glycol 9.6000Propylene Glycol 10.8800Glycerin 12.7618Triethanolamine Lauryl Sulfate 10.4500Alkoxylated Cetyl Alcohol 0.6650Tetrasodium Edta 0.1425Distyrl Biphenyl Derivative 0.0100Tallow/coconut Fatty Acid 19.0000Sodium Hydroxide (50%) 7.6000Sodium Alkyl Polyether Sulfonate 3.6100Sucrose 7.8400Sodium Cocoyl Isethionate 3.8000Sodium Chloride 0.7125Pentasodium Pentatate 0.0500Tetrasodium Etidronate 0.0500Citric Acid 0.7722Water 12.0560______________________________________

Polyethylene glycol, propylene glycol, glycerin, triethanolamine lauryl sulfate, akloxylated cetyl alcohol, tetrasodium EDTA and distyrl biphenyl derivative were added to a tank equipped with a heating jacket and variable speed mixer. This composite was heated and mixed until a temperature of 150.degree.-155.degree. F. was attained.

A 85% tallow acid 15% coconut oil fatty acid blend was heated to approximately 150.degree. F. and added to the mixed composite. The new composite was further mixed and heated until a temperature of 160.degree.-165.degree. F. was achieved.

A 50% aqueous solution of sodium hydroxide was slowly added to the mixture. Since the neutralization of the fatty acid is an exothermic reaction, sodium hydroxide addition must be controlled so the temperature will not exceed 195.degree. F. After all of the sodium hydroxide was added, the composite was mixed for 15 minutes at approximately 195.degree. F. The sodium alkyl polyether sulfonate was added and mixed for approximately 10 minutes.

Water and the sodium chloride were mixed and heated in a side kettle. After the sodium chloride was totally solubilized, the water/sodium chloride solution was added to the mixing tank, followed by sucrose and sodium cocoyl isethionate. This composite was mixed vigorously, at approximately 170.degree.-185.degree. F. for 15 minutes, or until all of the ingredients were in solution.

After the ingredients were solubilized the temperature was reduced to approximately 160.degree.-165.degree. F. Pentasodium pentetate and tetrasodium etidronate were added after cooling. The composite was mixed for 10 minutes to achieve uniformity. At the same time, the temperature was lowered to 150.degree.-155.degree. F. and the mixer speed was reduced to minimize entrapped air bubbles.

The pH conditions were monitored during cooling. A 10% solution of citric acid was added until the pH was reduced to 9.1-9.5 and the free fatty content was between 2.0 and 4.0%. After the pH and free fatty acid were in an acceptable range, the composite was placed in molds to solidify.

EXAMPLE 2

Moisture Content

This example demonstrates the importance of maintaining the correct moisture content. Transparent soap bars (Batch Nos. 141, 144, 151 and 152) were prepared in accordance with the formula and procedure of Example 1 (with different water content). Moisture content was measured and corresponding transparent qualities were noted for the various conditions. Objective criteria for acceptable transparency are described in the Background section. Results are indicated in Table 2.

TABLE 2______________________________________BATCH % TRANSPARENCYNO. MOISTURE ACCEPTABLE UNACCEPTABLE______________________________________141 20.05 X 19.65 X 19.29 X 18.59 X 18.37 X 17.47 X 17.14 X 16.60 X 15.91 X144 16.19 X151 13.23 X152 14.17 X______________________________________

In Batch 141 the soap base was maintained at 150.degree.-155.degree. F. in a holding tank and periodically sampled. Results showed that transparency was maintained as long as the moisture content was greater than 17%. Batches 144, 151 and 152 were also prepared with moisture values below 17%. In each instance, the transparency of the product was rated as "unacceptable."

EXAMPLE 3

pH and Free Fatty Acid Content

Experiments were conducted to show the critical balance between pH and free fatty acid content in order to obtain an acceptable transparent product. Soaps were made according to Example 1 with modifications for pH values. Batches were identified as numbers 163, 165 and 166. Free fatty acid content and pH were measured as citric acid was added, then later correlated with objective observations for transparency in the relevant end products. Adding citric acid increased the free fatty acid content of the product while decreasing pH.

As shown by Table 3A, the transparency of end products was maintained as long as the pH did not fall below 9.1 and the free fatty acid content did not exceed 4.0%.

TABLE 3A______________________________________ % TRANSPARENCYBATCH FATTY UN-NO. pH ACID ACCEPTABLE ACCEPTABLE______________________________________163 9.44 2.01 X 9.31 2.87 X 9.19 3.62 X 9.02 5.83 X______________________________________

It was discovered that end products should have a free fatty acid content of about 2.0-4.0%. Soaps which had higher relative free alkalinity (about 0.055%) demonstrated unacceptable transparency. Measurement of free alkalinity in separate experiments confirmed these findings. The results are set forth in Table 3B.

TABLE 3B______________________________________BATCH NO. % FREE ALKALINITY TRANSPARENCY______________________________________163 0.055 UNACCEPTABLE 0.055 UNACCEPTABLE______________________________________

EXAMPLE 4 REMELTABILITY

Tests were conducted to demonstrate the ability of the present formulations to be remelted and retain transparent qualities. Batch No. 150 was prepared according to the formula and procedure of Example 1 with modifications for moisture content. Because test conditions were designed to simulate high temperature recycling, the water content was raised above the ranges previously disclosed in this specification.

In the first set of experiments, the formulations were held at a high temperature for the time periods indicated in Table 4. At each time interval, moisture content and objective transparent qualities were noted.

TABLE 4______________________________________BATCH NO. 150TIME INTERVALPERCENT TRANSPARENCY150-160.degree. F. WATER ACCEPTABLE UNACCEPTABLE______________________________________0 Hour.sup. 20.87 X1 Hour.sup. 20.09 X2 Hours 19.63 X3 Hours 17.92 X4 Hours 20.11* X5 Hours 18.32 X6 Hours 19.40* X7 Hours 17.40 X8 Hours 15.35 X______________________________________ *Water was added to keep moisture content in the desired range.

The Table 4 results demonstrate that the present formulations are able to maintain transparency even at extreme temperatures, as long as proper moisture content is maintained. For instance, at 4 and 6 hours, the addition of water maintained transparent qualities without sacrificing hardness.

The above product was discharged from the tank and allowed to solidify. After 24 hours, the solidified product (Batch No. 151, simulating scrap soap) was placed in a reaction tank and remelted at 150.degree.-160.degree. F. As shown by Table 4B, the correct moisture content was achieved by adding approximately 5% water. Remelted products had acceptable transparency resulting from the higher moisture content.

TABLE 4B______________________________________BATCH NO. 151TIME INTERVALPERCENT TRANSPARENCY150-160.degree. F. WATER ACCEPTABLE UNACCEPTABLE______________________________________0 Hour.sup. 18.17 X1 Hour.sup. 18.79 X2 Hours 16.59 X3.5 Hours 13.23 X______________________________________

Various modifications and alterations to the present invention may be appreciated based on a review of this disclosure. These changes and additions are intended to be within the scope and spirit of this invention as defined by the following claims.

Claims

1. A transparent soap formulation which comprises:

(a) about 0.3 to about 45.0% polyol component;

(b) a transparency enhancing amount of about 17.0 to about 21.0% fatty acid component formulated from a combination of tallow and vegetable oil fatty acids;

(c) a transparency enhancing amount of about 6.0 to about 9.0% sodium hydroxide;

(d) a transparency enhancing amount of about 0.1 to about 1.5% citric acid;

(e) about 3.0 to about 12.0% sugar component; and

(f) a transparency enhancing amount of about 5.0 to about 15.0% water.

2. The formulation for making transparent soap of claim 1, wherein said polyol component is selected from the group consisting of polyethylene glycol, propylene glycol, glycerin and combinations thereof.

3. The formulation for making transparent soap of claim 2, wherein said polyol component comprises:

(a) about 0.1 to about 15.0% polyethylene glycol;

(b) about 0.1 to about 20.0% propylene glycol; and

(c) about 0.1 to about 20.0% glycerine.

4. The formulation for making transparent soap of claim 2, wherein said polyol component comprises:

(a) 9.60% polyethylene glycol;

(b) 10.90% propylene glycol; and

(c) 12.76% glycerine.

5. The transparent soap formulation of claim 1, wherein said fatty acid component comprises from about 70 to about 85% soap derived from tallow and from about 15 to about 30% soap derived from vegetable oil.

6. The transparent soap formulation of claim 1 which comprises about 7.6% of sodium hydroxide.

7. The transparent soap formulation of claim 1 which comprises about 0.77% of citric acid.

8. The transparent soap formulation of claim 1, wherein said sugar component comprises about 7.84% of sucrose.

9. The transparent soap formulation of claim 1 which comprises about 11.04% of added water.

10. A transparent soap formulation which comprises:

(a) about 0.1 to about 15.0% polyethylene glycol;

(b) about 0.1 to about 20.0% propylene glycol;

(c) about 0.1 to about 20.0% glycerine;

(d) a transparency enhancing amount of about 6.0 to about 9.0 sodium hydroxide;

(e) a transparency enhancing amount of about 0.1 to about 1.5% citric acid;

(f) about 3.0 to about 12.0 sucrose;

(g) about 0.1 to about 20.0% triethanolamine lauryl sulfate;

(h) about 0.1 to about 3.0% alkoxylated cetyl alcohol;

(i) about 0.1 to about 0.5% tetrasodium EDTA;

(j) 0.0 to about 0.1% distyrl biphenyl derivative;

(k) a transparency enhancing amount of about 17.0 to about 21.0% tallow/vegetable oil fatty acids;

(l) 0.1 to about 8.0% sodium alkyl polyether sulfonate;

(m) 1.0 to about 10.0% sodium cocyl isethionate;

(n) 0.1 to about 2.0% sodium chloride;

(o) 0.0 to about 0.2% pentasodium pentatate;

(p) 0.0 to about 0.05% tetrasodium etidronate;

(q) 0.0 to about 3.0% fragrance; and

(r) a transparency enhancing amount of 5.0 to about 15.0% water.

11. The transparent soap formulation of claim 10 which comprises:

(a) 9.60% polyethylene glycol;

(b) 10.90% propylene glycol;

(c) 12.76% glycerine;

(d) 7.6% sodium hydroxide;

(e) 0.77% citric acid;

(f) 7.84% sucrose;

(g) 10.45% triethanolamine lauryl sulfate;

(h) 0.67% alkoxylated cetyl alcohol;

(i) 0.14% tetrasodium EDTA;

(j) 0.01% distyrl biphenyl derivative;

(k) 19.0% tallow/vegetable oil fatty acids;

(l) 3.61% sodium alkyl polyether sulfonate;

(m) 3.8% sodium cocyl isethionate;

(n) 0.71% sodium chloride;

(o) 0.05% pentasodium pentatate;

(p) 0.05% tetrasodium etidronate;

(q) 1.0% fragrance; and

(r) 11.04% water.

12. The transparent soap formulation of claim 11, wherein said fatty acid component comprises from about 70 to about 85% soap derived from tallow and from about 15 to about 30% soap derived from coconut oil.

13. A method for making transparent soap which comprises the following steps:

(a) heating a composite of selected polyols to a first temperature range;

(b) heating a transparency enhancing amount of a blend of selected tallow and vegetable fatty acids to about the temperature range of said polyol composite;

(c) mixing said blend with said polyol composite at a second temperature range;

(d) adding a transparency enhancing amount of a 50% aqueous solution of sodium hydroxide to said mixture of step (c) at a temperature not to exceed about 195.degree. F.;

(e) adding heated, aqueous sodium chloride solution to the mixture of step (d) and mixing at a third temperature range until all ingredients are solubilized;

(f) cooling the mixture from step (e); and

(g) adjusting the pH with a transparency enhancing amount of citric acid.

14. The method of claim 13 for making transparent soap, wherein said first temperature range is from about 150.degree. to about 155.degree. F.

15. The method of claim 13 for making transparent soap, wherein said second temperature range is from about 160.degree. to about 165.degree. F.

16. The method of claim 13 for making transparent soap, wherein said third temperature range is from about 170.degree. to about 185.degree. F.

17. The method of claim 13 for making transparent soap, wherein said polyol composite is selected from the group consisting of polyethylene glycol, propylene glycol, glycerin and combinations thereof.

18. The method of claim 13 for making transparent soap, wherein said fatty acid blend comprises from about 70 to about 85% soap derived from tallow and from about 15 to about 30% soap derived from coconut oil.

19. The method of claim 13 for making transparent soap which comprises a neutralizing reaction for mixing said fatty acid blend and said polyol composite in a ratio which ranges from about 1:1 to about 1:3.

20. The method of claim 19 for making transparent soap, wherein said ratio of said fatty acid blend to said polyol composite ranges from about 1:1.9 to about 1:2.5.

21. The method of claim 20 for making transparent soap, wherein said ratio of said fatty acid blend to said polyol composite ranges from about 1:2.2.

22. The method of claim 13 for making transparent soap, wherein said pH ranges from about 9.1 to about 9.5.

23. The method of claim 22 for making transparent soap, wherein said pH is about 9.2.

24. The method of claim 22 for making transparent soap, wherein said pH adjustments provide a final product with about 2.0 to 4.0% of said fatty acid blend.

25. The method of claim 17 for making transparent soap which comprises the addition of triethanolamine lauryl sulfate, akloxylated cetyl alcohol, tetrasodium EDTA and distyrl biphenyl derivative.

26. The method of claim 13 for making transparent soap which comprises the addition of sodium alkyl polyether sulfonate.

27. The method of claim 13 for making transparent soap which comprises the addition of sucrose and sodium cocoyl isethionate.

28. The method of claim 13 for making transparent soap which comprises the addition of pentasodium pentetate and tetrasodium etidronate.