Claims
- 1. A transparent substrate comprising at least one monomolecule film formed as an outer most surface layer on at least one surface of the transparent substrate either directly or indirectly, wherein the monomolecule film contains a hydrophobic group and is bonded through a covalent bond to the surface of the substrate.
- 2. The transparent substrate according to claim 1, wherein the monomolecule film containing hydrophobic groups is bonded to the surface through a —Si— group.
- 3. The transparent substrate according to claim 1, wherein the monomolecule film containing hydrophobic group is bonded to the surface through siloxane bonds via a siloxane-based protective film prepared on the substrate.
- 4. The transparent substrate according to claim 1, wherein the hydrophobic group is a fluorine-containing hydrocarbon group.
- 5. A transparent substrate comprising a monomolecule film formed as an outer most surface layer on both surfaces of the transparent substrate either directly or indirectly, wherein one of the surfaces is covered with a covalently bonded monomolecule film containing a hydrophobic group, and the other surface is covered with a covalently bonded monomolecule film containing a hydrophilic group.
- 6. The transparent substrate according to claim 5, wherein the hydrophobic group is a fluorine-containing hydrocarbon group.
- 7. The transparent substrate according to claim 5, wherein the hydrophilic groups is a hydroxyl group.
- 8. A transparent substrate comprising at least one monomolecule film formed as an outer most surface layer on at least one surface of the transparent substrate either directly or via a protective film, wherein the monomolecule film is formed by a chemical covalent bonding from a silane halide-based or alkoxy silane-based surface active compound of the formula:
- 9. The transparent substrate according to claim 8, wherein the monomolecule film is bonded to the protective film covering the substrate through a chemical covalent bond.
- 10. The transparent substrate according to claim 8, wherein said silane halide-based surface active compound is a chlorosilane-based surface active compound of the formula:
- 11. A method of modifying a surface of a transparent substrate comprising:
applying, in a non-aqueous organic solvent, a silane-based surface active compound having a reactive silane group at one end and a hydrophobic group at the other end containing fluorine, to a surface of the transparent substrate or on a surface of a protective film provided on the transparent substrate under such conditions that the silane-based surface active compound is chemically adsorbed to the surface, thereby forming a monomolecule film having the hydrophobic group and —Si— group and being covalently bonded to the applied surface.
- 12. The method of according to claim 11, wherein the silane-based surface active compound is a chemical material containing an end chlorosilyl (—SiCl) group.
- 13. A method of modifying a surface of a transparent substrate comprising:
contacting a surface of a molded transparent substrate with an organic solvent solution of a silane-based surface active compound having a reactive silane group at one end and a hydrophobic group at the other end to form a chemically adsorbed monomolecule film from the silane-based surface active compound on at least one surface of the transparent substrate or over the entire surface area
- 14. The method according to claim 13, wherein the reactive silane group is a chlorosilane group.
- 15. The method according to claim 13, wherein the silane-based surface active compound is represented by the formula:
- 16. A transparent method of modifying a surface of a molded substrate having two surface, comprising:
(A) contacting both of the surface of the molded transparent substrate with a non-aqueous solvent containing a material having at least two chlorosilyl groups; (B) washing the transparent substrate using a non-aqueous organic solution to remove the non-reacted material having at least two chlorosilyl groups of the transparent substrate after the contacting step; (C) treating the transparent substrate with water after the non-reacted material washing step, thereby forming a hydrophilic monomolecule film composed of a silane material having at least one silanol group; and (D) treating the transparent substrate having thus formed silanol groups with silane-based surface active compound having a reactive silane group at one end and a hydrophobic group at the other end, thereby laminating a chemically adsorbed hydrophobic monomolecule film on the hydrophilic monomolecule film having silanol groups.
- 17. The method according to claim 16, which further comprises between the steps (C) and (D), coating one surface of the transparent substrate with a water-soluble coating film and, after the step (D), removing the water soluble coating film, thereby forming a hydrophobic monomolecule film on one surface and a hydrophilic monomolecule film on the other surface.
- 18. The method according to claim 16, wherein the reactive silane group is a chlorosilane group.
- 19. The method according to claim 16, wherein the silane-based surface active compound is represented by the formula:
- 20. The method according to claim 16, wherein the material having at least two chlorosilyl groups is selected from the group consisting of:
- 21. A transparent substrate comprising at least one monomolecule film formed as an outer most surface layer on at least one surface of an optical device, either directly or indirectly, wherein said monomolecule film contains a hydrophobic group and is bonded through a covalent bond to the surface of said optical device,
wherein said optical device is selected from the group consisting of motor vehicle glasses and windshields, building window glasses, mirrors, optical lenses, fresnel lenses, glass lenses, and transparent tempered glass.
- 22. The transparent substrate as recited in claim 21, wherein said optical device is a vehicle windshield.
- 23. The transparent substrate as recited in claim 21, wherein the outer surface of said substrate is sufficiently hydrophobic to render said substrate non-adherent to oil and water.
- 24. The transparent substrate as recited in claim 21, wherein said monomolecule film comprises a chlorosilane molecule having a fluoroalkyl group, wherein the number of fluorine atoms counted from the end of the molecule is between 9 and 31.
- 25. The transparent substrate as recited in claim 21, wherein said monomolecule film comprises a chlorosilane selected from the group consisting of CH3(CH2)9SiCl3, CH3(CH2)15SiCl3, CH3CH2 O(CH2)15SiCl3, and CH3(CH2)2Si(CH3)2(CH2)15SiCl3.
- 26. The transparent substrate as recited in claim 24, wherein said chlorosilane is selected from the group consisting of CF3(CF2)7(CH2)2SiCl3, CF3(CF2)7(CH2)2SiCl3, CF3CH2O(CH2)15SiCl3, CF3(CH2)2Si(CH3)2(CH2)15SiCl3, CF3(CF2)3(CH2)2Si(CH3)2(CH2)9SiCl3, CF3COO(CH2)15SiCl3, CF3(CF2)5(CH2)2SiCl3.
Priority Claims (2)
Number |
Date |
Country |
Kind |
2-405755 |
Dec 1990 |
JP |
|
3-38135 |
Feb 1991 |
JP |
|
RELATED APPLICATIONS
[0001] This application is a continuation of U.S. patent applications Ser. No. 08/279,686, filed Jul. 25, 1994, and of Ser. No. 08/383,428, filed Feb. 3, 1995, each of which claim parentage to original parent application 07/798,525, filed Nov. 26, 1991, which in turn claims the priority of Japanese Patent Applications 2-407555 and 3-038135 filed on Dec. 25, 1990 and Feb. 6, 1991, respectively.
Divisions (2)
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Number |
Date |
Country |
Parent |
09804854 |
Mar 2001 |
US |
Child |
10085248 |
Feb 2002 |
US |
Parent |
09570264 |
May 2000 |
US |
Child |
09804854 |
Mar 2001 |
US |
Continuations (2)
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Number |
Date |
Country |
Parent |
08279686 |
Jul 1994 |
US |
Child |
09570264 |
May 2000 |
US |
Parent |
08383428 |
Feb 1995 |
US |
Child |
09570264 |
May 2000 |
US |