The invention relates to the use of carboxylic acid diesters in the treatment of textiles and to a formulation intended for such a use.
In the various industrial painting workshops, such as, for example, in the automobile industry, the metal and plastic components are covered with various types of paint. Three layers are generally encountered:
The working overalls used by the employees who work in these painting workshops are very rapidly stained by these various coats and have to be changed at each change in shift. This results in major problems in cleaning.
Conventional detergents are inadequate in being able to act effectively against industrial paints and it is necessary to use solvents. As these are generally aggressive, either with regard to the user (corrosive, volatile) or with regard to the environment, or have properties which render them difficult to handle (excessively low flashpoint, high volatility), the demand for “green” solvents is high for this type of application.
Dicarboxylic acid diesters (also known as dibasic esters), the acid of which is linear, in particular the mixture of dimethyl succinate, glutarate and adipate, are known as “green” solvents.
U.S. Pat. No. 4,780,235 describes, for example, the combination of at least one di(C1-C4 alkyl) ester of a dibasic aliphatic acid with 1 to 80% of N-methylpyrrolidone (NMP), a thickener and an “activating” molecule, such as acetic acid, for removing paint from surfaces of inflexible objects (stripping).
U.S. Pat. No. 5,613,984 describes a method for cleaning clothes stained by various types of paints comprising the stages consisting in exposing the stained item of clothing to a dibasic ester, in washing the item of clothing using a detergent comprising a surfactant and a solvent, and in then drying it. The dibasic ester is, in particular, a dibasic ester having an acid which is linear, such as the dimethyl succinate, glutarate and adipate mixture.
U.S. Pat. No. 4,673,524 describes a cleaning composition for removing, from the surface of the hands, materials which are difficult to remove, for example paints or printing inks. This composition comprises a dimethyl succinate, glutarate and adipate mixture in combination with an aliphatic hydrocarbon solvent and with a surfactant of ethoxylated nonylphenol type or in association with octophenoxy-polyethoxyethanol.
The document WO 96/30453 describes cleaning or stripping compositions for removing materials which are difficult to remove, for example paints from surfaces of inflexible objects. These compositions comprise a dimethyl succinate, glutarate and adipate mixture in combination with an ether, such as anisole, with optionally an aliphatic hydrocarbon solvent and with optionally a surfactant of ethoxylated nonylphenol type.
The document EP 743 358 describes compositions for cleaning textiles comprising a dimethyl succinate, glutarate and adipate mixture and a surfactant of ethoxylated fatty alcohol type.
However, novel green solvents are always being sought for as replacement solutions equivalent to, indeed even better than, the existing solvents. There exists more particularly a need for solvents which are more effective in cleaning staining by paint on textile fibers, in order to make it easier to clean working clothes in particular.
The present invention meets this need by providing for the use of a dicarboxylic acid diester for the treatment of textiles, characterized in that the dicarboxylic acid diester corresponds to the formula (I):
R1—OOC-A-COO—R2 (1)
wherein
The use of this type of branched dicarboxylic acid diester makes it possible to clean textiles stained by paint with an effectiveness equal to or greater than that obtained with their unbranched homologs.
Furthermore, the dibasic esters mentioned in the context of this invention are among those families of solvents which release low amounts of volatile organic compounds and which do not exhibit a major risk at the HSE (Health, Safety and Environment) level.
According to the present invention, use is made of a specific diester of a dicarboxylic acid of formula (I), the A group of which is branched. In the present patent application, this diester of a dicarboxylic acid can be denoted by “specific diester”, “diester used in the invention” or “branched diester”.
It is possible to use one or more branched diesters. In the patent application, unless the presence of at least two branched diesters is explicitly mentioned, “a” branched diester can denote a single branched diester corresponding to the formula (I) or a mixture or a combination of several branched diesters corresponding to the formula (I).
The A group is a branched divalent alkylene group. The corresponding acid is the compound of formula HOOC-A-COOH. By misuse of language, the A group can be denoted by the acid to which it corresponds.
In the diester used in the invention, the A group can in particular be a C3, C4, C5, C6, C7, C8 or C9 group or a mixture. It is preferably a C4 group. An A group is preferably chosen from the following groups:
The R1 and R2 groups, which are identical or different, can be chosen in particular from the methyl, ethyl, n-propyl, isopropyl, benzyl, phenyl, n-butyl, isobutyl, cyclohexyl, hexyl, n-hexyl, isooctyl or 2-ethylhexyl groups. They correspond to the identical or different alcohols of formulae R1—OH and R2—OH.
Use may advantageously be made of the dimethyl ester of 2-methylglutaric acid, corresponding to the following formula:
CH3—OOC—CH(CH3)—CH2—CH2—COO—CH3.
According to a specific embodiment, the dicarboxylic acid diester is provided in the form of a mixture of different dicarboxylic acid diesters of formula (I).
According to a preferred embodiment, this mixture of branched diesters can comprise the dicarboxylic acid diesters of the following formulae (I′), (I″) and optionally (II):
—R1—OOC-AMG-COO—R2 (I′),
R1—OOC-AES-COO—R2 (I″),
optionally R2—OOC—(CH2)4—COO—R2 (II) (adipic acid diester),
wherein:
In these formulae (I′), (I″) and (II), the R1 and R2 groups can in particular be methyl, ethyl or isobutyl groups.
According to a particularly preferred embodiment of the present invention, use is made of a mixture of branched diesters comprising:
The diester used in the invention can be obtained by any known process leading to diesters, in particular by reaction of an alcohol corresponding to the R1 and R2 groups with a dicarboxylic acid corresponding to the A group or a di(acyl chloride) of formula ClOC-A-COCl or a corresponding dinitrile of formula NC-A-CN. In the case where use is made of several dicarboxylic acid diesters, for example the diesters of formulae (I′), (I″) and optionally (II), it is possible to carry out the same type of reaction starting from a corresponding mixture of dicarboxylic acids or acyl chlorides or dinitriles.
The mixed branched diester or diesters can in particular be obtained from a mixture of dinitrile compounds in particular produced and recovered in the process for the manufacture of adiponitrile by double hydrocyanation of butadiene. This process, used on a large scale industrially to produce the great majority of the adiponitrile consumed worldwide, is described in numerous patents and works. The reaction for the hydrocyanation of butadiene results predominantly in the formation of linear dinitriles but also in the formation of branched dinitriles, the two main ones of which are methylglutaronitrile and ethylsuccinonitrile. In the stages for separation and purification of the adiponitrile, the branched dinitrile compounds are separated by distillation and recovered, for example, as top fraction in a distillation column.
Typically, the mixture of branched dinitrile compounds is converted to diesters in order thus to obtain a novel solvent.
One of the possible processes for the conversion of the dinitrile compounds to diesters corresponds to the use of the Pinner reaction, described in particular in French patent No. 1 488 857. Basically, this process consists in reacting the dinitrile compounds with an alcohol in the presence of a strong inorganic acid, such as sulfuric acid, and in then hydrolyzing the products obtained in order to recover the diesters by distillation. This document also describes a specific embodiment of the process which consists in passing the mixture of dinitrile compounds and the alcohol into a bath of molten salts based on different alkali metal sulfates and ammonium sulfate in order to prevent the formation of ammonium sulfate and to recover the ammonia by extraction with steam.
The diesters used in the invention can also be obtained by a reaction between the dinitrile compounds, water and an alcohol in the gas phase and in the presence of a solid catalyst. The reaction temperature is advantageously greater than the condensation temperature of the diesters formed. Use may be made, as catalyst, of a solid acid catalyst, such as, for example, a silica gel, a silica/alumina mixture or boric or phosphoric acids which are supported. Use may also be made of macroporous aluminas, such as those described in European patent EP 0 805 801. The reaction temperature is between 200 and 450° C., preferably between 230 and 350° C. The reaction can be carried out under any pressure, advantageously a pressure of between 0.1 and 20 bar. At the reactor outlet, the vapors are rapidly cooled to a temperature of less than or equal to 150° C. The ammonia and then the water and the excess alcohol are separated by distillation from the mixture obtained.
The diesters of the invention can also be obtained by reaction between the dinitrile compounds and an inorganic base, in order to obtain salts of acids, and then neutralization of these salts by an acid, followed by an esterification with an alcohol.
Finally, the diesters can be purified according to the purification processes conventionally used in the technical field of the preparation of organic compounds and in particular by distillation in one or more columns.
The mixture can comprise other compounds than the diester of the invention. It can in particular comprise byproducts of an esterification reaction and/or products resulting from byproducts of a prior reaction.
The branched diester can be used pure, without any other additive.
According to another embodiment, the branched diester can be combined, in a liquid formulation, with at least one surfactant, preferably a nonionic surfactant.
According to an alternative form of the invention, the surfactant is other than a polyalkoxylated terpene nonionic surfactant.
The surfactant can be a standard surfactant, for example given in the work McCutcheon's Emulsifiers & Detergents, North American & International Edition, 2004 Annuals.
According to another alternative form of the invention, the surfactant is a polyalkoxylated terpene nonionic surfactant.
Advantageously, said polyalkoxylated terpene nonionic surfactant is a polyethoxylated and/or polypropoxylated, preferably polyethoxylated and polypropoxylated, terpene, the ethoxy and propoxy units being distributed randomly or sequentially.
Particularly advantageously, said polyalkoxylated terpene nonionic surfactant corresponds to the following formula (III):
Z—X—[CH(R5)—CH(R6)—O]n—[CH2CH2—O]p—[CH(R5)—CH(R6)—O]q—R7 (III)
in which formula:
Z represents a bicyclo[a.b.c]heptenyl or bicyclo[a.b.c.]heptyl radical, with
a+b+c=5
a=2, 3 or 4,
b=2 or 1
c=0 or 1,
said radical optionally being substituted by at least one C1-C6 alkyl radical and comprising a Z backbone chosen from those indicated below or with the corresponding backbones devoid of a double bond:
X represents —CH2—C(R3)(R4)—O— or —O—CH(R′3)—CH(R′4)—O—,
in which:
R3, R4, R′3 and R′4, which are identical or different, represent hydrogen or a saturated or unsaturated and linear, branched or cyclic C1-C22, preferably C1-C6, hydrocarbon radical;
R5 and R6, which are identical or different, represent hydrogen or a saturated or unsaturated and linear, branched or cyclic C1-C22 hydrocarbon radical, with the condition that at least one of the R5 and R6 radicals is other than hydrogen;
R7 represents hydrogen or a saturated or unsaturated, linear, branched or cyclic, aromatic or nonaromatic, C1-C22 hydrocarbon radical which is optionally substituted, for example by an OH group;
n, p and q are integers or nonintegers greater than or equal to 0,
n+p+q>1, preferably from 2 to 200, preferably from 5 to 50.
Preferably, n, p and q are chosen so that:
The use of surfactants of this specific type, which act synergistically with the branched diester, makes it possible to further increase the effectiveness of the branched diester in treating the textile.
Such a polyalkoxylated terpene nonionic surfactant is, for example, sold by Rhodia under the name Rhodoclean® MSC.
Compounds of a first type are defined by the formula (III) in which X is equal to
—CH2—C(R3)(R4)—O—.
Thus, this compound, hereinafter compound (IIIa), corresponds to the following formula:
Z—CH2—C(R3)(R4)—O—[CH(R5)—CH(R6)—O]n—[CH2CH2—O]p—[CH(R5)—CH(R6)—O]q—R7
in which formula Z, R3, R4, R5, R6, R7, n, p and q have the general meanings indicated above.
Preferably, the Z radical is chosen from the radicals of formulae c) to g).
It should be noted that the Z radical is more particularly attached to the remainder of the chain via any one of the carbon atoms 1 to 6, the carbon atoms 1, 5 and 6 being preferred.
Furthermore, the Z radical can be substituted on at least one of its carbon atoms by two C1-C6 alkyl radicals, preferably two methyl radicals.
More particularly, the carbon 7 is substituted by these two alkyl radicals, more specifically two methyl radicals.
One of the preferred compounds used in the present invention is thus composed of a compound, the Z radical of which corresponds to one of those appearing in the figure c) to g) and more preferably a d) and e) radical; the Z radical being substituted by two methyl radicals located on the carbon 7.
Particularly preferably, the Z radical corresponds to the formula d) or e), attached to the remainder of the chain via the carbon 5 or 1 and carrying two methyl substituents on the carbon 7.
Preferably, R3 and R4, which are identical or different, represent a hydrogen or a methyl radical. Preferably, R3 and R4 represent a hydrogen atom.
As was indicated above, the R5 and R6 radicals, which are identical or different, represent hydrogen or a saturated or unsaturated and linear, branched or cyclic C1-C22 hydrocarbon radical, with the condition that at least one of the R5 or R6 radicals is other than hydrogen.
More particularly, said radicals represent hydrogen or a C1-C6 alkyl radical, preferably the methyl radical or the ethyl radical, with the condition that at least one of these two radicals is other than hydrogen. Preferably, one of the radicals represents hydrogen and the other represents a methyl radical.
R7 represents hydrogen or a saturated or unsaturated, linear, branched or cyclic, aromatic or nonaromatic,
C1-C22 hydrocarbon radical which is optionally substituted, for example by an OH group.
In the case where R7 is a hydrocarbon radical, the latter is more particularly a C1-C6 alkyl radical or an alkylphenyl radical which is optionally substituted by a halogen (such as chlorine, for example).
Preferably, R7 is a hydrogen atom.
According to a first specific embodiment of the present invention, the value of n is 3.
In addition, the value of p is more particularly between 6.2 and 7, limits included. Preferably, p is between 6.3 and 7, limits included.
According to a second specific embodiment of the invention, n is between 4 and 5, limits included.
Furthermore, the value of p is preferably between 7 inclusive and 10 exclusive, preferably between 8 inclusive and 10 exclusive.
Preferably, q is equal to 0. If q is other than 0, then q is preferably between 5 and 25, limits included.
Compounds of a second type are defined by the formula (III) in which X represents:
—O—CH(R′3)—CH(R′4)—O—.
Thus, this compound, hereinafter compound (IIIb), corresponds to the following formula:
Z—O—CH(R′3)—C(R″4)—O—[CH(R5)—CH(R6)—O]n—[CH2CH2—O]p—[CH(R5)—CH(R6)—O]q—R7
in which formula Z, R′3, R′4, R5, R6, R7, n, p and q have the general meanings indicated above.
According to a preferred embodiment of the invention, the Z radical corresponds to the radical c), the bicyclic compound not comprising a double bond.
Here again, it should be noted that the Z radical is more particularly attached to the remainder of the chain via any one of the carbons 1 to 6. The carbon atoms 1, 3, 4 or 6 are more particularly selected.
Furthermore, the Z radical can be substituted on at least one of its carbon atoms by two C1-C6 alkyl radicals, preferably two methyl radicals.
More particularly, the carbon 7 is substituted by these two alkyl radicals, more specifically two methyl radicals.
Furthermore, the Z radical carries, on one of the carbon atoms 2 or 5, a C1-C6 alkyl substituent, preferably a methyl radical.
More particularly and as mentioned above, the R′3 and R′4 radicals, which are identical or different, represent hydrogen or a saturated or unsaturated and linear, branched or cyclic C1-C22 hydrocarbon radical, with the condition that one of the two is other than hydrogen.
According to a specific embodiment of the invention, said radicals represent hydrogen or a C1-C6 alkyl radical, preferably the methyl radical.
That which was indicated with regard to the R5, R6 and R7 radicals and with regard to the values of n, p and q and the preferred alternative forms related to these values remains valid and will not be repeated.
The compounds of formula (III) can be prepared by reacting:
in order to obtain compound (IIIa), a reactant of formula (IVa):
or, in order to obtain compound (IIIb), a reactant of formula (IVb):
with, in a first step, a reactant of formula (Vop):
and then, in a second step, with a reactant of formula (Voe):
The Z, R3, R4, R5 and R6 radicals have been defined above.
The reaction can in addition be carried out in the presence of a catalyst.
Mention may be made, among suitable catalysts, of strong bases, such as hydroxides of alkali metals, alkaline earth metals or quaternary ammoniums of N(R)4+ type, in which the R groups, which are identical or different, represent hydrogen or a C1-C6 alkyl radical, preferably methyl or ethyl. Sodium hydroxide, potassium hydroxide and tetramethylammonium hydroxide are suitable for the implementation of this reaction.
Use may likewise be made of catalysts chosen from alkali metal or alkaline earth metal alkoxides, such as, for example, sodium methoxide, sodium ethoxide, sodium tert-butoxide, potassium methoxide, potassium ethoxide or potassium tert-butoxide. It should be noted that it is also possible to employ, as catalyst, primary, secondary or tertiary amines, preferably aliphatic amines, it being possible for these amines to comprise other functional groups, such as, in particular, ether functional groups. Mention may be made, as example of catalysts of this type, of N,N-dimethyllaurylamine.
In the case of a basic catalyst, the amount is more particularly between 0.5 and 40 mg with respect to the weight of the final product.
It is possible to envisage carrying out this reaction in the presence of a Lewis acid, such as BF3 (gaseous or in solution in an ether), SnCl4 or SbCl5.
The amount of acid catalyst varies more particularly between 0.1 and 10 mmol per mole of reactant (IVa) or (IVb).
The contacting operation is carried out at a temperature sufficient to make it possible to accomplish the reaction. By way of indication, the temperature is greater than 100° C., more particularly between 120 and 250° C. and preferably between 150 and 200° C.
Advantageously, the reaction is carried out under an atmosphere which is inert under the reaction conditions, such as nitrogen, or a rare gas, such as argon, or also carbon monoxide. Nitrogen is preferred.
The reaction can take place at atmospheric pressure, under reduced pressure or with a slight excess pressure. Usually, it is preferable to operate under a pressure of between 1 and 4 bar.
The preparation of the reactants (IVa) and (IVb) has been described in patent application WO 96/01245, to which reference may be made.
The amounts of the compounds (Vop) and (Voe) are calculated according to the characteristics of the formula (III), more particularly according to the values desired for n and p.
These two compounds are introduced successively, so as to obtain a block compound of formula (III).
On conclusion of the reaction, the reaction mixture is preferably neutralized, in order to obtain a pH of between 5 and 8, preferably 6 and 7.
Neutralization is carried out using acetic acid or sodium hydroxide, sodium carbonate or sodium bicarbonate, according to the nature of the catalyst involved in the reaction.
On conclusion of this reaction, the compound (III) is such that the R7 radical is hydrogen.
It is entirely possible to carry out a stage of functionalization of said radical, that is to say a stage targeted at converting the terminal hydrogen into one of the other R7 radicals as defined above. Thus, it is possible to carry out an etherification or esterification operation on the terminal hydrogen atom; this stage is well known per se; it is preferably carried out after the neutralization.
Thus, the preparation of alkyl ethers (R7=hydrocarbon radical) can be carried out according to the procedure described in U.S. Pat. No. 2,913,416.
Further details relating to these methods of functionalization are described in the publication WO 96/01245.
Use is made of between 0.1 and 5% by weight, preferably between 0.5 and 4% by weight and more preferably still between 0.5 and 3% by weight of surfactants, with respect to the total amount of the formulation, preferably with respect to the total amount of compounds of the dicarboxylic acid diester type present in said liquid formulation.
The present invention relates to the use of branched diesters in the treatment of textiles, for example textiles made of polyester fibers. More particularly, said treatment of textiles can comprise cleaning in order to remove a stain on said textile. The use of branched diesters according to the invention is particularly advantageous when said stain is a stain of aqueous- or solvent-based single-component or two-component paint, of resin, of vegetable- or mineral-based lubricant, of products derived from bitumens and petroleum, of mud, of greasy substances, of food residues, and the like, in particular on a fabric made of polyester fibers. The stain can be fresh or older. The branched diester is effective whatever the type of paint to be cleaned off, such as epoxide, polyurethane, acrylic or alkyd paints, and the like.
The invention also relates to a liquid formulation intended to be used in particular in the treatment of textiles and comprising at least one dicarboxylic acid diester corresponding to the formula (I) as defined above and one surfactant, preferably a nonionic surfactant.
According to an alternative form of the invention, the formulation comprises a surfactant which is other than a polyalkoxylated terpene nonionic surfactant.
The surfactant can be a standard surfactant, for example an anionic, nonionic (nonterpenic), amphoteric, zwitterionic and/or cationic surfactant, for example given in the work McCutcheon's Emulsifiers & Detergents, North American & International Edition, 2004 Annuals.
The amount of surfactant, preferably of nonionic surfactant, preferably of polyalkoxylated terpene type, preferably the surfactant corresponding to the formula (III), is advantageously between 0.1 and 10% by weight, preferably between 0.1 and 5% by weight, preferentially between 0.5 and 4% by weight and more preferentially still between 0.5 and 3% by weight, preferably between 0.5 and 2% by weight or even between 0.5 and 1% by weight, for example by weight as is or by weight of active material, with respect to the total amount of the formulation, preferably with respect to the total amount of compounds of the dicarboxylic acid diester type present in said liquid formulation. The formulation of the invention proves to be surprisingly effective, even at low contents of surfactant.
According to a specific embodiment, the formulation is substantially devoid of other nonionic surfactants, preferably of other surfactants in general.
According to another alternative form of the invention, the formulation comprises, as surfactant, a polyalkoxylated terpene nonionic surfactant.
Advantageously, said polyalkoxylated terpene nonionic surfactant is a polyethoxylated and/or polypropoxylated, preferably polyethoxylated and polypropoxylated, terpene, the ethoxy and propoxy units being distributed randomly or sequentially.
Particularly advantageously, the nonionic surfactant is a polyalkoxylated terpene corresponding to the formula (III) as defined above.
In another alternative form, the liquid formulation can comprise both a polyalkoxylated terpene nonionic surfactant and another surfactant which is not a polyalkoxylated terpene nonionic surfactant, such as the standard surfactants mentioned above.
In addition to the solvent and the surfactants described above, the liquid formulation used can also comprise:
a. an antioxidant,
b. a corrosion inhibitor,
c. a thickening agent,
d. a colorant,
e. a fragrance,
f. a stabilizer, or
g. any combination of the abovementioned components.
According to a specific embodiment, the dicarboxylic acid diester corresponding to the formula (I) is not diluted in water and/or another organic solvent.
According to a specific embodiment, the formulation according to the invention does not comprise abrasive agents.
The branched diester, alone, as a mixture or in combination with additives in the form of a liquid formulation, can be applied to the textile to be treated by any appropriate means. Preferably, the textile is immersed in the branched diester or the formulation for the necessary time, for example one hour, at ambient temperature, or in a formulation heated to a temperature of between 30° C. and 80° C., for example 60° C. Subsequently, the textile is rinsed one or more times in municipal water and then dried in ambient air or in an oven. Alternatively, the textile can be subjected, following the stage of washing in the formulation of the present invention, to a second “conventional” washing, i.e. using a standard detergent, before final rinsing with water.
Other details or advantages of the present invention may become apparent in the light of the examples which follow, without being of a limiting nature.
Synthesis
Preparation of a Branched Diester Used in the Invention
43.26 g of a mixture M of dinitrile compounds are charged with 76.90 g of methanol in a glass reactor with a capacity of 500 ml which is equipped with a vertical reflux condenser and a stirrer and which is heated by an oil bath.
The mixture M of dinitrile compounds is composed of:
The remainder to 100% corresponds to the impurities present in this mixture, which are not generally dinitrile compounds.
The dinitrile compounds/methanol mixture is cooled to approximately 1° C. before the addition of 84.22 g of 98% by weight sulfuric acid.
The reaction medium is heated to reflux and maintained at this temperature for 3 h. The reaction mass is heterogeneous and fluid. After cooling to 60° C., 63 g of water are added. The reaction medium is maintained at 65° C. for 2 hours.
An additional 117 g of water are then added. The reaction medium becomes a two-phase medium. After removing the excess methanol by evaporation, the two phases are separated by settling and analyzed. The organic phase recovered is washed with a saturated aqueous sodium chloride solution with addition of aqueous ammonia solution in order to obtain a pH in the vicinity of 7.
A second washing is carried out with a saturated aqueous sodium chloride solution.
After distillation of the washed organic phase, a mixture with the following composition is obtained:
Use is made of polyester working overalls stained by paint for approximately one month. The stains correspond to the various types of paint coats supplied, namely an adhesion primer, a base coat (paint and metal pigments) and a clear coat (transparent pigment-free resin, acting as protective coat).
The performances of the formulations are evaluated using a tergotometer: it involves a miniature reproduction of the washing machines of the USA, composed of six stainless steel pots to which are fitted oscillating agitators with variable agitation. The pots are placed in a thermostatically controlled water tank.
The washing conditions are as follows:
The effectiveness of this treatment is evaluated by determining the percentage of surface area of paint removed. A grade is assigned according to the following table I:
The branched diester obtained according to the synthesis described above is used in carrying out the use according to the present invention.
Use is made, by way of comparison, of:
The various formulations are summarized in table II below:
The results obtained are shown in table III below:
The results of table III show that the use of a branched diester according to the invention in the cleaning of paints on fabrics makes it possible to obtain performances equal to or better than those obtained with a conventional detergent or an unbranched diester.
Furthermore, it has been observed, for the base coat type of stain, that the fabrics cleaned with the branched diester have a lighter appearance than those washed with the linear diester Rhodiasolv® RPDE. It thus appears that the branched diester described in the invention has a better solvating power with regard to the paints of the stain of base coat type than the unbranched diester Rhodiasolv® RPDE.
The branched diester obtained according to the synthesis described above in combination with 3% by weight of an ethoxylated/propoxylated terpene surfactant Rhodoclean® MSC, sold by Rhodia, is used in carrying out the use according to the present invention.
Use is made, by way of comparison, of:
The various formulations are summarized in table IV below:
The results obtained are shown in table V below:
The results of table V show, first, that the use of a branched diester in combination with a surfactant in the cleaning of paints on fabrics makes it possible to obtain better performances than those obtained with a conventional detergent or an unbranched diester, itself also combined with a surfactant.
Secondly, the results of table V show that the combination of a branched diester with an ethoxylated/propoxylated terpenic derivative surfactant corresponding to the formula (III) makes it possible to greatly enhance the cleaning performance in comparison with a branched diester used alone.
Number | Date | Country | Kind |
---|---|---|---|
0756630 | Jul 2007 | FR | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
---|---|---|---|---|
PCT/EP2008/059328 | 7/16/2008 | WO | 00 | 5/26/2010 |