Trim breaker for a structural cabinet that incorporates a structural glass contact surface

Information

  • Patent Grant
  • 10907891
  • Patent Number
    10,907,891
  • Date Filed
    Monday, February 18, 2019
    5 years ago
  • Date Issued
    Tuesday, February 2, 2021
    3 years ago
Abstract
A refrigerating appliance includes an inner liner, an outer wrapper and a trim breaker extending between the inner liner and the outer wrapper to define an insulating cavity therebetween. The trim breaker includes a liner portion coupled with the inner liner, a wrapper portion coupled to the outer wrapper and an outer glazing member that extends between the liner and wrapper portions. An external surface of the outer glazing member defines a contact surface that is configured to receive a seal of an operable panel in a closed position.
Description
FIELD OF THE DEVICE

The device is in the field of structural cabinets for appliances, and more specifically, a trim breaker for a structural cabinet that includes a glass and steel trim breaker that connects the inner liner and the outer wrapper.


BRIEF SUMMARY OF THE DEVICE

According to one aspect of the present disclosure, a refrigerating appliance includes an inner liner, an outer wrapper and a trim breaker extending between the inner liner and the outer wrapper to define an insulating cavity therebetween. The trim breaker includes a liner portion coupled with the inner liner, a wrapper portion coupled to the outer wrapper and an outer glazing member that extends between the liner and wrapper portions. An external surface of the outer glazing member defines a contact surface that is configured to receive a seal of an operable panel in a closed position.


According to another aspect of the present disclosure, a structural cabinet for an appliance includes an outer glazing member, an inner glazing member offset from the outer glazing member and an inner liner and an outer wrapper that cooperatively define a glazing receptacle. The outer glazing member engages an outer portion of the glazing receptacle and the inner glazing member engages an inner portion of the glazing receptacle.


According to yet another aspect of the present disclosure, a trim breaker for an appliance cabinet includes a metallic liner portion that is configured to attach to an inner liner, a metallic wrapper portion that is configured to attach to an outer wrapper and inner and outer glazing members that extend between the liner and wrapper portions. The outer glazing member is configured to define a contact surface that receives an operable panel in a closed position and the inner glazing member is configured to partially define an insulating cavity.


These and other features, advantages, and objects of the present disclosure will be further understood and appreciated by those skilled in the art by reference to the following specification, claims, and appended drawings.





BRIEF DESCRIPTION OF THE DRAWINGS

In the drawings:



FIG. 1 is a front perspective view of an appliance that incorporates a structural cabinet having the glass and steel trim breaker;



FIG. 2 is a rear perspective view of an aspect of the glass and steel trim breaker;



FIG. 3 is an exploded perspective view of the glass and steel trim breaker of FIG. 2;



FIG. 4 is a schematic cross-sectional view of the structural cabinet of FIG. 1, taken along line IV-IV and showing engagement of the glass and steel trim breaker with the metallic inner liner and the metallic outer wrapper;



FIG. 5 is a schematic cross-sectional view of an appliance cabinet showing the interface between the glass and steel trim breaker and an operable panel in a closed position;



FIG. 6 is an alternative cross-sectional view of the structural cabinet of FIG. 1;



FIG. 7 is a perspective view of the glass and steel trim breaker used in connection with a structural cabinet having an interior mullion; and



FIG. 8 is an exploded perspective view of the glass and steel trim breaker of FIG. 7.





The components in the figures are not necessarily to scale, emphasis instead being placed upon illustrating the principles described herein.


DETAILED DESCRIPTION

The present illustrated embodiments reside primarily in combinations of method steps and apparatus components related to a trim breaker for an appliance cabinet. Accordingly, the apparatus components and method steps have been represented, where appropriate, by conventional symbols in the drawings, showing only those specific details that are pertinent to understanding the embodiments of the present disclosure so as not to obscure the disclosure with details that will be readily apparent to those of ordinary skill in the art having the benefit of the description herein. Further, like numerals in the description and drawings represent like elements.


For purposes of description herein, the terms “upper,” “lower,” “right,” “left,” “rear,” “front,” “vertical,” “horizontal,” and derivatives thereof shall relate to the disclosure as oriented in FIG. 1. Unless stated otherwise, the term “front” shall refer to the surface of the element closer to an intended viewer, and the term “rear” shall refer to the surface of the element further from the intended viewer. However, it is to be understood that the disclosure may assume various alternative orientations, except where expressly specified to the contrary. It is also to be understood that the specific devices and processes illustrated in the attached drawings, and described in the following specification are simply exemplary embodiments of the inventive concepts defined in the appended claims. Hence, specific dimensions and other physical characteristics relating to the embodiments disclosed herein are not to be considered as limiting, unless the claims expressly state otherwise.


The terms “including,” “comprises,” “comprising,” or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. An element proceeded by “comprises a . . . ” does not, without more constraints, preclude the existence of additional identical elements in the process, method, article, or apparatus that comprises the element.


Referring to FIGS. 1-6, reference numeral 10 generally refers to a trim breaker used in connection with a structural cabinet 12 for an appliance 14, where the trim breaker 10 includes at least one structural glass member 16 for partially supporting the structural cabinet 12 and defining an insulating cavity 18 therein. According to various aspects of the device, the structural cabinet 12 for an appliance 14, such as a refrigerating appliance 14, includes an inner liner 20 and an outer wrapper 22 to define an insulating cavity 18 therebetween. The trim breaker 10 includes a liner portion 24 that is coupled with an inner liner 20 and a wrapper portion 26 that is coupled with the outer wrapper 22. The structural glass member 16 can include an outer glazing member 28 that extends between the liner and wrapper portions 24, 26. An external surface 30 of the outer glazing member 28 defines the contact surface 32 that is configured to receive a seal of an operable panel 36, when the operable panel 36 is in a closed position 38. It is contemplated that the structural glass member 16 of the trim breaker 10 can also include an inner glazing member 40 that is coupled to the liner and wrapper portions 24, 26. An interior surface 132 of the inner glazing member 40 is configured to partially define the insulating cavity 18 within the structural cabinet 12.


According to various aspects of the device, the inner liner 20 and the outer wrapper 22 are typically metallic members that form the outer walls 50 of the structural cabinet 12. The liner and wrapper portions 24, 26 of the trim breaker 10 are also metallic, typically steel, and can be welded to the inner liner 20 and outer wrapper 22 to form an airtight or substantially airtight seal at the location of the trim breaker 10. The outer and inner glazing members 28, 40 are then attached to the liner and wrapper portions 24, 26 and define an edge surface 52 of the structural cabinet 12. As discussed above, this edge surface 52 of the structural cabinet 12 is typically in the form of a contact surface 32 that receives one or more operable panels 36 in a closed position 38.


As exemplified in FIGS. 2-6, the outer glazing member 28 typically engages an outer surface 60 of the liner and wrapper portions 24, 26. In this manner, the outer glazing member 28 can define a contact surface 32 for the trim breaker 10 and for the structural cabinet 12. The inner glazing member 40 typically engages an inner surface 62 of the liner and wrapper portions 24, 26. Through this engagement, the outer glazing member 28 is offset from the inner glazing member 40 to define an interstitial space 64 therebetween. This interstitial space 64 can be used as an insulating space 66 of the trim breaker 10 for slowing or limiting the transfer of heat 112 from areas outside of the structural cabinet 12 to insulated compartments 68 within the structural cabinet 12. To provide additional insulation at the trim breaker 10, the interstitial space 64 defined between the outer glazing member 28 and the inner glazing member 40 can be defined by an at least partial vacuum 70. It is contemplated that this interstitial space 64 can include an insulating material 72. This insulating material 72 can include, but is not limited to, one or more insulating gasses, foam insulation, fumed silica, precipitated silica, other silica-based material, perlite, glass spheres, hollow glass spheres, combinations thereof and other similar insulating materials 72.


Referring again to FIGS. 1-6, the liner and wrapper portions 24, 26 of the trim breaker 10 can be welded to the inner liner 20 and outer wrapper 22. In this manner, the liner and wrapper portions 24, 26 as well as the inner liner 20 and outer wrapper 22 can be made of steel, alloys thereof, or other similar metallic material that can form a welded connection. The outer and inner glazing members 28, 40 can be bonded, welded or otherwise attached to the liner and wrapper portions 24, 26 of the trim breaker 10 via various connecting mechanisms and methods. The outer and inner glazing members 28, 40 can be attached to the liner and wrapper portions 24, 26 via various bonding adhesives that can include a polymer glazing such as butyl, frit soldering, epoxy, silicone, various sealants, and other similar bond adhesives. It is also contemplated that the outer and inner glazing members 28, 40 can be attached to the liner and wrapper portion 24, 26 via glass welding, typically used in combination with one or more sealant materials.


According to various aspects of the device, the outer and inner glazing members 28, 40 can be made of various materials. These materials can include, but are not limited to, glass, tempered glass, ceramic, combinations thereof, and other similar glazing materials that can be used in structural applications. In various aspects, the material of the outer glazing member 28 may be the same material as that of the inner glazing member 40. The outer and inner glazing members 28, 40 may also be made of different materials. Because the outer and inner glazing members 28, 40 are positioned at different locations and may engage different materials, the different materials may be selected to address the differing conditions experienced by the outer and inner glazing members 28, 40.


Through the use of the outer and inner glazing members 28, 40, the structural cabinet 12 can experience reduced permeation of gas through the area of the trim breaker 10, when compared to trim breakers 10 that are made of plastic or other similar polymer-type material. The use of the outer and inner glazing members 28, 40 also provide resistance to large thermal strain that may be experienced over a large temperature range. These temperatures may be experienced during use of the appliance 14, such as where a refrigerator is stored in a garage or other outdoor or semi-outdoor area. These extreme temperatures are also experienced during manufacture, transport, and storage of the appliance 14.


By way of example, where a particular appliance 14 is transported or stored in a metal container, the temperatures within these containers can regularly exceed 45° C. or more. In these extreme temperatures, conventional plastic or polymer trim members may experience greater degrees of gas permeation through the material of the conventional trim member that can result in a degradation of the vacuum contained within the insulating cavity 18. These extreme temperatures can also result in a structural weakening of the plastic and polymer material of conventional trim members.


Using the trim breaker 10 that contains the metallic liner and wrapper portions 24, 26 and the outer and inner glazing members 28, 40, greater resistance to gas permeation is achieved as well as greater resistance to thermal strain over large temperature ranges. Additionally, glass and steel can be relatively inexpensive materials to manufacture and also work with during manufacture of a particular structural cabinet 12. Accordingly, using the various aspects of the trim breaker 10 disclosed herein, the use of welding techniques and relatively convenient bonding geometry for forming the trim breaker 10, and also attaching a trim breaker 10 to the remainder of the structural cabinet 12 can achieve cost savings, faster production time and use of fewer resources.


Referring again to FIGS. 1-6, the structural cabinet 12 for the appliance 14 can include the outer glazing member 28 and the inner glazing member 40 that is offset from the outer glazing member 28. The inner liner 20 and the outer wrapper 22 cooperatively define a glazing receptacle 80. This glazing receptacle 80 can be in the form of the liner portion 24 and wrapper portion 26 that are welded to the inner liner 20 and outer wrapper 22, respectively. During manufacture, it is contemplated that the liner portion 24 and wrapper portion 26 can be welded to the inner liner 20 and outer wrapper 22, and then subsequently the outer and inner glazing members 28, 40 can be adhered to the liner and wrapper portions 24, 26 that form the glazing receptacle 80.


In alternative aspects of the device, it is contemplated that the trim breaker 10 can be formed where the outer and inner glazing members 28, 40 are adhered to the liner and wrapper portions 24, 26 in one assembly location. This trim breaker 10, in the form of an assembly, can then be attached to the inner liner 20 and outer wrapper 22 as a subsequent manufacturing step in forming the structural cabinet 12.


During the formation of the trim breaker 10, the outer glazing member 28 typically engages an outer portion of the glazing receptacle 80 and the inner glazing member 40 engages an inner portion of the glazing receptacle 80. Through this configuration, the outer and inner glazing members 28, 40 can be offset from one another to form the interstitial space 64 therebetween. As discussed above, this interstitial space 64 can be used as an additional insulating feature of the structural cabinet 12 that may be maintained at an at least partial vacuum 70. This interstitial space 64 can also be filled or partially filled with an insulating material 72 similar to those materials described above.


As exemplified in FIGS. 2-6, the outer glazing member 28 is typically configured to define a contact surface 32 that is used to receive a magnetic seal 34 of an operable panel 36 for the appliance 14, such as a door 90 or drawer 92. Through this configuration, the magnetic seal 34 for the operable panel 36 engages the smooth contact surface 32 of the outer glazing member 28 to define a substantially consistent seal at the contact surface 32. According to various aspects of the device, the interstitial space 64 defined between the outer and inner glazing members 28, 40 can include a magnetic material 100 that can be used to magnetically engage a magnet 104 defined within the magnetic seal 34 of the operable panel 36. This magnetic material 100 can be a type of magnet 104 or can be a ferromagnetic material 102 that is disposed within the interstitial space 64.


As exemplified in FIG. 5, the structural cabinet 12 can include a heat loop 110 that runs through a portion of the structural cabinet 12 near the trim breaker 10. This heat loop 110 is used to provide a heating function that emits heat 112 toward the contact surface 32 of the structural cabinet 12. Heat 112 provided to the contact surface 32 by the heat loop 110 is used to prevent condensation from forming on the contact surface 32. This condensation can result from a temperature difference that may exist between the surface of the structural cabinet 12 and the areas surrounding the exterior of the structural cabinet 12. If condensation forms on the contact surface 32, this condensation can accumulate and pool in an area on the floor in front of the appliance 14. Using the heat loop 110, the contact surface 32 can be at least partially heated to minimize any temperature difference and prevent the accumulation of condensation on the contact surface 32.


Referring now to FIGS. 1, 7 and 8, the trim breaker 10 that is formed by the outer and inner glazing members 28, 40 that are bonded or adhered to the liner and wrapper portions 24, 26 can include a mullion member 120 that extends through a central area of the trim breaker 10. In forming this trim breaker 10 having the mullion member 120, the trim breaker 10 can include a single wrapper portion 26 that extends around the perimeter of the trim breaker 10. The liner portion 24 of the trim breaker 10 can include multiple separate aperture members 122 that can be used to define apertures 124 for accessing separate insulated compartments 68 that will be defined within the appliance 14. The outer and inner glazing members 28, 40 can then be positioned between the wrapper portion 26 and the two or more aperture members 122 of the liner portion 24 to form the trim breaker 10 having at least one mullion member 120. Where the mullion member 120 is included, the wrapper portion 26 of the trim breaker 10 is welded to the outer wrapper 22. Each aperture member 122 of the liner portion 24 can be welded to a respective inner liner 20 that forms each insulated compartment 68 of the appliance 14.


Referring again to FIGS. 2 and 3, the trim breaker 10 that is formed by the liner and wrapper portions 24, 26 and the outer and inner glazing members 28, 40 can be used to define a trim breaker 10 for an insulated operable panel 36. In such an embodiment, the trim breaker 10 can be used to define the location of the operable panel 36 where the magnetic seal 34 is attached. Similar to the structural cabinet 12, the operable panel 36 can include an inner liner 20 and an outer wrapper 22 that are each welded to the wrapper and liner portions 26, 24, respectively, to define an insulating cavity 18 within the operable panel 36. The trim breaker 10 having the outer and inner glazing members 28, 40 can be used to define the trim breaker 10 that extends between the inner liner 20 and the outer wrapper 22.


As exemplified in FIGS. 4 and 6, the glazing receptacle 80 that is defined by the liner and wrapper portions 24, 26 of the trim breaker 10 can include various geometries that can be used to extend between the inner and outer glazing members 40, 28 and the inner liner 20 and outer wrapper 22. Various fillets, chamfers, and other similar rounded geometries can be used to extend between the outer and inner glazing members 28, 40 and the inner liner 20 and outer wrapper 22. Additionally, the liner and wrapper portions 24, 26 of the trim breaker 10 can include a recessed portion 130 that is configured to receive the outer glazing member 28 in a substantially flush configuration with the outer surface 60 of the liner and wrapper portions 24, 26. It is also contemplated that the outer glazing member 28 can be attached to the liner and wrapper portions 24, 26 and stand proud of the liner and wrapper portions 24, 26. In such a configuration, the outer glazing member 28 may include rounded or angled edges that can be incorporated to prevent nicks, chips, and scratches from occurring within outer edges of the outer glazing member 28.


As exemplified in FIGS. 4-6, the structural cabinet 12 can include an insulating material 72 that is disposed within the insulating cavity 18. This insulating material 72 can be any one of various materials that can include, but are not limited to, one or more insulating gasses, foam insulation, fumed silica, precipitated silica, other silica-based material, perlite, glass spheres, hollow glass spheres, combinations thereof and other similar insulating materials 72. It is contemplated that these insulating materials 72 contained within the insulating cavity 18 defined by the structural cabinet 12 can substantially fill the entire insulating cavity 18. In this manner, the insulating material 72 can directly engage the interior surface 132 of the inner glazing member 40.


According to various aspects of the device, the trim breaker 10 disclosed herein incorporates the at least one structural glass member 16 to be used within various appliances 14. Such appliances 14 can include, but are not limited to, refrigerators, freezers, coolers, ovens, dishwashers, laundry appliances, small appliances, combinations thereof, and other similar commercial and residential appliances and fixtures.


It will be understood by one having ordinary skill in the art that construction of the described disclosure and other components is not limited to any specific material. Other exemplary embodiments of the disclosure disclosed herein may be formed from a wide variety of materials, unless described otherwise herein.


For purposes of this disclosure, the term “coupled” (in all of its forms, couple, coupling, coupled, etc.) generally means the joining of two components (electrical or mechanical) directly or indirectly to one another. Such joining may be stationary in nature or movable in nature. Such joining may be achieved with the two components (electrical or mechanical) and any additional intermediate members being integrally formed as a single unitary body with one another or with the two components. Such joining may be permanent in nature or may be removable or releasable in nature unless otherwise stated.


It is also important to note that the construction and arrangement of the elements of the disclosure as shown in the exemplary embodiments is illustrative only. Although only a few embodiments of the present innovations have been described in detail in this disclosure, those skilled in the art who review this disclosure will readily appreciate that many modifications are possible (e.g., variations in sizes, dimensions, structures, shapes and proportions of the various elements, values of parameters, mounting arrangements, use of materials, colors, orientations, etc.) without materially departing from the novel teachings and advantages of the subject matter recited. For example, elements shown as integrally formed may be constructed of multiple parts or elements shown as multiple parts may be integrally formed, the operation of the interfaces may be reversed or otherwise varied, the length or width of the structures and/or members or connector or other elements of the system may be varied, the nature or number of adjustment positions provided between the elements may be varied. It should be noted that the elements and/or assemblies of the system may be constructed from any of a wide variety of materials that provide sufficient strength or durability, in any of a wide variety of colors, textures, and combinations. Accordingly, all such modifications are intended to be included within the scope of the present innovations. Other substitutions, modifications, changes, and omissions may be made in the design, operating conditions, and arrangement of the desired and other exemplary embodiments without departing from the spirit of the present innovations.


It will be understood that any described processes or steps within described processes may be combined with other disclosed processes or steps to form structures within the scope of the present disclosure. The exemplary structures and processes disclosed herein are for illustrative purposes and are not to be construed as limiting.

Claims
  • 1. A refrigerating appliance comprising: an inner liner;an outer wrapper; anda trim breaker extending between the inner liner and the outer wrapper to define an insulating cavity therebetween, the trim breaker comprising: a liner portion coupled with the inner liner;a wrapper portion coupled to the outer wrapper;an outer glazing member that extends between the liner and wrapper portions, wherein an external surface of the outer glazing member defines a contact surface that is configured to receive a seal of an operable panel in a closed position; andan inner glazing member that is coupled to the liner and wrapper portions, wherein an interior surface of the inner glazing member partially defines the insulating cavity, wherein the outer and inner glazing members define an interstitial space therebetween, and wherein the interstitial space defines an at least partial vacuum.
  • 2. The refrigerating appliance of claim 1, wherein the outer glazing member engages an outer surface of the liner and wrapper portions and the inner glazing member engages an inner surface of the liner and wrapper portions.
  • 3. The refrigerating appliance of claim 1, wherein the inner glazing member is tempered glass.
  • 4. The refrigerating appliance of claim 1, wherein the liner and wrapper portions are welded to the inner liner and the outer wrapper, respectively.
  • 5. The refrigerating appliance of claim 1, wherein the outer glazing member is glass.
  • 6. The refrigerating appliance of claim 1, wherein a heat loop is positioned proximate the outer glazing member to selectively heat the contact surface.
US Referenced Citations (290)
Number Name Date Kind
1849369 Frost Mar 1932 A
1921576 Muffly Aug 1933 A
2191659 Hintze Feb 1940 A
2464526 Palmer Oct 1945 A
2432042 Richard Dec 1947 A
2451884 Stelzer Oct 1948 A
2644605 Palmer Jul 1953 A
2729863 Kurtz Jan 1956 A
2792959 Diamond et al. May 1957 A
2809764 Diamond Oct 1957 A
2951609 Donnelly Sep 1960 A
2989156 Brooks et al. Jun 1961 A
3165221 Kasady Jan 1965 A
3290893 Haldopoulos Dec 1966 A
3338451 Kesling Aug 1967 A
3353301 Heilweil et al. Nov 1967 A
3353321 Heilweil et al. Nov 1967 A
3408316 Mueller et al. Oct 1968 A
3597850 Jenkins Aug 1971 A
3607169 Coxe Sep 1971 A
3632012 Kitson Jan 1972 A
3633783 Aue Jan 1972 A
3634971 Kesling Jan 1972 A
3670521 Dodge, III et al. Jun 1972 A
3768687 Spencer Oct 1973 A
3769770 Deschamps et al. Nov 1973 A
3862880 Feldman Jan 1975 A
3868829 Mann et al. Mar 1975 A
3875683 Waters Apr 1975 A
3910658 Lindenschmidt Oct 1975 A
3915328 Hawes et al. Oct 1975 A
3933398 Haag Jan 1976 A
3935787 Fisher Feb 1976 A
4005919 Hoge et al. Feb 1977 A
4118266 Kerr Oct 1978 A
4170391 Bottger Oct 1979 A
4180297 Abrams Dec 1979 A
4242241 Rosen et al. Dec 1980 A
4260876 Hochheiser Apr 1981 A
4303730 Torobin Dec 1981 A
4303732 Torobin Dec 1981 A
4330310 Tate, Jr. et al. May 1982 A
4396362 Thompson et al. Aug 1983 A
4529368 Makansi Jul 1985 A
4583796 Nakajima et al. Apr 1986 A
4681788 Barito et al. Jul 1987 A
4732432 Keil et al. Mar 1988 A
4781968 Kellerman Nov 1988 A
4865875 Kellerman Sep 1989 A
4870735 Jahr et al. Oct 1989 A
4914341 Weaver et al. Apr 1990 A
4951652 Ferrario et al. Aug 1990 A
5076984 Bisplinghoff et al. Dec 1991 A
5084320 Barito et al. Jan 1992 A
5094899 Rusek, Jr. Mar 1992 A
5121593 Forslund Jun 1992 A
5168674 Molthen Dec 1992 A
5171346 Hallett Dec 1992 A
5227245 Brands et al. Jul 1993 A
5251455 Cur et al. Oct 1993 A
5269099 Kennedy et al. Dec 1993 A
5284023 Silva et al. Feb 1994 A
5368381 Mandel Nov 1994 A
5375428 LeClear et al. Dec 1994 A
5500287 Henderson Mar 1996 A
5500305 Bridges et al. Mar 1996 A
5505810 Kirby et al. Apr 1996 A
5509248 Dellby et al. Apr 1996 A
5532034 Kirby et al. Jul 1996 A
5533311 Tirrell et al. Jul 1996 A
5599081 Revlett et al. Feb 1997 A
5600966 Valence et al. Feb 1997 A
5704107 Schmidt et al. Jan 1998 A
5768837 Sjoholm Jun 1998 A
5792539 Hunter Aug 1998 A
5792801 Tsuda et al. Aug 1998 A
5826780 Nesser et al. Oct 1998 A
5834126 Sheu Nov 1998 A
5866247 Klatt et al. Feb 1999 A
5876104 Kunkel et al. Mar 1999 A
5918478 Bostic et al. Jul 1999 A
5934085 Suzuki et al. Aug 1999 A
5950395 Takemasa et al. Sep 1999 A
5952404 Simpson et al. Sep 1999 A
6013700 Asano et al. Jan 2000 A
6029846 Hirath et al. Feb 2000 A
6037033 Hunter Mar 2000 A
6063471 Dietrich et al. May 2000 A
6163976 Tada et al. Dec 2000 A
6164739 Schultz et al. Dec 2000 A
6187256 Asian et al. Feb 2001 B1
6209342 Banicevic et al. Apr 2001 B1
6210625 Matsushita et al. Apr 2001 B1
6217140 Hirath et al. Apr 2001 B1
6244458 Frysinger et al. Jun 2001 B1
6266941 Nishimoto Jul 2001 B1
6266970 Nam et al. Jul 2001 B1
6294595 Tyagi et al. Sep 2001 B1
6336693 Nishimoto Jan 2002 B2
6485122 Wolf et al. Jan 2002 B2
6428130 Banicevic et al. Aug 2002 B1
6430780 Kim et al. Aug 2002 B1
6519919 Takenouchi et al. Feb 2003 B1
6629429 Kawamura et al. Oct 2003 B1
6655766 Hodges Dec 2003 B2
6689840 Eustace et al. Feb 2004 B1
6736472 Banicevic May 2004 B2
6860082 Yamamoto et al. Mar 2005 B1
7008032 Chekal et al. Mar 2006 B2
7197792 Moon Apr 2007 B2
7197888 LeClear et al. Apr 2007 B2
7207181 Murray et al. Apr 2007 B2
7234247 Maguire Jun 2007 B2
7263744 Kim et al. Sep 2007 B2
7360371 Feinauer et al. Apr 2008 B2
7475562 Jackovin Jan 2009 B2
7517031 Laible Apr 2009 B2
7614244 Venkatakrishnan et al. Nov 2009 B2
7665326 LeClear et al. Feb 2010 B2
7703217 Tada et al. Apr 2010 B2
7703824 Kittelson et al. Apr 2010 B2
7757511 LeClear et al. Jul 2010 B2
7794805 Aumaugher et al. Sep 2010 B2
7845745 Gorz et al. Dec 2010 B2
7938148 Carlier et al. May 2011 B2
7939179 DeVos et al. May 2011 B2
7992257 Kim Aug 2011 B2
8049518 Wern et al. Nov 2011 B2
8074469 Hamel et al. Dec 2011 B2
8079652 Laible et al. Dec 2011 B2
8083985 Luisi et al. Dec 2011 B2
8108972 Bae et al. Feb 2012 B2
8157338 Seo et al. Apr 2012 B2
8162415 Hagele et al. Apr 2012 B2
8182051 Laible et al. May 2012 B2
8197019 Kim Jun 2012 B2
8266923 Bauer et al. Sep 2012 B2
8382219 Hoffmann et al. Feb 2013 B2
8434317 Besore May 2013 B2
8439460 Laible et al. May 2013 B2
8486215 Amann Jul 2013 B2
8491070 Davis et al. Jul 2013 B2
8516845 Wuesthoff et al. Aug 2013 B2
8590992 Lim et al. Nov 2013 B2
8717029 Chae et al. May 2014 B2
8752921 Gorz et al. Jun 2014 B2
8763847 Mortarotti Jul 2014 B2
8764133 Park et al. Jul 2014 B2
8776390 Hanaoka et al. Jul 2014 B2
8840204 Bauer et al. Sep 2014 B2
8871323 Kim et al. Oct 2014 B2
8881398 Hanley et al. Nov 2014 B2
8905503 Sahasrabudhe et al. Dec 2014 B2
8943770 Sanders et al. Feb 2015 B2
8944541 Allard et al. Feb 2015 B2
9009969 Choi et al. Apr 2015 B2
RE45501 Maguire May 2015 E
9056952 Eilbracht et al. Jun 2015 B2
9062480 Litch Jun 2015 B2
9074811 Korkmaz Jul 2015 B2
9080808 Choi et al. Jul 2015 B2
9102076 Doshi et al. Aug 2015 B2
9103482 Fujimori et al. Aug 2015 B2
9125546 Kleemann et al. Sep 2015 B2
9140480 Kuehl et al. Sep 2015 B2
9140481 Curr et al. Sep 2015 B2
9170045 Oh et al. Oct 2015 B2
9170046 Jung et al. Oct 2015 B2
9188382 Kim et al. Nov 2015 B2
8955352 Lee et al. Dec 2015 B2
9221210 Wu et al. Dec 2015 B2
9228386 Thielmann et al. Jan 2016 B2
9267727 Lim et al. Feb 2016 B2
9303915 Kim et al. Apr 2016 B2
9328951 Shin et al. May 2016 B2
9353984 Kim et al. May 2016 B2
9410732 Choi et al. Aug 2016 B2
9423171 Betto et al. Aug 2016 B2
9429356 Kim et al. Aug 2016 B2
9448004 Kim et al. Sep 2016 B2
9463917 Wu et al. Oct 2016 B2
9482463 Choi et al. Nov 2016 B2
9506689 Carbajal et al. Nov 2016 B2
9518777 Lee et al. Dec 2016 B2
9568238 Kim et al. Feb 2017 B2
D781641 Incukur Mar 2017 S
D781642 Incukur Mar 2017 S
9605891 Lee et al. Mar 2017 B2
9696085 Seo et al. Jul 2017 B2
9702621 Cho et al. Jul 2017 B2
9759479 Ramm et al. Sep 2017 B2
9777958 Choi et al. Oct 2017 B2
9791204 Kim et al. Oct 2017 B2
9833942 Wu et al. Dec 2017 B2
9927169 Baker et al. Mar 2018 B2
10024544 Bhogal et al. Jul 2018 B2
10077342 An et al. Sep 2018 B2
20020004111 Matsubara et al. Jan 2002 A1
20020114937 Albert et al. Aug 2002 A1
20020144482 Henson et al. Oct 2002 A1
20030041612 Piloni et al. Mar 2003 A1
20030056334 Finkelstein Mar 2003 A1
20030157284 Tanimoto et al. Aug 2003 A1
20030167789 Tanimoto et al. Sep 2003 A1
20030173883 Koons Sep 2003 A1
20040144130 Jung Jul 2004 A1
20040226141 Yates et al. Nov 2004 A1
20050042247 Gomoll et al. Feb 2005 A1
20050229614 Ansted Oct 2005 A1
20060064846 Espendola et al. Mar 2006 A1
20060261718 Miseki et al. Nov 2006 A1
20060266075 Itsuki et al. Nov 2006 A1
20070266654 Noale Nov 2007 A1
20080044488 Zimmer et al. Feb 2008 A1
20080048540 Kim Feb 2008 A1
20080138458 Ozasa et al. Jun 2008 A1
20080196441 Ferreira Aug 2008 A1
20080257759 Stone Oct 2008 A1
20090032541 Rogala et al. Feb 2009 A1
20090131571 Fraser et al. May 2009 A1
20090205357 Lim et al. Aug 2009 A1
20090302728 Rotter et al. Dec 2009 A1
20090322470 Yoo et al. Dec 2009 A1
20100206464 Heo et al. Aug 2010 A1
20100218543 Duchame Sep 2010 A1
20100287843 Oh Nov 2010 A1
20100287974 Cur et al. Nov 2010 A1
20110011119 Kuehl et al. Jan 2011 A1
20110023527 Kwon et al. Feb 2011 A1
20110095669 Moon et al. Apr 2011 A1
20110215694 Fink et al. Sep 2011 A1
20110220662 Kim et al. Sep 2011 A1
20110309732 Horil et al. Dec 2011 A1
20120011879 Gu Jan 2012 A1
20120060544 Lee et al. Mar 2012 A1
20120099255 Lee et al. Apr 2012 A1
20120202049 Valladeau et al. Aug 2012 A1
20120240612 Wusthoff et al. Sep 2012 A1
20120280608 Park et al. Nov 2012 A1
20130026900 Oh et al. Jan 2013 A1
20130043780 Ootsuka et al. Feb 2013 A1
20130221819 Wing Aug 2013 A1
20130270732 Wu et al. Oct 2013 A1
20130285527 Choi et al. Oct 2013 A1
20130293080 Kim et al. Nov 2013 A1
20130328472 Shim et al. Dec 2013 A1
20140009055 Cho et al. Jan 2014 A1
20140015395 Anthony et al. Jan 2014 A1
20140047775 Litch Feb 2014 A1
20140097733 Seo et al. Apr 2014 A1
20140162162 Kalika et al. Jun 2014 A1
20140166926 Lee et al. Jun 2014 A1
20140190978 Bowman et al. Jul 2014 A1
20140196305 Smith Jul 2014 A1
20140216706 Melton et al. Aug 2014 A1
20140232250 Kim et al. Aug 2014 A1
20140311667 Siudzinski et al. Oct 2014 A1
20140346942 Kim et al. Nov 2014 A1
20150011668 Kolb et al. Jan 2015 A1
20150015133 Carbajal et al. Jan 2015 A1
20150017386 Kolb et al. Jan 2015 A1
20150047624 Luckhardt et al. Feb 2015 A1
20150059399 Hwang et al. Mar 2015 A1
20150115790 Ogg Apr 2015 A1
20150159936 Oh et al. Jun 2015 A1
20150176888 Cur et al. Jun 2015 A1
20150184923 Jeon Jul 2015 A1
20150190840 Muto et al. Jul 2015 A1
20150224685 Amstutz Aug 2015 A1
20150241115 Strauss et al. Aug 2015 A1
20150241118 Wu Aug 2015 A1
20150285551 Aiken et al. Oct 2015 A1
20160084567 Fernandez et al. Mar 2016 A1
20160116100 Thiery et al. Apr 2016 A1
20160123055 Ueyama May 2016 A1
20160161175 Benold et al. Jun 2016 A1
20160178267 Hao et al. Jun 2016 A1
20160178269 Hiemeyer et al. Jun 2016 A1
20160235201 Soot Aug 2016 A1
20160240839 Umeyama et al. Aug 2016 A1
20160258671 Allard et al. Sep 2016 A1
20160290702 Sexton et al. Oct 2016 A1
20160348957 Hitzelberger et al. Dec 2016 A1
20170038126 Lee et al. Feb 2017 A1
20170157809 Deka et al. Jun 2017 A1
20170159942 Ivanovic et al. Jun 2017 A1
20170176086 Kang Jun 2017 A1
20170184339 Liu et al. Jun 2017 A1
20170191746 Seo Jul 2017 A1
20190101320 Dherde Apr 2019 A1
Foreign Referenced Citations (179)
Number Date Country
626838 May 1961 CA
201748744 Feb 2011 CN
102717578 Oct 2012 CN
202973713 Jun 2013 CN
104816478 Aug 2015 CN
105115221 Dec 2015 CN
2014963379 Jan 2016 CN
3208686 Sep 1983 DE
4110292 Oct 1992 DE
4409091 Sep 1995 DE
19520020 Dec 1996 DE
19914105 Sep 2000 DE
19948361 Apr 2001 DE
102011051178 Dec 2012 DE
102015222224 May 2017 DE
0645576 Mar 1995 EP
1602425 Dec 2005 EP
1624263 Aug 2006 EP
1344008 Sep 2006 EP
1338854 Dec 2009 EP
2543942 Jan 2013 EP
2801774 Nov 2014 EP
2878427 Jun 2015 EP
2991698 Dec 2013 FR
58168875 Oct 1983 JP
131880 Dec 1989 JP
404165197 Jun 1992 JP
04165197 Oct 1992 JP
04309778 Nov 1992 JP
8145547 Jun 1996 JP
11159693 Jun 1999 JP
2000097390 Apr 2000 JP
20000117334 Apr 2000 JP
2000320958 Nov 2000 JP
2001038188 Feb 2001 JP
2001116437 Apr 2001 JP
2001336691 Dec 2001 JP
2001343176 Dec 2001 JP
2002068853 Mar 2002 JP
3438948 Aug 2003 JP
3478771 Dec 2003 JP
2004303695 Oct 2004 JP
2005069596 Mar 2005 JP
2005098637 Apr 2005 JP
2005114015 Apr 2005 JP
2005164193 Jun 2005 JP
2005256849 Sep 2005 JP
2006-77792 Mar 2006 JP
2006161834 Jun 2006 JP
2006161945 Jun 2006 JP
3792801 Jul 2006 JP
2006200685 Aug 2006 JP
2007263186 Oct 2007 JP
4111096 Jul 2008 JP
2008157431 Jul 2008 JP
2008190815 Aug 2008 JP
2009063064 Mar 2009 JP
2009162402 Jul 2009 JP
2009524570 Jul 2009 JP
2010017437 Jan 2010 JP
2010071565 Apr 2010 JP
2010108199 May 2010 JP
2010145002 Jul 2010 JP
4545126 Sep 2010 JP
2010236770 Oct 2010 JP
2010276309 Dec 2010 JP
2011002033 Jan 2011 JP
2011069612 Apr 2011 JP
4779684 Sep 2011 JP
2011196644 Oct 2011 JP
2012026493 Feb 2012 JP
4897473 Mar 2012 JP
2012063029 Mar 2012 JP
2012087993 May 2012 JP
2012163258 Aug 2012 JP
2012189114 Oct 2012 JP
2012242075 Dec 2012 JP
2013002484 Jan 2013 JP
2013050242 Mar 2013 JP
2013050267 Mar 2013 JP
2013076471 Apr 2013 JP
2013088036 May 2013 JP
2013195009 Sep 2013 JP
20020057547 Jul 2002 KR
20020080938 Oct 2002 KR
20030083812 Nov 2003 KR
20040000126 Jan 2004 KR
20050095357 Sep 2005 KR
100620025 Sep 2006 KR
20070044024 Apr 2007 KR
1020070065743 Jun 2007 KR
20080103845 Nov 2008 KR
20090026045 Mar 2009 KR
1017776 Feb 2011 KR
101017776 Feb 2011 KR
20120007241 Jan 2012 KR
20120046621 May 2012 KR
20120051305 May 2012 KR
20150089495 Aug 2015 KR
547614 May 1977 RU
2061925 Jun 1996 RU
2077411 Apr 1997 RU
2081858 Jun 1997 RU
2132522 Jun 1999 RU
2162576 Jan 2001 RU
2166158 Apr 2001 RU
2187433 Aug 2002 RU
2234645 Aug 2004 RU
2252377 May 2005 RU
2253792 Jun 2005 RU
2006120198 Nov 2006 RU
2349618 Mar 2009 RU
2414288 Mar 2011 RU
2422598 Jun 2011 RU
142892 Jul 2014 RU
2529525 Sep 2014 RU
2571031 Dec 2015 RU
203707 Dec 1967 SU
00476407 Jul 1975 SU
648780 Feb 1979 SU
01307186 Apr 1987 SU
9614207 May 1996 WO
1996032605 Oct 1996 WO
9721767 Jun 1997 WO
1998049506 Nov 1998 WO
9920961 Apr 1999 WO
9920964 Apr 1999 WO
1999020964 Apr 1999 WO
0160598 Aug 2001 WO
200160598 Aug 2001 WO
200202987 Jan 2002 WO
2002052208 Apr 2002 WO
02060576 Aug 2002 WO
03072684 Sep 2003 WO
2003089729 Oct 2003 WO
2004010042 Jan 2004 WO
2006045694 May 2006 WO
2006073540 Jul 2006 WO
2006120183 Nov 2006 WO
2007033836 Mar 2007 WO
2007085511 Aug 2007 WO
2007106067 Sep 2007 WO
2008065453 Jun 2008 WO
2008077741 Jul 2008 WO
2008118536 Oct 2008 WO
2008122483 Oct 2008 WO
2009013106 Jan 2009 WO
2009112433 Sep 2009 WO
2009147106 Dec 2009 WO
2010007783 Jan 2010 WO
2010029730 Mar 2010 WO
2010043009 Apr 2010 WO
2010092627 Aug 2010 WO
2010127947 Nov 2010 WO
2010127947 Nov 2010 WO
2011003711 Jan 2011 WO
2011058678 May 2011 WO
2011058678 May 2011 WO
2011081498 Jul 2011 WO
2012023705 Feb 2012 WO
2012026715 Mar 2012 WO
2012031885 Mar 2012 WO
2012043990 Apr 2012 WO
2012044001 Apr 2012 WO
2012085212 Jun 2012 WO
2012119892 Sep 2012 WO
2012152646 Nov 2012 WO
2013116103 Aug 2013 WO
2013116302 Aug 2013 WO
2014038150 Mar 2014 WO
2014038150 Mar 2014 WO
2014095542 Jun 2014 WO
2014121893 Aug 2014 WO
2014184393 Nov 2014 WO
2014184393 Nov 2014 WO
2013140816 Aug 2015 WO
2016082907 Jun 2016 WO
2017029782 Feb 2017 WO
2018199980 Nov 2018 WO
Non-Patent Literature Citations (2)
Entry
Cai et al., “Generation of Metal Nanoparticles by Laser Ablation of Microspheres,” J. Aerosol Sci., vol. 29, No. 5/6 (1998), pp. 627-636.
Raszewski et al., “Methods for Producing Hollow Glass Microspheres,” Powerpoint, cached from Google, Jul. 2009, 6 pages.
Related Publications (1)
Number Date Country
20200263919 A1 Aug 2020 US