This application is a U. S. National Stage application of International Application No. PCT/EP20201064519, filed May 26, 2020, which claims priority to Swiss Patent Application No. 00696/19, filed May 28, 2019, the contents of each of which are hereby incorporated by reference.
The invention relates to bundle heat exchangers comprising assemblies (which may or may not be designed as built-in elements) formed of deflection surfaces and directing sections in the outer chamber.
Since conventional bundle heat exchangers are usually made of a metallic material, we often refer to deflection panels rather than deflection surfaces. In this description, however, the term deflection surfaces is used to make it clear that their applicability is not limited to heat exchangers made of a metallic material.
The bundles can consist of tubes through which a heat exchange medium (for example a heating or cooling medium which heats or cools the product circulating in the outer chamber) is directed. Instead, however, other heat exchange elements combined into bundles, such as electric heating rods, electric heating coils and the like, can also be used. For the sake of simplicity of illustration, the terms “tubes” or “tube bundles” will be used hereafter, although after what has been said it should be understood that other extended heat exchange elements such as heating rods are also meant.
The usual design of deflection panels or deflection surfaces serves as a flow guide by guiding the flow of fluid in the outer chamber partly transversely and partly parallel to the tubes. These metal sheets have bores corresponding to the tube spacing, are perpendicular to the tubes and have segment-shaped windows for the axial passage of fluid. Other known embodiments consist alternately of discs and rings. They are installed as standard in turbulent (low-viscosity fluids) and laminar (viscous fluids) flow. For further functional and structural details, reference is made to the VDI Heat Atlas (6th edition), sections Gg5 and Ob7. These deflection surfaces improve heat transfer thanks to the more or less pronounced crossflow to the tubes, but they do not cause any mixing of the fluid. This applies in particular in the case of laminar flow of viscous fluids. As these materials have lower heat transfer coefficients as a result of their properties, they should be guided around the tubes (VDI Heat Atlas, section Ob4). In the case of viscous media that have to be cooled or heated, viscosity can change significantly with temperature. Partial flows that run through a different temperature-time history (flow paths) ultimately have very different properties. This applies in particular to viscosity. Without constant mixing, preferred paths and dead zones develop, known as maldistribution. This can lead to complete failure of the heat exchanger, but also to poor product properties. The problems are similar when the heat exchanger is to be used as a polymerization reactor or for other exothermic reactions with viscous, liquid substances, cf. for example Chemical Engineering & Technology (Chem Eng. Technol.) 13 (1990), pp. 214-220. Here, too, differences in turnover and viscosity lead to maldistribution. Similar problems occur in tube-bundle heat exchangers, in which viscous solutions partially evaporate and viscosity increases sharply in the process.
Many static mixers such as X mixers (SMX, SMXL) or helical mixers (Kenics mixers) are preferably used with laminar flow in double jacketed tubes to improve heat transfer, mixing and residence time distribution at the same time, el Process Engineering 34 (2000) No. 1-2, pp. 18-21, There are narrow limitations to the scale-up of these devices because the ratio of heat transfer surface to product volume decreases as the tube diameter increases or, if the tube diameter remains the same, the pressure loss would increase rapidly as the product quantity increases. As a solution, attempts are being made to also use static mixers in the tubes of tube-bundle heat exchangers, wherein the product flows in the tubes. Mixing within individual tubes then still takes place, but the partial flows in the tubes are completely isolated from one another and different flow states and product properties can develop in the individual tubes. The result can again be pronounced maldistribution in the tubes with the effects described. The problem is made even worse by the higher pressure loss of the mixing elements. A further disadvantage with reactive products is the additional volume in the hoods of a tube-bundle device. There is little or no heat transfer in this space.
DE 28 39 564 C2 presents a device for heat transfer and static mixing. In this mixer-heat exchanger or reactor (known as an SMR reactor), the product also flows through a flow channel with tube bundles and around the tubes in the outer chamber. The tubes are bent in a meandering manner to form coiled tubes. The tubes are at 45° to the flow direction, cross one another and form a mixer structure. The individual tube coils are guided outwards through the channel wall into a collector. As a result, simultaneous mixing and good heat transfer in the outer chamber is achieved, but with a great deal of effort and many disadvantages. The mixing effect is less compared to the known mixer consisting of crossing sections and takes place only in one direction within a bundle or mixing element. For practical reasons, the tube bundles should be as long as possible. As a result, only a few bundles which are rotated 90° can be used in a flow channel. Each mixing element or coil bundle requires its own collector for the heat carrier medium. The pressure loss on the heat carrier side in the tubes is high because of the long coils and many tube bends. Different lengths of the coils lead to an uneven distribution of the flows on the heat carrier side and can in turn cause maldistribution on the product side.
An advantageous countercurrent flow of heat carrier medium and product or evaporation or condensation in the tubes is also not possible due to the construction of the bundles.
A further solution to the problem is sought in EP 1 067 352 B2. Mixing elements with crossing sections according to the known SMX structure are provided with bores corresponding to the tube spacing of a tube-bundle heat exchanger and the tubes are inserted through the sections. Linking the mixing structure with the tube arrangement restricts the freedom of tube spacing and size on the one hand and the mixer structure on the other hand. If the sections are not firmly connected to the tubes, this structure is also rather weak mechanically. In terms of process technology, this heat exchanger can be superior to the design according to the previous paragraph, but its manufacture is enormously complex and demanding.
One object of the invention is to create a tube-bundle heat exchanger, mixer heat exchanger or mixing reactor of the type mentioned at the outset which avoids the disadvantages of the prior art. This object is achieved by the characterizing features described herein.
The tube-bundle heat exchanger according to embodiments of the invention is particularly suitable for viscous products and can be manufactured very inexpensively. In the tube-bundle heat exchanger, products can be heated, cooled or evaporated and exothermic reactions can be carried out with simultaneous, intensive mixing. With low axial backmixing and low pressure loss, it has no moving parts. The formation of maldistribution is prevented and the fixtures are, if necessary, easily accessible for cleaning from the outside. The device is also very easily scalable. The arrangement and the number of extended (axially aligned) tubes (or other heat exchange elements/heat exchangers) through which there is a flow can be freely selected.
The invention will be explained in more detail hereinafter with reference to the drawings.
With general reference to the drawings, the product flows in the casing space of a tube-bundle heat exchanger known per se with an inlet 2 and an outlet 3 for the product in the outer chamber 6. An inlet 4 and an outlet 5 are provided for the heat carrier medium which flows in the tubes 7. According to embodiments of the invention, the deflection panels (or deflection surfaces) 8 that are usually present, which are perpendicular to the tubes or to the axis of the heat exchanger and have bores 7′ for the tubes, are modified such that they leave two or more windows 12, 13 open for the axial passage of the product from the inlet side to the outlet side of the deflection surface. At least one directing section 10 or 11 is attached to the inlet side or the outlet side. These directing sections run parallel to the tubes and subdivide the cross section of the tube bundle into portions of approximately the same size. If necessary, the deflection surfaces can also be set at an angle to the heat exchanger or tube axis, cf. reference sign 9.
The directing sections 10, 11 on the inlet side and outlet side of the deflection surfaces are preferably at 90° to one another. The product flows divided by the directing section 10 on the inlet side in opposite directions, transversely to the tubes to the windows 12, 13; the deflection surface passes in the axial direction and opens onto opposite sides of the directing section 11 on the outlet side and is deflected in the direction of the directing section preferably by 90°. The flow direction of the partial flows transversely to the tubes on the outlet side is again opposite on both sides of the directing section 11. Deflection surfaces with windows and crossing directing sections each form a built-in element A or B. The directing sections 11, 10′ of successive built-in elements (A, B) in the flow direction preferably cross one another at 90°. Closed partial surfaces 8, 8′ and windows 12, 12′ and 13, 13′ of successive built-in elements A, B alternate.
In each built-in element, with laminar flow, there is a division into partial flows and mixing in such a way that in each built-in element, the number of layers at least doubles (with two partial flows or one directing section on the inlet side and on the outlet side) with simultaneous, intensive heat transfer. In the entire device, the number of layers formed increases exponentially from inlet to outlet with the number of built-in elements following one another in the flow direction. This process could be demonstrated on the basis of tests with rapidly hardening, tough polyester resin. In the case of a turbulent flow, the mixing is intensified by turbulence. The axial distance between successive deflection surfaces preferably corresponds to the height of two directing sections with no distances between them. The installation can, however, also take place with spacing or be shortened with directing sections pushed into one another. Instead of two windows with a directing section in between on the inlet side and on the outlet side, the deflection surfaces can also have a plurality of windows 25, 26, 27 and many pairs of directing sections (21, 22 and 23, 24). It is also possible that the number of directing sections on the inlet side and on the outlet side, or their height, is different. This increases the intensity of the mixing, but also increases the effort and pressure loss.
The flow path in the outer chamber is extended by the directing sections according to embodiments of the invention. This also increases the flow velocity around the tubes and the heat transfer. The intensive mixing prevents axial backmixing at the same time. The greater the number of successive assemblies/built-in elements in the heat exchanger and thus also the more streamlined the device, the narrower the residence time distribution will be, analogous to a cascade of stirred-tank reactors. In contrast to the fixtures according to embodiments of the invention, all previously known deflection panels (or deflection surfaces) for heat exchangers do not cause any mixing in the case of laminar flow or viscous products. Heat transfer is only improved as a result of the better crossflow to the tubes. The product flow is only diverted, but not divided and mixed.
In a further embodiment, as is customary with normal deflection panels, the fixtures are connected to one another and to the device by holding rods. It is also possible to manufacture sub-elements, including a directing section and closed partial surfaces, from sheet metal by flexing. The arrangement shown with U-tubes is only an example. Of course, the built-in elements are also suitable for all other tube-bundle heat exchangers, such as those with fixed, straight tubes and tube sheets or for multi-thread devices. Device cross sections that are not circular (e.g. square or rectangular) would also be possible. For the heating of liquids, electric heating rods or heating coils can also be used instead of tubes with a heat carrier medium.
An alternative embodiment is shown in
A detailed illustration of a variant of the invention based on
In
For further illustration,
The assemblies or built-in elements and their components such as deflection surfaces and directing sections can be manufactured from steel and welded in a manner known per se. However, cast parts can also be used. Finally, manufacturing from plastics is also possible, for example by injection molding or by means of additive manufacturing such as 3D printing.
Number | Date | Country | Kind |
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00696/19 | May 2019 | CH | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2020/064519 | 5/26/2020 | WO |
Publishing Document | Publishing Date | Country | Kind |
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WO2020/239734 | 12/3/2020 | WO | A |
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20090301699 | Karrs | Dec 2009 | A1 |
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20160025413 | Ernst | Jan 2016 | A1 |
Number | Date | Country |
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2839564 | Mar 1980 | DE |
1067352 | Oct 2001 | EP |
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09000901 | Jan 1997 | JP |
WO-2018026312 | Feb 2018 | WO |
Entry |
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International Search Report issued Aug. 28, 2020 in corresponding International Application No. PCT/EP2020/064519. |
Number | Date | Country | |
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20220236014 A1 | Jul 2022 | US |