Patent Application
20250009010
The present invention relates to a tubular body.
Conventionally, a double-layered tube (tubular body) manufactured from first and second material strip portions is known (see, for example, PTL 1). This double-layered tube is applicable, for example, to a flavor generating article for use in a non-combustible flavor inhaler for inhaling flavor or the like without combusting any material, or to a combustible smoking article.
In this tube, the second material strip portion is disposed around the first material strip portion, and the first and second material strip portions have abutment edges wound to be shifted from each other in a circumferential direction. Furthermore, in this tube, a positioning adhesive and a joint adhesive (collectively referred to as an adhesive) are provided on the entire surface or almost the entire surface between the first material strip portion and the second material strip portion.
When a tube described in PTL 1 is applied to a flavor generating article or a smoking article, this application includes incorporating the tube into a semifinished product of the flavor generating article or the smoking article, then irradiating the tube with laser beams from an outer circumference toward an inner circumference of the tube and combusting a material of the tube at irradiated spots. Consequently, vent holes extending through the tube can be formed intermittently over an entire circumference of the tube in a circumferential direction.
Here, in the tube described in PTL 1, an adhesive is provided on the entire surface or almost the entire surface between a first material strip portion and a second material strip portion. Therefore, when forming the vent holes, combustion ash of the adhesive may close the vent holes.
Specifically, paper constituting the tube is, for example, organic wood pulp (almost pure cellulose from which lignin, hemicellulose, and the like contained in trees are removed) and an inorganic filler (calcium carbonate), and the combustion ash generated by irradiation with laser beams is mainly calcium carbonate.
In contrast, the adhesive is, for example, a kneaded material of modified starch, vinyl acetate or ethylene vinyl acetate, which is an organic polymer, alcohols and water, and the combustion ash generated by the irradiation with laser beams contains organic polymers left over from combustion.
Therefore, the combustion ash in the vent holes formed at spots to which the adhesive is applied is a mixture of calcium carbonate and organic polymers and is stickier and more likely to close the vent holes than calcium carbonate-dominant combustion ash in the vent holes formed at spots to which the adhesive is not applied.
If the tube with the vent holes closed is applied to the flavor generating article or the smoking article, air is not introduced from the vent holes into the flavor generating article or the smoking article. Consequently, aerosol generated by heating the flavor generating article or by combusting the smoking article is not cooled, and aerosol concentration is not reduced. There is therefore concern that the flavor generating article or the smoking article deteriorates in quality.
The present invention has been made to solve at least some of such problems as described above, and an object of the present invention is to obtain a tubular body capable of inhibiting combustion ash of an adhesive from closing vent holes if the vent holes are formed.
In a first aspect of the present invention, a tubular body is provided. This tubular body includes a first sheet material that has a circular or elliptical cross-sectional shape perpendicular to an axial direction, a second sheet material that is provided on an outer circumference of the first sheet material and that has a circular or elliptical cross-sectional shape perpendicular to the axial direction, an adhesive layer that is provided between the first sheet material and the second sheet material and that bonds the first sheet material and the second sheet material to each other, and a plurality of vent holes formed in a circumferential direction of the tubular body through the first sheet material and the second sheet material, wherein the plurality of vent holes including at least one first vent hole in which the adhesive layer is exposed to a hole inner surface of the vent hole, and at least one second vent hole in which the adhesive layer is not exposed to the hole inner surface of the vent hole.
According to the first aspect of the present invention, the plurality of vent holes includes the at least one first vent hole in which the adhesive layer is exposed to the hole inner surface of the vent hole, and the at least one second vent hole in which the adhesive layer is not exposed to the hole inner surface of the vent hole. Consequently, probability of forming the vent hole at a spot provided with the adhesive layer can be reduced, and combustion ash of an adhesive can be inhibited from closing the vent holes.
For a second aspect of the present invention, in the first aspect, the first sheet material and the second sheet material are shifted from each other and stacked such that ends of the first and second sheet materials in the circumferential direction do not overlap each other, the first sheet material includes a first body portion, and a first extending portion extending from the first body portion in the circumferential direction with respect to the opposing second sheet material, the second sheet material includes a second body portion, and a second extending portion extending from the second body portion in the circumferential direction with respect to the opposing first sheet material, the adhesive layer includes a positioning adhesive layer that bonds the first body portion and the second body portion to each other, and a joint adhesive layer that bonds the first extending portion and the second extending portion to each other, and the positioning adhesive layer has an adhesive pattern of a positioning glue applied linearly.
According to the second aspect of the present invention, since the positioning adhesive layer bonding the first body portion of the first sheet material and the second body portion of the second sheet material to each other has the adhesive pattern of the positioning glue applied linearly, an amount of adhesive applied can be reduced as compared with a case where the positioning adhesive layer is provided on the entire surface.
For a third aspect of the present invention, in the second aspect, the positioning glue is applied linearly in two or more lines.
According to the third aspect of the present invention, since the positioning adhesive layer has an adhesive pattern of the positioning glue applied linearly in two or more lines, the amount of adhesive applied can be reduced as compared with the case where the positioning adhesive layer is provided on the entire surface.
For a fourth aspect of the present invention, in the third aspect, the positioning glue is applied in a straight line.
According to the fourth aspect of the present invention, since the positioning adhesive layer has an adhesive pattern of the positioning glue applied in two or more straight lines, the amount of adhesive applied can be reduced as compared with the case where the positioning adhesive layer is provided on the entire surface.
For a fifth aspect of the present invention, in the fourth aspect, the positioning glue is applied in a straight line parallel to the axial direction.
According to the fifth aspect of the present invention, since the positioning adhesive layer has an adhesive pattern of the positioning glue applied in two or more straight lines parallel to the axial direction, the amount of adhesive applied can be reduced as compared with the case where the positioning adhesive layer is provided on the entire surface.
For a sixth aspect of the present invention, in the fourth aspect, the positioning glue is applied in a straight line perpendicular to the axial direction.
According to the sixth aspect of the present invention, since the positioning adhesive layer has an adhesive pattern of the positioning glue applied in two or more lines perpendicular to the axial direction, the amount of adhesive applied can be reduced as compared with the case where the positioning adhesive layer is provided on the entire surface.
For a seventh aspect of the present invention, in the second aspect, the positioning glue is applied spirally along the axial direction.
According to the seventh aspect of the present invention, since the positioning adhesive layer has an adhesive pattern of the positioning glue applied spirally along the axial direction, the amount of adhesive applied can be reduced as compared with the case where the positioning adhesive layer is provided on the entire surface.
For an eighth aspect of the present invention, in any one of the first to seventh aspects, each of the first sheet material and the second sheet material is paper.
According to the eighth aspect of the present invention, the first sheet material and second sheet material made of paper can improve processability of the tubular body.
For a ninth aspect of the present invention, in any one of the first to eighth aspects, the number of vent holes in the plurality of vent holes is 12 or more and 30 or less.
According to the ninth aspect of the present invention, by setting the number of the vent holes in the plurality of vent holes to 12 or more and 30 or less, the probability of forming the vent hole at the spot provided with the adhesive layer can be reduced, and combustion ash of the adhesive can be inhibited from closing the vent holes, while introducing sufficient air into an interior.
For a tenth aspect of the present invention, in the ninth aspect, the number of vent holes in the plurality of vent holes is 21 or less.
According to the tenth aspect of the present invention, by setting the number of the vent holes in the plurality of vent holes to 12 or more and 21 or less, the probability of forming the vent hole at the spot provided with the adhesive layer can be reduced, and the combustion ash of the adhesive can be inhibited from closing the vent holes, while introducing sufficient air into the interior.
For an eleventh aspect of the present invention, in any one of the first to tenth aspects, the number of vent holes in the first vent holes is 6 or less.
According to the eleventh aspect of the present invention, by setting the number of the vent holes in the first vent holes to 6 or less, the probability of forming the vent hole at the spot provided with the adhesive layer can be reduced, and the combustion ash of the adhesive can be inhibited from closing the vent holes, while introducing sufficient air into the interior.
For a twelfth aspect of the present invention, in any one of the first to eleventh aspects, a ratio of the number of vent holes in the first vent holes to the total number of vent holes in the plurality of vent holes is less than ¼.
According to the twelfth aspect of the present invention, by setting the ratio of the number of the vent holes in the first vent holes to the total number of the vent holes in the plurality of vent holes to less than ¼, the probability of forming the vent hole at the spot provided with the adhesive layer can be reduced, and the combustion ash of the adhesive can be inhibited from closing the vent holes, while introducing sufficient air into the interior.
For a thirteenth aspect of the present invention, in any one of the first to twelfth aspects, the plurality of vent holes is formed in two or more rows along the axial direction.
According to the thirteenth aspect of the present invention, by forming the plurality of vent holes in two or more rows along the axial direction, more air can be introduced into the interior as compared with a case where the plurality of vent holes is formed in one row.
Hereinafter, embodiments of the present invention will be described with reference to the drawings. In the drawings described below, identical, or corresponding components are denoted with the same signs and duplicate descriptions are omitted. A tubular body according to the present invention may be applied, for example, to a flavor generating article for use in a non-combustible flavor inhaler for inhaling flavor or the like without combusting any material. The tubular body according to the present invention may be applied to a combustible smoking article.
In use, the tobacco-containing segment 11 is heated and inhaled from an end of the filter segment 15. Note that a position of the center hole segment 14 is not limited to a position shown in
The tobacco-containing segment 11 includes a tobacco filler 210 containing tobacco and an aerosol source, and a tubular wrapper 220 wrapping the tobacco filler 210. The tobacco filler 210 may further contain a volatile flavoring ingredient, water, and the like. A size of tobacco for use as a filler or a method of preparing the tobacco is not particularly limited.
The cooling segment 13 includes a tubular body 100. In the tubular body 100 and mouthpiece lining paper 400 described later, a plurality of vent holes 140 extending through walls of both the tubular body and the mouthpiece lining paper is formed concentrically in a circumferential direction of the tubular body 100. Each vent hole 140 is a hole for promoting inflow of air from outside by user's inhalation, and the inflow of air cools aerosol generated in the tobacco filler 210 and reduces aerosol concentration. A diameter (delivery length) of the vent hole 140 is not particularly limited, but may be, for example, from 0.5 mm to 1.5 mm.
The center hole segment 14 includes a filling layer 310 having a hollow portion and a first inner plug wrapper 320 wrapping the filling layer 310. The filling layer 310 can be, for example, a rod into which cellulose acetate fibers are highly densely filled and a plasticizer containing triacetin is added and cured.
The hollow portion has a diameter that is not particularly limited and that may be, for example, from 1.0 mm to 5.0 mm. Since the filling layer 310 has a high fiber filling density, air, and aerosol flow only through the hollow portion during inhaling, and barely flow in the filling layer 310. Since the filling layer 310 includes the hollow portion, an amount of aerosol to be filtered can be reduced, the aerosol containing flavor ingredients generated by heating the flavor generating article 10.
The filter segment 15 includes a filter medium 330, and a tubular second inner plug wrapper 340 wrapping the filter medium 330. The filter medium 330 may be a solid plug filled with a porous material. Since the filter segment 15 includes the solid plug, a delivery amount of aerosol can be appropriately adjusted by filtering the aerosol containing the flavor ingredients generated by heating the flavor generating article 10.
The center hole segment 14 and the filter segment 15 are connected to each other with an outer plug wrapper 350. The outer plug wrapper 350 may be, for example, cylindrical paper. Furthermore, the tobacco-containing segment 11, the cooling segment 13, and the connected center hole segment 14 and filter segment 15 are wrapped in the mouthpiece lining paper 400 and mutually connected, the mouthpiece lining paper having an inner surface with a glue such as vinyl acetate glue applied thereto.
Hereinafter, the tubular body 100 shown in
As shown in
Each of the first sheet material 110 and the second sheet material 120 may be made of paper or cardboard. Therefore, processability of the tubular body 100 can be improved. Note that the first sheet material 110 and the second sheet material 120 may have an elliptical cross-sectional shape perpendicular to the axial direction.
Here, the first sheet material 110 and the second sheet material 120 are positioned to be shifted from each other and stacked such that ends of the materials in the circumferential direction do not overlap each other. The first sheet material 110 includes a first body portion 111, and a first extending portion 112 extending from the first body portion 111 in the circumferential direction with respect to the opposing second sheet material 120. The first body portion 111 is a portion opposing the second sheet material 120 in
The second sheet material 120 includes a second body portion 121 and a second extending portion 122 extending from the second body portion 121 in the circumferential direction to the opposing first sheet material 110. The second body portion 121 is a portion opposing the first sheet material 110 in
The adhesive layer 130 includes a positioning adhesive layer 131 and a first joint adhesive layer 132 that bond the first body portion 111 and the second body portion 121 to each other, and a second joint adhesive layer 133 (joint adhesive layer) that bonds the first extending portion 112 and the second extending portion 122 to each other. The first joint adhesive layer 132 does not necessarily need to be provided, and the positioning adhesive layer 131 may function as the first joint adhesive layer 132.
The positioning adhesive layer 131, the first joint adhesive layer 132 and the second joint adhesive layer 133 may be made of a kneaded material of modified starch, vinyl acetate or ethylene vinyl acetate, which is an organic polymer, alcohols, and water. The positioning adhesive layer 131, the first joint adhesive layer 132 and the second joint adhesive layer 133 are not limited to the above and may be made of another adhesive.
The tubular body 100 is formed by applying the positioning adhesive layer 131, the first joint adhesive layer 132 and the second joint adhesive layer 133 onto the second sheet material 120, stacking the first sheet material 110 and molding a tubular shape. Here, the positioning adhesive layer 131 applied to the second sheet material 120 has an adhesive pattern of a positioning glue (adhesive) applied linearly. Additionally, the positioning adhesive layer 131, the first joint adhesive layer 132 and the second joint adhesive layer 133 may be applied to the first sheet material 110 in place of the second sheet material 120.
A plurality of vent holes 140 is formed in the circumferential direction of the tubular body 100 through the first sheet material 110 and the second sheet material 120. Here, since the positioning adhesive layer 131 applied to the second sheet material 120 has an adhesive pattern of the positioning glue (adhesive) applied linearly, the plurality of vent holes 140 includes a first vent hole 141 in which the adhesive layer 130 is exposed to a hole inner surface of a vent hole 140, and a second vent hole 142 in which the adhesive layer 130 is not exposed to the hole inner surface of the vent hole 140.
Specifically, the first vent hole 141 is formed through the first sheet material 110 and the second sheet material 120, together with any of the positioning adhesive layer 131, the first joint adhesive layer 132 and the second joint adhesive layer 133. Furthermore, the second vent hole 142 is formed through the first sheet material 110 and the second sheet material 120 at a spot that is not provided with any of the positioning adhesive layer 131, the first joint adhesive layer 132 and the second joint adhesive layer 133.
As described above, the plurality of vent holes 140 includes at least one first vent hole 141 in which the adhesive layer 130 is exposed to the hole inner surface of the vent hole 140, and at least one second vent hole 142 in which the adhesive layer 130 is not exposed to the hole inner surface of the vent hole 140, so that probability of forming the vent hole 140 at a spot provided with the adhesive layer 130 can be reduced, and combustion ash of an adhesive can be inhibited from closing the vent hole 140. As a result, the flavor generating article 10 to which the tubular body 100 is applied can be inhibited from deteriorating in quality.
Thus, since the positioning adhesive layer 131 has an adhesive pattern of the positioning glue applied in two straight lines parallel to the axial direction, an amount of adhesive applied can be reduced as compared with a case where the positioning adhesive layer is provided on the entire surface. Furthermore, the probability of forming the vent hole 140 at the spot provided with the adhesive layer 130 can be reduced, and the combustion ash of the adhesive can be inhibited from closing the vent hole 140.
Note that the adhesive pattern of the positioning adhesive layer 131 is not limited to that shown in
Thus, since the positioning adhesive layer 131 has an adhesive pattern of the positioning glue applied spirally along the axial direction, an amount of adhesive applied can be reduced as compared with the case where the positioning adhesive layer is provided on the entire surface. Furthermore, the probability of forming the vent hole 140 at the spot provided with the adhesive layer 130 can be reduced, and the combustion ash of the adhesive can be inhibited from closing the vent hole 140.
Thus, since the positioning adhesive layer 131 has an adhesive pattern of the positioning glue applied in three straight lines parallel to the axial direction, the amount of adhesive applied can be reduced as compared with the case where the positioning adhesive layer is provided on the entire surface. Furthermore, the probability of forming the vent hole 140 at the spot provided with the adhesive layer 130 can be reduced, and the combustion ash of the adhesive can be inhibited from closing the vent hole 140.
Thus, since the positioning adhesive layer 131 has an adhesive pattern of the positioning glue applied in three straight lines perpendicular to an axial direction, the amount of adhesive applied can be reduced as compared with the case where the positioning adhesive layer is provided on the entire surface. Furthermore, the probability of forming the vent hole 140 at the spot provided with the adhesive layer 130 can be reduced, and the combustion ash of the adhesive can be inhibited from closing the vent hole 140.
Here, the number of vent holes 140 in a plurality of vent holes 140 is preferably 12 or more and 30 or less, more preferably 21 or less. By setting the number of the vent holes 140 in the plurality of vent holes 140 to 12 or more and 30 or less, more preferably 21 or less, the probability of forming the vent hole 140 at the spot provided with the adhesive layer 130 can be reduced, and the combustion ash of the adhesive can be inhibited from closing the vent hole 140, while introducing sufficient air into an interior.
It is also preferable that the number of first vent holes 141 is 6 or less. By setting the number of the first vent holes 141 to 6 or less, the probability of forming the vent hole 140 at the spot provided with the adhesive layer 130 can be reduced, and the combustion ash of the adhesive can be inhibited from closing the vent hole 140, while introducing sufficient air into the interior.
Furthermore, a ratio of the number of the first vent holes 141 to the total number of the plurality of vent holes 140 is preferably less than ¼. By setting the ratio of the number of the first vent holes 141 to the total number of the plurality of vent holes 140 to less than ¼, the probability of forming the vent hole 140 at the spot provided with the adhesive layer 130 can be reduced, and the combustion ash of the adhesive can be inhibited from closing the vent hole 140, while introducing sufficient air into the interior.
Note that the plurality of vent holes 140 may be formed in two or more rows along the axial direction. By forming the plurality of vent holes 140 in two or more rows along the axial direction, more air can be introduced into the interior as compared with a case where the plurality of vent holes 140 are formed in one row.
Furthermore, by reducing the amount of adhesive applied by use of the second sheet materials 120 shown in
In addition, reduction in amount of adhesive applied also reduces cost. Furthermore, the reduction in amount of adhesive applied reduces glue residue of the adhesive adhering to a manufacturing apparatus of the tubular body 100 and also reduces risk of stopping the manufacturing apparatus, so that a time for removing the glue residue can be shortened, and productivity of the tubular body 100 can be improved.
Next, a method for manufacturing the tubular body 100 will be described.
The sheet material 24 is cut out in the longitudinal direction in a cutting-out part 23. Specifically, the sheet material 24 is cut out into the first sheet material 110 having a first width and the second sheet material 120 having a second width. The cut-out first sheet material 110 and second sheet material 120 are conveyed in parallel via the direction changing rollers 41 and separated from each other with a lateral conveying roller 32.
After the direction changing rollers 41 change a direction of the second sheet material 120, a gluing part 25 applies the positioning adhesive layer 131, the first joint adhesive layer 132 and the second joint adhesive layer 133 (see
Subsequently, a humidification nozzle 26 humidifies the second sheet material 120 (humidification step). The humidification nozzle 26 injects water onto the surface of the second sheet material 120 with the positioning adhesive layer 131 applied thereto. Note that the humidification nozzle 26 may inject alcohol onto the second sheet material 120 in place of water or spray steam onto the second sheet material 120.
Thus, spots of the second sheet material 120 with the positioning adhesive layer 131, the first joint adhesive layer 132 and the second joint adhesive layer 133 applied thereto and the other spots have an equivalent humidity. In a subsequent step of molding the second sheet material 120 into a tubular shape, the material can be uniformly deformed, and the tubular body 100 having a high roundness can therefore be obtained.
In contrast, the first sheet material 110, separated from the second sheet material 120, is conveyed and positioned to be shifted in a lateral direction with respect to the conveying direction by a position shifting section 29. Afterward, a pair of tensile rollers 28 integrates the first sheet material 110 and the second sheet material 120 (bonding step).
Consequently, the first sheet material 110 and the second sheet material 120 are shifted from each other and bonded such that ends of the materials in a width direction perpendicular to the longitudinal direction do not overlap each other. Specifically, the positioning adhesive layer 131 and the first joint adhesive layer 132, applied to the second sheet material 120, bond the first body portion 111 and the second body portion 121 to each other (see
Note that the tubular body manufacturing apparatus 1 may include a sensor that detects the ends of the first sheet material 110 and second sheet material 120 in the width direction, and a control mechanism for controlling an amount of position shift between the first sheet material 110 and the second sheet material 120.
Next, the first sheet material 110 and second sheet material 120, shifted from each other and bonded, are conveyed to a molding device 30. In the molding device 30, an endless molding belt 43 is guided endlessly via a plurality of direction changing rollers 41. The first sheet material 110 and the second sheet material 120 conveyed to the molding device 30 are pressed onto the molding belt 43 by a pressing part 44.
Afterward, the molding device 30 molds the first sheet material 110 and the second sheet material 120 into a tubular continuous body 31, for example, by a known method described in Japanese Patent Laid-Open No. 2018-121628 (molding step). In this step, the second joint adhesive layer 133 applied to the second sheet material 120 bonds the first extending portion 112 and the second extending portion 122 to each other (see
Subsequently, the first sheet material 110 and second sheet material 120 molded into the tubular continuous body 31 are heated by a heating part 37, to thereby cure the positioning adhesive layer 131, the first joint adhesive layer 132 and the second joint adhesive layer 133. Furthermore, the second sheet material 120 humidified by the humidification nozzle 26 is also dried in the heating part 37.
Next, a cutting part 38 cuts, to a predetermined length, the first sheet material 110 and second sheet material 120 molded into the tubular continuous body 31 (cutting step), to form the tubular body 100. In the tubular body manufacturing apparatus 1, the first sheet material 110 and the second sheet material 120 may be replaced with each other.
Subsequently, the tubular body 100 is incorporated into a semi-finished product of the flavor generating article or the smoking article and then irradiated with laser beams from an outer circumference toward an inner circumference of the tubular body 100, and the materials at irradiated spots are combusted, to form a plurality of vent holes 140 extending through the tubular body 100 intermittently over an entire circumference in the circumferential direction.
Next, results of various experiments performed by use of the tubular body manufacturing apparatus 1 will be described. First, an experiment was performed to find out appropriate humidification conditions by the humidification nozzle 26.
As shown in
Subsequently, according to the level 6 shown in
Then, an experiment was performed on the tubular body 100 (see
Next, an experiment was performed while changing an application amount of the positioning adhesive layer 131, for the tubular body 100 (see
As a result, it was confirmed that an application amount of 20 g/500 m (4.8 mg/line) is appropriate for the tubular body 100 with the positioning glue applied spirally, and 25 g/500 m (3.0 mg/line×2) is appropriate for the tubular body 100 with the positioning glue applied in two lines.
As shown in
Subsequently, on the humidification conditions and with the application amount of the positioning adhesive layer 131 as shown in
Here, the physical properties of the tubular body 100 immediately after the formation of the tubular body 100 and after 24 hours were measured in consideration of influence of humidification by the humidification nozzle 26, for the tubular body 100 with the positioning glue applied spirally and the tubular body 100 with the positioning glue applied in two lines. In addition, moisture was measured after one week.
As shown in
It was also confirmed that both the tubular body 100 with the positioning glue applied spirally and the tubular body 100 with the positioning glue applied in two lines have roundness equivalent to that of the standard product. Furthermore, both the tubular body 100 with the positioning glue applied spirally and the tubular body 100 with the positioning glue applied in two lines have the same structure of a joint portion between the first extending portion 112 and the second extending portion 122 as in the conventional product and therefore indicate a value of joint peel strength equal to that of the conventional product.
In addition, by setting an area of the positioning adhesive layer 131 to 10% or more and 50% or less of an area of an overlapping portion between the first body portion and the second body portion, a tubular body capable of suppressing an adhering defect between the first sheet material 110 and the second sheet material 120 and having excellent roundness and less influence on flavor and smoking taste can be obtained.
As described above, embodiments of the present invention have been described, and the embodiments of the above-described invention are for facilitating understanding of the present invention and are not intended to limit the present invention. The present invention may be modified or improved without departing from its gist, and the present invention includes equivalents thereto. Furthermore, respective components described in the claims and the specification can be combined or omitted to such an extent that at least some of the above-described issues can be solved or at least some of effects are achieved.
The present invention contains subject matter related to PCT Application No. PCT/JP2022/016387 filed on Mar. 31, 2022, the entire contents of which are incorporated herein by reference.
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP2022/016387 | Mar 2022 | WO |
| Child | 18892540 | US |
