The present invention relates to equipment, primarily in thermal power plants, for generating active and reactive electric power for high-voltage distribution or transmission networks connected to it. More specifically the invention relates to rotating electromechanical equipment for generating electric power for high-voltage distribution or transmission networks without intermediate transformers. The generator or generators included in the equipment have a magnetic circuit, normally comprising a core of iron and an air gap, a cooling system and at least one, usually two, windings disposed in the stator and rotor, respectively.
Thermal power plants are nowadays built in accordance with a number different principles. Various types of fuel, e.g. natural gas, oil, bio-fuel, coal, mixtures of the fuels just mentioned, or nuclear fuel, are used in order to achieve high temperature in a gas in either a combustion process or a nuclear process. This gas may be either waste gases from the combustion or indirectly heated steam. The heating is performed in a relatively small volume, which means that the pressure is extremely high. The hot gas is then conveyed in gradually larger and larger volumes, the thermal energy then being converted to kinetic energy. The fast-moving gas is allowed in a number of steps to influence the vanes in a turbine, thereby giving rise to a turning phase. At least one generator mounted on the same shaft as the turbine, or via a gear, converts the energy to electric power which, via a step-up transformer, is emitted to distribution or transmission networks, hereinafter also termed power networks.
Power plants consisting of only one unit in accordance with one of the principles explained above can naturally be the best solution in certain cases. However, a plant is often advantageously built up of more units. This offers greater flexibility and robustness against interference in the equipment, various units may also be designed for operation with different types of fuel so that the fuel that is currently cheapest can be used. Other combinations are possible to increase the total efficiency of the plant, where residual heat from one unit can be utilized by another.
A distinction is normally made between two types of turbines: gas turbines and steam turbines. Gas turbines are operated directly by combustion gases (possibly after cleaning), whereas steam turbines, as the name implies, are operated by steam heated to high pressure.
Vital parts of a gas turbine unit include at least one compressor step, a combustion chamber, at least one turbine step and a generator. In many cases it is advantageous for the actual turbine step to be in several steps in order to enable optimal utilization of the thermal energy. Each step is dimensioned for the pressure the gas has in the relevant part of the turbine. Typically a high and a low pressure part are used, or a high, an intermediate and a low pressure part. The compressor may also be designed in several steps, normally two. The pressure in the compressor step is adjusted in order to obtain optimal combustion. The air entering the combustion chamber is pre-heated.
Vital parts of a steam turbine unit include a combustion or reactor hearth, steam generator, steam turbine and an electric generator. The steam generator consists typically of steel pipes with water circulating in them, which pipes are located in the hearth in order to obtain optimal heat transfer. The steam, heated to high temperature and high pressure, is conveyed to the turbine. The steam turbine can also advantageously be divided into various sections in the same way as described above, depending on pressure.
In order to achieve the highest possible efficiency, a combination of both these turbine types is advantageously used in two steps, i.e. a combined cycle power plant. For example, a gas turbine power plant which generates most of its power via a gas turbine, is supplemented by a steam generator which utilizes residual heat in the waste gases after the last turbine step, thus obtaining additional energy yield. A coal power plant of PFBC (Pressurized Fluidized Bed Combustion) type, which today represents the best that can be achieved as regards efficiency and environmentally friendly combustion of coal, generates the majority of its electric energy via a steam generator in the hearth. The combustion gases, somewhat cooled after the steam generation, are conveyed to a gas turbine after dust separation.
Many power plants are also used for district heating and in many cases an extremely high degree of total efficiency is attainable.
Examples of relevant plant types are described below. A gas turbine in these plants is fired with gas (preferably natural gas), oil or a combination of gas and oil.
Gas Turbine Power Plant
A plant consisting of one or more units, each comprising one gas turbine and associated generator.
Combined Cycle Multi-Shaft Gas Turbine Power Plant
A plant consisting of one or more units, each comprising a gas turbine and associated electric generator, in which the hot gases from the gas turbines are conveyed to a heat exchanger for steam generation. The steam drives a steam turbine and associated electric generator.
Combined Cycle Single-Shaft Gas Turbine Power Plant
A plant consisting of one or more units, each comprising a gas turbine and associated electric generator, in which the hot gases from the gas turbines are conveyed to a heat exchanger for steam generation. The steam drives a steam turbine connected to the “free end” of one of the gas turbines.
Steam Power Plant
A plant in which a combustion process (such as oil, coal, PFBC, bio-fuel) via a steam generator (pipes conveying water which are located in the hearth) generates a steam pressure which drives a steam turbine and associated electric generator.
Nuclear Power Plant
A plant similar to the steam power plant but with the steam generator located in a nuclear reactor hearth.
Common to all the power plants described above is the connection of an electric generator via a common shaft, or via a gear, to the turbine for conversion to electric power. An electric generator may also be connected to two turbines. The conversion usually takes place in a synchronous generator which can be used for generating reactive power as well as for converting active power. Usually these are 2-pole or 4-pole electric generators of turbo-generator type, but other pole numbers and embodiments exist. A typical voltage range for today's generators is 10-30 kV.
An intermediate unit is used to enable reliable connection of the generator to an out-going power network. As is clear from
An alternative to allowing the step-up transformer 106 of each generator 100 be connected directly to the out-going power network 110 is to use the step-up transformer to transform the generator voltage to an intermediate voltage level and then connect this intermediate voltage level via a system transformer to the out-going power network 110. In a limited area or a plant with several units, this may offer a cheaper total solution, particularly if the power in each unit is slight in relation to the voltage level of the out-going power network.
The drawbacks of the above solutions are related to the low voltage level (10-30 kV) of the generator. The busbar systems must be dimensioned with a large copper area to keep down the losses. The generator breaker 107 becomes large and expensive in order to break the high currents resulting from the low voltage. The step-up transformer 106 is expensive and also constitutes a safety risk. It also causes deteriorated efficiency.
The magnetic circuit in individual electric generators usually comprises a laminated core, e.g. of sheet steel with a welded construction. To provide ventilation and cooling the core is often divided into stacks with radial and/or axial ventilation ducts. For larger machines the laminations are punched out in segments which are attached to the frame of the machine, the laminated core being held together by pressure fingers and pressure rings. The winding of the magnetic circuit is disposed in slots in the core, the slots generally having a cross section in the shape of a rectangle or trapezium.
In multi-phase electric generators the windings are made as either single or double layer windings. With single layer windings there is only one coil side per slot, whereas with double layer windings there are two coil sides per slot. By coil side is meant one or more conductors combined vertically or horizontally and provided with a common coil insulation, i.e. an insulation designed to withstand the rated voltage of the generator to earth.
Double-layer windings are generally made as diamond windings whereas single layer windings in the present context can be made as diamond or flat windings. Only one (possibly two) coil width exists in diamond windings whereas flat windings are made as concentric windings, i.e. with widely varying coil width. By coil width is meant the distance in arc dimension between two coil sides pertaining to the same coil.
Normally all large machines are made with double-layer winding and coils of the same size. Each coil is placed with one side in one layer and the other side in the other layer. This means that all coils cross each other in the coil end. If there are more than two layers these crossings complicate the winding work and the coil end is less satisfactory.
It is considered that coils for rotating generators can be manufactured with good results within a voltage range of 10-20 kV.
Attempts to develop the generator for higher voltages however, however, been in progress for a long time. This is obvious, for instance from “Electrical World”, Oct. 15, 1932, pages 524-525. This describes how a generator designed by Parson 1929 was arranged for 33 kV. It also describes a generator in Langerbrugge, Belgium, which produced a voltage of 36 kV. Although the article also speculates on the possibility of increasing voltage levels still further, the development was curtailed by the concepts upon which these generators were based. This was primarily because of the shortcomings of the insulation system where varnish-impregnated layers of mica oil and paper were used in several separate layers.
Some attempts at a new approach as regards the design of synchronous generators are described, for instance, in an article “Water-and-oil-cooled Turbo-generator TVM-300” in J. Elektrotechnika, No. 1, 1970, pages 6-8 in U.S. Pat. No. 4,429,244 “Stator of generator” and in Russian patent specification CCCP Parent 955369.
The water-and-oil-cooled synchronous machine described in J. Elektrotechnika is intended for voltages of up to 20 kV. The article describes a new insulation system consisting of oil/paper insulation, allowing the stator to be entirely immersed in oil. The oil can then be used as coolant while also serving as insulation. To prevent oil in the stator from leaking out to the rotor, a dielectric-oil-separating ring is provided at the internal surface of the core. The stator winding is manufactured from conductors with an oval, hollow shape, provided with oil and paper insulation. The coil sides with their insulation are retained in the slots formed with rectangular cross section by means of wedges. Oil is used as coolant both in the hollow conductors and in apertures in the stator walls. However, such cooling systems entail a large number of connections for both oil and electricity at the coil ends. The thick insulation also causes increased radius of curvature on the conductors, which in turn results in increased size for the coil overhang.
The above-mentioned US patent relates to the stator part of a synchronous machine comprising a magnetic core of laminated plate with trapezium-shaped slots for the stator winding. The slots are stepped since the need for insulation in the stator winding is less in towards the rotor where the part of the winding nearest the neutral point is located. The stator part also includes a dielectric oil-separating cylinder nearest the inner surface of the core. This part may require more excitation than a machine without this ring. The stator winding is manufactured from oil-saturated cables having the same diameter for each coil layer. The layers are separated from each other by means of spacer elements in the slots, and secured with wedges. Specific to the winding is that it consists of two so-called half-windings connected in series. One of these two half-windings is placed centrally inside an insulating sleeve. The conductors of the stator winding are cooled by the surrounding oil. A drawback with so much oil in the system is the risk of leakage and the major clean-up work necessary after a fault condition. The parts of the insulation sheath located outside the slots have a cylindrical part and a conical screen electrode, the purpose of which is to control the electric field strength in the area where the cable leaves the laminations.
CCCP 955369 reveals in another attempt to increase the rated voltage of the synchronous machine, that the oil-cooled stator winding consists of a high-voltage cable having the same dimension for all layers. The cable is placed in stator slots shaped as circular, radially located openings corresponding to the cross-sectional area of the cable and space required for fixing and coolant. The various radially placed layers of the winding are surrounded by and secured in insulating tubes. Insulating spacer elements fix the tubes in the stator slot. Here too, because of the oil cooling, an inner dielectric ring is required to seal the oil coolant from the inner air gap. The construction shows no stepping of the insulation or of the stator slots. The design shows a very small radial waist between the various stator slots, entailing a large slot stray flux which strongly affects the excitation requirement of the machine.
In a report from the Electric Power Research Institute, EPRI, EL-3391 from April 1984, an account is given of generator concepts for achieving higher voltage in an electric generator with the object of being able to connect such a generator to a power network without intermediate transformers. Such a solution is assessed in the report to offer good gains in efficiency and considerable financial advantages. The main reason that it was deemed possible in 1984 to start developing generators for direct connection to power networks was that a supra-conducting rotor had been developed at that time. The considerable excitation capacity of the supra-conducting field enables the use of airgap-winding with sufficient thickness to withstand the electrical stresses.
By combining the concept deemed most promising according to the project, that of designing a magnetic circuit with winding, known as “monolithe cylinder armature”, a concept in which two cylinders of conductors are enclosed in three cylinders of insulation and the whole structure is attached to an iron core without teeth, it was assessed that a rotating electric machine for high voltage could be directly connected to a power network. The solution entailed the main insulation having to be made sufficiently thick to withstand network-to-network and network-to-earth potentials. Obvious drawbacks with the proposed solution, besides its demanding a supra-conducting rotor, are that it also requires extremely thick insulation, which increases the machine size. The coil ends must be insulated and cooled with oil or freones in order to control the large electric fields at the ends. The whole machine must be hermetically enclosed in order to prevent the liquid dielectric medium from absorbing moisture from the atmosphere.
Against this background the object of the invention is to provide a plant comprising at least one generator for such a high voltage that the step-up transformer becomes superfluous. The generator breaker then also becomes superfluous. Functionally this is replaced by the already existing high-voltage breaker. The busbar system is replaced with screened high-voltage cable. It is thus an object of the invention to connect the electric generators in a power plant directly to the out-going power network.
This object has been achieved according to the invention from a first aspect in that a plant of the type described in the preamble to claim 1 comprises the special features defined in the characterizing part of this claim, from a second aspect in that a generator of the type described in the preamble to claim 29 comprises the special features defined in the characterizing part of this claim, and through the procedure described in claim 31.
Thanks to this design of the insulation system for the winding, the decomposition of the insulation is avoided which tends to appear in the relatively thick-walled insulating layers used conventionally for high-voltage generators, e.g. impregnated layers of mica tape, which decomposition is in some part caused by partial discharges, PD. Inner corona discharges occur in cavities, pores and the like which are present in these conventional insulations, and which arise during manufacture, when the insulation is subjected to excessive electrical field strengths. These corona discharges gradually break down the material and may result in electrical disruptive discharge through the insulation. Other defects, cracks or the like, occurring at thermal movement in the winding are avoided, thanks to the temperature coefficients of the layers being substantially equal. These problems constitute an important reason for it having been impossible to design generators for the voltage range above 36 kV previously.
This problem has been eliminated by the insulation system according to the invention. The insulation system according to the invention can be achieved by using layers for the insulation which are manufactured in such a way that the risk of cavities and pores is minimal, e.g. extruded layers of suitable permanent insulating material, such as PEX, thermo-plastics, including cross-linked thermo-plastics, EP rubber, other types of rubber, etc. By using only insulating layers which can be produced with a minimum of defects and also providing the insulation with an inner and an outer semiconducting part, it can be ensured that the thermal and electrical loading is reduced. In the event of temperature gradients, the insulating part with semiconducting layers will constitute a monolithic part and defects caused by different expansion due to temperature in the insulation and surrounding layers will not occur. The electrical load on the material decreases as a result of the semiconducting parts around the insulation constituting equipotential surfaces and of the electrical field in the insulation part thus being distributed uniformly over the thickness of the insulation. The outer semiconducting layer can be connected to earth potential. This means that, for such a cable, the outer sheath of the winding can be maintained at earth potential along its entire length.
The special features of a plant according to the invention, particularly as relating to the insulation system for the winding in the generator stator, have thus eliminated the obstacles preventing an increase in voltage level, and enable elimination of the step-up transformer even for voltages above 36 kV, with the associated advantages.
In the first place the mere absence of a transformer entails great savings in weight, space and expense.
When the transformer, as is often the case, is arranged at a distance from the turbine hall, busbars are required to connect generator and transformer. The need for these is thus also eliminated which saves not only the expense and space they require the power losses in these, which are considerable since the current is high, also disappear in busbar systems 2-phase and 3-phase faults can occur and the breakers and isolators required therefor demand a high level of maintenance. By the present invention the risk for these faults has been greatly reduced.
The fire risk entailed with an oil-insulated transformer is also reduced, thereby reducing the necessity for safety precautions against fire.
The turbo-generator plant according to the invention also has the advantage that it can be arranged with several connections to different voltage levels.
In all, the advantages mentioned above constitute radically improved total economy for the plant. The costs of building the plant are dramatically reduced and operating economy is improved by less need of service and maintenance and by an increase in the efficiency of approximately 0.5-1.5%.
The invention is also applicable and entails advantages for a turbo-generator for peak loads, used as synchronous compensator when necessary, so that the generator is disconnected from the turbine.
The purpose of the invention is also that auxiliary power shall be generated by the generator by means of an auxiliary power winding inserted in its stator, which gives considerably lower voltage than is generated by the main winding of the generator.
To accomplish this the magnetic circuit in the generator or generators included in the turbo-generator plant is formed with threaded permanent insulating cable with included earth.
The major and essential difference between known technology and the embodiment according to the invention is thus that this is achieved with a magnetic circuit included in an electric generator which is arranged to be directly connected via possible breakers and isolators to a high supply voltage in the vicinity of between 20 and 800 kV, preferably higher than 36 kV. The magnetic circuit thus comprises a laminated core having at least one winding consisting of a threaded cable with one or more permanently insulated conductors having a semiconducting layer both at the conductor and outside the insulation, the outer semiconducting layer being connected to earth potential.
To solve the problems arising with direct connection of electric machines to all types of high-voltage power networks, the generator in the plant according to the invention has a number of features as mentioned above, which differ distinctly from known technology. Additional features and further embodiments are defined in the dependent claims and are discussed in the following.
Such features mentioned above and other essential characteristics or the generator and thus of the turbo-generator plant according to the invention include the following:
The winding of the magnetic circuit is produced from a cable having one or more permanently insulated conductors with a semiconducting layer at both conductor and sheath. Some typical conductors of this type are PEX cable or a cable with EP rubber insulation which, however, for the present purpose are further developed both as regards the strands in the conductor and the nature of the outer sheath. PEX crosslinked polyethylene (XLPE) EP=ethylene propylene.
Cables with circular cross section are preferred, but cables with some other cross section may be used in order to obtain better packing density, for instance.
Such a cable allows the laminated core to be designed according to the invention in a new and optimal way as regards slots and teeth.
The winding is preferably manufactured with insulation in steps for best utilization of the laminated core.
The winding is preferably manufactured as a multi-layered, concentric cable winding, thus enabling the number of coil-end intersections to be reduced.
The slot design is suited to the cross section of the winding cable so that the slots are in the form of a number of cylindrical openings running axially and/or radially outside each other and having an open waist running between the layers of the stator winding.
The design of the slots is adjusted to the relevant cable cross section and to the stepped insulation of the winding. The stepped insulation allows the magnetic core to have substantially constant tooth width, irrespective of the radial extension.
The above-mentioned further development as regards the strands entails the winding conductors consisting of a number of impacted strata/layers, i.e. insulated strands that from the point of view of an electric machine, are not necessarily correctly transposed, uninsulated and/or insulated from each other.
The above-mentioned further development as regards the outer sheath entails that at suitable points along the length of the conductor, the outer sheath is cut off, each cut partial length being connected directly to earth potential.
The use of a cable of the type described above allows the entire length of the outer sheath of the winding, as well as other parts of the plant, to be kept at earth potential. An important advantage is that the electric field is close to zero within the coil-end region outside the outer semiconducting layer. With earth potential on the outer sheath the electric field need not be controlled. This means that no field concentrations will occur either in the core, in the coil-end regions or in the transition between them.
The mixture of insulated and/or uninsulated impacted strands, or transposed strands, results in low stray losses.
The cable for high voltage used in the magnetic circuit winding is constructed of an inner core/conductor with a plurality of strands, at least two semiconducting layers, the innermost being surrounded by in insulating layer, which is in turn surrounded by an outer semiconducting layer having an outer diameter in the order of 20-200 mm and a conductor area in the order of 50-3000 mm2.
Since the generator in a plant according to the invention is manufactured with the special insulation system, the stator need not be completed at the factory but can instead be delivered divided axially into sections and the winding threaded on site. This naturally gives obvious financial advantages from the transport point of view.
The invention thus also relates to a procedure in which this possibility is exploited.
From another aspect of the invention, the objectives listed have been achieved in that a plant of the type described in the preamble to claim 29 is given the special features defined in the characterizing part of this claim.
Since the insulation system, suitably permanent, is designed so that from the thermal and electrical point of view it is dimensioned for over 36 kV, the plant can be connected to high-voltage power networks without any intermediate step-up transformer, thereby achieving the advantages referred to. Such a plant is preferably, but not necessarily, constructed to include the features defined for the plant as claimed in any of claims 1-28.
The above-mentioned and other advantageous embodiments of the invention are defined in the dependent claims.
The invention will be described in more detail in the following detailed description of a preferred embodiment of the construction of the magnetic circuit of the electric generator in the turbo-generator plant, with reference to the accompanying drawings in which
In the schematic axial view through a sector of the stator 1 according to
The cables 6 are illustrated schematically in
A turbo-generator plant constructed in accordance with known technology is shown in
In the known turbo-generator plant the generator 100 normally generates a voltage of maximally 25-30 kV. To supply a high-voltage distribution or transmission network 110, normally supplying voltages of up to 800 kV, the output voltage from the known generator 100 must be stepped up, as illustrated by the step-up transformer 106. This also requires a generator breaker 107 to be connected between the generator 100 and the step-up transformer 106, which generator breaker comprises at least one set of isolators, power breakers and earth connectors.
Connection to the distribution or transmission network 110 is via additional isolators, breakers and flashover protection, here jointly designated 108.
The output voltage of the generator, lying at a medium voltage level of 25-30 kV, Is usually also branched off to a step-down transformer 109. The step-down transformer 109 supplies the generator 100 with excitation voltage via a rectifier circuit 111 and is also able to generate low voltage 112 for other requirements.
The step-down transformer 109 shown in
As can be seen in
With the turbo-generator arrangement according to the present invention, therefore, several transformer and breaker units that were previously necessary are eliminated which is obviously advantageous—not least from the expense and operating reliability aspects.
Number | Date | Country | Kind |
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9602079 | May 1996 | SE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/SE99/00886 | 5/27/1997 | WO | 00 | 4/10/1998 |
Publishing Document | Publishing Date | Country | Kind |
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WO97/45924 | 12/4/1997 | WO | A |
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4317001 | Silver et al. | Feb 1982 | A |
4320645 | Stanley | Mar 1982 | A |
4321426 | Schaeffer et al. | Mar 1982 | A |
4321518 | Akamatsu | Mar 1982 | A |
4330726 | Albright et al. | May 1982 | A |
4337922 | Streiff et al. | Jul 1982 | A |
4341989 | Sandberg et al. | Jul 1982 | A |
4347449 | Beau | Aug 1982 | A |
4347454 | Gellert et al. | Aug 1982 | A |
4353612 | Meyers | Oct 1982 | A |
4357542 | Kirschbaum | Nov 1982 | A |
4360749 | Neumann et al. | Nov 1982 | A |
4361723 | Hvizd, Jr. et al. | Nov 1982 | A |
4365178 | Lexz | Dec 1982 | A |
4367425 | Mendelsohn et al. | Jan 1983 | A |
4367890 | Spirk | Jan 1983 | A |
4368418 | Demello et al. | Jan 1983 | A |
4369389 | Lambrecht | Jan 1983 | A |
4371745 | Sakashita | Feb 1983 | A |
4384944 | Silver et al. | May 1983 | A |
4387316 | Katsekas | Jun 1983 | A |
4401920 | Taylor et al. | Aug 1983 | A |
4403163 | Rarmerding et al. | Sep 1983 | A |
4404486 | Keim et al. | Sep 1983 | A |
4411710 | Mochizuki et al. | Oct 1983 | A |
4421284 | Pan | Dec 1983 | A |
4425521 | Rosenberry, Jr. et al. | Jan 1984 | A |
4426771 | Wang et al. | Jan 1984 | A |
4429244 | Nikitin et al. | Jan 1984 | A |
4431960 | Zucker | Feb 1984 | A |
4432029 | Lundqvist | Feb 1984 | A |
4437464 | Crow | Mar 1984 | A |
4443725 | Derderian et al. | Apr 1984 | A |
4470884 | Carr | Sep 1984 | A |
4473765 | Butman, Jr. et al. | Sep 1984 | A |
4475075 | Munn | Oct 1984 | A |
4477690 | Nikitin et al. | Oct 1984 | A |
4481438 | Keim | Nov 1984 | A |
4484106 | Taylor et al. | Nov 1984 | A |
4488079 | Dailey et al. | Dec 1984 | A |
4490651 | Taylor et al. | Dec 1984 | A |
4503284 | Minnick et al. | Mar 1985 | A |
4508251 | Harada et al. | Apr 1985 | A |
4510077 | Elton | Apr 1985 | A |
4517471 | Sachs | May 1985 | A |
4520287 | Wang et al. | May 1985 | A |
4523249 | Arimoto | Jun 1985 | A |
4538131 | Baier et al. | Aug 1985 | A |
4546210 | Akiba et al. | Oct 1985 | A |
4551780 | Canay | Nov 1985 | A |
4557038 | Wcislo et al. | Dec 1985 | A |
4560896 | Vogt et al. | Dec 1985 | A |
4565929 | Baskin et al. | Jan 1986 | A |
4571453 | Takaoka et al. | Feb 1986 | A |
4588916 | Lis | May 1986 | A |
4590416 | Porche et al. | May 1986 | A |
4594630 | Rabinowitz et al. | Jun 1986 | A |
4607183 | Rieber et al. | Aug 1986 | A |
4615109 | Wcislo et al. | Oct 1986 | A |
4615778 | Elton | Oct 1986 | A |
4618795 | Cooper et al. | Oct 1986 | A |
4619040 | Wang et al. | Oct 1986 | A |
4622116 | Elton et al. | Nov 1986 | A |
4633109 | Feigel | Dec 1986 | A |
4650924 | Kauffman et al. | Mar 1987 | A |
4652963 | Fahlen | Mar 1987 | A |
4656316 | Meltsch | Apr 1987 | A |
4656379 | McCarty | Apr 1987 | A |
4677328 | Kumakura | Jun 1987 | A |
4687882 | Stone et al. | Aug 1987 | A |
4692731 | Osinga | Sep 1987 | A |
4723083 | Elton | Feb 1988 | A |
4723104 | Rohatyn | Feb 1988 | A |
4724345 | Elton et al. | Feb 1988 | A |
4732412 | van der Linden et al. | Mar 1988 | A |
4737704 | Kalinnikov et al. | Apr 1988 | A |
4745314 | Nakano | May 1988 | A |
4761602 | Leibovich | Aug 1988 | A |
4766365 | Bolduc et al. | Aug 1988 | A |
4771168 | Gundersen et al. | Sep 1988 | A |
4785138 | Breitenbach et al. | Nov 1988 | A |
4795933 | Sakai | Jan 1989 | A |
4827172 | Kobayashi | May 1989 | A |
4845308 | Womack, Jr. et al. | Jul 1989 | A |
4847747 | Abbondanti | Jul 1989 | A |
4853565 | Elton et al. | Aug 1989 | A |
4859810 | Cloetens et al. | Aug 1989 | A |
4859989 | McPherson | Aug 1989 | A |
4860430 | Raschbichler et al. | Aug 1989 | A |
4864266 | Feather et al. | Sep 1989 | A |
4883230 | Lindstrom | Nov 1989 | A |
4890040 | Gundersen | Dec 1989 | A |
4894284 | Yamanouchi et al. | Jan 1990 | A |
4914386 | Zocholl | Apr 1990 | A |
4918347 | Takaba | Apr 1990 | A |
4918835 | Wcislo et al. | Apr 1990 | A |
4924342 | Lee | May 1990 | A |
4926079 | Niemela et al. | May 1990 | A |
4942326 | Butler, III et al. | Jul 1990 | A |
4949001 | Campbell | Aug 1990 | A |
4982147 | Lauw | Jan 1991 | A |
4994952 | Silva et al. | Feb 1991 | A |
4997995 | Simmons et al. | Mar 1991 | A |
5012125 | Conway | Apr 1991 | A |
5030813 | Stanisz | Jul 1991 | A |
5036165 | Elton et al. | Jul 1991 | A |
5036238 | Tajima | Jul 1991 | A |
5066881 | Elton et al. | Nov 1991 | A |
5067046 | Elton et al. | Nov 1991 | A |
5083360 | Valencic et al. | Jan 1992 | A |
5086246 | Dymond et al. | Feb 1992 | A |
5091609 | Swada et al. | Feb 1992 | A |
5094703 | Takaoka et al. | Mar 1992 | A |
5095175 | Yoshida et al. | Mar 1992 | A |
5097241 | Smith et al. | Mar 1992 | A |
5097591 | Wcislo et al. | Mar 1992 | A |
5111095 | Hendershot | May 1992 | A |
5124607 | Rieber et al. | Jun 1992 | A |
5136459 | Fararooy | Aug 1992 | A |
5140290 | Dersch | Aug 1992 | A |
5153460 | Bovino et al. | Oct 1992 | A |
5168662 | Nakamura et al. | Dec 1992 | A |
5171941 | Shimizu et al. | Dec 1992 | A |
5182537 | Thuis | Jan 1993 | A |
5187428 | Hutchison et al. | Feb 1993 | A |
5231249 | Kimura et al. | Jul 1993 | A |
5235488 | Koch | Aug 1993 | A |
5246783 | Spenadel et al. | Sep 1993 | A |
5264778 | Kimmel et al. | Nov 1993 | A |
5287262 | Klein | Feb 1994 | A |
5304883 | Denk | Apr 1994 | A |
5305961 | Errard et al. | Apr 1994 | A |
5321308 | Johncock | Jun 1994 | A |
5323330 | Asplund et al. | Jun 1994 | A |
5325008 | Grant | Jun 1994 | A |
5325259 | Paulsson | Jun 1994 | A |
5327637 | Britenbach et al. | Jul 1994 | A |
5341281 | Skibinski | Aug 1994 | A |
5343139 | Gyugyi et al. | Aug 1994 | A |
5355046 | Weigelt | Oct 1994 | A |
5365132 | Hann et al. | Nov 1994 | A |
5387890 | Estop et al. | Feb 1995 | A |
5397513 | Steketee, Jr. | Mar 1995 | A |
5399941 | Grothaus et al. | Mar 1995 | A |
5400005 | Bobry | Mar 1995 | A |
5408169 | Jeanneret | Apr 1995 | A |
5449861 | Fujino et al. | Sep 1995 | A |
5452170 | Ohde et al. | Sep 1995 | A |
5468916 | Litenas et al. | Nov 1995 | A |
5499178 | Mohan | Mar 1996 | A |
5500632 | Halser, III | Mar 1996 | A |
5510942 | Bock et al. | Apr 1996 | A |
5530307 | Horst | Jun 1996 | A |
5533658 | Benedict et al. | Jul 1996 | A |
5534754 | Poumey | Jul 1996 | A |
5545853 | Hildreth | Aug 1996 | A |
5550410 | Titus | Aug 1996 | A |
5583387 | Takeuchi et al. | Dec 1996 | A |
5587126 | Steketee, Jr. | Dec 1996 | A |
5598137 | Alber et al. | Jan 1997 | A |
5607320 | Wright | Mar 1997 | A |
5612510 | Hildreth | Mar 1997 | A |
5654602 | Willyoung | Aug 1997 | A |
5663605 | Evans et al. | Sep 1997 | A |
5689223 | Demarmels et al. | Nov 1997 | A |
5807447 | Forrest | Sep 1998 | A |
5834699 | Buck et al. | Nov 1998 | A |
6572926 | Morgan et al. | Jun 2003 | B1 |
Number | Date | Country |
---|---|---|
399790 | Jul 1995 | AT |
565063 | Feb 1957 | BE |
391071 | Apr 1965 | CH |
SU 266037 | Oct 1965 | CH |
534448 | Feb 1973 | CH |
539328 | Jul 1973 | CH |
SU 646403 | Feb 1979 | CH |
657482 | Aug 1986 | CH |
SU 1189322 | Oct 1986 | CH |
40414 | Aug 1887 | DE |
277012 | Jul 1914 | DE |
336418 | Jun 1920 | DE |
372390 | Mar 1923 | DE |
386561 | Dec 1923 | DE |
387973 | Jan 1924 | DE |
406371 | Nov 1924 | DE |
425551 | Feb 1926 | DE |
426793 | Mar 1926 | DE |
432169 | Jul 1926 | DE |
433749 | Sep 1926 | DE |
435608 | Oct 1926 | DE |
435609 | Oct 1926 | DE |
441717 | Mar 1927 | DE |
443011 | Apr 1927 | DE |
460124 | May 1928 | DE |
482506 | Sep 1929 | DE |
501181 | Jul 1930 | DE |
523047 | Apr 1931 | DE |
568508 | Jan 1933 | DE |
572030 | Mar 1933 | DE |
584639 | Sep 1933 | DE |
586121 | Oct 1933 | DE |
604972 | Nov 1934 | DE |
629301 | Apr 1936 | DE |
673545 | Mar 1939 | DE |
719009 | Mar 1942 | DE |
846583 | Aug 1952 | DE |
875227 | Apr 1953 | DE |
975999 | Jan 1963 | DE |
1465719 | May 1969 | DE |
1807391 | May 1970 | DE |
2050674 | May 1971 | DE |
1638176 | Jun 1971 | DE |
2155371 | May 1973 | DE |
2400698 | Jul 1975 | DE |
2520511 | Nov 1976 | DE |
2656389 | Jun 1978 | DE |
2721905 | Nov 1978 | DE |
137164 | Aug 1979 | DE |
138840 | Nov 1979 | DE |
2824951 | Dec 1979 | DE |
2835386 | Feb 1980 | DE |
2839517 | Mar 1980 | DE |
2854520 | Jun 1980 | DE |
3009102 | Sep 1980 | DE |
2913697 | Oct 1980 | DE |
2920478 | Dec 1980 | DE |
3028777 | Mar 1981 | DE |
2939004 | Apr 1981 | DE |
3006382 | Aug 1981 | DE |
3008818 | Sep 1981 | DE |
209313 | Apr 1984 | DE |
3305225 | Aug 1984 | DE |
3309051 | Sep 1984 | DE |
3441311 | May 1986 | DE |
3543106 | Jun 1987 | DE |
2917717 | Aug 1987 | DE |
3612112 | Oct 1987 | DE |
3726346 | Feb 1989 | DE |
3925337 | Feb 1991 | DE |
4023903 | Nov 1991 | DE |
4022476 | Jan 1992 | DE |
4233558 | Mar 1994 | DE |
4402184 | Aug 1995 | DE |
4409794 | Aug 1995 | DE |
4412761 | Oct 1995 | DE |
4420322 | Dec 1995 | DE |
19620906 | Jan 1996 | DE |
4438186 | May 1996 | DE |
19020222 | Mar 1997 | DE |
19547229 | Jun 1997 | DE |
468827 | Jul 1997 | DE |
134022 | Dec 2001 | DE |
049104 | Apr 1982 | EP |
0493704 | Apr 1982 | EP |
0056580 | Jul 1982 | EP |
078908 | May 1983 | EP |
0102513 | Mar 1984 | EP |
0120154 | Oct 1984 | EP |
0130124 | Jan 1985 | EP |
0142813 | May 1985 | EP |
0155405 | Sep 1985 | EP |
0102513 | Jan 1986 | EP |
0174783 | Mar 1986 | EP |
0185788 | Jul 1986 | EP |
0277358 | Aug 1986 | EP |
0234521 | Sep 1987 | EP |
0244069 | Nov 1987 | EP |
0246377 | Nov 1987 | EP |
0265868 | May 1988 | EP |
0274691 | Jul 1988 | EP |
0280759 | Sep 1988 | EP |
0282876 | Sep 1988 | EP |
0309096 | Mar 1989 | EP |
0314860 | May 1989 | EP |
0316911 | May 1989 | EP |
0317248 | May 1989 | EP |
0335430 | Oct 1989 | EP |
0342554 | Nov 1989 | EP |
0221404 | May 1990 | EP |
0375101 | Jun 1990 | EP |
0406437 | Jan 1991 | EP |
0439410 | Jul 1991 | EP |
0440865 | Aug 1991 | EP |
0469155 | Feb 1992 | EP |
0490705 | Jun 1992 | EP |
0503817 | Sep 1992 | EP |
0571155 | Nov 1993 | EP |
0620570 | Oct 1994 | EP |
0620630 | Oct 1994 | EP |
0642027 | Mar 1995 | EP |
0671632 | Sep 1995 | EP |
0676777 | Oct 1995 | EP |
0677915 | Oct 1995 | EP |
0684679 | Nov 1995 | EP |
0684682 | Nov 1995 | EP |
0695019 | Jan 1996 | EP |
0732787 | Sep 1996 | EP |
0738034 | Oct 1996 | EP |
0739087 | Oct 1996 | EP |
0740315 | Oct 1996 | EP |
0749190 | Dec 1996 | EP |
0751605 | Jan 1997 | EP |
0739087 | Mar 1997 | EP |
0749193 | Mar 1997 | EP |
0780926 | Jun 1997 | EP |
0802542 | Oct 1997 | EP |
0913912 | May 1999 | EP |
805544 | Apr 1936 | FR |
841351 | Jan 1938 | FR |
847899 | Dec 1938 | FR |
916959 | Dec 1946 | FR |
1011924 | Apr 1949 | FR |
1126975 | Mar 1955 | FR |
1238795 | Jul 1959 | FR |
2108171 | May 1972 | FR |
2251938 | Jun 1975 | FR |
2305879 | Oct 1976 | FR |
2376542 | Jul 1978 | FR |
2467502 | Apr 1981 | FR |
2481531 | Oct 1981 | FR |
2556146 | Jun 1985 | FR |
2594271 | Aug 1987 | FR |
2708157 | Jan 1995 | FR |
123906 | Mar 1919 | GB |
268271 | Mar 1927 | GB |
293861 | Nov 1928 | GB |
292999 | Apr 1929 | GB |
319313 | Jul 1929 | GB |
518993 | Mar 1940 | GB |
537609 | Jun 1941 | GB |
540456 | Oct 1941 | GB |
589071 | Jun 1947 | GB |
666883 | Feb 1952 | GB |
685416 | Jan 1953 | GB |
702892 | Jan 1954 | GB |
715226 | Sep 1954 | GB |
723457 | Feb 1955 | GB |
739962 | Nov 1955 | GB |
763761 | Dec 1956 | GB |
805721 | Dec 1958 | GB |
827600 | Feb 1960 | GB |
854728 | Nov 1960 | GB |
870583 | Jun 1961 | GB |
913386 | Dec 1962 | GB |
965741 | Aug 1964 | GB |
992249 | May 1965 | GB |
1024583 | Mar 1966 | GB |
1053337 | Dec 1966 | GB |
1059123 | Feb 1967 | GB |
1103098 | Feb 1968 | GB |
1103099 | Feb 1968 | GB |
1117401 | Jun 1968 | GB |
1135242 | Dec 1968 | GB |
1147049 | Apr 1969 | GB |
1157885 | Jul 1969 | GB |
1174659 | Dec 1969 | GB |
1236082 | Jun 1971 | GB |
1268770 | Mar 1972 | GB |
1319257 | Jun 1973 | GB |
1322433 | Jul 1973 | GB |
1340983 | Dec 1973 | GB |
1341050 | Dec 1973 | GB |
1365191 | Aug 1974 | GB |
1395152 | May 1975 | GB |
1424982 | Feb 1976 | GB |
1426594 | Mar 1976 | GB |
1438610 | Jun 1976 | GB |
1445284 | Aug 1976 | GB |
1479904 | Jul 1977 | GB |
1493163 | Nov 1977 | GB |
1502938 | Mar 1978 | GB |
1525745 | Sep 1978 | GB |
2000625 | Jan 1979 | GB |
1548633 | Jul 1979 | GB |
2046142 | Nov 1979 | GB |
2022327 | Dec 1979 | GB |
2025150 | Jan 1980 | GB |
2034101 | May 1980 | GB |
1574796 | Sep 1980 | GB |
2070341 | Sep 1981 | GB |
2070470 | Sep 1981 | GB |
2071433 | Sep 1981 | GB |
2081523 | Feb 1982 | GB |
2099635 | Dec 1982 | GB |
2105925 | Mar 1983 | GB |
2106306 | Apr 1983 | GB |
2106721 | Apr 1983 | GB |
2136214 | Sep 1984 | GB |
2140195 | Nov 1984 | GB |
2150153 | Jun 1985 | GB |
2268337 | Jan 1994 | GB |
2273819 | Jun 1994 | GB |
2283133 | Apr 1995 | GB |
2289992 | Dec 1995 | GB |
2308490 | Jun 1997 | GB |
2332557 | Jun 1999 | GB |
175494 | Nov 1981 | HU |
60206121 | Mar 1959 | JP |
57043529 | Aug 1980 | JP |
57126117 | May 1982 | JP |
59076156 | Oct 1982 | JP |
59159642 | Feb 1983 | JP |
6264964 | Sep 1985 | JP |
1129737 | May 1989 | JP |
62320631 | Jun 1989 | JP |
2017474 | Jan 1990 | JP |
3245748 | Feb 1990 | JP |
4179107 | Nov 1990 | JP |
318253 | Jan 1991 | JP |
424909 | Jan 1992 | JP |
5290947 | Apr 1992 | JP |
6196343 | Dec 1992 | JP |
6233442 | Feb 1993 | JP |
6325629 | May 1993 | JP |
7057951 | Aug 1993 | JP |
7264789 | Mar 1994 | JP |
8167332 | Dec 1994 | JP |
7161270 | Jun 1995 | JP |
8264039 | Nov 1995 | JP |
9200989 | Jan 1996 | JP |
8036952 | Feb 1996 | JP |
8167360 | Jun 1996 | JP |
67199 | Mar 1972 | LU |
90308 | Sep 1937 | SE |
305899 | Nov 1968 | SE |
255156 | Feb 1969 | SE |
342428 | Dec 1971 | SE |
453236 | Jan 1982 | SE |
457792 | Jun 1987 | SE |
502417 | Dec 1993 | SE |
792302 | Jan 1971 | SU |
425268 | Sep 1974 | SU |
1019553 | Jan 1980 | SU |
694939 | Jan 1982 | SU |
955369 | Aug 1983 | SU |
1511810 | May 1987 | SU |
WO8202617 | Aug 1982 | WO |
WO8502302 | May 1985 | WO |
WO9011389 | Oct 1990 | WO |
WO9012409 | Oct 1990 | WO |
PCTDE 9000279 | Nov 1990 | WO |
WO9101059 | Jan 1991 | WO |
WO9101585 | Feb 1991 | WO |
WO9107807 | Mar 1991 | WO |
PCT SE 9100077 | Apr 1991 | WO |
WO9109442 | Jun 1991 | WO |
WO 9111841 | Aug 1991 | WO |
WO8115862 | Oct 1991 | WO |
WO 9115755 | Oct 1991 | WO |
WO9201328 | Jan 1992 | WO |
WO9203870 | Mar 1992 | WO |
WO9321681 | Oct 1993 | WO |
WO9406194 | Mar 1994 | WO |
WO9518058 | Jul 1995 | WO |
WO9522153 | Aug 1995 | WO |
WO9524049 | Sep 1995 | WO |
WO9622606 | Jul 1996 | WO |
WO9622607 | Jul 1996 | WO |
PCTCN 9600010 | Oct 1996 | WO |
WO9630144 | Oct 1996 | WO |
WO9710640 | Mar 1997 | WO |
WO9711831 | Apr 1997 | WO |
WO9716881 | May 1997 | WO |
WO 9729494 | Aug 1997 | WO |
WO45908 | Dec 1997 | WO |
WO9745288 | Dec 1997 | WO |
WO9745847 | Dec 1997 | WO |
WO9745848 | Dec 1997 | WO |
WO9745906 | Dec 1997 | WO |
WO9745907 | Dec 1997 | WO |
WO9745912 | Dec 1997 | WO |
WO9745914 | Dec 1997 | WO |
WO9745915 | Dec 1997 | WO |
WO9745916 | Dec 1997 | WO |
WO9745918 | Dec 1997 | WO |
WO9745919 | Dec 1997 | WO |
WO9745920 | Dec 1997 | WO |
WO9745921 | Dec 1997 | WO |
WO9745922 | Dec 1997 | WO |
WO9745923 | Dec 1997 | WO |
WO9745924 | Dec 1997 | WO |
WO9745925 | Dec 1997 | WO |
WO9745926 | Dec 1997 | WO |
WO9745927 | Dec 1997 | WO |
WO9745928 | Dec 1997 | WO |
WO9745929 | Dec 1997 | WO |
WO9745930 | Dec 1997 | WO |
WO9745931 | Dec 1997 | WO |
WO9745932 | Dec 1997 | WO |
WO9745933 | Dec 1997 | WO |
WO9745934 | Dec 1997 | WO |
WO9745935 | Dec 1997 | WO |
WO9745936 | Dec 1997 | WO |
WO9745937 | Dec 1997 | WO |
WO9745938 | Dec 1997 | WO |
WO9745939 | Dec 1997 | WO |
WO9747067 | Dec 1997 | WO |
WO9820595 | May 1998 | WO |
WO9820596 | May 1998 | WO |
WO9820597 | May 1998 | WO |
WO 9820598 | May 1998 | WO |
WO9820600 | May 1998 | WO |
WO 9820602 | May 1998 | WO |
WO9821385 | May 1998 | WO |
PCTFR 9800468 | Jun 1998 | WO |
WO9827634 | Jun 1998 | WO |
WO9827635 | Jun 1998 | WO |
WO9827636 | Jun 1998 | WO |
WO9829927 | Jul 1998 | WO |
WO9829928 | Jul 1998 | WO |
WO9829929 | Jul 1998 | WO |
WO9829930 | Jul 1998 | WO |
WO9829931 | Jul 1998 | WO |
WO9829932 | Jul 1998 | WO |
WO9833731 | Aug 1998 | WO |
WO9833736 | Aug 1998 | WO |
WO9833737 | Aug 1998 | WO |
WO9834238 | Aug 1998 | WO |
WO 9834239 | Aug 1998 | WO |
WO9834240 | Aug 1998 | WO |
WO9834241 | Aug 1998 | WO |
WO9834242 | Aug 1998 | WO |
WO9834243 | Aug 1998 | WO |
WO9834244 | Aug 1998 | WO |
WO9834245 | Aug 1998 | WO |
WO9834246 | Aug 1998 | WO |
WO9834247 | Aug 1998 | WO |
WO9834248 | Aug 1998 | WO |
WO9834249 | Aug 1998 | WO |
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WO9834312 | Aug 1998 | WO |
WO9834315 | Aug 1998 | WO |
WO9834321 | Aug 1998 | WO |
WO9834322 | Aug 1998 | WO |
WO9834323 | Aug 1998 | WO |
WO9834326 | Aug 1998 | WO |
WO9834327 | Aug 1998 | WO |
WO9834328 | Aug 1998 | WO |
WO9834329 | Aug 1998 | WO |
WO9834330 | Aug 1998 | WO |
WO9834331 | Aug 1998 | WO |
W99834325 | Aug 1998 | WO |
WO 9840627 | Sep 1998 | WO |
WO 9843336 | Oct 1998 | WO |
WO9917309 | Apr 1999 | WO |
WO9917311 | Apr 1999 | WO |
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WO9917313 | Apr 1999 | WO |
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WO9917315 | Apr 1999 | WO |
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WO9917422 | Apr 1999 | WO |
WO9917424 | Apr 1999 | WO |
WO9917425 | Apr 1999 | WO |
WO9917426 | Apr 1999 | WO |
WO9917427 | Apr 1999 | WO |
WO9917428 | Apr 1999 | WO |
WO9917429 | Apr 1999 | WO |
WO9917432 | Apr 1999 | WO |
WO9917433 | Apr 1999 | WO |
WO9919963 | Apr 1999 | WO |
WO9919969 | Apr 1999 | WO |
WO9919970 | Apr 1999 | WO |
PCTSE 9802148 | Jun 1999 | WO |
WO9927546 | Jun 1999 | WO |
WO9928919 | Jun 1999 | WO |
WO9928921 | Jun 1999 | WO |
WO 9928922 | Jun 1999 | WO |
WO9928923 | Jun 1999 | WO |
WO9928924 | Jun 1999 | WO |
WO9928925 | Jun 1999 | WO |
WO9928926 | Jun 1999 | WO |
WO9928927 | Jun 1999 | WO |
WO9928928 | Jun 1999 | WO |
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WO9929008 | Jun 1999 | WO |
WO9929011 | Jun 1999 | WO |
WO9929012 | Jun 1999 | WO |
WO9929013 | Jun 1999 | WO |
WO9929014 | Jun 1999 | WO |
WO9929015 | Jun 1999 | WO |
WO9929016 | Jun 1999 | WO |
WO9929017 | Jun 1999 | WO |
WO9929018 | Jun 1999 | WO |
WO9929019 | Jun 1999 | WO |
WO9929020 | Jun 1999 | WO |
WO9929021 | Jun 1999 | WO |
WO9929022 | Jun 1999 | WO |
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WO9929024 | Jun 1999 | WO |
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