Turbomachine including a ceramic matrix composite (CMC) bridge

Information

  • Patent Grant
  • 8347636
  • Patent Number
    8,347,636
  • Date Filed
    Friday, September 24, 2010
    14 years ago
  • Date Issued
    Tuesday, January 8, 2013
    11 years ago
Abstract
A turbomachine includes a turbine section including a turbine inlet. A transition piece includes a transition piece inlet and a transition piece outlet. A ceramic matrix composite (CMC) bridge member links the transition piece outlet and the turbine inlet.
Description
BACKGROUND OF THE INVENTION

The subject matter disclosed herein relates to the art of turbomachines and, more particularly, to a ceramic matrix composite (CMC) bridge that joins a transition piece with a turbine section of a turbomachine.


In general, gas turbomachine engines combust a fuel/air mixture that releases heat energy to form a high temperature gas stream. The high temperature gas stream is channeled to a turbine section via a hot gas path. The turbine section converts thermal energy from the high temperature gas stream to mechanical energy that rotates a turbine shaft. The turbine section may be employed in a variety of applications, such as for providing power to a pump or an electrical generator.


Many gas turbomachines include an annular combustor within which are formed combustion gases that create the high temperature gas stream. Other turbomachines employ a plurality of combustors arranged in a can-annular array. In such a turbomachine, the hot gas path includes a transition piece that links a group of combustors with a first stage of the turbine section. The combustion gases formed in the group of combustors are delivered to the turbine section through the transition piece.


BRIEF DESCRIPTION OF THE INVENTION

According to one aspect of the invention, a turbomachine includes a turbine section including a turbine inlet. A transition piece includes a transition piece inlet and a transition piece outlet. A ceramic matrix composite (CMC) bridge member links the transition piece outlet and the turbine inlet.


According to another aspect of the invention, a method of delivering combustion gases from a turbomachine combustor to a turbine section of a turbomachine includes producing combustion gases in the turbomachine combustor, directing the combustion gases into a transition piece, guiding the combustion gases along a ceramic matrix composite (CMC) bridge member linking the transition piece and the turbine section, and passing the combustion gases from the CMC bridge member into the turbine section.


According to yet another aspect of the invention, a turbomachine component includes a ceramic matrix composite (CMC) bridge member configured and disposed to link a transition piece and a turbine section of a turbomachine.


These and other advantages and features will become more apparent from the following description taken in conjunction with the drawings.





BRIEF DESCRIPTION OF THE DRAWING

The subject matter, which is regarded as the invention, is particularly pointed out and distinctly claimed in the claims at the conclusion of the specification. The foregoing and other features, and advantages of the invention are apparent from the following detailed description taken in conjunction with the accompanying drawings in which:



FIG. 1 is a partial cross-sectional view of a turbomachine including a composite matrix material (CMC) bridge including first and second CMC bridge members sealing an interface between a transition piece and a turbine section in accordance with an exemplary embodiment;



FIG. 2 is a lower right perspective view of the first CMC bridge member of FIG. 1;



FIG. 3 is a cross-sectional side view of a CMC bridge member in accordance with another aspect of the exemplary embodiment;



FIG. 4 is a cross-sectional side view of a CMC bridge member in accordance with still another aspect of the exemplary embodiment; and



FIG. 5 is a cross-sectional side view of a CMC bridge member in accordance with yet another aspect of the exemplary embodiment.





The detailed description explains embodiments of the invention, together with advantages and features, by way of example with reference to the drawings.


DETAILED DESCRIPTION OF THE INVENTION

The terms “axial” and “axially” as used in this application refer to directions and orientations extending substantially parallel to a center longitudinal axis of a turbomachine. The terms “radial” and “radially” as used in this application refer to directions and orientations extending substantially orthogonally to the center longitudinal axis of the turbomachine. The terms “upstream” and “downstream” as used in this application refer to directions and orientations relative to an axial flow direction with respect to the center longitudinal axis of the turbomachine.


With reference to FIG. 1, a turbomachine constructed in accordance with an exemplary embodiment is indicated generally at 2. Turbomachine 2 includes a turbine section 4 that is fluidly linked to a combustor (not shown) through a transition piece 10. Turbine section 4 includes a turbine section inlet 12 defined by an end wall 14. A first stage 16 of turbine section 4 is arranged downstream from turbine section inlet 12. First stage 16 includes a plurality of vanes, one of which is indicated at 17, that guide combustion gases 18 to a plurality of first stage blades, one of which is indicated at 19. Combustion gases 18 flow axially into a transition piece inlet 30, pass through transition piece 10, and exit from a transition piece outlet 31 into turbine section inlet 12. At this point, combustion gases 18 pass over vanes 17 before acting upon blades 19. Blades 19 translate thermal and kinetic energy from combustion gases 18 into mechanical, rotational energy that is employed to rotate a shaft (not shown). In addition to combustion gases 18, compressor discharge air 37 passes from a compressor section (not shown) into a wheel space portion 40 of turbine section 4.


In accordance with an exemplary embodiment, turbomachine 2 includes a ceramic composite material (CMC) bridge 47 that links transition piece outlet 31 with turbine section inlet 12. In accordance with one aspect of the exemplary embodiment, CMC bridge 47 is formed from one or more of silicon carbide-silicon carbide (SiC—SiC) composites, oxide-oxide composites, and silicon nitride composites. Of course it should be understood that various other CMC materials may also be employed. CMC bridge 47 includes a first CMC bridge member 54 arranged at an outer interface between transition piece outlet 31 and turbine section inlet 12, and a second CMC bridge member 55 arranged at an inner interface between transition piece outlet 31 and turbine section inlet 12. First CMC bridge member 54 includes a main body 56 having an outer surface 57 and an inner surface 58. Likewise, second CMC bridge member 55 includes a main body 59 having an outer surface 60 and an inner surface 61.


First CMC bridge member 54 includes a flow guide 64 arranged on inner surface 58. Flow guide 64 directs combustion gases 18 away from end wall 14. Similarly, second CMC bridge member 55 includes a flow guide 66 arranged on inner surface 61. Flow guide 66 directs combustion gases 18 away from end wall 14 and/or disrupts crossflow vortex generation. With this arrangement, end wall 14 is protected from damage that may result from exposure to combustion gases 18. More specifically, combustion gases passing into an inlet portion 68 of CMC bridge member 54 pass over flow guide 64. Flow guide 64 directs combustion gases 18 through an outlet portion 69 of CMC bridge member 54 at trajectory that is angled away from end wall 14. Likewise, combustion gases passing into an inlet portion 71 of CMC bridge member 55 pass over flow guide 66. Flow guide 66 directs combustion gases 18 through an outlet portion 72 of CMC bridge member 55 at trajectory that is angled away from end wall 14.


As best shown in FIG. 2, bridge member 54 includes a first section 76 that defines a first flange 77. First section 76 leads to a second section 79 that is substantially perpendicular to first section 76. A third section 82 extends from second section 79 and is substantially parallel to first section 76. A fourth section 85, that is substantially parallel to second section 79, extends from third section 82. A fifth section 88, that is substantially parallel to first and third sections 77 and 82, extends from fourth section 85. Third, fourth and fifth sections 82, 85, and 88 combine to define a second flange 89 that joins first CMC bridge member 54 to turbine section 4. In addition, bridge member 54 includes first and second mounting members 90 and 91 that are formed in second flange 89. Mechanical fasteners, one of which is indicated at 96 in FIG. 1, pass through mounting members 90, 91, and turbine section 4 to join first CMC bridge member 54 to turbine section 4. Second flange 89 also includes a plurality of mounting elements 98 and 99 that register with pins (not shown) to locate first CMC bridge member 54 on turbine section 4. Finally, turbomachine 2 is shown to include first and second flexible seals 104 and 106 that are configured to prevent combustion gases from leaking at an interface between transition piece outlet 31 and respective ones of inlet portions 68 and 71 of first and second CMC bridge member 54 and 55.


Reference will now be made to FIG. 3, wherein like reference numbers represent corresponding parts in the respective views, in describing a CMC bridge member 116 constructed in accordance with another exemplary embodiment. As will become more fully apparent below, CMC bridge member 116 is secured to turbine section 4 through a retaining ring 118 arranged at turbine section inlet 12. CMC bridge member 116 includes a main body 123 including an outer surface 130 and an inner surface 131 that defines an inlet portion 134 and an outlet portion 135. CMC bridge member 116 includes a first flange 140 arranged at inlet portion 134 and a second flange 143 arranged at outlet portion 135. A mounting member 147 extends substantially perpendicularly from outer surface 130. Mounting member 147 includes a dovetail section 149 that cooperates with corresponding structure (not separately labeled) on retaining ring 118 to secure CMC bridge member 116 to turbomachine 2. As further shown in FIG. 3, a first flexible seal 154 extends between inlet portion 134 and transition piece outlet 31 and a second flexible seal 157 extends between outlet portion 135 and turbine section inlet 12 to prevent compressor discharge air from bypassing the combustor and entering turbine inlet 12.


Reference will now be made to FIG. 4, wherein like reference numbers represent corresponding parts in the respective views, in describing a CMC bridge member 167 constructed in accordance with another exemplary embodiment. CMC bridge member 167 includes a main body 170 including an outer surface 172 and an inner surface 173 that defines an inlet portion 176 and an outlet portion 177. CMC bridge member 167 includes a first flange 180 arranged at inlet portion 176. First flange 180 is secured to transition piece outlet 31 through a mechanical fastener 181. CMC bridge 167 also includes a second flange 183 arranged at outlet portion 177. In the exemplary aspect shown, transition piece 10 includes an air channel 185 arranged at transition piece outlet 31. Air channel 185 directs a cooling fluid, for example compressor discharge air, onto first flange 180 to lower temperatures of CMC bridge member 167. As further shown in FIG. 4, a flexible seal 187 extends between outlet portion 177 and turbine section inlet 12 to prevent compressor discharge air from bypassing the combustor and entering turbine inlet 12.


Reference will now be made to FIG. 5, wherein like reference numbers represent corresponding parts in the respective views, in describing a CMC bridge member 197 constructed in accordance with another exemplary embodiment. CMC bridge member 197 includes a main body 200 including an outer surface 204 and an inner surface 205 that defines an inlet portion 209 and an outlet portion 210. CMC bridge member 197 includes a first flange 214 arranged at inlet portion 209 and a second flange 217 arranged at outlet portion 210. Second flange 217 is secured to turbine section inlet 12 through a mounting member 220. Mounting member 220 includes a sliding interface (not shown) that engages with corresponding structure on turbine section 4. CMC bridge 197 also includes a flexible seal 224 that extends between inlet portion 209 and transition piece outlet 31 to prevent compressor discharge air from bypassing the combustor and entering turbine inlet 12.


At this point it should be understood that the CMC bridge in accordance with exemplary embodiments provides a seal between the transition piece/turbine section interface in order to limit and/or prevent compressor discharge air from entering into the turbine inlet. The transition piece/turbine section interface is typically exposed to high temperatures and thus requires cooling in order to prolong component life. In contrast, the present invention provides a bridge formed from CMC materials that are able to withstand higher temperatures without degrading. By employing the CMC bridge in accordance with the exemplary embodiments the need for cooling airflow at the transition piece/turbine section interface is significantly reduced thereby enhancing turbomachine efficiency. The reduced cooling flow provides additional flow that can be used to extract work from the turbine.


While the invention has been described in detail in connection with only a limited number of embodiments, it should be readily understood that the invention is not limited to such disclosed embodiments. Rather, the invention can be modified to incorporate any number of variations, alterations, substitutions or equivalent arrangements not heretofore described, but which are commensurate with the spirit and scope of the invention. Additionally, while various embodiments of the invention have been described, it is to be understood that aspects of the invention may include only some of the described embodiments. Accordingly, the invention is not to be seen as limited by the foregoing description, but is only limited by the scope of the appended claims.

Claims
  • 1. A turbomachine comprising: a turbine section including a turbine inlet;a combustor transition piece including a transition piece inlet and a transition piece outlet;a ceramic matrix composite (CMC) bridge member linking the transition piece outlet and the turbine inlet, the CMC bridge member including an inlet portion having a first flange operatively connected to the combustor transition piece outlet and an outlet portion having a second flange operatively connected to the turbine inlet; anda seal member provided on one of the transition piece outlet and the turbine inlet, the seal member engaging one of the first and second flanges.
  • 2. The turbomachine according to claim 1, wherein the CMC bridge member includes an outer surface and an inner surface, the inner surface having a flow guide that directs combustion gases into the turbine inlet.
  • 3. The turbomachine according to claim 2, wherein the flow guide is configured and disposed to direct combustion gases away from an end wall portion of the turbine inlet.
  • 4. The turbomachine according to claim 1, wherein the first flange extends about the inlet portion and a second flange extends about the outlet portion.
  • 5. The turbomachine according to claim 4, wherein one of the first and second flanges is fastened to the corresponding one of the combustor and the turbine section.
  • 6. The turbomachine according to claim 5, wherein the seal member comprises a flexible seal member.
  • 7. The turbomachine according to claim 6, further comprising: a retaining ring operatively connected to the turbine section, the at least one bridge member being secured to the retaining ring through the mounting element.
  • 8. The turbomachine according to claim 7, further comprising: a first seal member arranged between the first flange and the combustor and a second seal member arranged between the second flange and the turbine section.
  • 9. The turbomachine according to claim 4, wherein the CMC bridge member includes a mounting element projecting radially outward from the body between the first and second flanges.
  • 10. The turbomachine according to claim 1, wherein the CMC bridge member is formed from one of a silicon carbide-silicon carbide (SiC—SiC) composite, oxide-oxide composite, and silicon nitride composite material.
  • 11. The turbomachine according to claim 1, further comprising: an air channel arranged at the transition piece outlet, the air channel guiding a fluid flow onto the CMC bridge member.
  • 12. A method of delivering combustion gases from a turbomachine combustor to a turbine section of a turbomachine, the method comprising: producing combustion gases in the turbomachine combustor;directing the combustion gases into a combustor transition piece;guiding the combustion gases along a ceramic matrix composite (CMC) bridge member linking the transition piece and the turbine section; andpassing the combustion gases from the CMC bridge member into the turbine section, the CMC bridge member including an inlet portion having a first flange operatively connected to a combustor transition piece outlet and an outlet portion having a second flange operatively connected to a turbine inlet; andsealing an interface between the CMC bride member and one of the transition piece and the turbine section to prevent compressor discharge air from entering into a turbine inlet of the turbine section.
  • 13. The method of claim 12, wherein, guiding the combustion gases through the CMC bridge member includes diverting the combustion gases away from an end wall portion of the turbine section.
  • 14. A turbomachine component comprising: a ceramic matrix composite (CMC) bridge member configured and disposed to link a combustor transition piece and a turbine section of a turbomachine, the CMC bridge member including an inlet portion having a first flange configured and disposed to operatively connect to a combustor transition piece outlet and an outlet portion having a second flange configured and disposed to operatively connect to a turbine inlet; anda seal member provided on one of the transition piece outlet and the turbine inlet, the seal member engaging one of the first and second flanges.
  • 15. The turbomachine component according to claim 14, wherein the CMC bridge member includes an outer surface and an inner surface, the inner surface having a flow guide.
  • 16. The turbomachine component according to claim 14, wherein the first flange extends about the inlet portion and the second flange extends about the outlet portion.
  • 17. The turbomachine component according to claim 16, wherein the CMC bridge member includes a mounting element projection radially outward from the body between the first and second flanges.
  • 18. The turbomachine according to claim 14, wherein the CMC bridge member is formed from one of a silicon carbide-silicon carbide (SiC—SiC) composite, oxide-oxide composite, and silicon nitride composite material.
US Referenced Citations (183)
Number Name Date Kind
5265412 Bagepalli et al. Nov 1993 A
5657998 Dinc et al. Aug 1997 A
5687572 Schrantz et al. Nov 1997 A
5854154 Radford et al. Dec 1998 A
6013592 Merrill et al. Jan 2000 A
6039537 Scheurlen Mar 2000 A
6060174 Sabol et al. May 2000 A
6071556 Beele Jun 2000 A
6106959 Vance et al. Aug 2000 A
6111599 Nance et al. Aug 2000 A
6197424 Morrison et al. Mar 2001 B1
6235370 Merrill et al. May 2001 B1
6251520 Blizzard et al. Jun 2001 B1
6287511 Merrill et al. Sep 2001 B1
6294260 Subramanian Sep 2001 B1
6296945 Subramanian Oct 2001 B1
6322897 Borchert et al. Nov 2001 B1
6350713 Petrak Feb 2002 B1
6382920 Dopper May 2002 B1
6384365 Seth et al. May 2002 B1
6387539 Subramanian May 2002 B1
6512379 Harrold et al. Jan 2003 B2
6514046 Morrison et al. Feb 2003 B1
6517959 Beele Feb 2003 B1
6528178 Srinivasan Mar 2003 B1
6528189 Beele Mar 2003 B1
6528190 Campbell et al. Mar 2003 B1
6575817 Czech Jun 2003 B2
6602053 Subramanian et al. Aug 2003 B2
6617013 Morrison et al. Sep 2003 B2
6641907 Merrill et al. Nov 2003 B1
6648597 Widrig et al. Nov 2003 B1
6670046 Xia Dec 2003 B1
6676783 Merrill et al. Jan 2004 B1
6677064 Subramanian Jan 2004 B1
6682300 Bolms Jan 2004 B2
6703137 Subramanian Mar 2004 B2
6709230 Morrison et al. Mar 2004 B2
6719853 Buergel et al. Apr 2004 B2
6733907 Morrison et al. May 2004 B2
6743393 Petrak Jun 2004 B1
6746755 Morrison et al. Jun 2004 B2
6751962 Kuwabara et al. Jun 2004 B1
6758653 Morrison Jul 2004 B2
6767659 Campbell Jul 2004 B1
6821578 Beele Nov 2004 B2
6827312 Riedell Dec 2004 B2
6835465 Allen et al. Dec 2004 B2
6838157 Subramanian Jan 2005 B2
6846574 Subramanian Jan 2005 B2
6860108 Soechting et al. Mar 2005 B2
6878041 Esser et al. Apr 2005 B2
6884384 Merrill et al. Apr 2005 B2
6902360 Meece et al. Jun 2005 B2
6929852 Lane et al. Aug 2005 B2
6933060 Subramanian et al. Aug 2005 B2
6939603 Oechsner Sep 2005 B2
6977060 Merrill et al. Dec 2005 B1
6984277 Morrison et al. Jan 2006 B2
7001679 Campbell et al. Feb 2006 B2
7017415 Harrold et al. Mar 2006 B2
7057176 Rothenfusser et al. Jun 2006 B2
7066717 Morrison et al. Jun 2006 B2
7067181 Burke Jun 2006 B2
7067447 Campbell Jun 2006 B2
7080513 Reichert Jul 2006 B2
7093359 Morrison et al. Aug 2006 B2
7108925 Campbell Sep 2006 B2
7123031 Twerdochlib Oct 2006 B2
7153096 Thompson et al. Dec 2006 B2
7163747 Cox et al. Jan 2007 B2
7176681 Zombo Feb 2007 B2
7179524 Merrill et al. Feb 2007 B2
7182580 Bostanjoglo et al. Feb 2007 B2
7182581 Bostanjoglo et al. Feb 2007 B2
7198458 Thompson Apr 2007 B2
7198462 Merrill et al. Apr 2007 B2
7198860 Vance Apr 2007 B2
7217088 Albrecht et al. May 2007 B2
7229254 Bast et al. Jun 2007 B2
7230205 Twerdochlib Jun 2007 B2
7237389 Ryan et al. Jul 2007 B2
7247002 Albrecht et al. Jul 2007 B2
7247003 Burke et al. Jul 2007 B2
7250222 Halberstadt et al. Jul 2007 B2
7250776 Twerdochlib Jul 2007 B2
7258530 Morrison et al. Aug 2007 B2
7270890 Sabol et al. Sep 2007 B2
7278820 Keller Oct 2007 B2
7291407 Merrill et al. Nov 2007 B2
7300621 Merrill Nov 2007 B2
7311790 Morrison et al. Dec 2007 B2
7316539 Campbell Jan 2008 B2
7326030 Albrecht et al. Feb 2008 B2
7334330 Vance Feb 2008 B2
7341428 Twerdochlib Mar 2008 B2
7351364 Morrison et al. Apr 2008 B2
7371043 Keller May 2008 B2
7387758 Merrill et al. Jun 2008 B2
7393183 Keller Jul 2008 B2
7402347 Morrison et al. Jul 2008 B2
20020168263 Bolms Nov 2002 A1
20020197465 Butner et al. Dec 2002 A1
20030035907 Campbell et al. Feb 2003 A1
20030207155 Morrison et al. Nov 2003 A1
20030223861 Morrison et al. Dec 2003 A1
20040001977 Subramanian Jan 2004 A1
20040043889 Campbell Mar 2004 A1
20040047726 Morrison Mar 2004 A1
20040058201 Merrill et al. Mar 2004 A1
20040219010 Merrill et al. Nov 2004 A1
20050022921 Morrison et al. Feb 2005 A1
20050064245 Campbell Mar 2005 A1
20050076504 Morrison et al. Apr 2005 A1
20050198967 Subramanian Sep 2005 A1
20050235493 Philip et al. Oct 2005 A1
20050238491 Morrison et al. Oct 2005 A1
20050254942 Morrison et al. Nov 2005 A1
20050287386 Sabol et al. Dec 2005 A1
20060019087 Mazzola et al. Jan 2006 A1
20060056959 Sabol et al. Mar 2006 A1
20060056960 Sabol et al. Mar 2006 A1
20060091546 Bostanjoglo et al. May 2006 A1
20060101827 Ryan et al. May 2006 A1
20060120874 Burke et al. Jun 2006 A1
20060121265 Thompson et al. Jun 2006 A1
20060121296 Morrison et al. Jun 2006 A1
20060171809 Albrecht et al. Aug 2006 A1
20060182971 Merrill et al. Aug 2006 A1
20060216547 Vance Sep 2006 A1
20060226290 Campbell Oct 2006 A1
20060228211 Vance et al. Oct 2006 A1
20060245984 Kulkarni et al. Nov 2006 A1
20060257688 Schutze et al. Nov 2006 A1
20060285973 Keller Dec 2006 A1
20060286401 Kaiser et al. Dec 2006 A1
20060292001 Keller et al. Dec 2006 A1
20070020105 Albrecht et al. Jan 2007 A1
20070031258 Campbell et al. Feb 2007 A1
20070047615 Twerdochlib Mar 2007 A1
20070048144 Morrison et al. Mar 2007 A1
20070059486 Anton et al. Mar 2007 A1
20070075455 Marini et al. Apr 2007 A1
20070077141 Keller Apr 2007 A1
20070108670 Merrill et al. May 2007 A1
20070128043 Morrison et al. Jun 2007 A1
20070140835 Albrecht et al. Jun 2007 A1
20070147996 Campbell et al. Jun 2007 A1
20070160466 Keller Jul 2007 A1
20070172676 Burns et al. Jul 2007 A1
20070189952 Easler et al. Aug 2007 A1
20070237630 Schiavo et al. Oct 2007 A1
20070237667 Merrill et al. Oct 2007 A1
20070258809 Mazzola et al. Nov 2007 A1
20070275210 Heselhaus Nov 2007 A1
20080008584 Shteyman et al. Jan 2008 A1
20080025838 Marini et al. Jan 2008 A1
20080025842 Marini et al. Jan 2008 A1
20080025846 Vance et al. Jan 2008 A1
20080053107 Weaver et al. Mar 2008 A1
20080087021 Radonovich et al. Apr 2008 A1
20080101683 Zombo et al. May 2008 A1
20080107521 Morrison et al. May 2008 A1
20080116614 Morrison et al. May 2008 A1
20080131699 Vance Jun 2008 A1
20080178465 Schiavo et al. Jul 2008 A1
20080181766 Campbell et al. Jul 2008 A1
20080199307 Keller Aug 2008 A1
20080199661 Keller et al. Aug 2008 A1
20080203236 Mazzola et al. Aug 2008 A1
20080206542 Vance et al. Aug 2008 A1
20080207075 Merrill et al. Aug 2008 A1
20080273967 Marini et al. Nov 2008 A1
20080274336 Merrill et al. Nov 2008 A1
20080279678 Merrill et al. Nov 2008 A1
20080279679 Morrison Nov 2008 A1
20080280101 Morrison et al. Nov 2008 A1
20080284059 Merrill et al. Nov 2008 A1
20090003988 Campbell Jan 2009 A1
20090010755 Keller et al. Jan 2009 A1
20090014926 Marini Jan 2009 A1
20090071160 Keller et al. Mar 2009 A1
20090081033 Schiavo et al. Mar 2009 A1
Foreign Referenced Citations (24)
Number Date Country
1126221 Aug 2001 EP
1318215 Jun 2003 EP
1329592 Jul 2003 EP
1528343 May 2005 EP
1739356 Jan 2007 EP
1787967 May 2007 EP
1884714 Feb 2008 EP
1903184 Mar 2008 EP
2052853 Apr 2009 EP
9948837 Sep 1999 WO
0052307 Sep 2000 WO
0146084 Jun 2001 WO
0161250 Aug 2001 WO
0218674 Mar 2002 WO
02092536 Nov 2002 WO
2005043058 May 2005 WO
2005070613 Aug 2005 WO
2006040220 Apr 2006 WO
2006040235 Apr 2006 WO
2006121570 Nov 2006 WO
2007014005 Feb 2007 WO
2007025842 Mar 2007 WO
2007145607 Dec 2007 WO
2008091289 Jul 2008 WO
Related Publications (1)
Number Date Country
20120073304 A1 Mar 2012 US