Claims
- 1. A two-part room temperature curable composition comprising:
- A. A first liquid comprising, as essential components:
- d. an organic polymer containing reactive silicon groups, and
- b. an accelerator for the polymerization of a radically-polymerizable monomer; and
- B. a second liquid comprising, as essential components:
- a. a radically-polymerizable monomer,
- c. an initiator for the polymerization of said radically-polymerizable monomer, and
- e. an accelerator for curing said organic polymer containing reactive silicon groups
- wherein said first liquid A and said second liquid B are maintained at temperatures prior to admixture with each other such that said component d does not react to any substantial extent prior to their admixture, and
- wherein said first liquid A and said second liquid B react together at room temperature to directly form a cured product with up to about 10 minutes.
- 2. A two-part room temperature curable composition comprising:
- A. a first liquid comprising, as essential components:
- d. an organic polymer containing reactive silicon groups and
- c. an initiator for the polymerization of a radically-polymerizable monomer; and
- B. a second liquid comprising, as essential components:
- a. a radically-polymerizable monomer,
- b. an accelerator for the polymerization of said radically-polymerizable monomer, and
- e. an accelerator for curing said organic polymer containing reactive silicon groups
- wherein said first liquid A and said second liquid B are maintained at temperatures prior to admixture with each other such that said component a does not polymerize, and the reactive silicon groups in said component d do not react to any substantial extent prior to their admixture, and
- wherein said first liquid A and said second liquid B react together at room temperature to directly form a cured product within up to about 10 minutes.
- 3. A two-part room temperature curable composition comprising:
- A. a first liquid comprising, as essential components:
- d. an organic polymer containing reactive silicon groups,
- a. radically-polymerizable monomer, and
- b. an accelerator for the polymerization of said radically-polymerizable monomer; and
- B. a second liquid comprising, as essential components:
- a. a radically-polymerizable monomer,
- c. an initiator for the polymerization of said radically-polymerizable monomer, and
- e. an accelerator for curing said organic polymer containing reactive silicon groups
- wherein said first liquid A and said second liquid B are maintained at temperatures prior to admixture with each other such that said component a does not polymerize, and the reactive silicon groups in said component d do not react to any substantial extent prior to their admixture, and
- wherein said first liquid A and said second liquid B react together at room temperature to directly form a cured product within up to about 10 minutes.
- 4. A two-part room temperature curable composition comprising:
- A. a first liquid comprising, as essential components:
- d. an organic polymer containing reactive silicon groups,
- a. a radically-polymerizable monomer, and
- c. an initiator for the polymerization of said radically-polymerizable monomer; and
- B. a second liquid comprising, as essential components:
- a. a radically-polymerizable monomer,
- b. an accelerator for the polymerization of said radically-polymerizable monomer, and
- e. an accelerator for curing said organic polymer containing reactive silicon groups
- wherein said first liquid A and said second liquid B are maintained at temperatures prior to their admixture together such that said component a does not polymerize, and the reactive silicon groups in said component d do not react to any substantial extent prior to their admixture together, and
- wherein said first liquid A and said second liquid B react together at room temperature to directly form a cured product within up to about 10 minutes.
- 5. A two-part room temperature curable composition comprising:
- A. a first liquid comprising:
- d. an organic polymer containing reactive silicon groups,
- a. a radically-polymerizable monomer, and
- c. an initiator for the polymerization of said radically-polymerizable monomer; and
- B. a second liquid comprising, as essential components:
- e. an accelerator for curing said organic polymer containing reactive silicon groups, and
- b. an accelerator for the polymerization of said radically-polymerizable monomer;
- wherein said first liquid A and said second liquid B are maintained at temperatures prior to their admixture together such that said component a does not polymerize, and the reactive silicon groups in said component d do not react to any substantial extent prior to said admixture together, and
- wherein said first liquid A and said second liquid B react together at room temperature to directly form a cured product within up to about 10 minutes.
- 6. A two-part room temperature curable composition comprising:
- A. a first liquid comprising, as essential components:
- d. an organic polymer containing reactive silicon groups,
- a. a radically-polymerizable monomer, and
- b. an accelerator for the polymerization of said radically-polymerizable monomer; and
- B. a second liquid comprising, as essential components:
- e. an accelerator for curing said organic polymer containing reactive silicon groups, and
- c. an initiator for the polymerization of said radically-polymerizable monomer
- wherein said first liquid A and said second liquid B are maintained at temperatures prior to their admixture together such that said component a does not polymerize, and the reactive silicon groups in said component d do not react to any substantial extent prior to their admixture, and
- wherein said first liquid A and said second liquid B react together at room temperature to directly form a cured product within up to about 10 minutes.
- 7. A two-part room temperature curable composition comprising:
- A. a first liquid comprising, as essential components:
- d. an organic polymer containing reactive silicon groups,
- a. a radically-polymerizable monomer,
- b. an accelerator for the polymerization of said radically-polymerizable monomer, and
- e. an accelerator for curing said organic polymer containing reactive silicon group; and
- B. a second liquid comprising, as essential components:
- c. an initiator for the polymerization of said radically-polymerizable monomer
- wherein said first liquid A and said second liquid B are maintained at temperatures prior to their admixture together such that said component a does not polymerize, and the reactive silicon groups in said component d do not react to any substantial extent prior to their admixture, and
- wherein said first liquid A and said second liquid B react together at room temperature to directly form a cured product within up to about 10 minutes.
- 8. A composition as claimed in claim 1 wherein said reactive silicon groups are represented by the following formulae (I) and/or (II): ##STR3## wherein R represents a monovalent organic group having 1 to 20 carbon atoms, or a triorganosiloxy group; x represents a hydroxyl group or a heterogeneous or homogeneous hydrolyzable group; a is an integer of 0, 1 or 2; b is an integer of 0, 1, 2 or 3, provided that a is not 2 when b is 3; and m is an integer of 0 to 18; ##STR4## wherein R is as defined in formula (I) and n is an integer of 0, 1 or 2.
- 9. A composition as claimed in claim 2 wherein said reactive silicon groups are represented by the following general formulae (I) and/or (II). ##STR5## wherein R.sup.- represents a monovalent organic group having 1 to 20 carbon atoms, or a triorganosiloxy group; x represents a hydroxyl group or a heterogeneous or homogeneous hydrolyzable group; a is an integer of 0, 1 or 2; b is an integer of 0, 1, 2 or 3, provided that a is not 2 when b is 3; and m is an integer of 0 to 18; ##STR6## wherein R.sup.1 is as defined in formula (i) and n is an integer of 0, 1 or 2.
- 10. A composition as claimed in claim 3 wherein said reactive silicon groups are represented by the following general formulae (I) and/or (II): ##STR7## wherein R.sup.1 represents a monovalent organic group having 1 to 20 carbon atoms, or a triorganosiloxy group; x represents a hydroxyl group or a heterogeneous or homogeneous hydrolyzable group; a is an integer of 0, 1 or 2; b is an integer of 0, 1, 2 or 3, provided that a is not 2 when b is 3; and m is an integer of 0 to 18; ##STR8## wherein R.sup.1 is as defined in formula (I) and n is an integer of 0, 1 or 2.
- 11. A composition as claimed in claim 4 wherein said reactive silicon groups are represented by the following general formulae (I) and/or (II): ##STR9## wherein R.sup.1 represents a monovalent organic group having 1 to 20 carbon atoms, or a triorganosiloxy group x represents a hydroxyl group of a heterogeneous or homogeneous hydrolyzable group; a is an integer of 0, 1 or 2; b is an integer of 0, 1, 2 or 3, provided that a is not 2 when b is 3; and m is an integer of 0 to 18; ##STR10## wherein R.sup.1 is as defined in formula (I) and n is an integer of 0, 1 or 2.
- 12. A composition as claimed in claim 5 wherein said reactive silicon groups are represented by the following general formulae (I) and/or (II): ##STR11## wherein R.sup.1 represents a monovalent organic group having 1 to 20 carbon atoms, or a triorganosiloxy group; x represents a hydroxyl group or a heterogeneous or homogeneous hydrolyzable group; a is an integer of 0, 1 or 2; b is an integer of 0, 1, 2 or 3, provided that a is not 2 when b is 3; and m is an integer of 0 to 18; ##STR12## wherein R.sup.1 is as defined in formula (I) and n is an integer of 0, 1 or 2.
- 13. A composition as claimed in claim 6 wherein said reactive silicon groups are represented by the following general formulae (I) and/or (II): ##STR13## wherein R.sup.1 represents a monovalent organic group having 1 to 20 carbon atoms, or a triorganosiloxy group; x represents a hydroxyl group or a heterogeneous or homogeneous hydrolyzable group; a is an integer of 0, 1 or 2; b is an integer of 0, 1, 2 or 3, provided that a is not 2 when b is 3; and m is an integer of 0 to 18; ##STR14## wherein R.sup.1 is as defined in formula (I) and n is an integer of 0, 1 or 2.
- 14. A composition as claimed in claim 7 wherein said reactive silicon groups are represented by the following general formulae (I) and/or (II): ##STR15## wherein R.sup.1 represents a monovalent organic group having 1 to 20 carbon atoms, or a triorganosiloxy group; x represents a hydroxyl group or a heterogeneous or homogeneous hydrolyzable group; a is an integer of 0, 1 or 2; b is an integer of 0, 1, 2 or 3, provided that a is not 2 when b is 3; and m is an integer of 0 to 18; ##STR16## wherein R.sup.1 is as defined in formula (I) and n is an integer of 0, 1 or 2.
- 15. A process of producing a cured polymeric product comprising:
- forming a first liquid A comprising, as essential components:
- d. a curable organic polymer containing reactive silicon, and
- b. an accelerator for the polymerization of a radically polymerizable monomer;
- forming a second liquid B comprising, as essential components:
- a. a radically polymerizable monomer, the polymerization of which is accelerated by said accelerator "b",
- c. an initiator for the polymerization of said radically polymerizable monomer, and
- e. an accelerator for curing said organic polymer containing reactive silicon groups;
- maintaining said first liquid A and said second liquid B separate and at temperatures, respectively, such that said component "a" does not polymerize and the reactive silicon in said component "d" does not react to any substantial extent;
- mixing said liquids A and B at room temperature to form a mixture;
- holding said mixture for up to about 10 minutes at room temperature sufficient to polymerize said component "a", to cure said polymer, and to react said reactive silicon to an extent sufficient form a cured, solid polymeric product; and
- recovering said cured solid polymeric product.
- 16. A process of producing a cured polymeric product comprising:
- forming a first liquid A comprising, as essential components:
- d. a curable organic polymer containing reactive silicon groups, and
- c. an initiator for the polymerization of a radically polymerizable monomer;
- forming a second liquid B comprising, as essential components:
- a. a radically-polymerizable monomer, the polymerization of which is initiated by said initiator "c",
- b. an accelerator for the polymerization of said radically-polymerizable monomer, and
- e. an accelerator for curing said organic polymer containing reactive silicon groups;
- maintaining said first liquid A and said second liquid B separate and at temperatures, respectively, such that said component "a" does not polymerize and the reactive silicon in said component "d" does not react to any substantial extent;
- mixing said liquids A and B at room temperature to form a mixture;
- holding said mixture for up to about 10 minutes at room temperature sufficient to polymerize said component "a", to cure said polymer, and to react said reactive silicon to an extent sufficient form a cured, solid polymeric product; and
- recovering said cured solid polymeric product.
- 17. A process of producing a cured polymeric product comprising:
- forming a first liquid A comprising, as essential components:
- d. a curable organic polymer containing reactive silicon groups,
- a radically-polymerizable monomer, and
- an initiator for the polymerization of said radically-polymerizable monomer;
- forming a second liquid B comprising, as essential components:
- a. a radically-polymerizable monomer,
- b. an accelerator for the polymerization of said radically-polymerizable monomer, and
- e. an accelerator for curing said organic polymer containing reactive silicon groups;
- maintaining said first liquid A and said second liquid B separate and at temperatures, respectively, such that said component "a" does not polymerize and the reactive silicon in said component "d" does not react to any substantial extent;
- mixing said liquids A and B at room temperature to form a mixture;
- holding said mixture for up to about 10 minutes at room temperature sufficient to polymerize said component "a", to cure said polymer, and to react said reactive silicon to an extent sufficient form a cured, solid polymeric product; and
- recovering said cured solid polymeric product.
- 18. A process of producing a cured polymeric product comprising:
- forming a first liquid A comprising, as essential components:
- d. a curable polymer containing reactive silicon,
- a radically-polymerizable monomer, and
- c. an initiator for the polymerization of said radically-polymerizable monomer;
- forming a second liquid B comprising, as essential components
- a. a radically-polymerizable monomer,
- b. an accelerator for the polymerization of said radically-polymerizable monomer, and
- e. an accelerator for curing said organic polymer containing silicon groups;
- maintaining said first liquid A and said second liquid B separate and at temperatures, respectively, such that said component "a" does not polymerize and the reactive silicon in said component "d" does not react to any substantial extent;
- mixing said liquids A and B at room temperature to form a mixture;
- holding said mixture for up to about 10 minutes at room temperature sufficient to polymerize said component "a", to cure said polymer, and to react said reactive silicon to an extent sufficient form a cured, solid polymeric product; and
- recovering said cured solid polymeric product.
- 19. A process of producing a cured polymeric product comprising:
- forming a first liquid A comprising, as essential components:
- d. a curable polymer containing reactive silicon groups,
- a. a radically-polymerizable monomer, and
- c. an initiator for the polymerization of said radically-polymerizable monomer;
- forming a second liquid B comprising, as essential components:
- e. an accelerator for curing said organic polymer containing reactive silicon groups, and
- b. an accelerator for the polymerization of said radically-polymerizable monomer;
- maintaining said first liquid A and said second liquid B separate and at temperatures, respectively, such that said component "a" does not polymerize and the reactive silicon in said component "d" does not react to any substantial extent;
- mixing said liquids A and B at room temperature to form a mixture;
- holding said mixture for up to about 10 minutes at room temperature sufficient to polymerize said component "a", to cure said polymer, and to react said reactive silicon to an extent sufficient form a cured, solid polymeric product; and
- recovering said cured solid polymeric product.
- 20. A process of producing a cured polymeric product comprising:
- forming a first liquid A comprising, as essential components:
- d. a curable organic polymer containing reactive silicon groups,
- a. radically-polymerizable monomer, and
- b. an accelerator for the polymerization of said radically-polymerizable monomer;
- forming a second liquid B comprising, as essential components:
- e. an accelerator for curing said organic polymer containing reactive silicon groups, and
- c. an initiator for the polymerization of said radically-polymerizable monomer;
- maintaining said first liquid A and said second liquid B separate and at temperatures, respectively, such that said component "a" does not polymerize and the reactive silicon in said component "d" does not react to any substantial extent;
- mixing said liquids A and B at room temperature to form a mixture;
- holding said mixture for up to about 10 minutes at room temperature sufficient to polymerize said component "a", to cure said polymer, and to react said reactive silicon to an extent sufficient form a cured, solid polymeric produce; and
- recovering said cured solid polymeric product.
- 21. A process of producing a cured polymeric product comprising:
- forming a first liquid A comprising, as essential components:
- d. a curable polymer containing reactive silicon groups,
- a. radically-polymerizable monomer,
- b. an accelerator for the polymerization of said radically-polymerizable monomer, and
- e. an accelerator for curing said organic polymer containing reactive silicon groups;
- forming a second liquid B comprising, as its essential component:
- c. an initiator for the polymerization of said radically-polymerizable monomer;
- maintaining said first liquid A and said second liquid B separate and at temperatures, respectively, such that said component "a" does not polymerize and the reactive silicon in said component "d" does not react to any substantial extent;
- mixing said liquids A and B at room temperature to form a mixture;
- holding said mixture for up to about 10 minutes at room temperature sufficient to polymerize said component "a", to cure said polymer, and to react said reactive silicon to an extent sufficient form a cured, solid polymeric product; and
- recovering said cured solid polymeric product.
Priority Claims (2)
| Number |
Date |
Country |
Kind |
| 4-76937 |
Mar 1992 |
JPX |
|
| 5-05755 |
Jan 1993 |
JPX |
|
CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of U.S. application Ser. No. 08/034, 813 filed Mar. 19, 1993, now abandoned.
US Referenced Citations (1)
| Number |
Name |
Date |
Kind |
|
4746702 |
Greco et al. |
May 1988 |
|
Continuation in Parts (1)
|
Number |
Date |
Country |
| Parent |
34813 |
Mar 1993 |
|
Patent Grant
5459206
