Claims
- 1. A hydroprocessing method comprising the steps of:
mixing a liquid feed with reactor effluent and flashing with hydrogen, then separating any gas from the liquid upstream of the reactor and then reacting the feed/diluent/hydrogen mixture with a catalyst in the reactor, removing the liquid from the ractor partially down the reactor, reflashing the liquid with hydrogen gas to resaturate with hydrogen, separating the gas from the liquid and reintroducing the liquid back into the reactor at the point it was withdrawn.
- 2. The method as in claim 1 where the liquid is introduced into a second reactor containing a different catalyst.
- 3. In a hydroprocessing method for treating an oil feed with hydrogen in a reactor, the improvement comprising a two liquid hydroprocessing method comprising the steps of:
mixing and flashing the hydrogen and the oil to be treated in the presence of a solvent or diluent wherein the percentage of hydrogen in solution is greater than the percentage of hydrogen in the oil feed to form a liquid feed/diluent/hydrogen mixture, then separating any gas from the liquid mixture upstream of the reactor, and then reacting the liquid feed/diluent/hydrogen mixture with a catalyst in the reactor to at least one of remove contaminants and saturate aromatics.
- 4. The method as recited in claim 3 wherein the solvent or diluent is selected from the group of heavy naptha, propane, butane, pentane, light hydrocarbons, light distillates, naptha, diesel, VG0, previously hydroprocessed stocks, or combinations thereof.
- 5. The method as recited in claim 4 wherein the feed is selected from the group of oil, petroleum fraction, distillate, resid, diesel fuel, deasphatted oil, waxes, lubes, and specialty products.
- 6. A two liquid phase hydroprocessing method comprising the steps of blending a feed with a diluent, saturating the diluent/feed mixture with hydrogen ahead of a reactor to form a liquid feed/diluent/hydrogen mixture, separating any excess gas from the liquid mixture ahead of the reactor, and reacting the liquid feed/diluent/hydrogen mixture with a catalyst in the reactor to remove at least one of sulphur, nitrogen, oxygen, metals, and combinations thereof.
- 7. The method as recited in claim 6, wherein the reactor is kept at a pressure of 500-5000 psi.
- 8. The method as recited in claim 7, further comprising the step of running the reactor at super critical solution conditions so that there is no solubility limit.
- 9. The method as recited in claim 6, wherein the process is a multi-stage process using a series of two or more reactors.
- 10. The method as recited in claim 8, further comprising the step of removing heat from the reactor effluent, separating the diluent from the reacted feed, and recycling the diluent to a point upstream of the reactor.
- 11. The method as recited in claim 6, wherein multiple reactors are used to remove at least one of sulphur, nitrogen, oxygen, metals, and combinations thereof and then to saturate aromatics.
- 12. The method as recited in claim 6, wherein a portion of the reacted feed is recycled and mixed with the blended feed ahead of the reactor.
- 13. The method as recited in claim 9, wherein a first stage is operated at conditions sufficient for removal of sulfur, nitrogen, and oxygen contaminants from the feed, at least 620 K. 100 psi, after which, the contaminant H2S, NH3 and water are removed and a second stage reactor is then operated at conditions sufficient for aromatic saturation of the processed feed.
- 14. The method as recited in claim 13, wherein in addition to hydrogen, CO (carbon monoxide) is mixed with the hydrogen and the resultant liquid feed/diluent/hydrogen/CO mixture is contacted with a Fischer-Tropsch catalyst in the reactor for the synthesis of hydrocarbon chemicals.
- 15. The method as recited in claim 3, wherein in addition to hydrogen, CO (carbon monoxide) is mixed with the hydrogen and the resultant feed/diluent/hydrogen/CO mixture is contacted with a Fischer-Tropsch catalyst in the reactor for the synthesis of hydrocarbon chemicals.
- 16. The method as recited in claim 6, wherein in addition to hydrogen, CO (carbon monoxide) is mixed with the hydrogen and the resultant feed/diluent/hydrogen/CO mixture is contacted with a Fischer-Tropsch catalyst in the reactor for the synthesis of hydrocarbon chemicals.
- 17. The method as recited in claim 6, wherein the reactor is kept at a pressure of 1000-3000 psi.
- 18. The method as recited in claim 1, wherein the reactor is kept at a pressure of 500-5000 psi.
- 19. The method as recited in claim 1, wherein the reactor is kept at a pressure of 1000-3000 psi.
- 20. The method as recited in claim 1, further comprising the step of running the reactor at super critical solution conditions so that there is no solubility limit.
- 21. The method as recited in claim 1, wherein the process is a multi-stage process using a series of two or more reactors.
- 22. The method as recited in claim 20, further comprising the step of removing heat from the reactor effluent, separating the diluent from the reacted feed, and recycling the diluent to a point upstream of the reactor.
- 23. The method as recited in claim 1, wherein multiple reactors are used to remove at least one of sulphur, nitrogen, oxygen, metals, and combinations thereof and then to saturate aromatics.
- 24. The method as recited in claim 1, wherein a portion of the reacted feed is recycled and mixed with the blended feed ahead of the reactor.
- 25. The method as recited in claim 21, wherein the first stage is operated at conditions sufficient for removal of sulfur, nitrogen, and oxygen contaminants from the feed, at least 620 K, 100 psi, after which, the contaminant H2S, NH3 and water are removed and a second stage reactor is then operated at conditions sufficient for aromatic saturation of the processed feed.
- 26. The method as recited in claim 1, wherein multiple reactors are used for molecular weight reduction.
- 27. The method as recited in claim 1, wherein multiple ractors are used for cracking.
- 28. The method as recited in claim 12, wherein said recycled and mixed reacted feed reduces the temperature rise through the reactor.
- 29. The method as recited in claim 24, wherein said recycled and mixed reacted feed reduces the temperature rise through the reactor.
- 30. The method as recited in claim 12, wherein the recycle ratio is about 1/1 to 2.5/1 based on volume.
- 31. The method as recited in claim 24, wherein the recycle ratio is about 1/1 to 2.5/1 based on volume.
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application claims the benefit of and is a continuation of U.S. patent application Ser. No. 09/104,079, filed Jun. 24, 1998, which is a continuation-in-part of U.S. provisional application, Serial No. 60/050,599, filed Jun. 24, 1997, now abandoned.
Provisional Applications (1)
|
Number |
Date |
Country |
|
60050599 |
Jun 1997 |
US |
Continuations (3)
|
Number |
Date |
Country |
Parent |
09599913 |
Jun 2000 |
US |
Child |
10162310 |
Jun 2002 |
US |
Parent |
09538541 |
Mar 2000 |
US |
Child |
10162310 |
Jun 2002 |
US |
Parent |
09104079 |
Jun 1998 |
US |
Child |
09538541 |
Mar 2000 |
US |