The present invention relates to the field of material drying. More particularly, the invention relates to an energy-efficient method and apparatus for drying organic waste materials such as animal and poultry waste, municipal wastewater sludge, urban post-consumer food waste, or manufactured food byproducts and residuals into solid fuel.
Organic waste material such as such as livestock or poultry waste, municipal wastewater sludge, urban post-consumer food waste, or manufactured food byproducts has a significant quantity of combustible content. For example, dairy waste is typically 70,000 BTU/day/1,000-lbmass Steady State Live Weight (0.16 MJ/day/kg of live animal weight). However, this material can not be economically combusted to generate heat or power because the moisture content of the waste is too high, typically 90-95%. Mechanical dewatering can remove 50-70% of the moisture, but mechanical dewatering only reduces free water, with the resulting wet press cake having a moisture content of 55-70%. Evaporative drying is required to reduce the moisture content in organic material to less than 10% moisture. Drying the material to less than 10% moisture will suppress natural aerobic biodegradation, extending the shelf life of the material so that its will retain its heat value in storage. It is also important to reduce moisture to increase the energy content in the dried material to greater than 9,500 BTU/lbmass (greater than 22 MJ/kg) so that it is suitable as a substitute for fuel without degrading the combustion process that is generating steam for thermal energy or electricity. The preferred shape of the dried solid fuel is a pellet, which is suitable for a variety of standard bulk handling and material transport equipment.
An example of a process to produce pelletized, dried organic material is provided in U.S. Pat. No. 6,692,642 (Josse et al.) which describes complete biological treatment of hog manure with anaerobic stabilization, mechanical dewatering of solids, and indirect heat drying using a hot-oil disk dryer followed by pelletization for use as fertilizer. The problem with this process is that anaerobic stabilization lowers the potential fuel value of pelletized hog manure.
There are numerous examples of non-organic pellet drying. For example, U.S. Pat. Nos. 7,421,802 and 7,171,762 (Roberts et al.); U.S. Pat. No. 7,024,794 (Mynes); U.S. Pat. No. 6,938,357 (Hauch); U.S. Pat. Nos. 6,807,748 and 6,237,244 (Bryan et al.); U.S. Pat. Nos. 6,505,416, 6,467,188 and 6,438,864 (Sandford); U.S. Pat. No. 5,661,150 (Yore, Jr.); and U.S. Pat. No. 5,265,347 (Woodson et al.) are examples of centrifugal pellet dryers used in plastic manufacturing for liquid-solid plastic pellet slurry separation. These are not suitable for organic materials because the pellet strength is not high enough to hold its shape in high g-force centrifugal screening.
Another example of non-organic pellet drying is given in U.S. Pat. No. 6,807,749 (Norman et al.) wherein the use of warm, carbon black smoke is used to dry carbon black pellets. The waste heat in the carbon black smoke in the '749 patent is an example of the use of waste heat recovery of a process stream from the manufacturing process. Similar waste heat for drying of organic material is described in U.S. Pat. No. 4,114,289 (Boulet) wherein a vertical dryer with co-current gas flow and multiple chamber trays uses waste heat recovery from the exhaust gas of a bagasse-fired steam boiler as a heat source. A similar application is described in U.S. Pat. No. 4,047,489 (Voorheis et al.) wherein the process of using waste heat from a bagasse-fired boiler is used to dry wet bagasse prior to firing in the boiler. In the '489 patent, wet bagasse is dried from 50% moisture to 15-25% moisture using 610-650° F. (321-343° C.) waste heat flue gas from bagasse-fired boiler. All three of these applications have sources of waste heat available from existing, co-located manufacturing processes. A more economical method of drying is required in those instances wherein waste heat is not available from an existing process.
An example of pellet drying in the plastic industry that is more closely related to organic waste pellet drying is given in U.S. Pat. No. 5,546,763 (Weagraff et al) where warm, dehumidified air is used to dry pellets in a cylindrical, vertical dryer. The low melting point of the plastic material to be dried restricts the use of high temperature air.
This constraint on the use of high temperature is similar to the problem of drying organic waste material for use as fuel. Organic waste material such as livestock or poultry waste, municipal wastewater sludge, urban post-consumer food waste, or manufactured food byproducts needs to be dried at low temperatures—typically below 320° F. (160° C.) to prevent ignition if the intent is to dry the product for use as a solid, renewable fuel.
Fluidized bed dryers such as those described in U.S. Pat. Nos. 5,161,315 and 5,238,399 (Long) and U.S. Pat. No. 6,635,297 (Moss et al.) have been effectively used for drying and roasting of organic waste materials. The problem with low-temperature fluidized bed dryers is that the exhaust gas temperatures are typically 200-250° F. (93-121° C.). At these temperatures, the evaporation efficiency is 2,500-3,000 BTU/lbmass H2O removed (5.8-7.0 MJ/kg).
There are numerous examples of low-temperature drying of organic product streams. The application of low temperature drying of residuals from corn processing to produce animal feed is described in U.S. Pat. Nos. 4,181,748 and 4,171,384 (Chwalek et. al.) wherein hulls, germ cake, fine fiber tailings, and the protein-rich fraction from corn starch separation are dewatered and then dried in a convection oven at 215° F. (102° C.) for four hours (14,400 s). Another example of low temperature drying is described in U.S. Pat. No. 7,413,760 (Green et al.) in the processing of parboiled rice to make ready-to-eat cereal. The process in the '760 patent describes wet-pellet drying using warm-air drying at 122-158° F. (50-70° C.) for 20-30 minutes (1,200-1,800 seconds) to make flakes.
Vertical, static dryers with low temperatures and long residence time can be designed so that dryer exhaust gas can be saturated at temperatures as low as 15-20° F. (8.3-11.1° C.) above ambient air temperature. At these temperatures, the evaporation efficiency is 1,200-1,300 BTU/lbmass H2O removed (2.8-3.0 MJ/kg). Static dryers are more energy efficient and have a lower initial capital cost than other dryers with the same dryer capacity rating.
There are numerous examples of low-temperature organic pellet drying using vertical, static dryers. For example, U.S. Pat. No. 6,311,411 (Clark) used a vertical dryer with multiple decks; independent temperature and airflow control; and counter-current air flow for drying pellets made from agricultural products. U.S. Pat. No. 6,168,815 (Kossmann et al.) used low-temperature warm-air drying in vertical dryers to avoid denaturing proteins in the manufacture of fish feed directly from fresh raw fish. U.S. Pat. Nos. 6,125,550, 6,082,251, and 5,852,882 (Kendall et al.) used either a static bed or vertical dryer with non-fluidizing air flow of 100 ft/min (1.5 m/s) to lower moisture in pre-cooked, packaged rice. The final product moisture was reduced from 15-17% to 6-10% in a static bed dryer or vertical bed dryer with a residence time of 5-7 minutes (300-420 s) at 212° F. (100° C.). Another example of low-temperature drying is found in U.S. Pat. No. 5,233,766 (Frederiksen et al.) wherein a vertical dryer with a series of multiple inclined baffles are used to redirect the flow of granular material to obtain uniform residence time of grain in the manufacturing of Ready-to-Eat breakfast cereal. U.S. Pat. No. 4,424,634 (Westelaken) claims that a gravity flow vertical dryer is better than a free-fall gravity vertical dryer for drying freshly harvested grain. U.S. Pat. No. 4,258,476 (Caughey), describes a vertical dryer consisting of slow-moving gravity flow bed with low-velocity air flow of 100-500 ft/min (0.5-2.5 m/s) to dry wood chips.
A problem with static dryers is that organic waste material has a low shear stress. Static dryers are usually designed with solid bed depths of 6-12 ft (2-4 m). At these bed depths, the organic material can crush and compress, causing catastrophic failure of the dryer. U.S. Pat. No. 6,168,815 (Kossmann et al.) observed that drying pelletized, fresh raw fish to 6-10% moisture provided sufficient mechanical strength to maintain pellet shape during transport. U.S. Pat. No. 4,873,110 (Short et al.) observed that drying pelletized cereal product below 9.5% moisture resulted in the product becoming hardened. Reducing moisture to control pellet durability was also reported in U.S. Pat. No. 7,413,760 (Green et al.) for wet-pellet drying of parboiled rice cereal.
One solution is to extrude the moist organic material into pellets strands and then rapidly char the exterior of the pellet in a high temperature dryer. The outside crust of a pellet strand that has been rapidly dried at the surface can provide the rigidity to withstand the shear stress and crush pressure of a deep static bed. The charring of the pellet exterior is similar to toasting of ready-to-eat cereal flakes at high temperatures for short durations as described in U.S. Pat. No. 4,873,110 (Short et al.) and U.S. Pat. No. 7,413,760 (Green et al.).
Therefore, the object of this invention is to provide a method and apparatus that provides a rapid, high temperature static drying process in a shallow bed, followed by a traditional vertical, static dryer with a deep bed. Hot exhaust gas from a shallow-bed depth hot-temperature static dryer is then recirculated to provide thermal energy to the deep-bed warm-air static dryer.
The invention consists of a two-stage static dryer with a smaller, shallow-bed hot-temperature upper stage stacked on top of a deep-bed warm-temperature lower stage. Wet organic waste material in the form of pellet strands is fed to the upper hot-temperature stage. The solid organic material flows downward by gravity through the upper hot-temperature stage and into the lower warm-temperature stage.
In a further preferred embodiment, hot air flows counter-currently up through the static shallow bed of pellet strands in the upper hot-temperature stage. Warm air flows counter-currently up through the static deep bed of pellet strands in the lower warm-temperature stage.
In a further preferred embodiment, concave upward baffles distribute the flow of pellets evenly across the cross-section of the static dryer stages, while concave downward diffuser cones distribute the flow of hot air and warm air across the cross-section of the static dryer stages.
In a further preferred embodiment, thermal energy is added to the hot-temperature stage by heating hot air with either steam, gas, oil, electric, or waste heat. Waste heat in the upper hot-temperature stage exhaust is routed to and mixed with ambient air to provide thermal energy for the warm-air temperature stage. Additional thermal energy is added to the warm-temperature stage by heating ambient air with steam, gas, oil, electric, or waste heat.
In a further preferred embodiment, temperature controllers are provided for both stages of the two-stage static dryer. The upper hot-temperature stage controller is used to control maximum temperature to prevent ignition. The lower warm-temperature stage controller is used to control the inlet air to approximately 15-50° F. (8.3-27.8° C.) above ambient air temperature to maintain the energy efficiency of the dryer.
The subject of the invention is a method and apparatus (10) for drying organic waste material into solid fuel. The method consists of two stages of drying. In the first stage, pelletized, wet organic material is heated for a short time interval in a high-temperature, vertical static dryer stage (1). The short residence time in the high temperature dryer rapidly dries the outer crust of the pellets, increasing the rigidity of the pellet and its ability to withstand shear stress and crush pressure in a downstream drying stage. In the second stage, pellets that have a dry exterior and moist interior are heated for a long time interval in a warm-temperature, vertical static dryer stage (2).
The process conditions in the first, high-temperature stage consist of:
The process conditions in the second, warm-temperature stage consist of:
The upper, high temperature stage (1) of the apparatus consists of a top inlet (2) to receive wet, pelletized organic material (3) and a bottom outlet hopper (4) to discharge partially dried pellets. A forced draft fan (5) and air heater (6) whose thermal energy source may be from gas, steam, electric, or waste-heat provides hot air to the upper, high-temperature stage air to the inlet (7) in the bottom outlet hopper (4). Warm exhaust gas exits through the upper, high-temperature stage exhaust gas outlet (8). A filter screen (9) in the upper, high temperature stage prevents pellets from being entrained in the warm exhaust gas. An upper diffuser cone (11) and lower diffuser cone (13) distribute hot air evenly across the cross-sectional area of the upper, high-temperature stage. One or more pellet baffles (12) distribute moist pellets evenly across the cross-sectional area of the upper, high-temperature stage and prevent short-circuiting. A plurality of temperature indicators in the upper portion (14) and lower portion (15) of the upper, high-temperature stage provide monitoring information for operators. A temperature indicator and controller (16) on the discharge side of the forced draft fan (5) and air heater (6) controls hot air temperature.
The lower, warm-temperature stage (20) of the apparatus consists of a top inlet (21) to receive partially dried pellets from the upper, hot-temperature stage bottom hopper (4) and a bottom hopper and outlet (22) to discharge dried pellets (23). A forced draft fan (240) and air heater (25) whose thermal energy source may be from gas, steam, electric, or waste-heat provides warm air to one inlet branch (26) of a venturi mixing tee (27). The other inlet branch to the venturi mixing tee (27) is an extension of the upper, high-temperature stage exhaust gas outlet (8). The venturi tee (27) mixes the two warm gas streams. The discharge of the mixture of warm gases from the venturi tee (27) is connected to the lower, warm-temperature stage air inlet (28) in the bottom hopper and outlet (22). Cool, exhaust gas exits through the lower, warm-temperature stage exhaust gas outlet (29). A filter screen (30) in the lower, warm-temperature stage prevents pellets from being entrained in the cool exhaust gas. An upper diffuser cone (31) and lower diffuser cone (33) distribute hot air evenly across the cross-sectional area of the lower, warm-temperature stage. One or more pellet baffles (32) distribute partially dried pellets evenly across the cross-sectional area of the lower, warm-temperature stage and prevent short-circuiting. A plurality of temperature indicators in the upper portion (34) and lower portion (35) of the lower, warm-temperature stage provide monitoring information for operators. A temperature indicator and controller (36) on the discharge side of the forced draft fan (24) and air heater (25) controls the warm air temperature.
In a further preferred embodiment, the sensible heat in the exhaust gas from the upper, high temperature stage (8) is mixed with ambient air from the lower, warm-temperature stage forced draft fan (24) in a venturi tee mixer (27) without any additional thermal energy input from the lower, warm-temperature air heater (25). All of the input thermal energy input is added to the upper, high temperature stage to partially dry the outer crust of the pellets. The excess sensible heat of the air plus evaporated water vapor from the upper, high temperature stage is recirculated to heat the warm inlet air added to the lower, warm-temperature stage.
The following example for converting dewatered dairy waste into solid fuel provides representative operating conditions for the invention. Dairy waste that has been dewatered and pelletized has a moisture content of 58%. The dry solids in the dairy waste have a heat capacity of 0.70 BTU/lbmass-° F. (2,900 J/kg-° C.). The heat capacity of the moist pellets composed of water and dry dairy waste solids is 0.87 BTU/lbmass-° F. (3,600 J/kg-° C.). Ambient air is 75° F. (23.9° C.), and relative humidity is 75%. In order to dry the pelletized organic dairy waste to 10% moisture, 643 BTU/lbmass of pellets (1.5 MJ/kg) is added as thermal energy to the inlet air that is fed into the upper, hot-temperature dryer, resulting in the following operating conditions:
The addition of 643 BTU/lbmass of pellets (1.5 MJ/kg) results in the removal of 0.533 lbmass of H2O per lbmass of pellets (0.533 kg/kg) for an overall thermal efficiency of 1,205 BTU/lbmass H2O removed (2.8 MJ/kg). This thermal efficiency is superior to fluid bed dryers, disk dryers, convection oven dryers, and rotary dryers, all of which have thermal removal efficiencies of 2,500-5,000 BTU/lbmass H2O removed (5.8-11.6 MJ/kg).
While this invention has been described with respect to particular embodiments thereof, it is apparent that numerous other forms and modifications of this invention will be obvious to those skilled in the art. The appended claims and this invention generally should be construed to cover all such obvious forms and modifications which are within the true spirit and scope of the present invention.
Number | Name | Date | Kind |
---|---|---|---|
3290788 | Seelandt | Dec 1966 | A |
3920505 | Helleur | Nov 1975 | A |
4047489 | Voorheis et al. | Sep 1977 | A |
4079585 | Helleur | Mar 1978 | A |
4114289 | Boulet | Sep 1978 | A |
4171384 | Chwalek et al. | Oct 1979 | A |
4181748 | Chwalek et al. | Jan 1980 | A |
4258476 | Caughey | Mar 1981 | A |
4424634 | Westelaken | Jan 1984 | A |
4873110 | Short et al. | Oct 1989 | A |
4987252 | Kuragano et al. | Jan 1991 | A |
5161315 | Long | Nov 1992 | A |
5207734 | Day et al. | May 1993 | A |
5233766 | Frederiksen et al. | Aug 1993 | A |
5238399 | Long | Aug 1993 | A |
5265347 | Woodson et al. | Nov 1993 | A |
5476990 | Hittner et al. | Dec 1995 | A |
5546673 | Weagraff et al. | Aug 1996 | A |
5611150 | Yore, Jr. | Mar 1997 | A |
5616296 | Hittner et al. | Apr 1997 | A |
5711018 | Hittner et al. | Jan 1998 | A |
5843307 | Faivre et al. | Dec 1998 | A |
5852882 | Kendall et al. | Dec 1998 | A |
6082251 | Kendall et al. | Jul 2000 | A |
6125550 | Kendall et al. | Oct 2000 | A |
6168815 | Kossmann et al. | Jan 2001 | B1 |
6184373 | Bernard et al. | Feb 2001 | B1 |
6237244 | Bryan et al. | May 2001 | B1 |
6311411 | Clark | Nov 2001 | B1 |
6332909 | Teshima et al. | Dec 2001 | B1 |
6438864 | Sandford | Aug 2002 | B1 |
6467188 | Sandford | Oct 2002 | B1 |
6505416 | Sandford | Jan 2003 | B2 |
6635297 | Moss et al. | Oct 2003 | B2 |
6692642 | Josse et al. | Feb 2004 | B2 |
6719821 | Yadav et al. | Apr 2004 | B2 |
6782947 | de Rouffignac et al. | Aug 2004 | B2 |
6807748 | Bryan et al. | Oct 2004 | B2 |
6807749 | Norman et al. | Oct 2004 | B2 |
6877555 | Karanikas et al. | Apr 2005 | B2 |
6880633 | Wellington et al. | Apr 2005 | B2 |
6915850 | Vinegar et al. | Jul 2005 | B2 |
6918442 | Wellington et al. | Jul 2005 | B2 |
6918443 | Wellington et al. | Jul 2005 | B2 |
6923257 | Wellington et al. | Aug 2005 | B2 |
6929067 | Vinegar et al. | Aug 2005 | B2 |
6932155 | Vinegar et al. | Aug 2005 | B2 |
6938357 | Hauch | Sep 2005 | B2 |
6948562 | Wellington et al. | Sep 2005 | B2 |
6951247 | de Rouffignac et al. | Oct 2005 | B2 |
6964300 | Vinegar et al. | Nov 2005 | B2 |
6966374 | Vinegar et al. | Nov 2005 | B2 |
6969123 | Vinegar et al. | Nov 2005 | B2 |
6981548 | Wellington et al. | Jan 2006 | B2 |
6991032 | Berchenko et al. | Jan 2006 | B2 |
6991033 | Wellington et al. | Jan 2006 | B2 |
6991036 | Sumnu-Dindoruk et al. | Jan 2006 | B2 |
6991045 | Vinegar et al. | Jan 2006 | B2 |
6994169 | Zhang et al. | Feb 2006 | B2 |
6997518 | Vinegar et al. | Feb 2006 | B2 |
7004247 | Cole et al. | Feb 2006 | B2 |
7004251 | Ward et al. | Feb 2006 | B2 |
7011154 | Maher et al. | Mar 2006 | B2 |
7013972 | Vinegar et al. | Mar 2006 | B2 |
7024794 | Mynes | Apr 2006 | B1 |
7032660 | Vinegar et al. | Apr 2006 | B2 |
7040397 | de Rouffignac et al. | May 2006 | B2 |
7040398 | Wellington et al. | May 2006 | B2 |
7040399 | Wellington et al. | May 2006 | B2 |
7040400 | de Rouffignac et al. | May 2006 | B2 |
7051807 | Vinegar et al. | May 2006 | B2 |
7051808 | Vinegar et al. | May 2006 | B1 |
7051811 | de Rouffignac et al. | May 2006 | B2 |
7055600 | Messier et al. | Jun 2006 | B2 |
7063145 | Veenstra et al. | Jun 2006 | B2 |
7066254 | Vinegar et al. | Jun 2006 | B2 |
7066257 | Wellington et al. | Jun 2006 | B2 |
7077198 | Vinegar et al. | Jul 2006 | B2 |
7077199 | Vinegar et al. | Jul 2006 | B2 |
7086465 | Wellington et al. | Aug 2006 | B2 |
7090013 | Wellington | Aug 2006 | B2 |
7096942 | de Rouffignac et al. | Aug 2006 | B1 |
7100994 | Vinegar et al. | Sep 2006 | B2 |
7104319 | Vinegar et al. | Sep 2006 | B2 |
7114566 | Vinegar et al. | Oct 2006 | B2 |
7128153 | Vinegar et al. | Oct 2006 | B2 |
7152616 | Zucchelli et al. | Dec 2006 | B2 |
7156176 | Vinegar et al. | Jan 2007 | B2 |
7165615 | Vinegar et al. | Jan 2007 | B2 |
7171762 | Roberts et al. | Feb 2007 | B2 |
7225866 | Berchenko et al. | Jun 2007 | B2 |
7378070 | Megy | May 2008 | B2 |
7413760 | Green et al. | Aug 2008 | B2 |
7421802 | Roberts et al. | Sep 2008 | B2 |
7461691 | Vinegar et al. | Dec 2008 | B2 |
7640766 | Shelton | Jan 2010 | B2 |
7735274 | Constantz et al. | Jun 2010 | B2 |
7735935 | Vinegar et al. | Jun 2010 | B2 |
7744761 | Constantz et al. | Jun 2010 | B2 |
7749476 | Constantz et al. | Jul 2010 | B2 |
7753618 | Constantz et al. | Jul 2010 | B2 |
7754169 | Constantz et al. | Jul 2010 | B2 |
7771684 | Constantz et al. | Aug 2010 | B2 |
7815880 | Constantz et al. | Oct 2010 | B2 |
7829053 | Constantz et al. | Nov 2010 | B2 |
7866638 | Neumann et al. | Jan 2011 | B2 |
7887694 | Constantz et al. | Feb 2011 | B2 |
7902262 | Armstrong et al. | Mar 2011 | B2 |
7906028 | Constantz et al. | Mar 2011 | B2 |
7910080 | Megy | Mar 2011 | B2 |
7914685 | Constantz et al. | Mar 2011 | B2 |
7931809 | Constantz et al. | Apr 2011 | B2 |
20020178865 | Yadav et al. | Dec 2002 | A1 |
20030071069 | Shelton | Apr 2003 | A1 |
20030079877 | Wellington et al. | May 2003 | A1 |
20030080604 | Vinegar et al. | May 2003 | A1 |
20030098149 | Wellington et al. | May 2003 | A1 |
20030098605 | Vinegar et al. | May 2003 | A1 |
20030100451 | Messier et al. | May 2003 | A1 |
20030102124 | Vinegar et al. | Jun 2003 | A1 |
20030102125 | Wellington et al. | Jun 2003 | A1 |
20030102126 | Sumnu-Dindoruk et al. | Jun 2003 | A1 |
20030102130 | Vinegar et al. | Jun 2003 | A1 |
20030108460 | Andreev et al. | Jun 2003 | A1 |
20030111223 | Rouffignac et al. | Jun 2003 | A1 |
20030116315 | Wellington et al. | Jun 2003 | A1 |
20030130136 | Rouffignac et al. | Jul 2003 | A1 |
20030131993 | Zhang et al. | Jul 2003 | A1 |
20030131994 | Vinegar et al. | Jul 2003 | A1 |
20030131995 | de Rouffignac et al. | Jul 2003 | A1 |
20030131996 | Vinegar et al. | Jul 2003 | A1 |
20030136558 | Wellington et al. | Jul 2003 | A1 |
20030136559 | Wellington et al. | Jul 2003 | A1 |
20030137181 | Wellington et al. | Jul 2003 | A1 |
20030141066 | Karanikas et al. | Jul 2003 | A1 |
20030141067 | Rouffignac et al. | Jul 2003 | A1 |
20030141068 | Pierre de Rouffignac et al. | Jul 2003 | A1 |
20030142964 | Wellington et al. | Jul 2003 | A1 |
20030146002 | Vinegar et al. | Aug 2003 | A1 |
20030148894 | Vinegar et al. | Aug 2003 | A1 |
20030155111 | Vinegar et al. | Aug 2003 | A1 |
20030164239 | Wellington et al. | Sep 2003 | A1 |
20030173072 | Vinegar et al. | Sep 2003 | A1 |
20030173078 | Wellington et al. | Sep 2003 | A1 |
20030173080 | Berchenko et al. | Sep 2003 | A1 |
20030173081 | Vinegar et al. | Sep 2003 | A1 |
20030173082 | Vinegar et al. | Sep 2003 | A1 |
20030173085 | Vinegar et al. | Sep 2003 | A1 |
20030178191 | Maher et al. | Sep 2003 | A1 |
20030183390 | Veenstra et al. | Oct 2003 | A1 |
20030192691 | Vinegar et al. | Oct 2003 | A1 |
20030192693 | Wellington | Oct 2003 | A1 |
20030196788 | Vinegar et al. | Oct 2003 | A1 |
20030196789 | Wellington et al. | Oct 2003 | A1 |
20030196801 | Vinegar et al. | Oct 2003 | A1 |
20030196810 | Vinegar et al. | Oct 2003 | A1 |
20030201098 | Karanikas et al. | Oct 2003 | A1 |
20030205378 | Wellington et al. | Nov 2003 | A1 |
20030209348 | Ward et al. | Nov 2003 | A1 |
20040020642 | Vinegar et al. | Feb 2004 | A1 |
20040040715 | Wellington et al. | Mar 2004 | A1 |
20040055969 | Barnes | Mar 2004 | A1 |
20040074252 | Shelton | Apr 2004 | A1 |
20040139821 | Yadav | Jul 2004 | A1 |
20040211554 | Vinegar et al. | Oct 2004 | A1 |
20040211557 | Cole et al. | Oct 2004 | A1 |
20040211569 | Vinegar et al. | Oct 2004 | A1 |
20050056313 | Hagen et al. | Mar 2005 | A1 |
20050092483 | Vinegar et al. | May 2005 | A1 |
20050109396 | Zucchelli et al. | May 2005 | A1 |
20060083694 | Kodas et al. | Apr 2006 | A1 |
20060213657 | Berchenko et al. | Sep 2006 | A1 |
20070054106 | Armstrong et al. | Mar 2007 | A1 |
20070095393 | Zucchelli et al. | May 2007 | A1 |
20070160899 | Atanassova et al. | Jul 2007 | A1 |
20070178163 | Kodas et al. | Aug 2007 | A1 |
20070209799 | Vinegar et al. | Sep 2007 | A1 |
20070253882 | Megy | Nov 2007 | A1 |
20070290384 | Kodas et al. | Dec 2007 | A1 |
20080108122 | Paul et al. | May 2008 | A1 |
20080210089 | Tsangaris et al. | Sep 2008 | A1 |
20080219909 | Megy | Sep 2008 | A1 |
20080289385 | Megy | Nov 2008 | A1 |
20080289692 | Zucchelli et al. | Nov 2008 | A1 |
20080314593 | Vinegar et al. | Dec 2008 | A1 |
20090001020 | Constantz et al. | Jan 2009 | A1 |
20090020044 | Constantz et al. | Jan 2009 | A1 |
20090039000 | Zucchelli et al. | Feb 2009 | A1 |
20090165380 | Lau et al. | Jul 2009 | A1 |
20090169452 | Constantz et al. | Jul 2009 | A1 |
20100011956 | Neumann et al. | Jan 2010 | A1 |
20100083880 | Constantz et al. | Apr 2010 | A1 |
20100126037 | Moss et al. | May 2010 | A1 |
20100126727 | Vinegar et al. | May 2010 | A1 |
20100132556 | Constantz et al. | Jun 2010 | A1 |
20100132591 | Constantz et al. | Jun 2010 | A1 |
20100135865 | Constantz et al. | Jun 2010 | A1 |
20100135882 | Constantz et al. | Jun 2010 | A1 |
20100154679 | Constantz et al. | Jun 2010 | A1 |
20100158786 | Constantz et al. | Jun 2010 | A1 |
20100229725 | Farsad et al. | Sep 2010 | A1 |
20100230830 | Farsad et al. | Sep 2010 | A1 |
20100236242 | Farsad et al. | Sep 2010 | A1 |
20100270015 | Vinegar et al. | Oct 2010 | A1 |
20100275781 | Tsangaris et al. | Nov 2010 | A1 |
20100313793 | Constantz et al. | Dec 2010 | A1 |
20100319539 | Neumann et al. | Dec 2010 | A1 |
20100320294 | Neumann et al. | Dec 2010 | A1 |
20110036014 | Tsangaris et al. | Feb 2011 | A1 |
20110054084 | Constantz et al. | Mar 2011 | A1 |
20110059000 | Constantz et al. | Mar 2011 | A1 |
20110091366 | Kendall et al. | Apr 2011 | A1 |
20110091955 | Constantz et al. | Apr 2011 | A1 |
Number | Date | Country |
---|---|---|
3904262 | Aug 1990 | DE |
4445745 | Aug 1996 | DE |
10310258 | Sep 2004 | DE |
44375 | Jan 1982 | EP |
504647 | Sep 1992 | EP |
58007744 | Jan 1983 | JP |
63097299 | Apr 1988 | JP |
09066230 | Mar 1997 | JP |
2003227316 | Aug 2003 | JP |
WO 9504908 | Feb 1995 | WO |
WO 9810223 | Mar 1998 | WO |
Number | Date | Country | |
---|---|---|---|
20100126037 A1 | May 2010 | US |