Ultrasonic welding device and method for producing a metal foil stack
The invention relates to an ultrasonic welding device comprising a sonotrode and an anvil. The invention also relates to a method for producing a metal foil stack of metal foils, in particular for a cell of a lithium-ion battery.
A cell of a lithium-ion battery has a number of cathodes and anodes. The cathodes and anodes are in this case typically formed by means of metal foils, the cathodes (cathode foils) and the anodes (anode foils) being stacked alternately on top of one another, and a separator (a separator foil) being arranged between the cathodes and the anodes. The cathodes are each electrically conductively connected to one another and in particular additionally to what is referred to as a cell arrester (tab). Analogously, the anodes are each electrically conductively connected to one another and in particular additionally to what is referred to as a cell arrester (tab).
The anode foils and the cathode foils typically have a portion which is coated with an anode material and with a cathode material, respectively. In order to interconnect the anode foils and the cathode foils, respectively, said foils suitably each have a laterally protruding and uncoated second portion, which is also referred to as a flag, and which is provided for connecting to the other foils and possibly to the cell arrester.
For example, the flags of the anodes and the flags of the cathodes are respectively ultrasonically welded together with or without the relevant cell arrester. Such a connection by means of ultrasonic welding is, however, comparatively unreliable, i.e. not durable, such that the connections can become detached from one another over the life of the battery.
Alternatively, the metal foils are welded to one another, with or without the cell arrester, by means of a laser beam. In this case, however, air pockets and/or cavities can occur between the metal foils, as a result of which the electrical conductivity is comparatively low and/or the robustness of the connection is reduced.
A method for producing a foil stack is known from DE 10 2012 018 912 A1, in which method the metal foils to be joined are first pre-fixed and compressed by means of an ultrasonic welding device and are then integrally bonded to one another by means of laser welding (laser beam welding).
In this case, however, in particular due to an insufficiently defined area for the laser beam welding, the laser beam can act outside the region compressed by the ultrasonic welding. Consequently, a connection of the metal foils is comparatively unreliable and/or the robustness of the connection is comparatively low, and the connection of the metal foils to one another and to the cell arrester therefore is also not durable.
The problem addressed by the invention is that of providing a particularly suitable method for producing a metal foil stack, an ultrasonic welding device, and a metal foil stack of this kind. In particular, a particularly reliable connection of the metal foils to one another, and preferably additionally to a cell arrester, is to be provided by means of the ultrasonic welding device and/or by means of the method.
With regard to the ultrasonic welding device, the problem is solved according to the invention by the features of claim 1. With regard to the method, the problem is solved according to the invention by the features of claim 7, and, with regard to the metal foil stack, the problem is solved by the features of claim 10. Advantageous embodiments and developments are the subject matter of the dependent claims. The statements relating to the ultrasonic welding device also apply analogously to the method and to the metal foil stack and vice versa.
The ultrasonic welding device is used to introduce an embossed surface into a metal foil stack, which is provided and designed in particular for a cell of a lithium-ion battery. The ultrasonic welding device has an anvil and a sonotrode, which is also referred to as a horn, the anvil or the sonotrode having a number of first protrusions projecting from the working surface thereof. The first protrusions are used to form the, in particular strip-like, embossed surface by compacting (compressing, pressing) the metal foil stack in the course of the ultrasonic welding process.
In the course of the ultrasonic welding process, the metal foils of the metal foil stack that are stacked on top of one another are pressed against one another by means of the protrusions and the metal foil stack is compressed in the region of the first protrusions. In this way, a depression is pressed into the metal foil stack to form the embossed surface.
The embossed surface in this case defines a region which is acted on by a laser beam following the ultrasonic welding, or a strip along which the laser beam is moved for laser beam welding of the metal foils.
A strip-like surface is in this case understood to be a surface which is longer than it is wide, and in particular extends along a predetermined line (strip) in the longitudinal direction. Furthermore, a number of protrusions is to be understood to be a single protrusion or more than one protrusion.
The embossed surface does not have to be contiguous in this case. Due to the compacting of the metal foil stack, the distance between the individual metal foils is reduced in the region of the embossed surface, in particular a zero gap is set. Furthermore, the formation of cavities, and the resulting air pockets, between the metal foils during laser beam welding is prevented or at least the risk thereof is significantly reduced. Furthermore, due to the compacting, fluctuations in the thickness of the metal foil stack, i.e., in the extension of the metal foil stack in a direction perpendicular to the metal foils, are reduced in the region of the embossed surface. Homogeneous conditions, for example with respect to a penetration depth of the laser beam, are thus provided over the embossed surface for the subsequent laser beam welding process.
In the prior art mentioned at the outset, specifically DE 10 2012 018 912 A1, the anvil and the sonotrode used for compression are roughened as little as possible in order to prevent damage to the metal foils during compression. In this case, for a metal foil thickness of 10 μm, the thickness of the roughening is in the range of from 0.1 μm to 1.0 μm. In contrast thereto, according to the invention, a defined surface is specifically formed for the laser beam entry. The surface on which the laser beam for laser welding is to impinge, or along which the laser is to travel, is defined by means of the protrusions by compressing the metal foils, i.e., by compressing the metal foils by means of the protrusions to form the embossed surface. The first protrusions thus form a type of negative form for the embossed surface. In this way, the embossed surface is formed in the region of the metal foils that is arranged between the first protrusions and the sonotrode or anvil opposite said protrusions.
According to an advantageous development of the ultrasonic welding device, if the sonotrode has the first protrusions, the anvil has a contour which is formed by means of a number of second protrusions projecting from the working surface of said anvil. Alternatively, the anvil has a number of recesses in its working surface, by means of which recesses the contour is formed and which correspond to the first protrusions, in particular to the shape and arrangement of said protrusions with respect to one another.
If the anvil has the first protrusions, the sonotrode has the contour which is formed by means of a number of second protrusions projecting from the working surface of said sonotrode. Alternatively, the sonotrode has the contour which is formed by means of recesses which correspond to the first protrusions, in particular to the shape and arrangement of said protrusions with respect to one another.
In this case, the anvil and the sonotrode are oriented with respect to one another such that the first protrusions and the second protrusions are opposite one another in a direction perpendicular to the working surfaces, i.e., are arranged in opposition. In this way, the embossed surface is introduced in a region of the metal foils that is arranged between the first protrusions and the second protrusions opposite the first protrusions. If the contour is formed by means of the recesses, the anvil and the sonotrode are oriented with respect to one another such that the first protrusions and the recess are opposite one another in a direction perpendicular to the working surfaces, i.e., are arranged in opposition. In particular, in the course of the ultrasonic welding process, the first protrusions engage in the corresponding recesses at least partially in a direction perpendicular to the working surfaces of the sonotrode and the anvil. In this way, the embossed surface is introduced into the metal foils in the recesses, i.e., within the sonotrode or the anvil.
Alternatively, the first protrusions and the second protrusions are offset from the second protrusions, in particular in a grid-like manner, with respect to a direction parallel to the working surfaces. This is also referred to as the intermediate position of the first protrusions and the second protrusions. In the course of the ultrasonic welding process, the embossed surface is thus introduced into a region of the metal foils which is arranged between the first protrusions and the tool opposite said protrusions, i.e. the sonotrode or the anvil. In this case, the embossed surface is arranged between the second protrusions. The first protrusions in particular engage between the second protrusions at least partially in a direction perpendicular to the working surfaces of the sonotrode and the anvil. In this case, the first protrusions and the second protrusions together form a type of negative mold for the embossed surface.
Reference points are expediently provided both on the sonotrode and on the anvil for orienting the anvil and the sonotrode with respect to one another. These reference points are oriented with respect to one another for the ultrasonic welding of the metal foils, for example such that the reference points of the sonotrode are aligned with the reference points of the anvil that correspond thereto in a common direction perpendicular to the working surfaces. The first protrusions and the contour are in this case expediently arranged at a defined distance with respect to the respective reference points and in a defined relative position with respect to the reference points. As an alternative to reference points, a reference line, a reference curve, a reference surface or a combination thereof can also be used.
Sonotrodes have comparatively high requirements with respect to their structure-borne sound conduction and/or their vibration behavior compared to the anvil. The sonotrode can be damaged or misaligned, for example, during orientation. As a result, the anvil is preferably oriented with respect to the sonotrode. For example, the anvil is attached by means of suitable clamping in accordance with the reference points. The tolerances of the reference points with respect to the protrusions and the (manufacturing) tolerances of the protrusions themselves are expediently selected to be as small as possible.
The first protrusions, the recess and/or the second protrusions can, for example, be pyramid-shaped, hemispherical or semi-cylindrical. According to a preferred embodiment, the first protrusions, the recess and/or the second protrusions are in the shape of a prism or truncated pyramid. The relevant prism has, for example, a triangle or a trapezoid as a base, the prism extending in parallel with the corresponding working surface. The embossed surface and, correspondingly, a region of the metal foils to be fused by means of the laser beam, which fused region in particular forms a (laser) weld seam, can be set or is set by means of a suitable selection of the shape of the first protrusions, the recess and/or the second protrusions. In this way, an arrangement, i.e. a position and a course of the laser weld seams can be set, for example according to the tensile forces to be expected and/or a predetermined robustness, i.e. a reliability of the connection. The extension direction of the, in particular prism-shaped or hemispherical, protrusions is oriented parallel or at an angle to the vibration direction of the sonotrode. However, the extension direction of the protrusions is preferably transverse, i.e., perpendicular, to the vibration direction of the sonotrode.
According to a suitable embodiment, the first protrusions, the recess and/or the second protrusions have a height of between 0.02 mm and 1.0 mm, in particular between 0.05 mm and 0.5 mm. The height of the first protrusions and/or of the second protrusions is selected in particular depending on the number of metal foils to be joined and depending on their thickness. The height of the recess is selected in particular on the basis of the height of the first protrusions. The height is in this case understood to mean the extension of the protrusions or the recess in a direction perpendicular to the relevant working surface.
In particular if a cell arrester (tab) is to be fixed, in particular tack welded, to the metal foils by means of the ultrasonic welding device, according to an expedient development, the second protrusions have a lower height than the first protrusions. In this case, the second protrusions are in particular used to hold the cell arrester in the course of the ultrasonic welding process. For example, the height of the second protrusions is less than half the height, in particular less than a quarter of the height, of the first protrusions.
According to a preferred embodiment, the sonotrode has a plurality of first protrusions extending in parallel with one another. In this case, the first protrusions are preferably prism-shaped, preferably with a trapezoid as the base. The second protrusions in particular have a smaller height than the first protrusions, the second protrusions being designed as pyramids. For example, the second protrusions, which are designed as pyramids, are arranged in a plurality of rows which extend in parallel with the prism-shaped first protrusions. In this case, two or three of the rows of the second protrusions are arranged between two of the first protrusions in a direction parallel to the working surfaces and perpendicular to the extension direction of the first protrusions designed as prisms. The first protrusions and the second protrusions are thus arranged offset from one another, in particular in a grid-like manner, in a direction perpendicular to the extension direction of the prisms and parallel to the working surfaces.
The method is used to produce a metal foil stack of metal foils, in particular for a cell of a lithium-ion battery, which cell is designed as a pouch cell, for example. In a first step, metal foils which are stacked on top of one another are provided. These metal foils in particular form the anodes or the cathodes of the (battery) cell.
In a second step, the metal foils, in particular in a laterally protruding portion, which is also referred to as a flag of the relevant metal foil, are compacted and fixed to one another by means of an ultrasonic welding device to form the embossed surface. The ultrasonic welding device is in this case preferably designed according to one of the variants described above.
In a subsequent third step, the metal foils are welded to one another in the region of the embossed surface by means of a laser beam. For this purpose, as described above, the embossed surface is acted on by a laser beam or is moved along a strip defined by means of the embossed surface. For example, a spot seam, a stitch seam or a continuous linear or curved weld seam is produced by means of the laser beam. For example, the laser is also operated with what is referred to as a wobble function, such that the weld seam is comparatively wide and the laser beam travels over a comparatively large region.
Correspondingly, a device for producing the metal foil stack comprises the ultrasonic welding device, preferably in one of the variants described above, and a laser device which generates the laser beam, the laser device expediently being oriented with respect to the first protrusions. This device is in particular therefore used to carry out the method.
According to a suitable development, in the course of the compacting, i.e. in the course of the second step of the method, the electrical cell arrester is fixed to the metal foils. For this purpose, the cell arrester is expediently compacted together with the metal foils by means of the anvil and the sonotrode of the ultrasonic welding device by ultrasonic welding. The cell arrester fixed in this way is then welded to the metal foils in the region of the embossed surface by means of the laser beam.
Alternatively, the cell arrester is only welded to the metal foils in the course of the laser beam welding. In this case, the cell arrester preferably abuts the compacted region, i.e. in the region of the embossed surface of the metal foils. As a result, the formation of cavities between the metal foil stack and the cell arrester in the course of the laser beam welding is prevented or at least reduced.
It is possible for the laser beam to be incident on the metal foils or, alternatively, for the laser beam to be incident on the cell arrester. In other words, in the course of the laser beam welding, either the cell arrester is arranged between the laser device and the metal foil stack, or the metal foil stack is arranged between the laser device and the cell arrester.
According to an expedient embodiment, a working surface of the anvil of the ultrasonic welding device is oriented with respect to the working surface of the sonotrode of the ultrasonic welding device for compacting. The reference points, in particular the reference points of the sonotrode, are in particular used for this purpose.
In addition, in order to weld the metal foils by means of the laser beam, i.e., for the third step of the method, the laser device is oriented with respect to the sonotrode such that the laser beam impinges on the region of the embossed surface or is moved or moves along the embossed surface.
According to an advantageous development, a metal foil stack is produced according to the method described above and/or by means of an ultrasonic welding device in one of the variants described above. In particular, a comparatively reliable integral bonding (joining) of the metal foils to one another and of the cell arrester to the metal foil stack is achieved in this way.
Embodiments of the invention are explained in more detail below with reference to the drawings, which show:
Corresponding parts and dimensions are always provided with the same reference signs in all figures.
The sonotrode 4 has two first protrusions 8 on the working surface 4c thereof, which working surface faces the anvil 6 and against which the workpiece to be processed rests in the course of an ultrasonic welding process. The anvil 6 has a contour which is formed by means of three second protrusions 10, said protrusions projecting from the working surface 6a of the anvil 6. Both the first protrusions 8 and the second protrusions 10 are each parallel to one another and are prism-shaped, the prisms each having a trapezoid as the base, and the prisms extending in parallel with the working surface 4c or 6a. The first protrusions 8 and the second protrusions 10 extend transversely to the vibration direction S of the sonotrode 4.
The sonotrode 4 and the anvil 6 are oriented with respect to one another such that the first protrusions 8 and the second protrusions 10 are offset from one another in a grid-like manner in a direction parallel to the relevant working surface 4c or 6a and perpendicular to the extension direction of the prisms, i.e., in the vibration direction S of the sonotrode 4.
According to a variant which is not further shown, the anvil 6 and the sonotrode 4 are oriented with respect to one another such that the first protrusions 8 and the second protrusions 10 are opposite one another in a direction which extends perpendicularly to the working surfaces 4c and 6a; in other words, the first protrusions 8 and the second protrusions 10 are arranged in opposition with respect to this direction.
Metal foils 12 stacked on top of one another are introduced between the anvil 6 and the sonotrode 4. The metal foil stack 14 formed by the metal foils 12 stacked on top of one another is provided in particular for a cell (not further shown) of a lithium-ion battery, which is designed, for example, as what is referred to as a pouch cell. When the ultrasonic welding device 2 is used, i.e., in the course of the ultrasonic welding of the metal foils 12, said metal foils are pressed (compressed) by means of the first protrusions 8 to form an embossed surface 16. The embossed surface 16, which can be seen relatively well in particular in
The metal foils only rest in portions on the working surface 6a of the anvil 6. The portions of the metal foils 12 shown in
In
The three rows of the first protrusions 8 are in this case arranged so as to be spaced apart from one another. In
In the embodiment of the sonotrode 4 shown in
In contrast to the embodiment in
The prisms of the embodiments in
In
In
In the variant of the anvil 6 shown in
In
In further variants which are not shown, the first protrusions 8 and/or the second protrusions 10 are hemispherical or cylindrical, in particular semi-cylindrical.
The first protrusions 8 shown in
Furthermore, the sonotrode 4 and the anvil 6 each have two reference points R1 and R2 or R1′ and R2′, by means of which the anvil 6 is oriented with respect to the sonotrode 4. In the oriented state, the reference point R1 corresponds to the reference point R1′ and, analogously, the reference point R2 corresponds to the reference point R2′. The mutually corresponding reference points R1 and R1′ or R2 and R2′ are thus each arranged on a common straight line which extends in a direction perpendicular to the working surfaces 4c and 6a.
As can be seen in
In a variant which is not further shown, the cell arrester 20 is already fixed, in particular tack welded, to the metal foil stack 16 in the course of the compacting of the metal foils 12 by the ultrasonic welding process and is subsequently welded to the metal foil stack 16 in the course of the welding of the metal foils 12 by means of the laser beam 18 in the region of the embossed surface 16.
According to an alternative of
In summary, in a method for producing the metal foil stack 14, metal foils 12 which are stacked on top of one another are provided in a first step. In a second step, the metal foils 12 are compacted to form the embossed surface 16 by means of the ultrasonic welding device 2, which is designed according to one of the embodiments in
The invention is not restricted to the embodiments described above. Rather, other variants of the invention can also be derived therefrom by a person skilled in the art without departing from the subject matter of the invention. In particular, all of the individual features described in connection with the embodiments can also be combined with one another in other ways without departing from the subject matter of the invention.
Number | Date | Country | Kind |
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10 2018 221 843.9 | Dec 2018 | DE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2019/085024 | 12/13/2019 | WO | 00 |