The present invention relates to sterilization of air by means of ultraviolet light, preferably in the ultraviolet-C(UVC) band (i.e., 200-280 nanometers wavelength). Many air purifying systems have been built that incorporate UVC light for germicidal purpose. The prior art devices result in suboptimum use of ultraviolet energy, are limited in flow rate, and result in wide variances in UVC dose amongst ingested target pathogens as a result of turbulence in the air flow.
Referring to U.S. Pat. No. 9,855,362 B2 to Rolf Englehard (hereinafter “the 362 patent”), the efficiency of the device is significantly lower than in the case of the present invention. Please refer to the applicable design principles enumerated in the Summary of Invention.
Referring to U.S. Pat. No. 10,039,852 B2 to Yi et, al (hereinafter “the 852 patent”), and referring again to the UVC air treatment chamber design principles enumerated below, the short distance across the UVC treatment chamber, relative to the cross sectional area of the UVC treatment chamber radiates any suspended pathogens over only a short distance. In order to achieve any given dose rate, measured for example in Joules/square centimeter, the air velocity and, therefore, the air flow rate must be limited. The illustrated design results in significant turbulence within the UVC treatment chamber. This results in some suspended pathogens receiving less than the average dose of UVC radiation, further limiting the acceptable air flow rate. The UVC treatment chamber configuration with the air flow impinging on a flat UVC emitter illustrated in the 852 patent results in unnecessary aerodynamic losses and requires a higher power blower than would be necessary in accordance with the present patent application. The high proportion of nonreflective area to reflective area in the UVC treatment chamber results in low UVC intensities in relation to the UVC power. The low UVC efficiency combined with the low aerodynamic efficiency combine to make the 852 patent less efficient than the UVC air sterilization system described in the present application.
To better convey the advantages of the present invention, some basic UVC treatment chamber design principles should first be presented. This combination of principles appears to have been unknown or ignored in conjunction with much of the prior art. These principles are enumerated as follows:
1) UVC photons may be lost with every reflection. It is important to minimize the number of reflections. Sharp corners that would require extra reflections should be avoided.
2) The probability of a pathogen kill for any photon is proportional to the total travel distance of the photon within the UVC treatment chamber. A large chamber will maximize the probable travel distance by minimizing the required number of reflections.
3) High reflectivity is very important. If there were no photons lost to the air inlets and air outlets of the UVC treatment chamber, a UVC treatment chamber internal reflectivity of 98% would result in a UVC light intensity 5 times greater than in the case of a UVC treatment chamber internal reflectivity of 90%, using the same UVC source. The higher the UVC intensity within the UVC treatment chamber, the higher may be the air flow rate for a specified UVC dose (in Joules/square centimeter) to any pathogens.
4) UVC lost through the air inlet ports or air outlet ports of the UVC treatment chamber reduces the illumination intensity throughout the chamber. It is important that these losses be minimized. This can be done by minimizing inlet and outlet areas while avoiding excessive aerodynamic losses and noise.
5) Large scale turbulence within the UVC treatment chamber results in a high probability than some pathogens may be carried through without exposure to the specified UVC dose.
Suppression of large-scale turbulence within the UVC treatment chamber is critical to effective performance and to attaining a high probability of pathogen kill. Small scale turbulence over short distances associated with an array of entry nozzles has little effect on dosage probability distribution.
5) Aerodynamic losses may be minimized by incorporation of efficient nozzles to accelerate flow and the incorporation of efficient diffusers to decelerate flow.
6) Aerodynamic losses may be recovered by converting the kinetic energy at an exhaust port of limited size to useful kinetic energy in conjunction with the blower system. This may be accomplished with diffuser vanes or fan blades, for example. Fan blades may achieve their best efficiency point with the velocity vector of the air exiting the UVC treatment chamber, for example.
7) UVC photons that unavoidably escape from the UVC treatment chamber through an array of fine inlet nozzles, for example, may be put to good use in conjunction with a photocatalyst positioned upwind of the inlet nozzles. In this manner, these otherwise wasted photons are put to good use in powering photochemical decomposition of noxious substances in the air.
8) It is desirable in certain installations, such as in the case of ceiling fan replacement with a UVC air treatment system, to gather stratified heated and exhaled air from one plane (adjacent the ceiling in a restaurant, for example) and discharge it downward and out of the plane from whence it came. This results in more effective turnover and sterilization of all the air within a room. Returning stratified air to the same stratus from whence it came is much less effective in treating all the air within a room.
The present invention is a UVC air treatment system that is uniquely configured to suppress turbulence within the air treatment chamber and thereby provide all the processed air with precisely the same UVC dose. Providing the same dose to all the air is required in order to provide maximum germicidal effect for a given chamber volume, fan power level, UVC power level, acoustic noise level, system capital cost, and system operating cost. In addition to the benefits of suppressing turbulence, the unique configuration of the present invention maximizes the utilization of the lamp generated UVC energy by maximizing the mean free path between reflections off the chamber surfaces, while also minimizing the area of inlet and outlet ports where UVC radiation would otherwise be wasted. The inlet ports (nozzles) may be oriented at right angles to the UVC lamp and thus result in no loss of direct (not-yet-reflected) lamp energy. The result is that the total (direct plus reflected) UVC intensity is very high and is also nearly isotropic within the UVC treatment chamber without resorting to many high output UVC lamps with a high combined power consumption and maintenance cost. The unique configuration allows UVC photons to follow long pathogen-intercepting paths between efficient reflections, with minimal UVC loss at air inlets and air outlets. Reflection efficiency is maximized by incorporating highly reflective surfaces, such as expanded polytetrafluoroethylene (ePTFE) sintered polytetrafluoroethylene (PTFE), or polished aluminum, for example, throughout. The long photon paths between reflections are beneficial because attenuation (loss of photons) occurs upon each encounter with a reflective surface if those surfaces are highly reflective (98% efficient).
Turbulence suppression is preferably accomplished by first passing the air through filters which suppress any turbulence in the incoming air. From the filters the air is then accelerated in a uniform manner to one or more nozzles. The pressure gradient between the filters and the nozzles prevents flow separation and delivers air with laminar flow to each nozzle. In accordance with one embodiment of the invention, each nozzle delivers air to the treatment chamber in a precisely tangential manner without flow separation. The rotating air within the treatment chamber then behaves as free vortex flow as it migrates spirally inward within the treatment chamber. The radial pressure gradient within the treatment chamber prevents any flow separation. A light source consisting of one or more UVC lamps are situated to not interfere with the inherent spiral laminar flow pattern. A lamp or cluster of lamps may be coaxially situated in the center of the treatment chamber where they may be mounted to one face of the chamber, for example. Alternatively, tubular lamps may be inserted through the nozzles in an orientation parallel to the incoming air flow. In yet another embodiment, standard long tubular lamps may be installed behind flush quartz windows on either face of the generally cylindrical treatment chamber.
In accordance with another embodiment of the invention, large scale turbulence within the UVC treatment chamber may be suppressed by introducing the air through an array of perferations in a panel of UVC reflective material. The nozzles are preferably configured to have minimal entrance losses in order to maximize flow capacity, while introducing small scale turbulence in the plane normal to the flow direction such that the jets exiting the nozzles converge within a short distance to establish uniform velocity flow across the remainder of the UVC treatment chamber. The uniform velocity flow assures uniform UVC dosage for all air and pathogens traversing the UVC treatment chamber flow at a uniform velocity.
In accordance with a further aspect of the invention, a porous structure of photocatalytic material such as titanium dioxide may be positioned upwind of the nozzles at a distance of one nozzle spacing, for example, in order to illuminate the catalyst with UVC energy that would otherwise be lost through the nozzles. The provision of a stand-off distance between the nozzles and the catalyst structure allows for more uniform illumination of the catalyst than in the case of placement of the catalyst against the nozzle array. The stand off distance also allows air flowing uniformly through the photocatalytic structure to flow laterally between the photocatalytic structure and holes through the reflective inlet panel.
In accordance with a further aspect of the invention a flat or otherwise shaped panel of porous ePTFE may be used as a reflector and air inlet port of a UVC treatment chamber. In this manner air may be admitted with minimal loss of UVC energy.
In accordance with a further aspect of the invention, the air exiting the UVC treatment chamber may be directed through a streamlined narrow rectangular nozzle, circular nozzle or annular nozzle, for example, in order to minimize the loss of UVC energy through the air exit. The kinetic energy of the air passing through such a slot or nozzle may be largely recovered by means of a matching diffuser.
In accordance with a further aspect of the invention, one or more air filters may be used upwind of the nozzles, and upwind of the photochemical catalyst, if used. Such filters may include, but are not limited to, prefilters, HEPA filters, carbon filters electrostatic filters, and the like. One of the purposes of such filters is to remove any UVC opaque particles in which pathogens might be harbored, and to remove larger pathogens that may be relatively UVC resistant.
In accordance with a further aspect of the invention, prefilters, HEPA filters, carbon filters electrostatic filters, and the like may additionally, or alternatively, by used downwind of the UVC treatment chamber.
In accordance with a further aspect of the invention, at least one UVC treatment chamber inlet nozzle may be provided that is responsive to differential pressure across the nozzle. In this manner the nozzle opening may automatically adjust to preserve as much UVC light within the treatment chamber as possible for the instantaneously demanded flow rate. Flow rates may vary with time of day, building occupancy, nigh time blower noise constraints, personal oxygen demands, or, in the case of personal protective equipment, with breathing. In the case of a circular treatment chamber, the turbulence suppressing free vortex air flow pattern may be preserved for a period, even after air flow temporarily ceases to enter through the treatment chamber inlet nozzle(s).
In an analogous manner, a differential pressure responsive and UVC reflective exhaust valve may control air flow from the UVC treatment chamber. In this manner, UVC light loss through the exhaust port may be minimized.
In accordance with a further aspect of the invention, a UVC reflective propeller may be used to allow free flow of air through a port into or out of the UVC treatment chamber, while reflecting and containing most of the UVC that would have exited a simple open circular hole.
In accordance with a further aspect of the invention, a UVC reflective fan may be positioned within an entry or exit port of the UVC treatment chamber.
In accordance with a further aspect of the invention, the air outlet from the UVC treatment chamber may be through a porous UVC reflective material such as sintered PTFE. In this manner air may be discharged from the UVC treatment chamber with minimal loss of UVC energy from the UVC treatment chamber.
In accordance with a further aspect of this invention, other finely divided electrically insulating material that is resistant to UVC damage, such as sintered PTFE, bonded silica powder, non-woven silica fiber paper, or quartz fiber cloth, for example may be used as porous UVC reflectors for air flow into or out of the UVC treatment chamber.
In accordance with a further aspect of the invention, a porous UVC reflective material may be used as both a treatment chamber reflector and as a mechanical filter.
In accordance with a further aspect of this invention, the air outlet area may be configured as one or more nozzles to allow air to isentropically exit the UVC treatment chamber while minimizing the escape of UVC radiant energy. Such nozzles by their nature accelerate the air. The resulting kinetic energy in the air may be largely recovered by means of well-designed diffusers, an example being a cone of approximately 14 degrees total included angle. An annular nozzle may be provided in conjunction with an annular diffuser. Annular nozzles at the intersection of a cylindrical UVC treatment chamber and a generally planar end wall cause the required air exit area to be placed in a corner where some UVC energy would in any case have been attenuated by multiple reflections between cylindrical wall and end wall. This principal applies as well to the sides and end wall of a rectangular treatment chamber.
In accordance with a further aspect of the invention a UVC treatment chamber in accordance with the present invention may be used to sterilize the exhaust stream from a vacuum cleaner. For example, a spiral flow path treatment chamber may be fitted with an inlet connection that fits the outlet of a standard shop type vacuum cleaner and an outlet that fits the same vacuum cleaner hose. In this manner sterilized air may be conveniently directed.
In accordance with a further aspect of the invention, the UVC treatment chamber described herein may be incorporated into a vacuum cleaner. By this means, the exhaust air from the vacuum cleaner may be rendered less hazardous. Cyclone separators within a vacuum cleaner may also serve as UVC treatment chambers. Such an arrangement might use UVC transparent and wear resistant quartz cyclone housings in conjunction with ePTFE reflectors protected from dirt contamination and abrasion by the quartz housings. A periodic water spray could be used to remove dust from the interior of the cyclone housings. The required UVC lamps could conveniently be installed on the exterior of the quartz housing.
In accordance with a further aspect of this invention, the UVC air sterilizer described herein may be used to capture the air from a hand dryer in order to sterilize such air before reintroducing it to the room. Prior art hand dryers energetically disperse potentially infectious droplets and create a hazard for both the user and for bystanders.
In accordance with a further aspect of the invention, the UVC air sterilizer described herein may be used in conjunction with a toilet to prevent biohazardous mist from spreading throughout the room when the toilet is flushed. The spreading of this biohazardous mist is exacerbated by the convention of providing restroom ventilation fans near the ceiling despite toilet bowls being located nearer the floor. In many instances it may be more feasible to run electrical power to air sterilizers collocated with toilets than to run air ducts from each toilet to a central air sterilizer. Air sterilizers in accordance with the present invention may be located above a toilet tank, underneath a toilet tank, above or below a high capacity flush valve used in lieu of a tank, or behind a service wall, for example. Toilet seats with connection ports for forced ventilation are available and may be connected to the UVC air sterilizer of the present invention. Alternatively, in accordance with a further aspect of the invention, a toilet may be manufactured with an annular vent just beneath the rim of the toilet bowl in conjunction with a duct leading to a UVC treatment chamber and associated fan. The UVC treatment chamber could be integrated into the toilet.
In accordance with a further aspect of the invention, a propeller with little or no blade camber in conjunction with a shallow pitch angle may be made of or be coated with a UV reflective material. Such propellers may be mounted on bearings and used without a motor for the purpose of permitting air flow while simultaneously reflecting most of the UVC radiation that would otherwise escape out through the UVC treatment chamber air inlet or UVC treatment chamber air outlet. A simple polished aluminum propeller could be used for this purpose. Counter rotating reflective propellers could also be used in order to obstruct direct light paths between blades and reflect back at least a portion of the UVC radiation that would otherwise escape between blades parallel to the blade pitch angle.
In accordance with a further aspect of this invention, the UVC air sterilizer described herein may be used to sterilize air used for an air curtain in a doorway, for example. In this manner, the sheet of moving air not only serves to keep pathogens from crossing the air curtain, the sterile blowing air also serves to displace any pathogen contaminated air in the vicinity. The resulting sterilized curtains of air may be used to create virtual walls between dinner tables at a restaurant. between aircraft passengers, between aircraft passengers and crew members, between medical staff and patients, between a checkout clerk and customers or between the passengers and the driver of a taxi, Uber or Lyft automobile, for example. Numerous other applications are made possible by the unique high volume air sterilization capacity of the UVC air sterilizers in accordance with the present invention.
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The best embodiment of the present invention for any given application depends on available space, required orientation of inlets and outlets, and required electrical efficiency. The free vortex UVC treatment chamber 1 provides the best electrical efficiency due largely to the nearly isentropic air flow. It may be the best choice for battery powered applications such as vacuum cleaners or battery powered personal protective equipment (PPE). It is also likely the best choice if air is to be drawn through or exhaled through the UVC chambers by the user and without electrical power. The free vortex UVC treatment chamber 1 is also a likely first choice for very high flow rate HVAC applications where space is not an issue. This is due again to low pressure losses across the system and lower blower power requirements.
For applications where straight through air flow is preferred or a compact form factor is better suited, a UVC treatment chamber with a UVC reflective porous air inlet panel may be better. This embodiment may take the form of a tube, in which case it may be conveniently fitted with commercially available round filters and round duct blowers. The resulting UVC treatment chamber shape is very similar to that of the free vortex UVC treatment chamber. The UVC treatment system may vary in shape according to the application and may be for example a venturi shape as in
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The lamp intensity can be selected within a wide range. The costs of higher UVC lamp power include original cost, replacement cost, electricity use, and any power needed to air condition the space to which heat is added by the UVC source. In general, it is desirable to obtain the greatest germicidal effect using the least amount of electrical power. In fact it is the essence of the present invention to accomplish that goal more perfectly than does the prior art. Germicidal effect might be measured in terms of flow rate (kg of air per second) times dose rate (Joules per square meter) divided by the combined power consumption of the fan(s) plus the UVC lamps. The dose rate should be based on the dose rate for the least treated parcels of air that make it through the UVC treatment chamber. In the case of prior art UVC treatment chambers, air turbulence within the treatment chamber results in great disparities in residence time in the chamber for various parcels of air. In the case of prior art, the least treated air typically has a substantially lower dose rate than the median treated air because of differences in velocity transiting the treatment chamber and differences in path length transiting the treatment chamber, as well as differences in UVC intensity throughout the UVC treatment chamber. Each of the illustrated and disclosed embodiments of the present invention incorporate countermeasures to large scale turbulence.
One of these countermeasures is the use of an accelerating free vortex flow path. A principal advantage of this configuration is that it is nearly isentropic because pressure energy of the incoming air is converted to kinetic energy in a nearly lossless manner through one or more efficient nozzles.
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Other types of fans may be used, such as mixed flow or radial fans. In the case of installation within a motor vehicle or aircraft, for example, the air source may be taken from the impinging flow of air on the exterior of the vehicle or aircraft.
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It should be noted that the unique accelerating free vortex flow path that is a salient part of many of the embodiments of this invention suppresses turbulence and allows no parcels of air to take a short cut form UVC treatment chamber inlet to the UVC treatment chamber outlet. All the transiting air follows a uniform path length with a transit time that does not materially vary, while the high proportion of reflective surface provides a uniformly high UVC intensity within the treatment chamber. The UVC radiation is reflected so many times that after the first few reflections it has dispersed uniformly throughout the UVC treatment chamber.
It should be noted that proprietors of some of the prior art brag about the benefits of turbulence as a means of exposing all sides of a pathogen. In the case of the present invention the number of reflections of the UVC radiant energy is enough to render the UVC flux within the UVC treatment chamber isotropic. This isotropic radiant UVC flux is beneficial on account of not needing otherwise undesirable turbulence to achieve exposure on all sides of transiting pathogens and is also beneficial in providing six times the exposure provided by a single axis unidirectional UVC flux. In the case of the present invention, UVC flux is maintained at a uniformly high level in two directions along each of three axes. This isotropic flux is the result of the unique combination of low UVC loss at air inlets and outlets, materials of high diffuse reflectivity, a chamber configured for long path lengths, fewer required reflections, and an overall longer mean total path, from emission at the lamp to eventual absorption, for each UVC photon.
The nozzle configuration associated with the aforementioned embodiments functions very nearly isentropically, i.e., with negligible energy loss as air is accelerated through the nozzle into the UVC treatment chamber. Furthermore, almost no energy is lost as air transits the treatment chamber as it follows a free vortex spiral toward the central chamber exit. The exiting air has accumulated kinetic energy that may be largely recovered by either of several methods or by a combination thereof. In the case of an axial flow blower at the UVC treatment chamber exit, the velocity vectors of the exiting air may be precisely coordinated with bespoke blades to eliminate nearly all tangential velocity in the air exiting the fan. The axial velocity of air exiting the fan may then be substantially recovered by means of a conical diffuser or equal. Air being treated may thus be accelerated into the treatment chamber where the induced free vortex suppresses turbulence, and then decelerated again as it passes through the fan and subsequent diffuser. The inlet filter pressure drop can be controlled by selecting the size and quantity of filters and the number of nozzles to use in conjunction with the UVC treatment chamber under consideration. Finer filters with a lower flow rating may be compensated for by increasing the quantity and area of the filters.
As an alternative to swirling air entering the blower directly from the treatment chamber, a set of diffuser vanes may be provided that efficiently remove the swirl component from the exiting air. In this manner the air may enter a standard axial flow fan operating at its design point. It should be noted that such a standard axial flow fan will leave a residual tangential velocity component in the exiting flow. The kinetic energy represented by this tangential velocity component may not be entirely recoverable. This is not a disadvantage peculiar to this invention but is due rather to the nature of axial flow fans without guide vanes and applies to prior art air treatment systems incorporating axial flow fans without guide vanes.
The use of diffuser vanes at the UVC treatment chamber central outlet also allows the tangential kinetic energy of the rotating air to be recovered as the air exits the UVC treatment chamber without the use of a special fan for that purpose.
Further, each of the various elements of the invention and claims may also be achieved in a variety of manners. This disclosure should be understood to encompass each such variation, be it a variation of an embodiment of any apparatus embodiment, a method or process embodiment, or even merely a variation of any element of these. Particularly, it should be understood that as the disclosure relates to elements of the invention, the words for each element may be expressed by equivalent apparatus terms or method terms—even if only the function or result is the same. Such equivalent, broader, or even more generic terms should be considered to be encompassed in the description of each element or action. Such terms can be substituted where desired to make explicit the implicitly broad coverage to which this invention is entitled. As but one example, it should be understood that all actions may be expressed as a means for taking that action or as an element which causes that action. Similarly, each physical element disclosed should be understood to encompass a disclosure of the action which that physical element facilitates. Regarding this last aspect, as but one example, the disclosure of a “means for treating air with UVC light” or a “UVC air treatment system” should be understood to encompass disclosure of the act of “treating air”—whether explicitly discussed or not—and, conversely, were there effectively disclosure of the act of “treating air”, such a disclosure should be understood to encompass disclosure of a “UVC air treatment system” and even a “means for treating air”. Such changes and alternative terms are to be understood to be explicitly included in the description. The light in the ultraviolet-C bandwidth is specified because it is the most efficient wavelength to accomplish the serialization of air as specified herein. However, light in the ultraviolet-A and ultraviolet-B bandwidths may also be used.
The term UVC is meant broadly to include, not only UVC radiation, but also UVA and UVB as alternatives that may be used in some instances.
Thus, the applicant(s) should be understood to claim at least: i) each of the input devices as herein disclosed and described, ii) the related methods disclosed and described, iii) similar, equivalent, and even implicit variations of each of these devices and methods, iv) those alternative designs which accomplish each of the functions shown as are disclosed and described, v) those alternative designs and methods which accomplish each of the functions shown as are implicit to accomplish that which is disclosed and described, vi) each feature, component, and step shown as separate and independent inventions, vii) the applications enhanced by the various systems or components disclosed, viii) the resulting products produced by such systems or components, ix) methods and apparatuses substantially as described hereinbefore and with reference to any of the accompanying examples, x) the various combinations and permutations of each of the elements disclosed, xi) each potentially dependent claim or concept as a dependency on each and every one of the independent claims or concepts presented, xii) processes performed with the aid of or on a computer as described throughout the above discussion, xiii) a programmable apparatus as described throughout the above discussion, xiv) a computer readable memory encoded with data to direct a computer comprising means or elements which function as described throughout the above discussion, xv) a computer configured as herein disclosed and described, xvi) individual or combined subroutines and programs as herein disclosed and described, xvii) the related methods disclosed and described, xviii) similar, equivalent, and even implicit variations of each of these systems and methods, xix) those alternative designs which accomplish each of the functions shown as are disclosed and described, xx) those alternative designs and methods which accomplish each of the functions shown as are implicit to accomplish that which is disclosed and described, xxi) each feature, component, and step shown as separate and independent inventions, and xxii) the various combinations and permutations of each of the above.
It should also be understood that for practical reasons and so as to avoid adding potentially hundreds of claims, the applicant may eventually present claims with initial dependencies only. Support should be understood to exist to the degree required under new matter laws—including but not limited to European Patent Convention Article 123(2) and United States Patent Law 35 USC 132 or other such laws—to permit the addition of any of the various dependencies or other elements presented under one independent claim or concept as dependencies or elements under any other independent claim or concept. Further, if or when used, the use of the transitional phrase “comprising” is and will be used to maintain the “open-end” claims herein, according to traditional claim interpretation. Thus, unless the context requires otherwise, it should be understood that the term “comprise” or variations such as “comprises” or “comprising”, are intended to imply the inclusion of a stated element or step or group of elements or steps but not the exclusion of any other element or step or group of elements or steps. Such terms should be interpreted in their most expansive form so as to afford the applicant the broadest coverage legally permissible.
Patents, publications, or other references mentioned in this application for patent are hereby incorporated by reference. In addition, as to each term used it should be understood that unless its utilization in this application is inconsistent with such interpretation, both traditional and common dictionary definitions should be understood as incorporated for each term and all definitions, alternative terms, and synonyms such as contained in the Random House Webster's Unabridged Dictionary, second edition are hereby incorporated by reference. Finally, all references listed in this application are hereby appended and hereby incorporated by reference, however, as to each of the above, to the extent that such information or statements incorporated by reference might be considered inconsistent with the patenting of this/these invention(s) such statements are expressly not to be considered as made by the applicant(s). Please be aware that cited works of non-patent literature such as scientific or technical documents or the like may be subject to copyright protection and/or any other protection of written works as appropriate based on applicable laws.
Copyrighted texts may not be copied or used in other electronic or printed publications or re-distributed without the express permission of the copyright holder.
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Filing Document | Filing Date | Country | Kind |
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PCT/US2021/033773 | 5/21/2021 | WO |
Number | Date | Country | |
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63028531 | May 2020 | US |