The invention relates to thermal detectors in general and particularly to infrared detectors that operate at ambient temperatures.
Temperature sensing using cooled detectors, such as those made of such as those based on mercury-cadmium-telluride materials or those based on superconducting materials, has been known for some time.
Temperature sensing systems based on quartz resonators that operate at ambient temperatures have been described by Vig in various patents, including U.S. Pat. Nos. 5,686,779 and 5,744,902. Vig teaches the use of quartz crystals cut at specific orientations. In particular, Vig explains that, since quartz is anisotropic, crystal cut orientations can be found to minimize, or alternatively, to selectively increase sensitivity to temperature.
There is a need for an ambient temperature sensing system that is more sensitive than existing systems.
According to one aspect, the invention relates to a nanoelectromechanical sensing element. The nanoelectromechanical sensing element comprises a substrate having a surface, the substrate comprising an isotropic material, the surface having defined therein a cavity for accommodating a nanoelectromechanical structure; a nanoelectromechanical torsional resonator having a width w and a length l, and having a torsional support connecting a first side and a second side of the nanoelectromechanical torsional resonator to the substrate, the torsional resonator having a Q greater than 1000 in vacuo, the nanoelectromechanical torsional resonator and the torsional support configured to provide an oscillation of the nanoelectromechanical torsional resonator at a predetermined frequency; and a displacement sensor configured to sense a displacement of the nanoelectromechanical torsional resonator relative to the substrate and configured to provide an output signal. When a stimulus is received by the nanoelectromechanical torsional resonator, the displacement sensor provides an output signal indicative of a parameter of the stimulus.
In one embodiment, the nanoelectromechanical sensing element has a temperature resolution below 100 mK.
In another embodiment, the nanoelectromechanical sensing element has a temperature resolution below 50 mK.
In yet another embodiment, the nanoelectromechanical sensing element has a temperature resolution below 10 mK.
In one embodiment, the isotropic material is amorphous silicon. In one embodiment, the width w is 10 microns and the length l is 20 microns.
In one embodiment, the isotropic material is amorphous silicon. In one embodiment, the width w is 2 microns and the length l is 5 microns.
In one embodiment, the stimulus is a thermal signal.
In one embodiment, the thermal signal is an infrared signal.
In one embodiment, the nanoelectromechanical sensing element further comprises a material configured to absorb thermal radiation disposed on the nanoelectromechanical torsional resonator.
In one embodiment, the material configured to absorb thermal radiation is TiN.
In one embodiment, the cavity defined in the surface of the substrate is configured to provide a quarter wave cavity.
In one embodiment, the cavity comprises a reflector.
In one embodiment, the thermal signal is a signal selected from the group consisting of gamma rays, x-rays, ultraviolet light, visible light, microwave energy and millimeter wave energy.
In one embodiment, the displacement sensor is a laser interferometric displacement detector.
In one embodiment, the displacement sensor is a Hall displacement sensor.
In one embodiment, the substrate has defined therein a plurality of cavities for accommodating a nanoelectromechanical structure.
In one embodiment, the nanoelectromechanical sensing element further comprises a first plurality of nanoelectromechanical torsional resonators, each nanoelectromechanical torsional resonator having a width w and a length l, and each having a torsional support connecting a first side and a second side of the nanoelectromechanical torsional resonator to the substrate, each of the nanoelectromechanical torsional resonators having a Q greater than 1000 in vacuo, and a second plurality of displacement sensors, at least one of the plurality of displacement sensors configured to sense a displacement of a respective one of the plurality of nanoelectromechanical torsional resonators relative to the substrate and configured to provide an output signal indicative of a stimulus applied to the nanoelectromechanical torsional resonator. In one embodiment, the first plurality is equal to the product N×M, where N and M are integers. In one embodiment, the N×M nanoelectromechanical torsional resonators are configured each to receive an infrared stimulus.
In one embodiment, the sensing element is configured to provide as output an image.
In one embodiment, the image is configured in an HDTV format.
The foregoing and other objects, aspects, features, and advantages of the invention will become more apparent from the following description and from the claims.
The objects and features of the invention can be better understood with reference to the drawings described below, and the claims. The drawings are not necessarily to scale, emphasis instead generally being placed upon illustrating the principles of the invention. In the drawings, like numerals are used to indicate like parts throughout the various views.
Nanoelectromechanical systems (NEMS) provide an opportunity to construct systems and devices that provide useful functions which cannot conveniently be attained in more conventional macroscopic systems. We describe nanomechanical torsional resonators for frequency-shift-based infrared (IR) thermal sensing. Nanoscale torsion rods, ˜1 μm long and 50-100 nm in diameter, provide both extraordinary thermal isolation and excellent angular displacement and torque sensitivities, of order ˜10−7 rad·Hz−1/2 and ˜10−22 (N·m)Hz−1/2 , respectively. Furthermore, these nanorods act as linear torsional springs, yielding a maximum angular displacement of 3.6° and a dynamic range of over 100 dB. These results exceed the performance of flexural modes by as much as 5 orders of magnitude. These attributes lead to superior noise performance for torsional-mode sensing. We demonstrate the operational principles of torsional-mode IR detection, attaining an uncooled noise equivalent temperature difference (NETD) of 390 mK. By modeling the fundamental noise processes, we project that further reduction of device size can significantly improve thermal responsivity; a room-temperature NETD below 10 mK is believed to be feasible.
We describe a new method for achieving sensitive infrared (IR) detection based on temperature-induced frequency shifts to a mechanical resonator. The local temperature rise of the resonator is induced by the absorption of radiation. This concept can form the basis for individual bolometers, or subsequently assembled—for example—to populate an infrared focal plane array for imaging applications.
Turning to
The embodiment of
In the embodiment shown in
The thermal responsivity of our frequency shift IR bolometer can be analyzed as follows. If G denotes the thermal conductance through the supporting rods, C is the heat capacity of the sensitive volume, and P0 is the IR radiation power impinging on the paddle that is modulated with frequency ωm, then the temperature rise of the sensitive area will be ΔT=(ηP0)/[G((1+ωm2τ2)]1/2 where η is the fraction of the incident IR power absorbed, and τ=C/G is the time constant characterizing the thermal response. From the definition of the temperature coefficient of frequency shift TCF=(1/f)[(df)/(dT)], where f is the device resonant frequency. The responsivity R, which represents the frequency shift induced by power absorption, can be expressed as
The mode-dependent TCF formulas for a stressed torsional resonator, which is derived in the APPENDIX—Supporting Information, can be expressed as follows
Here α=(1/l)[(dl/dT)] is the linear thermal expansion coefficient, β=(1/E)[(dE/dT)] is the temperature coefficient of Young's modulus E, and l and h are the length and thickness of the torsion rods, respectively. For a silicon nitride (SiN) film, α=3×10−6 K−1 and β=−4.8×10−5 K−1. Note that the TCF of the flexural mode possesses an additional term −(l/t)2α. This geometric factor, which is enhanced for structures with a large aspect ratio, originates from the thermally induced stress, denoted as σth=−αEΔT. This thermal stress has a component along the direction of motion of the flexural mode and thus acts to soften its spring constant (see
Upon a uniform downscaling of all dimensions by a common factor, the resonant frequency f0 will be increased by the same factor, as will the thermal resistance 1/G=1/κA; A is the cross sectional area of the supporting rod. Hence, according to eq (1), the frequency-shift-based thermal responsivity, R, will scale inversely with linear dimension squared. This favorable scaling gives NEMS devices their advantageous thermal responsivity compared to MEMS. The scaling law should also apply for a structures patterned from composite materials where the parameters, E, density ρ, stress σ, and α, can be replaced with effective values that represent weighted averages of the two materials.
The ultimate sensitivity of our frequency-shift-based detector is limited by various frequency noise processes, of either intrinsic or extrinsic origin. We concentrate on three fundamental limits: the radiation background fluctuations, temperature fluctuations, and thermomechanical noise.
All thermodynamic systems are subject to energy fluctuations with the environment, given their finite thermal conductance and heat capacity. These energy fluctuations are manifested as temperature fluctuations, their mean square value, integrated over all frequencies, is
NETD is defined as the minimum resolvable temperature difference within an imaged scene. It depends on the intrinsic properties of the detector, but also on the detector assembly's efficiency to capture the IR radiation emanating from the scene (see eq S26 in APPENDIX—Supporting Information.) The limitation to NETD imposed by temperature fluctuations is depicted by the “TF” labeled curve in
Thermomechanical noise also imposes a fundamental limit to the device's frequency stability. It induces fluctuations in the resonator's position at finite temperatures, thus imposing a fundamental limit on the displacement sensitivity of the device. Thermal displacement fluctuations with a spectral density Sx(ω) generate phase fluctuations Sφ(ω)=Sx2(ω)x2, and in turn frequency fluctuations Sω(ω)=[ω0/(2Q)]2Sφ(ω) with a spectral density of Sφ(ω) and Sω(ω), respectively. Here x is the rms of the resonator amplitude and ω0 is the resonant angular frequency. The frequency fluctuations caused by thermomechanical noise are represented as δω0={[(kBT)/(Ec)](ω0BW)/Q}1/2, where Ec is the carrier energy and BW is the measurement bandwidth. For the torsional mode, we have Ec=Iω02 θc2, where I is the moment of inertia, and θc is the displacement angle of 3.6° (the maximum value observed with our device, see below). These frequency fluctuations δω0 can be referred back to the input domain and represented as equivalent power fluctuations, δPTM=Gδω0/(ω0TCF). The NETD limited by such thermomechanical noise processes is labeled by “TM” in
The total NETD=[(NETDTF)2+(NETDTM)2]1/2 is shown by the curve labeled TF+TM in
Microscale torsional resonators have been employed in applications such as optical mirrors in digital light processing (DLP) technology, switches, intensity, and/or phase modulators. Compared with their microscale counterparts, there have been relatively few studies of nanoscale torsional resonators. Evoy et al. report micrometer-scale silicon torsional devices. The smallest torsional devices reported are those that incorporate a carbon nanotube tube (CNT) as the torsional spring for a submicrometer size metal paddle. These devices exhibit appealing properties including an unusually large deflection angle of 180° due to the extremely soft spring constant (κ)˜3×10−18 N·m, a torsional piezoresistive effect, and electrically detected torsional resonances. Nevertheless, their Qs are low, only in the range of 78-250 and they suffer from the fact that it is very problematic to implement large-scale integration of these devices to make pixel arrays. Their soft torsion spring also results in a high angular displacement noise floor of 3°, consequently yielding a rather limited dynamic range of only ˜35 dB. We report dynamic properties of SiN-based torsional resonators with nanoscale supporting rods, with particular focus on their superior torque and angular displacement sensitivities, dynamic range, frequency stability, and thermal sensitivities for IR detection.
Our torsional resonators are made from 100 nm thick low stress SiN grown by low pressure chemical vapor deposition (LPCVD) onto a Si substrate (fabrication details are presented in APPENDIX—Supporting Information). Each of the supporting rods is 50-100 nm wide, 2 μm long, and its paddle is 2 μm wide and 5 μm long. The devices are mounted on piezoceramic disks for actuation and are characterized by laser interferometric displacement detection that is schematically shown in
The driven torsional and flexural resonances are depicted in
The torsional angular displacement noise spectral density can be expressed as Sθ1/2=[(4 kBTQ)/(ω0κ)]1/2, where κ=2KGs/L is the torsional spring constant, Gs is the shear modulus, and K is the torsional moment of inertia expressed in APPENDIX—Supporting Information eq S21. It can be experimentally determined by κ=ωθ2I. Using the expression of Sθ1/2, an angular displacement resolution of 1.18×10−7 rad·Hz−1/2is obtained. Details of that calculation can be found in Li, M.; Tang, H. X.; Roukes, M. L. Nat. Nanotechnol. 2007, 2, 114-120. The torque thermomechanical noise spectral density is ST1/2=Sθ1/2(κ/Q)=[(4 kBTκ)/(ω0Q)]1/2. Following similar procedures, a torque resolution on the order of 10−22 (N·m)Hz−1/2 is obtained. Table 1 summarizes the analyzed results for both modes.
The dynamic range (DR) of NEMS is the ratio of its largest linear amplitude and the rms of the amplitude noise floor Sx. Typically expressed in decibels (dB), it specifies the linear operating range of the device. For a flexural mechanical resonator, it is formulated as DR(dB)=20 log[0.745xnc/(2SxBW)1/2], where 0.745xnc is the 1 dB compression point of the onset of the nonlinear resonance. On the basis of the data presented in
Torsional vibration studies of dynamic range are hampered by the inherent nonlinearity of the optical transduction technique, which has many experimental manifestations.
We find that the optical nonlinear effect in our experiment can be accounted for by a simple interference model (see APPENDIX— Supporting Information). When the device vibrates at an amplitude x, the laser interference intensity, I(r), becomes modulated. The modulation depth in I(r), ΔI recorded by the photodetector provides measure of the device resonant amplitude, that is, the optical displacement signal
ΔI=4A0 sin(2kd)sin(2kx)=A1 sin(2kx) (3)
Here d is the interference cavity separation, k is the wave vector of the laser light, and A0 and A1 are constants. Equation 3 justifies the sinusoidal dependence in the top inset of
V is the RF voltage applied on the piezodisk, which acts as a linear actuator in the power range described herein. Vc is the RF voltage when xc=λ/8. Plotted in
These results unambiguously demonstrate the linear nature of the torsional mode despite the artifacts caused by the optical nonlinearity. While nonlinear Duffing behavior of the torsional mode has been reported in previous studies, these nonlinearities appear to originate either from the electrostatic driving and detection method, or by the increase of the intershell coupling in the multiwalled CNT torsional rod. As such, they are not applicable to our devices.
In our torsional devices with ˜100×100 nm2 cross sectional supporting rods, the torsional dynamic range is 40-50 dB higher than that of the flexural mode. Theory predicts a dependence of the dynamic range on D[(D/L)5]1/2 and (D7L)1/4 for the flexural and torsional mode, respectively, where D is the diameter and L is the length of the supporting rods. (See APPENDIX— Supporting Information) The torsional dynamic range degrades much more slowly as the rod diameter is reduced. Increasing the rod length L, which is favorable for enhancing thermal isolation, will give an advantageous torsional dynamic range but will adversely affect the flexural DR.
We compare the frequency stability of both modes in the time domain, as characterized by their Allan deviation (AD). The device in
The measured ADs at τA=1 s are plotted in
We have also studied the TCFs of both modes. There are two types of devices investigated in this study: one has 10 nm thick gold film only on the paddle while the rod is pristine SiN; and the other has 12 nm thick gold film covering the whole surface. The focused laser can generate local heating to induce a frequency shift of the device. The laser power is varied between 0.125 and 1.25 mW with the resulting mode-dependent relative frequency shifts listed in Table 2. Since the temperature distribution profile remains identical during the measurement, we can infer that the flexural mode possesses a 6-8 fold larger TCF than the torsional mode.
We have also quantitatively measured the TCF by applying Joule heating to the device through the thin gold film overlayer. The applied voltages are converted into temperatures by finite element method (FEM) simulations. The obtained TCFs as shown in
The noticeable resonance frequency shift with the temperature indicates that the torsional devices can be used as sensitive thermal detectors. We deposit a TiN film as an IR absorber by the magnetron sputtering method. Its IR reflection and transmission shows a strong function of the film thickness in the several-tens-of-nanometer range. The near-infrared absorption reaches a maximum 30% when the film thickness is about 15 nm.
We use an all-optical system shown in
It is believed that one can improve the NETD of these NEMS-based devices. The device thermal conductance can be lowered by 1 order of magnitude if α-Si is employed as the structural material. Another technical path is to improve the collection efficiency of the infrared optics by employing a low f-number IR lens. By adopting such technical innovations, we believe that a NEMS-based frequency shift infrared bolometer should be able to reach a NETD<10 mK.
We have demonstrated ultrahigh angular displacement, torque sensitivities, wide dynamic range (>100 dB), and superior frequency stability of nanoscale torsional resonators. We predict that the torsional resonator could be used as an ultrasensitive IR detector with achievable temperature resolution in the range below 10 mK. We have demonstrated the first prototype devices based on very small paddle structures supported by thin nanorods, with significant promise for further scaling and optimization.
Resonant RF NEMS Bolometer Comprising Pixels
In one embodiment, the resonator is a high-Q torsional resonator operating in the vicinity of 10 MHz, and having a Q>100,000 in vacuo, and an Allan Deviation, σA, of the order of 10−7. The Allan Deviation is a non-classical statistic used to estimate stability.
The bolometer operates using the temperature dependence of its resonance in order to detect absorbed radiation. The temperature coefficient, TC, of the resonant frequency is given by
TC=[1/f0][∂f0/∂T]
and is expected to have as a value TC˜10,000 ppm/K (or 10,000 parts per million per Kelvin).
The responsivity, f, is given by
We will use the values fo˜10 MHz and TC˜10,000 ppm/K in the following derivations.
We will estimate G under the assumption that the torsional rod support is made from pure a-silicon. We have
κ(T=300K)a-Si˜0.25 W/(K·m)
The torsion rod cross section is given by
A=(5×10−8 m)2=2.5×10−15 m2
The torsion rod length l=1 μm=1×10−6 m. Thus an estimate for G is
G=κA/l˜(0.5 W/(K·m))·(2.5×10−15 m2)/(1×10−6 m)˜1.25×10−9 W/K
An estimate for f is
Noise equivalent power (NEP) for frequency shift detection is defined as
NEP|fo=<δf2>1/2/f˜2√2σAfo/f
The noise equivalent power (NEP) is a measure of the minimum thermal power detectable by the IR bolometer, and is set by the noise processes of the detector (both intrinsic and extrinsic). In order to project the ultimate performance of our IR bolometers, it proves illuminating to classify the noise contributions into two terms—one term that broadly reflects the noise sources typically found in NEMS operated for frequency-shift detection, and a term that, while typically ignored in our previous NEMS application efforts, becomes significant for these unique structures. The first of these terms, which we will call NEP|f0, can be parametrized in terms of the typical fractional frequency fluctuations, or Allan deviation σA, during a frequency-shift measurement of a NEMS device. The origins of these fluctuations are manifold, from thermomechanical noise to transduction and amplifier contributions. For NEMS resonators operating at room temperature in atmospheric pressure, we have achieved σA<10−6, while for cryogenically-cooled NEMS in UHV conditions, we have realized Allan deviations approaching σA˜10−8. Assuming a median Allan deviation of σA<10−7, we derive NEP|f0 from
The second noise term comes from the extreme thermal isolation of the paddle from its environment, which results in thermodynamic fluctuations of the resonator's temperature. For a small body thermally isolated from its environment, the temperature noise power due to thermal fluctuations is
We assume that our noise integration bandwidth Δω is maximal, meaning we integrate up to the thermal time constant roll-off Thus the total thermal noise power in our measurement bandwidth can be estimated, and then converted into the noise equivalent power NEP|TF using the thermal conductance, like so:
The total noise equivalent power is thus determined by adding the two noise terms in quadrature:
NEP|tot˜√{square root over ((NEP|f0)2+(NEP|TF)2)}=661 fW.
As can be seen, thermal fluctuation is expected to be the dominant noise source for our IR bolometers.
Finally, the noise equivalent temperature difference (NETD) can be determined. The NETD is defined as the minimum detectable temperature difference of a target relative to its environment; thus it not only depends on intrinsic properties of the detector, but also how the target radiation is delivered to the detector. The amount of power received by an IR detector δPt can be related to the temperature difference δTt of a target relative to its surroundings (assuming classic blackbody radiation) in the following formula:
Here αo is the absorption efficiency of the detector, Ad the detector capture area, F the f-number of the supporting optics of the detector system, and dP/dT is the variation of blackbody power with temperature at the background temperature, within the IR wavelength band set by λ1 and λ2. We will assume typically-realizable numbers for these parameters: αo=0.9, F=1.0, and, for a medium IR band of 8-14 μm, dP/dT=2.62 W/m2·K. Inserting these numbers, we have
We can then directly determine the NETD by combining this with the previously-derived NEP:
We can estimate a thermal time constant, τth, as
τth=Ctot(T)/G
The components of Ctot include, for 50 nm thick a-silicon having an area of 10 μm×20 μm,
Ca-Si(T=300K)=(1.6×106 J/K·m3)·(2.5×10−18 m3)=4.0×10−12(J/K)
For 4 nm thick TiN (also with an area of 10 μm×20 μm)
CTiN(T=300K)=(2.3×106 J/K·m3)·(2.5×10−18 m3)=5.8×10−12(J/K)
We then estimate τth as
The Figure of Merit (FOM) typically quoted is
FOM=NETD×τth=(5.6 mk)(14.3 ms)=80 mK·msec
This FOM is about 3 to 5 times better than that for current state of the art uncooled detectors.
It is expected that one can attain high areal packing densities using NEMS processing technology. For example, all the pixels of a detector sufficient to provide an image for HDTV are expected to be fabricated on a single chip.
It is expected that one will be able to read out data from such a HDTV-capable chip using a phase-locked loop and taking the signal as the deviation or “error” in the loop voltage signal. Alternatively, one could use the NEMS device as the frequency-determining element in an electronic oscillator circuit. It is expected that one can multiplex the output signals to be observed using a single transmission line for a plurality of signals of interest.
Sensing Methods
Nanomagnets
The fringe field of a nanomagnet falls off on a very short distance scale. Coupling this to a NEMS resonator enables a new displacement sensing method.
Hall Displacement Sensing
Many routes to vibrational actuation and subsequent displacement sensing can be employed. Best will be those that do not involve any use of the torsion rod so that its thermal conductance can be minimized. Electrostatic actuation is probably the most straightforward. One possible technique for transduction that scales well to nanometer dimensions is local Hall displacement sensing, for example as described in U.S. Pat. No. 6,593,731.
In operation, a bolometer pixel according to the invention will receive incoming electromagnetic radiation, and will be heated. The change in temperature will be observable as a change in the operational characteristics of the pixel. Using a device comprising a plurality of pixels, as shown in
Another sensing approach that is expected to provide signals of interest is to bias the device pixels to a temperature above ambient using a heater and a thermal control loop. One would then read out the error signal (e.g., the signal needed to maintain constant temperature of a pixel) as data. This approach is expected to increase the dynamic range of the sensors of the invention.
It is expected that thermal excursions to lower temperatures can also be sensed, for example by observing a deviation caused by a reduction of the temperature of a pixel. Because optical losses in the vicinity of ambient temperature are small, such detection of thermal excursion may occur on a longer time scale than observations of excursions to higher temperature in response to the application of an active signal (or “forcing function”).
Applications
Molecular Sensing
Nanoresonators are expected to be useful to measure changes in frequency based on changes in mass. In one embodiment, the nanoresonators are expected to be used by attaching a specific different binding material to each of N resonators, and observing which resonators change mass in the presence of a test fluid or gas so as to identify what substance might be present. As an example, an array of N resonators could each be provided with a different DNA and/or RNA moiety, and the array could be used to test for the presence of specific molecules that bind to one or ore of the DNA and/or RNA moieties. The resonators that indicate a change in frequency, indicative of binding, would provide a data set to permit determination of what molecules are present in a sample that is brought in contact with the N resonator array.
It is expected that an array having a plurality of pixel can be used to detect an optical or IR signature. In this application, one binds some material to N resonators and probes each resonator with a different wavelength, e.g., a frequency comb, to see the spectral response, for example, absorption causing a change in resonance by heating, and failure to absorb resulting in no frequency change. By analyzing the N frequencies of interest, one would expect to obtain a spectral analysis in digital form.
Operation Near Thermoelastic Resonance
In one embodiment, it is contemplated to tune IR probes according to the invention to be at or near the thermoelastic resonance frequency of the devices, so as to maximize detection. This mode of operation is the antithesis of the operation of MEMS gyros that are tuned to operate at frequencies far from the thermoelastic resonance frequency, so as to avoid losses in the gyros related to thermoelastic resonance.
In the present example, expected performance has been calculated for a specific embodiment. However, using the principles of the invention, one can generalize the results of the calculation to other absorbing configurations and types of mechanical resonators (which themselves may employ a whole range of different transducers and actuators). In some embodiments, the types of electromagnetic radiation that may be detected by the present invention include gamma rays, x-rays, ultraviolet light, visible light, infrared radiation, and microwave or millimeter wave energy.
Theoretical Discussion
Although the theoretical description given herein is thought to be correct, the operation of the devices described and claimed herein does not depend upon the accuracy or validity of the theoretical description. That is, later theoretical developments that may explain the observed results on a basis different from the theory presented herein will not detract from the inventions described herein.
Any patent, patent application, or publication identified in the specification is hereby incorporated by reference herein in its entirety. Any material, or portion thereof, that is said to be incorporated by reference herein, but which conflicts with existing definitions, statements, or other disclosure material explicitly set forth herein is only incorporated to the extent that no conflict arises between that incorporated material and the present disclosure material. In the event of a conflict, the conflict is to be resolved in favor of the present disclosure as the preferred disclosure.
While the present invention has been particularly shown and described with reference to the preferred mode as illustrated in the drawing, it will be understood by one skilled in the art that various changes in detail may be affected therein without departing from the spirit and scope of the invention as defined by the claims.
This application claims priority to and the benefit of U.S. patent application Ser. No. 12/536,036, filed Aug. 5, 2009, now U.S. Pat. No. 8,487,385 which itself claimed priority to and the benefit of then U.S. provisional patent application Ser. No. 61/137,939, filed Aug. 5, 2008, each of which applications is incorporated herein by reference in its entirety.
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Entry |
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Zhang et. al., “Nanomechanical Torsional Resonators for Frequency-Shift Infrared Thermal Sensing”, Nano Letters, ASC Publications, received Dec. 19, 2012; revised Feb. 14, 2013; possibly published Mar. 4, 2013, dx.doi.org/10.1021/nl304687p. |
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20150253196 A1 | Sep 2015 | US |
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61137939 | Aug 2008 | US |
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Parent | 12536036 | Aug 2009 | US |
Child | 13919642 | US |