The present subject matter relates generally to caloric heat pumps for appliances.
Conventional refrigeration technology typically utilizes a heat pump that relies on compression and expansion of a fluid refrigerant to receive and reject heat in a cyclic manner so as to effect a desired temperature change or transfer heat energy from one location to another. This cycle can be used to receive heat from a refrigeration compartment and reject such heat to the environment or a location that is external to the compartment. Other applications include air conditioning of residential or commercial structures. A variety of different fluid refrigerants have been developed that can be used with the heat pump in such systems.
While improvements have been made to such heat pump systems that rely on the compression of fluid refrigerant, at best such can still only operate at about forty-five percent or less of the maximum theoretical Carnot cycle efficiency. Also, some fluid refrigerants have been discontinued due to environmental concerns. The range of ambient temperatures over which certain refrigerant-based systems can operate may be impractical for certain locations. Other challenges with heat pumps that use a fluid refrigerant exist as well.
Magneto-caloric materials (MCMs), i.e. materials that exhibit the magneto-caloric effect, provide a potential alternative to fluid refrigerants for heat pump applications. In general, the magnetic moments of MCMs become more ordered under an increasing, externally applied magnetic field and cause the MCMs to generate heat. Conversely, decreasing the externally applied magnetic field allows the magnetic moments of the MCMs to become more disordered and allow the MCMs to absorb heat. Some MCMs exhibit the opposite behavior, i.e. generating heat when the magnetic field is removed (which are sometimes referred to as para-magneto-caloric material but both types are referred to collectively herein as magneto-caloric material or MCM). The theoretical Carnot cycle efficiency of a refrigeration cycle based on an MCMs can be significantly higher than for a comparable refrigeration cycle based on a fluid refrigerant. As such, a heat pump system that can effectively use an MCM would be useful.
Challenges exist to the practical and cost competitive use of an MCM, however. In addition to the development of suitable MCMs, equipment that can attractively utilize an MCM is still needed. Currently proposed equipment may require relatively large and expensive magnets, may be impractical for use in e.g., appliance refrigeration, and may not otherwise operate with enough efficiency to justify capital cost.
Accordingly, a heat pump system that can address certain challenges, such as those identified above, would be useful. Such a heat pump system that can also be used in a refrigerator appliance would also be useful.
Aspects and advantages of the invention will be set forth in part in the following description, or may be apparent from the description, or may be learned through practice of the invention.
In a first example embodiment, a caloric regenerator system includes a flow body that defines a plurality of cold side channels, a plurality of hot side channels and a central passage. The plurality of cold side channels are spaced from the plurality of hot side channels within the flow body along an axial direction. Each of the plurality of cold side channels extends from the central passage along a radial direction. The cold side channels of the plurality of cold side channels are distributed within the flow body along a circumferential direction. Each of the plurality of hot side channels extends from the central passage along the radial direction. The hot side channels of the plurality of hot side channels are distributed within the flow body along the circumferential direction. A port body is received within the central passage of the flow body such that the flow body is rotatable relative to the port body. The port body defines a hot side port and a cold side port. The hot side port is spaced from the cold side port on the port body along the axial direction. The hot side port is positioned coplanar with the plurality of hot side channels in a plane that is perpendicular to the axial direction. The cold side port is positioned coplanar with the plurality of cold side channels in another plane that is perpendicular to the axial direction. The hot side port defines a width along the circumferential direction. The cold side port defines a width along the circumferential direction. The width of the hot side port is less than the width of the cold side port. An annular caloric regenerator is in flow communication with the plurality of cold side channels and the plurality of hot side channels such that a heat transfer fluid is flowable into the annular caloric regenerator through the plurality of cold side channels and out of the annular caloric regenerator through the plurality of hot side channels.
In a second example embodiment, a caloric regenerator system includes a flow body that defines a plurality of cold side channels, a plurality of hot side channels and a central passage. The plurality of cold side channels are spaced from the plurality of hot side channels within the flow body along an axial direction. Each of the plurality of cold side channels extends from the central passage along a radial direction. The cold side channels of the plurality of cold side channels are distributed within the flow body along a circumferential direction. Each of the plurality of hot side channels extends from the central passage along the radial direction. The hot side channels of the plurality of hot side channels are distributed within the flow body along the circumferential direction. A port body is received within the central passage of the flow body such that the flow body is rotatable relative to the port body. The port body defines a hot side port and a cold side port. The hot side port is spaced from the cold side port on the port body along the axial direction. The hot side port is positioned coplanar with the plurality of hot side channels in a plane that is perpendicular to the axial direction. The cold side port is positioned coplanar with the plurality of cold side channels in another plane that is perpendicular to the axial direction. The hot side port defines a width along the circumferential direction. The cold side port defines a width along the circumferential direction. The width of the hot side port is less than the width of the cold side port. An annular caloric regenerator is in flow communication with the plurality of cold side channels and the plurality of hot side channels such that a heat transfer fluid is flowable into the annular caloric regenerator through the plurality of cold side channels and out of the annular caloric regenerator through the plurality of hot side channels. A hot side seal extends around the hot side port. The hot side seal spans a gap between the port body and the flow body along the radial direction at the hot side port. A cold side seal extends around the cold side port. The cold side seal spans a gap between the port body and the flow body along the radial direction at the cold side port. A pump is operable to flow the heat transfer fluid. A field generator is configured to apply a field to a portion of the annular caloric regenerator.
These and other features, aspects and advantages of the present invention will become better understood with reference to the following description and appended claims. The accompanying drawings, which are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.
A full and enabling disclosure of the present invention, including the best mode thereof, directed to one of ordinary skill in the art, is set forth in the specification, which makes reference to the appended figures.
Reference now will be made in detail to embodiments of the invention, one or more examples of which are illustrated in the drawings. Each example is provided by way of explanation of the invention, not limitation of the invention. In fact, it will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the scope or spirit of the invention. For instance, features illustrated or described as part of one embodiment can be used with another embodiment to yield a still further embodiment. Thus, it is intended that the present invention covers such modifications and variations as come within the scope of the appended claims and their equivalents.
The present subject matter is directed to a caloric heat pump system for heating or cooling an appliance, such as a refrigerator appliance. While described in greater detail below in the context of a magneto-caloric heat pump system, one of skill in the art using the teachings herein will recognize that other suitable caloric materials may be used in a similar manner to heat or cool an appliance, i.e., apply a field, move heat, remove the field, move heat. For example, electro-caloric material heats up and cools down within increasing and decreasing electric fields. As another example, elasto-caloric material heats up and cools down when exposed to increasing and decreasing mechanical strain. As yet another example, baro-caloric material heats up and cools down when exposed to increasing and decreasing pressure. Such materials and other similar caloric materials may be used in place of or in addition to the magneto-caloric material described below to heat or cool liquid/water within an appliance. Thus, caloric material is used broadly herein to encompass materials that undergo heating or cooling when exposed to a changing field from a field generator, where the field generator may be a magnet, an electric field generator, an actuator for applying mechanical stress or pressure, etc.
Referring now to
Refrigerator 10 is provided by way of example only. Other configurations for a refrigerator appliance may be used as well including appliances with only freezer compartments, only chilled compartments, or other combinations thereof different from that shown in
The heat transfer fluid flows out of first heat exchanger 32 by line 44 to heat pump 100. As will be further described herein, the heat transfer fluid receives additional heat from caloric material in heat pump 100 and carries this heat by line 48 to pump 42 and then to second heat exchanger 34. Heat is released to the environment, machinery compartment 40, and/or other location external to refrigeration compartment 30 using second heat exchanger 34. A fan 36 may be used to create a flow of air across second heat exchanger 34 and thereby improve the rate of heat transfer to the environment. Pump 42 connected into line 48 causes the heat transfer fluid to recirculate in heat pump system 52. Motor 28 is in mechanical communication with heat pump 100 as will further described.
From second heat exchanger 34 the heat transfer fluid returns by line 50 to heat pump 100 where, as will be further described below, the heat transfer fluid loses heat to the caloric material in heat pump 100. The now colder heat transfer fluid flows by line 46 to first heat exchanger 32 to receive heat from refrigeration compartment 30 and repeat the cycle as just described.
Heat pump system 52 is provided by way of example only. Other configurations of heat pump system 52 may be used as well. For example, lines 44, 46, 48, and 50 provide fluid communication between the various components of the heat pump system 52 but other heat transfer fluid recirculation loops with different lines and connections may also be employed. For example, pump 42 can also be positioned at other locations or on other lines in system 52. Still other configurations of heat pump system 52 may be used as well. For example, heat pump system 52 may be configured such that the caloric material in heat pump 100 directly cools air that flows through refrigeration compartment 30 and directly heats air external to refrigeration compartment 30. Thus, system 52 need not include a liquid working fluid in certain example embodiments.
Pump 43 may be operable to flow heat transfer fluid through cold side channels 212 and hot side channels 214. Flow body 210 and port body 220 cooperate to collectively form an uneven flow valve that regulates the flow of heat transfer fluid through cold side channels 212 and hot side channels 214. Operation of caloric regenerator system 200 and the flow of heat transfer fluid within caloric regenerator system 200 during operation of caloric regenerator system 200 are discussed in greater detail below.
Cold side channels 212 are spaced from hot side channels 214 within flow body 210, e.g., along an axial direction A. Thus, e.g., heat transfer fluid flowing through cold side channels 212 may be separate from heat transfer fluid flowing through hot side channels 214. However, flow body 210 may also define a plurality of connecting channels 217. Each connecting channel 217 may extend between a respective pair of hot and cold side channels 212, 214, e.g., along the axial direction A, to allow fluid flow from both hot and cold side channels 212, 214 to a recess 218, as discussed in greater detail below. Each cold side channel 212 also extends from central passage 216 along a radial direction R. In addition, cold side channels 212 are distributed, e.g., uniformly, within flow body 210 along a circumferential direction C. As may be seen from the above, cold side channels 212 may be distributed in a radial array within flow body 210.
Like cold side channels 212, each hot side channel 214 extends from central passage 216 along the radial direction R. However, as noted above, hot side channels 214 may be positioned is a separate axial cross-section of flow body 210 as shown in
In the example embodiments shown in
Port body 220 may be received within central passage 216 of flow body 210 such that cold side port 222 is aligned and in fluid communication with one or more of cold side channels 212 and hot side port 224 is aligned and in fluid communication with one or more of hot side channels 214. In particular, as flow body 210 relative to port body 220, cold side port 222 may be aligned and in fluid communication with a varying subset of cold side channels 212 and hot side port 224 may be aligned and in fluid communication with a varying subset of hot side channels 214. In the example shown in
Caloric regenerator system 200 may also include seals 226 and/or seals 228. Each seal 226 extends around a respective one of cold side port 222 and hot side port 224. In addition, each seal 226 may extend along the radial direction R between flow body 210 and port body 220. Thus, seals 226 may limit fluid flow at the interface between flow body 210 and port body 220. Seals 228 may extend around port body 220, e.g., along the circumferential direction C, and may also extend along the radial direction R between flow body 210 and port body 220. In addition, seals 228 may be positioned at opposite each other about cold side port 222 and hot side port 224. Seals 228 also assist with limiting fluid flow at the interface between flow body 210 and port body 220. An outer diameter of port body 220 may also be selected to complement a diameter of central passage 216 of flow body 210 in order to limit fluid flow at the interface between flow body 210 and port body 220. Thus, thermal losses and short circuiting of heat transfer fluid within caloric regenerator system 200 may be reduced with seals 226, seals 228 and/or with suitable sizing of port body 220 relative to central passage 216.
Seals 226 and/or seals 228 may be constructed of or with suitable materials. For example, each seal 226 and/or seal 228 may include one or more of an elastomer, polytetrafluoroethylene and polyurethane. As a particular example, each seal 226 and/or seal 228 may include an elastomer ring positioned on port body 220 that urges a polytetrafluoroethylene or polyurethane ring against flow body 210 along the radial direction R. Thus, the elastomer may act as a spring, applying consistent sealing pressure to the polytetrafluoroethylene or polyurethane ring towards the flow body 210 along the radial direction R. The polytetrafluoroethylene or polyurethane ring may contact flow body 210 but with relatively low friction compared to other materials, such as elastomers, to thus limit interference by the seals with the rotation of flow body 210 relative to port body 220.
Turning now to
Field generator 250 is configured to generate a field that reacts with a caloric material in annular caloric regenerator 240. Thus, e.g., the field from field generator 250 may generate phase changes within the caloric material in annular caloric regenerator 240 that result in temperature changes of the caloric material in annular caloric regenerator 240. Field generator 250 may be a magnet, and annular caloric regenerator 240 may include magneto-caloric material in certain example embodiments.
The caloric material in annular caloric regenerator 240 may be constructed from a single caloric material or may include multiple different caloric materials. By way of example, appliance 10 may be used in an application where the ambient temperature changes over a substantial range. However, a specific caloric material may exhibit the caloric effect over only a much narrower temperature range. As such, it may be desirable to use a variety of caloric materials within a given portion of annular caloric regenerator 240 to accommodate the wide range of ambient temperatures over which appliance 10 and/or caloric regenerator system 200 may be used.
Field generator 250 is sized such that only a portion of annular caloric regenerator 240 is positioned within the field of field generator 250, the portion is shown with dashed lines in
The portion of annular caloric regenerator 240 that is positioned within the field of field generator 250 may be less than the portion of annular caloric regenerator 240 that is positioned out of the field of field generator 250. For example, annular caloric regenerator 240 and field generator 250 may be sized such that the portion of annular caloric regenerator 240 that is positioned within the field of field generator 250 is no great than half, no greater than a quarter, no greater than a third, etc. of the portion of annular caloric regenerator 240 that is positioned out of the field of field generator 250. Such sizing may facilitate efficient operation of caloric regenerator system 200, as described in greater detail below.
When field generator 250 is a magnet and annular caloric regenerator 240 includes magneto-caloric material, the magneto-caloric material in the annular caloric regenerator 240 may move into and out of the magnetic field from the magnet. Movement of magneto-caloric material of annular caloric regenerator 240 into the magnetic field from the magnet may cause the magnetic moments of the magneto-caloric material to orient and the magneto-caloric material to heat (or alternatively cool) as part of the magneto-caloric effect. Conversely, movement of magneto-caloric material of annular caloric regenerator 240 out of the magnetic field from the magnet may cause the magnetic moments of the magneto-caloric material to disorient and the magneto-caloric material to cool (or alternatively heat) as part of the magneto-caloric effect. Being “out” of the magnetic field means that the magneto-caloric material is generally or substantially uninfluenced by the magnetic field from the magnet. Accordingly, the magneto-caloric material may not be actively heating (or cooling) as it would if within the magnetic field (and instead may be actively or passively cooling (or heating) due to such removal of the magnetic field). Being “in” the magnetic field means that the magneto-caloric material is generally or substantially influenced by the magnetic field from the magnet. Accordingly, the magneto-caloric material may not be actively cooling (or heating) as it would if out of the magnetic field (and instead may be actively or passively heating (or cooling) due to the reaction of the magneto-caloric material to the magnetic field).
Annular caloric regenerator 240 is in flow communication with cold side channels 212 and hot side channels 214. Thus, heat transfer fluid is flowable into annular caloric regenerator 240, e.g., through cold side channels 212, and out of annular caloric regenerator 240, e.g., through hot side channels 214. The heat transfer fluid may reject heat to or receive heat from the caloric material in annular caloric regenerator 240.
When the portion of the caloric material in annular caloric regenerator 240 is fully within the field from field generator 250, the caloric material may heat as part of the caloric effect due to phase changes within the caloric material. In turn, the heat transfer fluid may be heated by the caloric material when the portion of the caloric material in annular caloric regenerator 240 is within the field from field generator 250. As indicated by arrow QH-OUT in
The heat transfer fluid flowing through the portion of the caloric material in annular caloric regenerator 240 has a relatively high velocity when within the field from field generator 250. Such high velocity may be caused by the sizing of width WH of hot side port 224 described above. For example, because the width WH of hot side port 224 allows only fluid communication with one of hot side channels 214, the heat transfer fluid flowing through the portion of the caloric material in annular caloric regenerator 240 may be forced to have a relatively high velocity due to the restriction generated by such sizing.
When the portion of the caloric material in annular caloric regenerator 240 is out of the field from field generator 250, the caloric material may cool as part of the caloric effect due to phase changes within the caloric material. In turn, the heat transfer fluid may be cooled by the caloric material when the portion of the caloric material in annular caloric regenerator 240 is outside of the field from field generator 250. As indicated by arrow QC-OUT in
The heat transfer fluid flowing through the portion of the caloric material in annular caloric regenerator 240 has a relatively low velocity when outside of the field from field generator 250. Such low velocity may be caused by the sizing of width WC of cold side port 222 described above. For example, because the width WC of cold side port 222 allows fluid communication with multiple cold side channels 212 (e.g., more cold side channels 212 than the width WH of hot side port 224 allows for fluid communication with hot side channels 214), the heat transfer fluid flowing through the portion of the caloric material in annular caloric regenerator 240 may be permitted to have a relatively low velocity due to the lesser restriction generated by such sizing.
As may be seen from the above, caloric regenerator system 200 may include an uneven flow valve that is configured to provide relatively short and fast heat transfer fluid flow toward a hot side of the caloric material and relatively long and slow heat transfer fluid flow toward a cold side of the caloric material. However, total displacement of the heat transfer fluid is the same in both directions. The uneven flow valve may be configured to provide any suitable velocity profile, e.g., as long as the average velocity of the heat transfer fluid is lower towards the cold side. The uneven flow valve may also be configured to provide zero velocity portions between the flow period towards the hot and cold sides. Thus, the heat transfer fluid may be stationary within the caloric material as the caloric material shifts from in field to out of field. The uneven flow valve may include a sliding seal valve on either end of the caloric material. Ports on a static component of the uneven flow valve may line up with different sections of a rotating component with the caloric material to direct flow.
In such a manner, a cost effective magneto-caloric regenerator system may have a relatively small magnetized regenerator portion (and thus a relatively large demagnetized portion) with an uneven flow profile. Viscous dissipation overall can be decreased, and the viscous dissipation on the cold side may be decreased the most. This is a critical loss area for performance, as generated heat must be provided by a pump and directly deducts from cooling ability of the magneto-caloric regenerator; a double impact on efficiency.
This written description uses examples to disclose the invention, including the best mode, and also to enable any person skilled in the art to practice the invention, including making and using any devices or systems and performing any incorporated methods. The patentable scope of the invention is defined by the claims, and may include other examples that occur to those skilled in the art. Such other examples are intended to be within the scope of the claims if they include structural elements that do not differ from the literal language of the claims, or if they include equivalent structural elements with insubstantial differences from the literal languages of the claims.
Number | Name | Date | Kind |
---|---|---|---|
668560 | Fulner et al. | Feb 1901 | A |
1985455 | Mosby | Dec 1934 | A |
2671929 | Gayler | Mar 1954 | A |
2765633 | Muffly | Oct 1956 | A |
3618265 | Croop | Nov 1971 | A |
3816029 | Bowen et al. | Jun 1974 | A |
3844341 | Bimshas, Jr. et al. | Oct 1974 | A |
3956076 | Powell, Jr. et al. | May 1976 | A |
4037427 | Kramer | Jul 1977 | A |
4102655 | Jeffery et al. | Jul 1978 | A |
4107935 | Steyert, Jr. | Aug 1978 | A |
4197709 | Hochstein | Apr 1980 | A |
4200680 | Sasazawa et al. | Apr 1980 | A |
4259843 | Kausch | Apr 1981 | A |
4332135 | Barclay et al. | Jun 1982 | A |
4408463 | Barclay | Oct 1983 | A |
4507927 | Barclay | Apr 1985 | A |
4507928 | Johnson | Apr 1985 | A |
4549155 | Halbach | Oct 1985 | A |
4554790 | Nakagome et al. | Nov 1985 | A |
4557228 | Samodovitz | Dec 1985 | A |
4599866 | Nakagome et al. | Jul 1986 | A |
4625519 | Hakuraku et al. | Dec 1986 | A |
4642994 | Barclay et al. | Feb 1987 | A |
4735062 | Woolley et al. | Apr 1988 | A |
4741175 | Schulze | May 1988 | A |
4785636 | Hakuraku et al. | Nov 1988 | A |
4796430 | Malaker et al. | Jan 1989 | A |
5062471 | Jaeger | Nov 1991 | A |
5091361 | Hed | Feb 1992 | A |
5156003 | Yoshiro et al. | Oct 1992 | A |
5190447 | Schneider | Mar 1993 | A |
5249424 | DeGregoria et al. | Oct 1993 | A |
5336421 | Kurita et al. | Aug 1994 | A |
5351791 | Rosenzweig | Oct 1994 | A |
5465781 | DeGregoria | Nov 1995 | A |
5599177 | Hetherington | Feb 1997 | A |
5661895 | Irgens | Sep 1997 | A |
5718570 | Beckett et al. | Feb 1998 | A |
5934078 | Lawton, Jr. et al. | Aug 1999 | A |
6332323 | Reid et al. | Dec 2001 | B1 |
6423255 | Hoechsmann et al. | Jul 2002 | B1 |
6446441 | Dean | Sep 2002 | B1 |
6467274 | Barclay et al. | Oct 2002 | B2 |
6517744 | Hara et al. | Feb 2003 | B1 |
6526759 | Zimm et al. | Mar 2003 | B2 |
6588215 | Ghoshal | Jul 2003 | B1 |
6612816 | Vanden Brande et al. | Sep 2003 | B1 |
6668560 | Zimm et al. | Dec 2003 | B2 |
6826915 | Wada et al. | Dec 2004 | B2 |
6840302 | Tanaka et al. | Jan 2005 | B1 |
6915647 | Tsuchikawa et al. | Jul 2005 | B2 |
6935121 | Fang et al. | Aug 2005 | B2 |
6946941 | Chell | Sep 2005 | B2 |
6971245 | Kuroyanagi | Dec 2005 | B2 |
7148777 | Chell et al. | Dec 2006 | B2 |
7297270 | Bernard et al. | Nov 2007 | B2 |
7313926 | Gurin | Jan 2008 | B2 |
7481064 | Kitanovski et al. | Jan 2009 | B2 |
7552592 | Iwasaki et al. | Jun 2009 | B2 |
7644588 | Shin et al. | Jan 2010 | B2 |
7863789 | Zepp et al. | Jan 2011 | B2 |
7897898 | Muller et al. | Mar 2011 | B2 |
7938632 | Smith | May 2011 | B2 |
8061147 | Dinesen et al. | Nov 2011 | B2 |
8069662 | Albert | Dec 2011 | B1 |
8099964 | Saito et al. | Jan 2012 | B2 |
8174245 | Carver | May 2012 | B2 |
8191375 | Sari et al. | Jun 2012 | B2 |
8209988 | Zhang et al. | Jul 2012 | B2 |
8216396 | Dooley et al. | Jul 2012 | B2 |
8310325 | Zhang et al. | Nov 2012 | B2 |
8375727 | Sohn | Feb 2013 | B2 |
8378769 | Heitzler et al. | Feb 2013 | B2 |
8448453 | Bahl et al. | May 2013 | B2 |
8551210 | Reppel et al. | Oct 2013 | B2 |
8596084 | Herrera et al. | Dec 2013 | B2 |
8616009 | Dinesen et al. | Dec 2013 | B2 |
8656725 | Muller et al. | Feb 2014 | B2 |
8695354 | Heitzler et al. | Apr 2014 | B2 |
8729718 | Kuo et al. | May 2014 | B2 |
8763407 | Carroll et al. | Jul 2014 | B2 |
8769966 | Heitzler et al. | Jul 2014 | B2 |
8869541 | Heitzler et al. | Oct 2014 | B2 |
8904806 | Cramet et al. | Dec 2014 | B2 |
8935927 | Kobayashi et al. | Jan 2015 | B2 |
8978391 | Muller et al. | Mar 2015 | B2 |
9175885 | Katter | Nov 2015 | B2 |
9245673 | Carroll et al. | Jan 2016 | B2 |
9377221 | Benedict | Jun 2016 | B2 |
9400126 | Takahashi et al. | Jul 2016 | B2 |
9523519 | Muller | Dec 2016 | B2 |
9534817 | Benedict et al. | Jan 2017 | B2 |
9548151 | Muller | Jan 2017 | B2 |
9599374 | Takahashi et al. | Mar 2017 | B2 |
9631843 | Benedict | Apr 2017 | B2 |
9702594 | Vetrovec | Jul 2017 | B2 |
9739510 | Hassen | Aug 2017 | B2 |
9746214 | Zimm et al. | Aug 2017 | B2 |
9797630 | Benedict et al. | Oct 2017 | B2 |
9810454 | Tasaki et al. | Nov 2017 | B2 |
9857105 | Schroeder et al. | Jan 2018 | B1 |
9857106 | Schroeder | Jan 2018 | B1 |
9927155 | Boeder et al. | Mar 2018 | B2 |
9978487 | Katter et al. | May 2018 | B2 |
10006675 | Benedict et al. | Jun 2018 | B2 |
10018385 | Radermacher et al. | Jul 2018 | B2 |
10684044 | Schroeder | Jun 2020 | B2 |
20020040583 | Barclay et al. | Apr 2002 | A1 |
20020066368 | Zornes | Jun 2002 | A1 |
20020087120 | Rogers et al. | Jul 2002 | A1 |
20030010054 | Esch et al. | Jan 2003 | A1 |
20030051774 | Saito | Mar 2003 | A1 |
20040093877 | Wada | May 2004 | A1 |
20040182086 | Chiang et al. | Sep 2004 | A1 |
20040187510 | Jung | Sep 2004 | A1 |
20040187803 | Regev | Sep 2004 | A1 |
20040250550 | Bruck | Dec 2004 | A1 |
20050017394 | Hochsmann et al. | Jan 2005 | A1 |
20050046533 | Chell | Mar 2005 | A1 |
20050109490 | Harmon et al. | May 2005 | A1 |
20050217278 | Mongia et al. | Oct 2005 | A1 |
20050263357 | Kuwahara | Dec 2005 | A1 |
20050274676 | Kumar et al. | Dec 2005 | A1 |
20060130518 | Kang et al. | Jun 2006 | A1 |
20060231163 | Hirosawa et al. | Oct 2006 | A1 |
20060279391 | Xia | Dec 2006 | A1 |
20070130960 | Muller et al. | Jun 2007 | A1 |
20070220901 | Kobayashi | Sep 2007 | A1 |
20080223853 | Muller et al. | Sep 2008 | A1 |
20080236171 | Saito et al. | Oct 2008 | A1 |
20080236175 | Chaparro Monferrer et al. | Oct 2008 | A1 |
20080303375 | Carver | Dec 2008 | A1 |
20090032223 | Zimmerman et al. | Feb 2009 | A1 |
20090091411 | Zhang et al. | Apr 2009 | A1 |
20090158749 | Sandeman | Jun 2009 | A1 |
20090217674 | Kaji et al. | Sep 2009 | A1 |
20090236930 | Nashiki | Sep 2009 | A1 |
20090266083 | Shin et al. | Oct 2009 | A1 |
20090308080 | Han et al. | Dec 2009 | A1 |
20090314860 | Wang et al. | Dec 2009 | A1 |
20090320499 | Muller et al. | Dec 2009 | A1 |
20100000228 | Wiest et al. | Jan 2010 | A1 |
20100058775 | Kaji et al. | Mar 2010 | A1 |
20100071383 | Zhang et al. | Mar 2010 | A1 |
20100116471 | Reppel et al. | May 2010 | A1 |
20100122488 | Fukai | May 2010 | A1 |
20100150747 | Mehta et al. | Jun 2010 | A1 |
20100162747 | Hamel et al. | Jul 2010 | A1 |
20100209084 | Nelson et al. | Aug 2010 | A1 |
20100236258 | Heitzler et al. | Sep 2010 | A1 |
20100276627 | Mazet | Nov 2010 | A1 |
20100303917 | Watson et al. | Dec 2010 | A1 |
20110000206 | Aprad | Jan 2011 | A1 |
20110042608 | Reesink | Feb 2011 | A1 |
20110048031 | Barve | Mar 2011 | A1 |
20110048690 | Reppel et al. | Mar 2011 | A1 |
20110058795 | Kleman et al. | Mar 2011 | A1 |
20110061398 | Shih et al. | Mar 2011 | A1 |
20110062821 | Chang et al. | Mar 2011 | A1 |
20110082026 | Sakatani et al. | Apr 2011 | A1 |
20110094243 | Carroll et al. | Apr 2011 | A1 |
20110129363 | Sakai et al. | Jun 2011 | A1 |
20110154832 | Barve et al. | Jun 2011 | A1 |
20110162388 | Barve et al. | Jul 2011 | A1 |
20110168363 | Reppel et al. | Jul 2011 | A9 |
20110173993 | Muller et al. | Jul 2011 | A1 |
20110182086 | Mienko et al. | Jul 2011 | A1 |
20110192836 | Muller et al. | Aug 2011 | A1 |
20110218921 | Addala et al. | Sep 2011 | A1 |
20110239662 | Bahl et al. | Oct 2011 | A1 |
20110284196 | Zanadi | Nov 2011 | A1 |
20110302931 | Sohn | Dec 2011 | A1 |
20110308258 | Smith et al. | Dec 2011 | A1 |
20110314836 | Heitzler et al. | Dec 2011 | A1 |
20120031108 | Kobayashi et al. | Feb 2012 | A1 |
20120033002 | Seeler et al. | Feb 2012 | A1 |
20120036868 | Heitzler et al. | Feb 2012 | A1 |
20120045698 | Shima | Feb 2012 | A1 |
20120060526 | May et al. | Mar 2012 | A1 |
20120079834 | Dinesen | Apr 2012 | A1 |
20120222427 | Hassen | Sep 2012 | A1 |
20120222428 | Celik et al. | Sep 2012 | A1 |
20120266591 | Morimoto et al. | Oct 2012 | A1 |
20120266607 | Morimoto et al. | Oct 2012 | A1 |
20120267090 | Kruglick | Oct 2012 | A1 |
20120272665 | Watanabe et al. | Nov 2012 | A1 |
20120272666 | Watanabe | Nov 2012 | A1 |
20120285179 | Morimoto | Nov 2012 | A1 |
20120291453 | Watanabe et al. | Nov 2012 | A1 |
20130019610 | Zimm et al. | Jan 2013 | A1 |
20130020529 | Chang et al. | Jan 2013 | A1 |
20130104568 | Kuo et al. | May 2013 | A1 |
20130106116 | Kuo et al. | May 2013 | A1 |
20130145573 | Bizhanzadeh | Jun 2013 | A1 |
20130180263 | Choi et al. | Jul 2013 | A1 |
20130186107 | Shih et al. | Jul 2013 | A1 |
20130187077 | Katter | Jul 2013 | A1 |
20130192269 | Wang | Aug 2013 | A1 |
20130199460 | Duplessis et al. | Aug 2013 | A1 |
20130200293 | Zhao et al. | Aug 2013 | A1 |
20130227965 | Yagi et al. | Sep 2013 | A1 |
20130232993 | Saito et al. | Sep 2013 | A1 |
20130255279 | Tomimatsu et al. | Oct 2013 | A1 |
20130269367 | Meillan | Oct 2013 | A1 |
20130298571 | Morimoto et al. | Nov 2013 | A1 |
20130300243 | Gieras et al. | Nov 2013 | A1 |
20130319012 | Kuo et al. | Dec 2013 | A1 |
20130327062 | Watanabe et al. | Dec 2013 | A1 |
20140020881 | Reppel et al. | Jan 2014 | A1 |
20140075958 | Takahashi et al. | Mar 2014 | A1 |
20140116538 | Tanaka et al. | May 2014 | A1 |
20140157793 | Johnson et al. | Jun 2014 | A1 |
20140165594 | Benedict | Jun 2014 | A1 |
20140165595 | Zimm et al. | Jun 2014 | A1 |
20140190182 | Benedict | Jul 2014 | A1 |
20140216057 | Oezcan | Aug 2014 | A1 |
20140260373 | Gerber et al. | Sep 2014 | A1 |
20140290273 | Benedict et al. | Oct 2014 | A1 |
20140290275 | Muller | Oct 2014 | A1 |
20140291570 | Klausner et al. | Oct 2014 | A1 |
20140305137 | Benedict | Oct 2014 | A1 |
20140305139 | Takahashi et al. | Oct 2014 | A1 |
20140311165 | Watanabe et al. | Oct 2014 | A1 |
20140325996 | Muller | Nov 2014 | A1 |
20140366557 | Mun et al. | Dec 2014 | A1 |
20150007582 | Kim et al. | Jan 2015 | A1 |
20150027133 | Benedict | Jan 2015 | A1 |
20150030483 | Ryu | Jan 2015 | A1 |
20150033762 | Cheng et al. | Feb 2015 | A1 |
20150033763 | Saito et al. | Feb 2015 | A1 |
20150047371 | Hu et al. | Feb 2015 | A1 |
20150068219 | Komorowski et al. | Mar 2015 | A1 |
20150089960 | Takahashi et al. | Apr 2015 | A1 |
20150096307 | Watanabe et al. | Apr 2015 | A1 |
20150114007 | Neilson et al. | Apr 2015 | A1 |
20150168030 | Leonard et al. | Jun 2015 | A1 |
20150184903 | Mun et al. | Jul 2015 | A1 |
20150211440 | Joffroy | Jul 2015 | A1 |
20150260433 | Choi et al. | Sep 2015 | A1 |
20150267943 | Kim et al. | Sep 2015 | A1 |
20150362224 | Benedict et al. | Dec 2015 | A1 |
20150362225 | Schwartz | Dec 2015 | A1 |
20150369524 | Ikegami et al. | Dec 2015 | A1 |
20160000999 | Focht et al. | Jan 2016 | A1 |
20160025385 | Auringer et al. | Jan 2016 | A1 |
20160032920 | Hatami Aghdam | Feb 2016 | A1 |
20160084544 | Radermacher et al. | Mar 2016 | A1 |
20160091227 | Leonard et al. | Mar 2016 | A1 |
20160146515 | Momen et al. | May 2016 | A1 |
20160216012 | Benedict et al. | Jul 2016 | A1 |
20160238287 | Benedict | Aug 2016 | A1 |
20160273811 | Smith et al. | Sep 2016 | A1 |
20160282021 | Zhao et al. | Sep 2016 | A1 |
20160298880 | Humburg | Oct 2016 | A1 |
20160355898 | Vieym Villegas et al. | Dec 2016 | A1 |
20160356529 | Humburg | Dec 2016 | A1 |
20160367982 | Pennie | Dec 2016 | A1 |
20170059213 | Barclay et al. | Mar 2017 | A1 |
20170059215 | Watanabe et al. | Mar 2017 | A1 |
20170071234 | Garg | Mar 2017 | A1 |
20170138648 | Cui et al. | May 2017 | A1 |
20170176083 | Sul et al. | Jun 2017 | A1 |
20170309380 | Benedict et al. | Oct 2017 | A1 |
20170328603 | Barclay et al. | Nov 2017 | A1 |
20170328649 | Brandmeier | Nov 2017 | A1 |
20170370624 | Zimm et al. | Dec 2017 | A1 |
20180005735 | Scharf et al. | Jan 2018 | A1 |
20180023852 | Schroeder et al. | Jan 2018 | A1 |
20180045437 | Vetrovec | Feb 2018 | A1 |
20180195775 | Schroeder et al. | Jul 2018 | A1 |
20180283740 | Holladay et al. | Oct 2018 | A1 |
20180340715 | Benedict et al. | Nov 2018 | A1 |
20190206578 | Wong | Jul 2019 | A1 |
Number | Date | Country |
---|---|---|
2893874 | Jun 2014 | CA |
2919117 | Jan 2015 | CA |
1977131 | Jun 2007 | CN |
101280983 | Oct 2008 | CN |
101495818 | Jul 2009 | CN |
101842647 | Sep 2010 | CN |
101979937 | Feb 2011 | CN |
201772566 | Mar 2011 | CN |
102165615 | Aug 2011 | CN |
101788207 | Sep 2011 | CN |
102345942 | Feb 2012 | CN |
202432596 | Sep 2012 | CN |
103090583 | May 2013 | CN |
103712401 | Apr 2014 | CN |
102077303 | Apr 2015 | CN |
106481842 | Mar 2017 | CN |
106949673 | Jul 2017 | CN |
107003041 | Aug 2017 | CN |
84694 | Apr 1951 | DE |
1514388 | Jun 1969 | DE |
102013223959 | May 2015 | DE |
202015106851 | Mar 2016 | DE |
0187078 | Jul 1986 | EP |
2071255 | Jun 2009 | EP |
2108904 | Oct 2009 | EP |
2215955 | Aug 2010 | EP |
2322072 | May 2011 | EP |
2420760 | Feb 2012 | EP |
2813785 | Dec 2014 | EP |
3306082 | Apr 2018 | EP |
2935468 | Mar 2010 | FR |
59232922 | Dec 1984 | JP |
H08166182 | Jun 1996 | JP |
3205196 | Sep 2001 | JP |
2002315243 | Oct 2002 | JP |
2007147136 | Jun 2007 | JP |
2007291437 | Nov 2007 | JP |
2008051412 | Mar 2008 | JP |
2010112606 | May 2010 | JP |
2010525291 | Jul 2010 | JP |
6212955 | Dec 2014 | JP |
2014228216 | Dec 2014 | JP |
5907023 | Apr 2016 | JP |
6079498 | Feb 2017 | JP |
6191539 | Sep 2017 | JP |
2017207222 | Nov 2017 | JP |
101100301 | Dec 2011 | KR |
101238234 | Mar 2013 | KR |
WO0133145 | May 2001 | WO |
WO0212800 | Feb 2002 | WO |
WO03016794 | Feb 2003 | WO |
WO2004068512 | Aug 2004 | WO |
WO2007036729 | Apr 2007 | WO |
WO2007086638 | Aug 2007 | WO |
WO2009024412 | Feb 2009 | WO |
WO2009098391 | Aug 2009 | WO |
WO2010119591 | Oct 2010 | WO |
WO2011034594 | Mar 2011 | WO |
WO2011152179 | Dec 2011 | WO |
WO2014099199 | Jun 2014 | WO |
WO2014170447 | Oct 2014 | WO |
WO2014173787 | Oct 2014 | WO |
WO2015017230 | Feb 2015 | WO |
WO2016005774 | Jan 2016 | WO |
WO2016035267 | Mar 2016 | WO |
WO2017042266 | Mar 2017 | WO |
WO2017081048 | May 2017 | WO |
WO2017097989 | Jun 2017 | WO |
Entry |
---|
Stefano Dall'Olio, et al., Numerical Simulation of a Tapered Bed AMR, Technical University of Denmark, 2015, 2 pages. |
International Search Report issued in connection with PCT Application No. PCT/US2014/042485 dated Oct. 23, 2014. |
International Search Report issued in connection with PCT Application No. PCT/US2014/017431 dated May 9, 2014. |
International Search Report issued in connection with PCT/US2013/070518, dated Jan. 22, 2014. |
Tetsuji Okamura, Performance of a room-temperature rotary magnet refrigerator, dated Nov. 28, 2005, Elsevier. |
Journal of Alloys and Compounds, copyright 2008 Elsevier B..V. |
Evaluation of Ni—Mn—In—Si Alloys for Magnetic Refrigerant Application, Rahul Das, A. Perumal and A. Srinivasan, Dept of Physics, Indian Institute of Technology, Oct. 10, 2011. |
Effects of annealing on the magnetic entropy change and exchange bias behavior in melt-spun Ni—Mn—In ribbons, X.Z. Zhao, C.C. Hsieh, et al Science Direct, Scripta Materialia 63 (2010). |
PCT International Search Report and Written Opinion issued in connection with PCT Application No. PCT/US2013/070023 dated Feb. 27, 2014. |
Barbara Pulko, Epoxy-bonded La—Fe—Co—Si magnetocaloric plates, Journal of Magnetism and Magnetic Materials, 375 (2015) 65-73. |
International Search Report of PCT/US2014/047925 dated Nov. 10, 2014. |
Andrej Kitanovski, Present and future caloric refrigeration and heat-pump technologies, International Journal of Refrigeration, vol. 57, Sep. 2015, pp. 288-298. |
C Aprea, et al., An innovative rotary permanent magnet magnetic refrigerator based on AMR cycle, Thermal Energy Systems: Production, Storage, Utilization and the Environment, dated May 2015, Napoli, Italy, pp. 1-5. |
International Search Report, PCT Application No. PCT/CN2019/096188, dated Oct. 15, 2019, 5 pages. |
International Search Report, PCT Application No. PCT/CN2019/096187, dated Sep. 30, 2019, 4 pages. |
Number | Date | Country | |
---|---|---|---|
20200217563 A1 | Jul 2020 | US |