Universally compatible pigment dispersants

Abstract

The invention is a copolymer P, dispersant for dyes and/or pigments in standard plastic substances SK, wherein P exhibits a universal compatibility with standard plastics SK, with the feature that copolymer P is synthesized from monomer units:(m1) methyl methacrylate,(m2) (meth)acrylate of formula I: ##STR1## (m3) (meth)acryl compound of formula II: ##STR2## and optionally (m4) methacrylate of formula III: ##STR3##

Description

Claims

1. A polymer synthesized from monomers comprising:

(1) 30 to 94.5 wt % methyl methacrylate;

(2) 5 to 50 wt % (meth)acrylate of formula I ##STR4## wherein R.sub.1 is a hydrogen or methyl, and

R.sub.2 is a cycloalkyl radical with 5 to 7 ring carbon atoms; and

(3) 0.5 to 20 wt % (meth)acryl compound of formula II ##STR5## wherein: R.sub.3 is a hydrogen or methyl; and

R.sub.4 is a substituent containing at least one oxygen or nitrogen atom, and

Z is NH or NR.sub.5, with R.sub.5 .dbd.C.sub.1-6 alkyl or R.sub.4, or

R.sub.4 is a substituent containing at least one nitrogen atom, a substituent containing a heterocycle having an oxygen atom, or an alkoxy group, and

Z is O.

2. The copolymer of claim 1, wherein said monomers further comprise:

(4) 0.5 to 30 wt % methacrylate of formula III ##STR6## wherein R.sub.6 is an alkyl radical with 3 to 24 carbon atoms.

3. The copolymer of claim 1 wherein said (meth)acryl compound of formula II (3) is selected from the group consisting of dialkylaminoalkyl (meth)acrylates, dialkylaminoalkyl(meth)acrylamides, alkoxy (meth)acrylates, alkyl (meth)acrylates and alkyl(meth)acrylamides.

4. The copolymer of claim 1, wherein said copolymer has an average molecular weight M.sub.w of 5.times.10.sup.3 and 5.times.10.sup.4 daltons.

5. The copolymer of claim 1, wherein compound of formula I (2) is selected from the group consisting of cyclopentyl (meth)acrylate, cyclohexyl (meth)acrylate and 4-methylcyclohexyl (meth)acrylate.

6. The copolymer of claim 2, wherein compound of formula III (4) is selected from the group consisting of n-propyl methacrylate, isopropyl methacrylate, isobutyl methacrylate, n-pentyl methacrylate, n-hexyl methacrylate, 2-ethylhexyl methacrylate, n-octyl methacrylate, n-decyl methacrylate, n-dodecyl methacrylate, n-tetradecyl methacrylate, n-hexadecyl methacrylate, n-octadecyl methacrylate, n-eicosyl methacrylate, and n-butyl methacrylate.

7. The copolymer of claim 2, wherein said copolymer comprise 1 to 25 wt % methacrylate of formula III (4).

8. A copolymer synthesized from monomers consisting of:

(1) 30 to 94.5 wt % methyl methacrylate;

(2) 5 to 50 wt % (meth)acrylate of formula I ##STR7## wherein R.sub.1 is a hydrogen or methyl, and

R.sub.2 is a cycloalkyl radical with 5 to 7 ring carbon atoms;

(3) 0.5 to 20 wt % (meth)acryl compound of formula II ##STR8## wherein: R.sub.3 is a hydrogen or methyl,

R.sub.4 is a substituent containing at least one oxygen or nitrogen atom, and

Z is NH or NR5, with R5.dbd.C.sub.1-6 alkyl or R.sub.4, or R.sub.4 is a substituent containing at least one nitrogen atom, a substituent containing a heterocycle having an oxygen atom, or an alkoxy group and Z is 0

(4) optionally 0.5 to 30 wt % methacrylate of formula III ##STR9## wherein R.sub.6 is an alkyl radical with 3 to 24 carbon atoms.