Unlockable non-return valve for very high system pressures

Information

  • Patent Grant
  • 6820645
  • Patent Number
    6,820,645
  • Date Filed
    Wednesday, July 16, 2003
    21 years ago
  • Date Issued
    Tuesday, November 23, 2004
    20 years ago
Abstract
An unlockable non-return valve reduces the tendency of the poppet piston to jam by providing a first insert that has a guide diameter for the poppet piston over just a short section of its end side facing the piston collar, and wherein a supporting ring is arranged axially between the high-pressure seal and the first insert in a receiving element, the diameter of which is substantially smaller than the outside diameters of the inserts, the supporting ring likewise being produced from a metallic material having good sliding properties and being produced with a narrow clearance from the end section of the poppet piston and with a large radial clearance from the receiving element.
Description




The invention is based on an unlockable non-return valve which is intended to be usable for very high system pressures and which has the features from the preamble of claim


1


.




Non-return valves readily permit pressure medium to flow from a first orifice to a second orifice, with the closing element being raised from a seat counter to the force exerted by the pressure prevailing in the second orifice and counter to the force of the closing spring by means of a force produced by the pressure in the first orifice. Since the closing element is conventionally acted upon by the pressures on surfaces of identical size, a pressure arises in the first orifice which is higher than the pressure in the second orifice by a pressure difference which is equivalent to the force of the closing spring. The closing spring is only weak so as to keep the losses via the valve small, unless the intention is to deliberately build up the pressure medium in the first orifice. The flow through a non-return valve in the direction from the second orifice to the first orifice is possible only by additional measures through which an unlockable non-return valve is created. A poppet part is then provided which can act on the closing element in the opening direction and can raise it from the seat counter to the force of the closing spring and counter to the pressure difference between the first and second orifice.




DE 197 14 505 A1 has disclosed an unlockable non-return valve which has all of the features from the preamble of claim


1


. The internal high-pressure forming of tubular semi-finished products is mentioned in the above-mentioned document as an example of use of a non-return valve of this type. The non-return valve which is shown has a valve housing having a continuous receiving bore which is stepped and is composed essentially of three sections. The diameter of the receiving bore is larger in the two outer sections than in a central section into which the two outer sections merge in steps lying in radial planes. High-strength inserts which are exposed to the system pressure and inserts serving to guide a poppet piston are placed into the two outer sections. The central section of the receiving bore is divided by a piston collar of the poppet piston into two annular spaces of which the one can be acted upon by control pressure via a pilot valve in order to control the non-return valve or can be relieved from pressure to a tank, and the other is permanently connected to a pressure-medium reservoir and contains a restoring spring for the poppet piston. It has been found that, in the known non-return valve, the poppet piston is not always smooth-running to the desired extent.




DE 198 56 018 A1 has also disclosed an unlockable non-return valve which has, all of the features from the preamble of claim


1


and which is likewise used, in particular, in plants for the internal high-pressure forming of tubular semi-finished products. In the non-return valve shown in DE 198 56 018 A1, the tendency of the poppet piston to jam has been reduced by the fact that the receiving bore has essentially the same diameter in the region of the inserts and between them, apart from short turned grooves in the axial direction which may be present, so that they can be machined from just one side of the valve housing, i.e. without changing the position of the valve housing or of the tool. A spacer bushing is arranged axially between two inserts, said bushing ensuring a fixed distance between two inserts on different sides of the piston, even when the diameter of the receiving bore remains constant. The insert which is close to the piston collar on each side of the piston collar is manufactured from a metallic material having good sliding properties, for example from a copper beryllium alloy, and has, at its inside diameter, a quite narrow clearance over its entire axial extent from the corresponding end section of the poppet piston, i.e. guides the corresponding end section tightly over its entire axial length. In spite of an obtained improvement over the non-return valve disclosed in DE 197 14 505 A1, even in the non-return valve according to DE 198 56 018 A1, jamming of the poppet piston has still been established at very high pressures.




The invention is therefore based on the object of developing an unlockable non-return valve having the features from the preamble of claim


1


in such a manner that the tendency of the poppet piston to jam is reduced.




According to the invention, this object is achieved in an unlockable non-return valve according to the preamble of claim


1


by the fact that this valve is additionally provided with the features from the characterizing part of claim


1


. The invention is first of all based on the finding that the stiffness or even the jamming of the poppet piston in the known valves is also caused by deformation of the first inserts close to the piston collar. The deformation is caused by the high-pressure seal which is held in the turnout of the second insert and is supported axially on the first insert close to its inside diameter. At very high pressures, the force exerted on the first insert by the high-pressure seal is so large that the insert becomes deformed, its inside diameter, and the poppet piston becomes jammed.




According to the invention, first of all the first insert has a guide diameter for the end section of the poppet piston over just a short section of its end side facing the piston collar. Within the section described, the inside diameter of the insert is not reduced if the insert becomes deformed. Outside the section described, the inside diameter of the first insert is selected to be such a size that, in spite of a reduction in the inside diameter caused by the deformation, jamming of the poppet piston is still not caused. The supporting ring, which is situated axially between the high-pressure seal and the first insert in a receiving element which is formed between the two inserts and is open radially toward the end section of the poppet piston, has, at its outside diameter, a larger clearance in the receiving element, so that changes, which are caused by deformation, in the diameter of the receiving element do not have an effect on the supporting ring. The latter also has a substantially smaller outside diameter than the inserts, so that the engagement point of the force exerted by the high-pressure seal and the bearing point of the supporting ring against the first insert are situated axially at least approximately one above the other and the supporting ring is also hardly deformed directly. In spite of the narrow clearance between the supporting ring and end section of the poppet piston, the clearance preventing the high-pressure seal from migrating into the gap between the supporting ring and the end section of the poppet piston, in an unlockable non-return valve according to the invention, the force exerted by the high-pressure seal in the axial direction on the supporting ring and the first insert no longer causes the poppet piston to jam.




Advantageous refinements of an unlockable non-return valve according to the invention can be gathered from the subclaims.




As described in claim


2


, the first insert preferably has, in front of its section with the guide diameter, a clearance of at {fraction (1/10)} mm, preferably of {fraction (2/10)} mm, radially with respect to the end section of the poppet piston. As a result, the distance from the poppet piston is sufficiently large in order, despite deformation, to avoid jamming. On the other hand, a radial seal between the insert and end section is still supported axially to such an extent that it does not migrate [lacuna] the gap which is present.




According to patent claim


3


, the outside diameter of the supporting ring is approximately 1.1 times as large as the diameter of the turn-out for the high-pressure seal, i.e. extends radially only a relatively small distance beyond the high-pressure seal, so that a not all too large offset between the point at which the force is introduced by the high-pressure seal and the point at which the supporting ring bears against the first insert can occur.




According to patent claim


4


, the radial clearance between the supporting ring and the end section of the poppet piston is very small, so that migration of a part of the high-pressure seal into the radial gap between the supporting ring and end section of the poppet piston is very reliably avoided.




Other advantageous developments of an unlockable non-return valve according to the invention are the subject matter of further subclaims.











An exemplary embodiment of an unlockable non-return valve according to the invention and the principle of a hydraulic circuit for the internal high-pressure forming, within which circuit a non-return valve according to the invention can be used, are illustrated in the drawings. The invention will now be explained in greater detail with reference to these-drawings, in which





FIG. 1

shows the hydraulic circuit diagram, and





FIG. 2

shows a longitudinal section through the exemplary embodiment of a non-return valve according to the invention.











The circuit diagram of

FIG. 1

only shows an excerpt from the hydraulic part of an internal high-pressure forming system. The most important part of the hydraulics of a system of this type is a pressure intensifier


10


which contains, in a multi-part housing


11


, a differential piston


12


whose surface ratio determines the ratio of pressure intensification. The diameter of the differential piston


12


is substantially smaller at a secondary piston section


13


than at a primary piston section


14


. The latter divides an interior space of the housing


11


into an annular space


15


and a cylindrical space


16


. The two spaces are connected via working lines


17


and


18


to a proportionally adjustable directional control valve


19


which, in its central rest position, connect the two working lines, and therefore the annular space


15


and the cylindrical space


16


, to a tank via a tank connection T. In a first working position of the directional control valve


19


, the annular space


15


is connected to a hydraulic pump


20


via a pump connection P, while the cylindrical space


16


remains connected to the tank. In the other working position of the directional control valve


19


, the cylindrical space


16


is connected to the hydraulic pump and the annular space


15


is connected to the tank.




A displacement sensor


23


senses the position of the differential piston


12


with respect to the housing


11


.




The space


24


upstream of the end side of the secondary piston section


13


is connected, on the one hand, via a simple non-return valve


25


, which opens toward it, to a storage container


26


which contains a hydraulic fluid based on water. On the other hand, an unlockable non-return valve


30


according to the invention is connected to the pressure space


24


and pressure medium can readily flow out of the pressure space


24


through said non-return valve


30


to a line


31


which can be connected to the semi-finished product to be formed. The line


31


is also connected to the storage container


26


via a non-return valve


32


which opens toward it. During operation, the semi-finished product is filled with hydraulic fluid from the storage container


26


via the line


31


and the non-return valve


32


, it also being possible to arrange a pump between the storage container


26


and the non-return valve


32


, which pump brings about filling up to a certain pressure. The directional control valve


19


is then brought into its second working position, in which hydraulic oil is supplied by the pump


20


to the cylindrical space


16


of the pressure intensifier


10


. The differential piston


12


moves upward, as viewed in

FIG. 1

, and displaces hydraulic fluid from the pressure space


24


via the unlockable non-return valve


30


into the line


31


, so that the pressure in the semi-finished product to be deformed increases. Depending in each case on how large the volume of the semi-finished product, the increase in the volume due to the deformation and the level of the final pressure are, one or more strokes of the differential piston


12


are necessary. For a second stroke, the directional control valve


19


is brought into its first working position, so that the differential piston


12


travels downward and hydraulic fluid is sucked into the pressure space


24


from the storage container


26


via the non-return valve


25


. After the directional control valve


19


is switched over again, hydraulic fluid is pressed in turn out of the pressure space


24


into the line


31


via the non-return valve


30


.




After deformation and calibration of the workpiece are finished, the non-return valve


30


is unlocked, by applying a control pressure to a control channel


33


, so that the space within the workpiece and the line


31


can be decompressed by the differential piston


12


moving back.




The construction and the manner of operation of the non-return valve


30


emerge in greater detail from FIG.


2


. The exemplary embodiment shown there of a non-return valve according to the invention has a valve housing


35


through which a receiving bore


36


, whose axis may be referred to as the valve axis


37


, passes. The receiving bore


36


has the same diameter throughout, apart from two sections


38


at its two ends, which sections are provided with an internal thread, and apart from flat turned grooves


39


,


40


,


41


,


42


and


43


further to the inside, and, in the region of this constant diameter, may be machined from only one side of the valve housing


35


. A total of six parts are inserted clamped axially against one another into the receiving bore


36


. First of all, high-strength inserts


44


and


45


are screwed into the sections


38


of the receiving bore


36


, and each of said inserts has, on the valve axis


37


, a respective threaded bore


46


and


47


serving as the first and second orifices of the valve and to which a respective pressure line can be connected. The inserts


44


and


45


dip via the sections


38


into the region of constant diameter of the receiving bore


36


and are centered therein. The insert


45


has an inwardly open blind bore


48


which is connected via a relatively narrow channel


49


to the threaded bore


47


and which receives and guides a closing element


50


, which is loaded in the direction out of the blind bore


48


by a weak closing spring


51


.




The insert


45


is followed axially by a likewise high-strength insert


55


which is in the form of a washer and has a central passage


56


with two steps. Around the narrowest section of the central passage, the insert


55


serves as a seat for the closing element


51


. The insert


55


is followed by a washer


60


having a central passage


61


, then by a spacer bushing


62


whose inside diameter is substantially larger than the diameter of the central passage


61


in the washer


60


, then by a further washer


60


having a central passage


61


, which washer is identical to the former washer


60


but is fitted in the opposite direction thereto, and then by the insert


44


. Like the insert


45


, said insert


44


has an inwardly open blind bore


63


which, however, is less deep than the blind bore


48


and also has a smaller diameter. This diameter corresponds, except for slight differences, with the diameter of the central passages


61


in the washers


60


and with the diameter of the central section of the central passage in the insert


55


. The blind bore


63


is also connected to the threaded bore


46


via a channel


64


which is narrower in diameter.




A poppet piston


70


is accommodated in the interior of the inserts


55


,


60


and


44


and in the interior of the spacer bushing


62


and, with the aid of the poppet piston, the closing element


50


can be raised from its seat counter to the force of the closing spring


51


and counter to a force produced by the pressure in the second orifice


47


of the valve.




The poppet piston has a piston collar


71


which is situated within the spacer bushing


62


and divides the space surrounded by the washers


60


and the spacer bushing


62


into two annular spaces


72


and


73


. The annular space


72


can be acted upon by a control pressure or can be relieved from pressure via an external connection


75


and with the aid of a pilot valve (not illustrated in greater detail). The turn-out


40


of the valve housing


35


and an oblique bore


76


in the spacer bushing


62


lie in the flow path between the external connection


75


and the annular space


72


. The other annular space


73


is connected via a second external connection


77


to an oil container, for the purpose of equalizing the volume and for conducting away leaked fluid, and also accommodates a restoring spring


78


for the poppet piston


70


. In addition, a bushing


74


, by means of which the stroke of the poppet piston


70


is limited, is situated in the annular space


73


radially between the restoring spring and the spacer bushing


62


. Said poppet piston thus strikes against the washer


60


but not in the vicinity of its inside diameter where there would also be the risk of a deformation of material due to an annular groove


69


of the washer


60


, which groove is situated at a short distance from the end side facing the annular space


73


, and which accommodates a seal


68


.




On both sides of the piston collar


71


, the poppet piston has shaft-journal-like end sections


79


and


80


with which it dips through the central passages


61


of the washers


60


and into the blind bore


63


of the insert


44


and into the central passage


56


of the insert


55


. Toward the closing element


50


, the one end section


80


is extended by a finger


81


which can act upon the closing element


50


through the narrowest section of the central passage


56


of the insert


55


. In the rest position shown of the poppet piston


70


, there is a small distance between the finger


81


and the closing element


50


. The flow path between the orifices


46


and


47


of the valve leads axially through the poppet piston


70


which, for this purpose, has a long axial bore


82


, which opens into the blind bore


63


of the insert


44


, and a plurality of small oblique bores


83


at the base of the finger


81


.




A high-pressure seal


86


is accommodated in a turn-out


84


, which forms that section of the central passage


56


of the insert


55


which is the widest and open axially toward the one washer


60


, said seal being acted upon axially in the direction of the washer


60


by the high pressure prevailing in the passage


56


, but, of course, also acting radially toward the poppet piston


70


. In the present case, the high-pressure seal comprises a guide ring bearing against the poppet piston, a rubber-elastic O-ring lying in a groove of the guide ring, which groove is open radially outward, and a metallic, wedge-shaped ring bearing on the outside against a conically tapering surface on the guide ring. The seal


68


also acts radially in the annular groove


69


of the washer


60


. Identical seals


68


and


86


are located in a turn-out


84


of the insert


44


and in an annular groove


69


of the other washer


60


.




The high-pressure seals


86


are not pressed directly against the washers


60


by the high pressure. Rather, each washer


60


has a receiving element


87


which is open axially toward the insert


44


or


55


and radially toward the end section


79


or


80


of the poppet piston


70


and accommodates a supporting ring


88


which is made of the same material, which has good sliding properties, as the washers


60


, for example a copper beryllium alloy, and which is guided on the end section


79


or


80


with the narrow clearance of approximately {fraction (2/100)} mm. The high-pressure seal


86


bears against this supporting ring


88


. The outside diameter of the supporting ring


88


is only approximately 1.1 times as large as the outside diameter of the high-pressure seal


86


and the turnout


84


accommodating the latter, while the outside diameter of the washers


60


is more than 2.5 times as large. The diameter of the receiving element


87


is at least larger than the outside diameter of the supporting ring


88


by such an amount that said outside diameter is not loaded even when the diameter of the receiving element is reduced due to forces radially from the outside which act on the washer


60


. When a force is introduced by the high-pressure seal


86


onto the supporting ring


88


, this force in every case is passed to the washer


60


radially not further to the outside than at the outside diameter of the supporting ring, therefore virtually precisely opposite it. In the axial direction, the receiving element


87


and the supporting ring


88


are dimensioned in such a manner that the supporting ring has sufficiently great dimensional stability even at the maximum possible radial offset of the force transmission point between it, the high-pressure seal and the washer


60


. In the present case, the supporting ring extends for this purpose axially approximately over ⅕ of the axial length of the washers


60


. It could also be longer, but then more chip-forming machining of the washers


60


would be necessary.




The inside diameter of the washers


60


is, in the section


90


between their end side facing the annular space


72


or


73


and the annular groove


69


, i.e. just over a short section from the end side, is only slightly larger than the diameter of an end section


79


,


80


of the poppet piston. In the section


90


of a washer


60


, an end section


79


,


80


of the poppet piston


70


is guided with a radial clearance of {fraction (1/100)} mm to {fraction (2/100)} mm. Between the annular groove


69


and the receiving element


87


there is, between a washer


60


and an end section


79


,


80


, a larger radial gap with a width in the region of {fraction (2/10)} mm. This gap, which is shown greatly enlarged in

FIG. 2

for the sake of clarity, is of a sufficient size so as to avoid, when a washer


60


is deformed during the operation by the force exerted on it by a high-pressure seal


86


via a supporting ring


88


, a fixed positioning of the washer on an end section


79


,


80


of the poppet piston


70


and therefore jamming of the latter.




In the valve which is shown, the separating gaps between the one washer


60


and the insert


44


, between the other washer


60


and the insert


55


and between the insert


55


and the insert


45


, and the radial gap, located axially between the seal


69


and a supporting ring


88


, between a washer


60


and an end section


79


,


80


of the poppet piston


70


are relieved from pressure. For the pressure relief between the two inserts


55


and


45


, that end side of the insert


55


which faces the insert


45


is formed such that it is slightly conically toward the outside at a distance from the valve axis


37


, with the result that, on the one hand, for radial sealing, the inserts


45


and


55


can bear tightly against each other a good distance inward, and, on the other hand, an annular space is provided which increases in its axial extent radially toward the outside and from which leaked fluid is conducted away via a housing bore.




For pressure relief between the washers


60


and the inserts


44


and


45


, a plurality of radial bores


93


pass through each washer


60


, said radial bores opening on the inside into a receiving element


87


and being open on the outside toward a turned groove


39


or


42


. In that end side of a supporting ring


88


which faces a washer


60


are situated two or more tracks


94


which run from the inside to the outside and via which the radial gap between a washer


60


and the end section


79


,


80


of the poppet piston


70


is connected to the radial gap between a supporting ring


88


and a washer


60


. The pressure medium passing, owing to leakage, into the turned grooves


39


and


42


is conducted away through housing bores


95


. The washers


60


are therefore never exposed to the maximum pressure which is possible in the orifices


46


and


47


of the valve and, as regards the selection of material, can be matched entirely to their function as guides for the poppet piston


70


. They are primarily produced from a copper beryllium alloy. In contrast, the inserts


44


,


45


and


55


are loaded during operation by the maximum pressure and are therefore produced from a high-strength material. The fit between the end sections


79


and


80


of the poppet piston and the inserts


44


and


55


is selected in such a manner that the guiding of the poppet piston


70


takes place in the washers


60


.




The seals in the washer


60


between the spacer bushing


62


and the insert


55


seal off spaces from one another in which essentially the same pressure prevails. Their function essentially involves separating different hydraulic fluids from one another. This is because the annular space


73


is conventionally filled with oil while the pressure medium used for the high-pressure forming is water.




When the unlockable non-return valve, which is shown in

FIG. 2

, is used in the hydraulic circuit according to

FIG. 1

, the first orifice


46


is connected to the pressure space


24


of the pressure intensifier


10


and the second orifice


47


is connected to the line


31


. If the pressure intensifier displaces water out of the pressure space


24


, said water flows to the second orifice


47


via the channels


64


,


82


,


83


,


56


, via the closing element


50


which is raised from its seat, and via the channel


49


in the insert


45


. For the already mentioned decompression of the liquid forming means, the annular space


72


is acted upon via the external connection


75


with control pressure, so that the poppet piston


70


moves toward the closing element


50


and raises the latter from its seat. The raising takes place counter to the force of the restoring spring


78


and counter to a compressive force which is caused by a possible pressure difference between the orifices


45


and


46


and by different engagement surfaces on the closing element


50


for the pressures in the orifices


45


and


46


, and counter to the negligibly small force of the closing spring


51


. The compressive force can indeed be brought virtually to zero at the beginning by a pressure-controlled movement of the differential piston


12


. However, during the decompression which then follows, a quantity of hydraulic fluid, the amount of which depends on the desired speed at which said decompression takes place, has to flow out of the line


31


via the valve


30


into the pressure space


24


, as a result of which a pressure difference occurs via the closing element


50


. The closing element has to be held open by the poppet piston


70


counter to this pressure difference. Owing to the large diameter of the piston collar


71


, this is achieved by control pressures which can conventionally be built up nowadays by hydraulic pumps.



Claims
  • 1. An unlockable non-return valve for very high system pressures having a valve housing (35) with a continuous receiving bore (36) located on a valve axis (37), having a closing element (50) which is prestressed in closing direction by a closing spring (51) and moveable in direction of the valve axis (37), having a poppet piston (70) which is actable upon at a piston collar (71) by a control pressure in order to unlock the closing element (50) and, on both sides of the piston collar (71), is guided on end sections (79, 80) of at least approximately identical diameters in the direction of the valve axis (37), and having two inserts (44, 60, 55, 60), which are placed into the receiving bore (36), on each side of the piston collar (71), into which the poppet piston (70) dips with an end section (79, 80), the end section (79, 80) being guided in an insert (60) which is close to the piston collar (71) and is made from a metallic material having good sliding properties, and a second insert (44, 55) following the first insert (60) has, in a turn-out (84) which is open radially toward the end section (79, 80) and axially toward the first insert (60), a high-pressure seal (86) which bears radially against the end section (79, 80) of the poppet piston (70) and is supported axially by the first inset (60), wherein the first insert (60) has a guide diameter for the end section (79, 80) of the poppet piston (70) over just a short section of its end side facing the piston collar (71), and by the fact that a supporting ring (88) is arranged axially between the high-pressure seal (86) and the first insert (60) in a receiving element (87) which is formed between the two inserts (44, 60, 55, 60) and is open radially toward the end section (79, 80) of the poppet piston (70) and diameter of which is substantially smaller than the outside diameter of the inserts (44, 60, 55, 60), said supporting ring (88) likewise being made of a metallic material having good sliding properties and being produced with a narrow clearance from the end section (79, 80) of the poppet piston (70) and with a large radial clearance from the receiving element (87).
  • 2. The unlockable non-return valve as claimed in claim 1, wherein the first insert (60) has, in front of its section (72) with the guide diameter, a clearance of at least {fraction (1/10)} mm, radially with respect to the end section (79, 80) of the poppet piston (70).
  • 3. The unlockable non-return valve as claimed in claim 1, wherein the first insert (60) has, in front of its section (72) with a guide diameter, a clearance of at least {fraction (2/10)} mm, radially with respect to the end section (79, 80) of the poppet piston (70).
  • 4. The unlockable non-return valve as claimed in claim 1, wherein the outside diameter of the supporting ring (88) is approximately 1.1 times as large as the diameter of a turn-out for the high-pressure seal (86).
  • 5. The unlockable non-return valve as claimed in claim 1, wherein the radial clearance between the supporting ring (88) and the end section (79, 80) of the poppet piston (70) lies in a range of {fraction (1/100)} mm to {fraction (2/100)} mm.
  • 6. The unlockable non-return valve as claimed in claim 1, wherein the receiving element (87) for the supporting ring (88) is situated entirely in the first insert (60).
  • 7. The unlockable non-return valve as claimed in claim 1, wherein axial extent of the supporting ring (88) is approximately ⅕ of axial extent of the first insert (60).
  • 8. The unlockable non-return valve as claimed in claim 1, wherein in at least one of axial surfaces, which bear against each other, of the first insert (60) and supporting ring (88) is situated at least one track (94) extending from inside diameter of the surface as far as outside diameter of the supporting ring (88), and wherein a leakage duct (93, 39, 42, 95) leads to outside from a gap on the outside diameter of the supporting ring (88).
Priority Claims (1)
Number Date Country Kind
100 42 716 Aug 2000 DE
PCT Information
Filing Document Filing Date Country Kind
PCT/EP01/04806 WO 00
Publishing Document Publishing Date Country Kind
WO02/18799 3/7/2002 WO A
US Referenced Citations (4)
Number Name Date Kind
3631887 Schlechtriem et al. Jan 1972 A
3631888 Anton et al. Jan 1972 A
4562862 Mucheyer et al. Jan 1986 A
4624445 Putnam Nov 1986 A
Foreign Referenced Citations (4)
Number Date Country
3904978 Aug 1990 DE
19714505 Oct 1998 DE
19856018 Jun 2000 DE
0687843 Dec 1995 EP