Patent Grant
9857293
During counterinsurgency operations, improvised explosive devices (IEDs) pose a great threat to conventional ground forces. IEDs have been based on a wide variety of explosive materials, including military explosives and propellants, agricultural materials (e.g. ammonium nitrate), industrial explosives, and a non-standard exotic chemical explosives (e.g. potassium chlorate or organic peroxides). Counterinsurgency strategy involves the determination of materials transfer points and IED manufacturing locations. Thus, there is a strong demand for explosives detection and identification. A simple, rapid and reliable method in the field would be a significant enabler of military operations.
Current technology deployed in the field for detection and identification of explosives has a number of limitations. Deployable lab systems using liquid chromatography and mass spectrometry for chemical identification are not acceptable for time-sensitive missions and require logistic support. In addition, hand held systems for chemical identification including IR spectroscopy (TruDefender) and Raman spectroscopy (FirstDefender) need bulk samples that are frequently not available. Other developing technologies include detection of volatile organic compounds (VOCs), often referred to as electronic nose or tongue technology. These comprise colorimetric and fluorescent arrays (see refs. 1-3), modified field effect transistors (see refs. 4,5), and modified quartz resonators (see ref. 6). The use of fluorescent semiconductor polymers for explosives detectors may detect common military-grade compounds used in homemade explosives and IEDs, including pentaerythritol tetranitrate (PETN). However, all these instruments require manual collection or analysis by persons directly at the suspect sites.
Remote sensing technology capable of detecting explosives at an appreciable distance, although highly desirable, has not been perfected despite considerable research. For example laser systems for standoff detection including hyperspectral imaging are of low sensitivity in soils, in that the target may be less than one pixel and signature may not be distinguishable from background.
A need exists for a simple and inexpensive method for detecting explosives, particularly using remote sensing.
One embodiment is a system for detecting including an unmanned aerial vehicle platform operably connected to a testing rig, the testing rig comprising filter paper, a deep eutectic solvent consisting of a mixture of ethylene glycol and choline chloride, and a testing device configured to perform voltammetry and/or spectroscopy on the filter sampler following contact of the filter paper with a surface or a soil. The detection may be completed on board the UAV (with results communicated, e.g., via radio), or the UAV may capture a sample on filter paper in one location for analysis at a second location.
Before describing the present invention in detail, it is to be understood that the terminology used in the specification is for the purpose of describing particular embodiments, and is not necessarily intended to be limiting. Although many methods, structures and materials similar, modified, or equivalent to those described herein can be used in the practice of the present invention without undue experimentation, the preferred methods, structures and materials are described herein. In describing and claiming the present invention, the following terminology will be used in accordance with the definitions set out below.
As used in this specification and the appended claims, the singular forms “a”, “an,” and “the” do not preclude plural referents, unless the content clearly dictates otherwise.
As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.
As used herein, the term “about” when used in conjunction with a stated numerical value or range denotes somewhat more or somewhat less than the stated value or range, to within a range of ±10% of that stated.
Overview
Described herein is an approach using inexpensive, disposable chemical sensor probes that can be mounted on a small unmanned aerial vehicles (UAVs) and used to analyze a site (such as one known or suspected to contain spilled material or contaminated soil) without the need for a person to conduct ground operations at the site. Possible applications include the enabling of autonomous systems to carry out the remote electrochemical detection of chemicals of importance to military missions, particularly detecting explosives. While explosives detection is the main intent of this technology, this sampling system would also be useful for detection of other chemicals, such as illicit drugs, nerve agents, other chemicals of interest such as toxic industrial compounds (TICs), biologicals, and other electrochemically active analytes of interest.
It is possible to integrate sample collection, processing and analysis of samples taken from complex soil and on surfaces with contaminating interferrents. A combination of electrodes (optionally modified electrodes) with filter paper (preferably a paper based on cellulose) absorptive coupon infiltrated with a suitable solvent can used for the extraction and electrochemical detection of explosives and explosive components in soils, as well as other possible analytes. The electrodes are typically metal or carbon and may be discrete parts in physical contact with the filter paper or optionally in the form of metal or carbon impregnated into the filter paper fibers.
In the case of a preferred solvent mixture of ethylene glycol and choline chloride, also known as ethanal, the ethylene glycol can extract nitro-aromatic, nitrates or other explosives from soils, and the choline chloride provides for the electrolyte for the detection of analytes via electrochemistry using modified electrodes.
Suitable Solvents and Analysis
In a preferred embodiment, the solvent is a deep eutectic solvent, for example a deep eutectic mixture of ethylene glycol and choline chloride such as can be obtained from a 2:1 mol ratio of ethylene glycol and choline chloride. Other suitable solvents include room temperature ionic liquids (RTILs, which are salts that are liquid at room temperature, not to be confused with salts dissolved in another liquid), and high-boiling (thus having a low evaporation rate) polar aprotic or protic solvents such as dimethyl sulfoxide (DMSO) or dimethylformamide (DMF). A low rate of evaporation is desirable as it allows time for the analysis to be performed without requiring a sealed chamber or the like to reduce evaporation.
Preferably, the solvents are able to dissolve and extract nitro-aromatic, nitrates, and/or other explosives from soils across abroad temperature range without significant evaporation, and in combination with dry filter paper permits capillary movement of the solubilized analytes to allow for the detection of the analytes via electrochemistry.
In on embodiment, the solvent has a boiling point of 100° C. or greater, measured at a pressure of one atmosphere. Further embodiments may feature solvents boiling at about, e.g., 110° C. or greater, 120° C. or greater, 130° C. or greater, 140° C. or greater, or 150° C. or greater. For example, DMF boils at 153° C. while DMSO boils at 189° C.
In a preferred embodiment, the paper is analyzed by electrochemical analysis, such as voltammetry including cyclic, square wave, and/or linear sweep voltammetry. Voltammetry can be conducting using one or more types of electrodes. Optionally such electrodes may be modified, for example by electroplating to obtain, e.g., a copper-modified carbon electrode. The electrodes may optionally be cleaned, polished, and/or electrochemically activated, and/or otherwise treated as known in the art. Exemplary electrodes include glassy carbon electrodes and/or screen printed electrode as well as other types known the in art such as electrodes of graphite, graphene, and/or graphene oxides. An analyte of interest may be detected by a variation in the current measured the working electrode and the counter electrode at a specific potential measured relative to a reference electrode as compared to either an expected current (for example, one stored in memory of a device), or current measured in a control sample.
Common military-grade explosives give distinctive electrochemical signatures at carbon electrodes, while Cu and Mo/W modified electrodes can detect nitrates (as in ref. 8) and chlorates (as in ref. 9). Techniques for electroanalysis described in refs. 7-10 and variants thereof may be employed, as apparent to one skilled in the art. Variations in electrochemical signature (e.g., current in analysis by voltammetry) can indicate the a degree of presence (or lack thereof) of one or more analytes. In embodiments, the variations may be detected automatically.
It is also possible to use the filter paper to obtain samples for spectroscopic analysis, as it is believed this use of the paper would remove interferrents and possible increase detection limits. Exemplary forms of spectroscopic analysis include the use of a Fourier transform infrared (FTIR) spectrophotometer (e.g., the TruDefender™), Raman spectroscopy (used by the FirstDefender™), and other related techniques such as those involving a polymer which changes optical properties on contact with an analyte.
To analyze sample soils containing nitrates at various percentages, filter paper saturated with solvent/electrolyte is mounted on a flexible holder. The paper is then pressed on to the surface of the soil manually or by a robot. The flexible holder conforms to the shape of the surface, evenly sampling the soil onto the filter paper as shown in
One surprising and unexpected aspect emerged from this testing: the soil did not foul the copper-modified screen printed electrodes. The sensitivity of the response for the detection of nitrates varied with the different soil types in which sand gives the largest response and clay the smallest.
Another example is illustrated in
Unmanned Aerial Vehicle
This method is amenable to being carried out through the use of an unmanned aerial vehicle (UAV). Suitable UAVs may be directed in real time by an operator and/or operate autonomously. They may optionally include one or more still and/or video cameras and may take the form of a rotorcraft having one or more rotors, a fixed wing aircraft, or other forms of aerial vehicle.
Experiments demonstrated use of a UAV to remotely sample soil for electrochemical detection. A sampler was amounted on an UAV and was used to sample spilled nitrates in soil at a remote target. The samples were retrieved and rapidly analyzed at a copper-modified screen printed electrode. The detection of nitrate was clearly demonstrated as shown in
In embodiments, solvent is applied after filter paper contacts a surface to be analyzed. This may include injection of a solvent aliquot into a contacted and/or collected sample to solubilze/extract one or more analytes of interest, followed by contact of the filter paper to the sample wetted with solvent to initiate analyte transport from the smaple onto the filter paper to the electrode.
In embodiments, a test rig is attached to an unmanned aerial vehicle platform. The test rig includes filter paper, suitable solvent, and optionally a testing device. The filter paper may be pre-wetted with the solvent or the test rig could include a mechanism for wetting the filter paper (for example, a solvent reservoir and a pump). The testing device is operable to conduct analysis as described herein, either by voltammetry or spectroscopy or both.
The detection may be completed on board the UAV (with automated analysis followed by results communicated, e.g., via radio), or the UAV may capture a sample on filter paper in one location for analysis at a second location.
Advantages
Because of the viscous nature of ethylene glycol, it is a non-obvious choice for an electrochemical solvent since analytes would have a smaller diffusion coefficient attenuating the signal. However because of this property, the filter paper saturated with the ethylene glycol is able to capture and retrieve soil samples directly using a UAV.
Ethylene glycol/choline chloride is very slow to evaporate and acts as both an electrolyte with large potential window for electrochemical detection and as a solvent to extract nitro-aromatic compounds and other explosive components from soil.
Using this technique with filter paper, the electrodes do not foul in the presence of soil and are able to respond to the desired analyte. This is counter-intuitive and non-obvious since it was expected that the soils would block and foul the electrodes.
The detection of TNT or nitrate is accomplished in air saturated solvents demonstrating that the reduction of oxygen does not interfere with the measurement, eliminating the need to purge the system with argon or nitrogen (a common practice in electroanalytical bench top experiments) which would complicate field work.
For trace level detection, the wicking property of the filter paper is able to remove electrochemically active interferences which are most likely natural organic matter containing quinone and catechol chemical moieties. Impurities stick to the paper away from the electrodes, while the explosives remain soluble in the liquid and can reach the electrode for detection.
The paper surface can optionally be selected and/or modified to bind impurities having specific functional groups not the same as those of the explosives to remove those impurities from the sample before electrochemistry.
For other explosives of interest including chlorates and peroxides, the electrodes can be modified with catalysts to detect chlorates and indirect electrochemical schemes can be incorporation in the chemistry of the filter paper for the detection of peroxide.
Concluding Remarks
All documents mentioned herein are hereby incorporated by reference for the purpose of disclosing and describing the particular materials and methodologies for which the document was cited.
Although the present invention has been described in connection with preferred embodiments thereof, it will be appreciated by those skilled in the art that additions, deletions, modifications, and substitutions not specifically described may be made without departing from the spirit and scope of the invention. Terminology used herein should not be construed as being “means-plus-function” language unless the term “means” is expressly used in association therewith.
| Number | Name | Date | Kind |
|---|---|---|---|
| 20090029480 | Loane | Jan 2009 | A1 |
| 20150126834 | Wang | May 2015 | A1 |
| Number | Date | Country | |
|---|---|---|---|
| 20170074825 A1 | Mar 2017 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 14469895 | Aug 2014 | US |
| Child | 15356021 | US |
