Claims
- 1. Unsymmetrical diperoxides of the structure ##STR8## where R.sub.1 is a substituted or unsubstituted cyclohexylene or cyclohexenylene diradical, R.sub.2 is an alkylene diradical of 7 to 11 carbons, alkenylene diradical of 9 to 11 carbons or an alkadienylene diradical of 11 carbons, R.sub.3 and R.sub.4 can be the same or different and are substituted or unsubstituted acyl radicals of 1 to 18 carbon atoms, alkenoyl radicals of 3 to 11 carbons, alkadienoyl radicals of 6 carbons, hydrocarbon-aroyl radicals of 7 to 11 carbons, alkoxycarbonyl radicals of 2 to 19 carbons and cycloalkoxycarbonyl radicals of 6 to 13 carbons wherein substituents for R.sub.1 are selected from one or more alkyl radicals of 1 to 6 carbons, alkenyl radicals of 4 to 6 carbons, alkadienyl radicals of 6 carbons, --C(O)OOR.sub.3, --C(O)OOR.sub.4 and carboxy, and the substituents for R.sub.3 and R.sub.4 are selected from lower alkyl.
- 2. A di(diacyl peroxide) and a di(diacyl peroxide) mixture according to claim 1 wherein said acyl group is lauroyl.
- 3. A di(diacyl peroxide) and a di(diacyl peroxide) mixture according to claim 1 wherein said acyl group is acetyl.
- 4. A di(diacyl peroxide) according to claim 1 which selected from 4-(acylperoxycarbonyl)-3-hexyl-6-(7-acylperoxycarbonylheptyl)cyclohexene, 5-(acylperoxycarbonyl)-3-hexyl-6(7-acylperoxycarbonylheptyl)cyclohexene, 4-(acylperoxycarbonyl)-3-pentyl-6-(8-acylperoxycarbonyloctyl)cyclohexene and 5-(acylperoxycarbonyl)-3-pentyl-6-(8-acylperoxycarbonyloctyl)cyclohexene and mixtures thereof.
- 5. A di(diacyl peroxide) according to claim 1 which selected from 4-(aroylperoxycarbonyl)-3-hexyl-6-(7-aroylperoxycarbonylheptyl)cyclohexene, 5-(aroylperoxycarbonyl)-3-hexyl-6-7-aroylperoxycarbonylheptyl)cyclohexene, 4-(aroylperoxycarbonyl)-3-pentyl-6-(8-aroylperoxycarbonyloctyl)cyclohexene and 5-(aroylperoxycarbonyl)-3-pentyl-6-(8-aroylperoxycarbonyloctyl)cyclohexene and mixtures thereof.
Parent Case Info
This is a division of application Ser. No. 757,185, filed Jan. 6, 1977, now U.S. Pat. No. 4,079,074.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
3706818 |
Mageli et al. |
Dec 1972 |
|
4079074 |
Sanchez et al. |
Mar 1978 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
43-18527 |
Aug 1968 |
JPX |
Non-Patent Literature Citations (1)
Entry |
Sosnovsky, et al., J. Organic Chem., vol. 25, pp. 899-903 (1960). |
Divisions (1)
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Number |
Date |
Country |
Parent |
757185 |
Jan 1977 |
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