Claims
- 1. A method of using 9-anthrylalkyl compounds having the general formula ##STR4## wherein R is hydrogen or an alkyl group, whereby, however, not more than one of the groups R is an alkyl group; R.sub.1 is hydrogen, lower alkyl, halogen or nitro; n is an integer of from 1 to 7, whereby, however, the total number of carbon atoms in the group --CHR--(CHR).sub.n -- does not exceed 8; and X is halogen, an azide group or a succinimidyl group, as derivatization reagents for separation and detection purposes, wherein the compounds are reacted with compounds containing primary and/or secondary and/or tertiary amino groups for formation of carbamates which can be detected or with compounds containing hydroxyl groups for formation of carbonates which can be detected.
- 2. The method of claim 1, wherein the total number of carbon atoms in the group --CHR--(CHR).sub.n does not exceed 4.
- 3. The method according to claim 1, wherein when R is an alkyl group it is positioned on the .beta.-carbon atom, counted from the anthryl nucleus.
- 4. The method according to claim 1, wherein the total number of carbon atoms in the group --CHR--(CHR).sub.n does not exceed 3.
- 5. The method according to claim 1, wherein X is chlorine.
- 6. The method according to claim 1, wherein the 9-anthrylalkyl compound is 2-(9-anthryl)ethyl chloroformate or 1-(9-anthryl)-2-propyl chloroformate.
- 7. The method according to claim 6, wherein the 9-anthryl compound is (-)-1-(9-anthryl)-2-propyl chloroformate or (+)-1-(9-anthryl)-2-propyl chloroformate.
Priority Claims (1)
Number |
Date |
Country |
Kind |
8802932 |
Aug 1988 |
SEX |
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Parent Case Info
This application is a divisional, of application Ser. No. 391,957, filed Aug. 10, 1989, now U.S. Pat. No. 5,015,755.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
3324148 |
Cotter |
Jun 1967 |
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Foreign Referenced Citations (1)
Number |
Date |
Country |
WO8706929 |
Nov 1987 |
WOX |
Non-Patent Literature Citations (4)
Entry |
Journal of Chromatography, "Determination of Amino Acids with 9-Fluorenylmethyl Chloroformate and Reversed-Phase High-Performance Liquid Chromatograph", 282 (1983), pp. 609-618. |
Journal of Organic Chemistry, "Synthesis and Photochemical Isomerization of 1,2-Di-9-anthrylethanol and 1,2-Di-9-anthrylethanone", (1986), pp. 2956-2961. |
Journal of Organic Chemistry, vol. 42, No. 2, (1977), pp. 399-400. |
Beilstein E III, vol. 6 (1967), p. 3573. |
Divisions (1)
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Number |
Date |
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Parent |
391957 |
Aug 1989 |
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