Patent Application
20080283409
This invention relates to methods for improving the conductivity of intrinsically conductive organic polymers and capacitors prepared by using such methods which exhibit reduced equivalent series resistance (ESR) and robust performance during the surface mounting process of the capacitor to a circuit board. More specifically, the invention relates to a method of forming a capacitor wherein a conductive polymer is formed by a combination of monomers, and conjugated oligomers with no more than five repeating units.
Electrolytic capacitors having valve metal anodes impregnated with a highly conductive liquid electrolyte such as an aqueous solution of sulfuric acid have been in commercial use for many years. There are many liquid electrolyte solutions which have been used in electrolytic capacitors. The liquid electrolytes conduct current by an ionic conduction mechanism and tend to have high resistance. Haring et. al., in U.S. Pat. No. 3,093,883, disclosed the use of pyrolytic manganese dioxide produced via the pyrolysis of aqueous manganese nitrate solutions as the cathode material. Manganese dioxide as a solid state conductor with lower resistivity (1-3 orders of magnitude lower than liquid electrolyte solutions) substantially reduced the resistance of the cathode layer and overall resistance of these devices.
With the continuing development of ever-faster microprocessors and lower-voltage logic circuits, the demand for lower ESR capacitors for use in conjunction with faster microprocessors has motivated capacitor manufacturers to develop solid state cathode materials which are more conductive, less electrically resistive, than manganese dioxide.
In the early 1980's, electrolytic capacitors were introduced which were fabricated having a tetracyanoquinodimethane amine complex acting as the cathode. These capacitors established the stability and high conductivity achievable with solid-state organic cathode materials. The ongoing effort to increase the maximum temperature capability of organic cathode electrolytic capacitors has led to the development of methods of capacitor fabrication employing intrinsically conductive organic polymers, such as polypyrrole, polythiophenes, polyanilines and their derivatives. Numerous substituted monomers, or derivatives, are useful as are mixtures of two or more monomers from different types, i.e., mixtures. High electric conductivity, good thermal stability and benign failure mode led to the widespread use of these intrinsically conductive organic polymers in solid electrolytic capacitors since the 1990s.
Both chemical and electrochemical polymerization has been used to form intrinsically conductive polymers for electrolytic capacitors. Chemical polymerization is well described in U.S. Pat. No. 4,910,645, to Jonas et. al., U.S. Pat. No. 6,136,176 to D. Wheeler, et. al. and U.S. Pat. No. 6,334,966 to Hahn et al. The process consists of immersing the anodized substrate first in a solution of an oxidizing agent such as, but not necessarily limited to, iron (III) p-toluenesulfonate. After a drying step the anode bodies are then immersed in a solution of the monomer. Once the solution of monomer, which may consist entirely of monomer, is introduced into the capacitor anode bodies, the anodes are allowed to stand to facilitate production of the intrinsically conductive polymer material. Repeated dipping sequences may be employed to more completely fill the pore structure of the anode bodies. In practice, rinsing cycles are generally employed to remove reaction by-products, such as ammonium sulfate, sulfuric acid, iron salts (when an iron (I) oxidizer is employed), or other by-products depending on the system employed. Chemical production of intrinsically conductive organic polymers may also be carried-out with capacitor anode bodies by first introducing the monomer to the capacitor bodies, followed by introduction of the oxidizer and dopant (the reverse order of polymer precursor introduction described above). It is also possible to mix the dopant acid(s) with the monomer solution rather than with the oxidizer solution if this is found to be advantageous. U.S. Pat. Nos. 6,001,281 and No. 6,056,899 describe a chemical means of producing an intrinsically conductive organic polymer through the use of a single solution which contains both the monomer and the oxidizing agent, which has been rendered temporarily inactive via complexing with a high vapor pressure solvent. As the solution is warmed and the inhibiting solvent evaporates, the oxidative production of conductive polymers ensues. The dopant acid anion is also contained in the stabilized poly-precursor solution.
The demand for capacitors exhibiting lower equivalent series resistance (ESR) and dissipation factor, which has led to the development of electrolytic capacitors based on conductive polymer cathode materials, has been accompanied by a demand for capacitors exhibiting higher reliability, particularly a lower incidence of high leakage current/short circuit failures.
Intrinsically conductive organic polymers generally contain one dopant anion for each 3 to 4 monomer units which have been joined to form the polymer. The presence of a strong dopant acid anion is thought to result in a delocalization of electric charge on the conjugated molecular chain and therefore provides electrical conductivity. In the case of ferric salt being used as the oxidizer, the presence of an acid also keeps the Fe3+ ions from precipitating out of the solution. In the sequential dipping process the acid could accumulate in the monomer solution. It is known that an acid can promote the formation of non-conjugated dimers and trimers through acid catalyzed reaction. U.S. Pat. No. 6,891,016 to Rueter et al. disclosed the formation of non-conjugated ethylenedioxythiophene (EDT) dimer, structure (I), and trimer, structure (II), in the presence of an acid catalyst.
These non-conjugated dimers and trimers can result in a decrease in conjugation length which deteriorates conductivity of the polymer. This would cause an increase in ESR of conductive polymer based solid electrolytic capacitors. In U.S. patent application (docket number 31433-117 filed Apr. 16, 2007) procedures to control the acid content in the monomer solution are disclosed. Although the conductivity of polymer made according to U.S. patent application (docket number 31433-117 filed Apr. 16, 2007) was maintained high, the growth rate of the conductive polymer could be decreased. More production cycles may be required to provide adequate polymer coverage.
There has been an ongoing, and increasing, desire to provide a conductive polymer layer with improved conductivity. There has also been a desire to provide a capacitor, comprising the conductive polymer, with an improved ESR and reliability.
It is an object of the present invention to provide an improved polymer coating as indicated by a reduced resistance.
It is another object of the present invention to provide an improved capacitor wherein the capacitor has a lower ESR due to a lower resistance in the polymeric cathode layer.
A particular advantage of the present invention is the ability to implement the improvement with minimal alterations to existing manufacturing facilities or processes.
These and other advantages, as will be understood, are provided in a process for forming a capacitor. The process includes providing an anode; providing a dielectric on the anode such as by anodizing the anode; exposing, such as by dipping, the anode into a polymer precursor solution comprising monomers, conjugated oligomers and optionally solvents and polymerizing the polymer precursor. The ratio of monomers to conjugated oligomers ranges from 99.9/0.1 to 75/25 by weight, the solvent content of the solution of polymer precursor is from 0 to 99% by weight.
A preferred embodiment is provided in a capacitor formed by the process of: providing an anode; forming a dielectric on the anode; exposing the anodized anode into a polymer precursor solution comprising monomer, conjugated oligomer and optionally solvent and polymerizing the polymer precursor. The ratio between monomers and conjugated oligomers ranges from 99.9/0.1 to 90/10 by weight, the solvent content in the solution of precursors is preferably from 10-90% by weight.
A particularly preferred embodiment is provided in a process for forming a capacitor comprising: providing an anode comprising a material selected from niobium, aluminum, tantalum, titanium, zirconium, hafnium, tungsten and NbO; forming a dielectric on the anode to form an anodized anode; dipping the anodized anode into a polymer precursor solution comprising monomer, conjugated oligomers and optionally solvents to form a polymer precursor coating and polymerizing the polymer precursor coating. The ratio of monomers to conjugated oligomers ranges from 99.9/0.1 to 75/25 by weight and the solvent content in the solution of precursor is from 0 to 99% by weight with the monomer defined as:
and the conjugated oligomer is defined as:
where n=0 to 3.
a and 2b provide Fourier transform infrared (FT-IR) spectra of conjugated and nonconjugated EDT dimmers, respectively.
a and 3b provide proton nuclear magnetic resonance (1H NMR) spectra of conjugated and nonconjugated EDT dimmers, respectively.
An improvement in a conductive polymer, and capacitor formed with the conductive polymer, is achieved by adding conjugated oligomer, preferably conjugated dimer or conjugated trimer, to the monomer solution. The addition of conjugated oligomer provides adequate polymer growth rate for good polymer coverage of the dielectric surface of the anode.
The invention will be described with reference to the
In
The anode is a conductive material preferably comprising a valve-metal preferably selected from niobium, aluminum, tantalum, titanium, zirconium, hafnium, or tungsten or a conductive oxide such as NbO. Aluminum, tantalum, niobium and NbO are most preferred as the anode material. Aluminum is typically employed as a foil while tantalum, niobium and NbO are typically prepared by pressing a powder and sintering to form a compact. For convenience in handling, the anode is typically attached to a carrier thereby allowing large numbers of elements to be processed at the same time.
The anode in the form of a foil is preferably etched to increase the surface area. Etching is preferably done by immersing the anode into at least one etching bath. Various etching baths are taught in the art and the method used for etching the valve metal is not limiting herein.
A dielectric is formed on the anode. In a preferred embodiment the surface of the anode is coated with a dielectric layer comprising an oxide. It is most desirable that the dielectric layer be an oxide of the anode material. The oxide is preferably formed by dipping the anode into an electrolyte solution and applying a positive voltage. The process of forming the dielectric layer oxide is well known to those skilled in the art. Other methods of forming the dielectric layer may be utilized such as vapour deposition, sol-gel deposition, solvent deposition or the like. The dielectric layer may be an oxide of the anode material formed by oxidizing the surface of the anode or the dielectric layer may be a material which is different from the anode material and deposited on the anode by any method suitable therefore.
The polymer precursors are polymerized to form the conductive layer which functions as the cathode of the capacitor. The polymer precursors are preferably polymerized by either electrochemical or chemical polymerization techniques with oxidative chemical polymerization being most preferred. In one embodiment the conductive layer is formed by dipping the anodized substrate first in a solution of an oxidizing agent such as, but not necessarily limited to iron (III) p-toluenesulfonate. After a drying step, the anode bodies are then immersed in a solution comprising monomer and oligomer of the conductive polymer and solvents.
The present invention utilizes a polymer precursor comprising a monomer and conjugated oligomer. The monomer preferably represents 75-99.9 wt % of the polymer precursors and the conjugated oligomer represents 0.1-25 wt % of the polymer precursors. More preferably the monomer represents 90-99.9 wt % of the polymer precursors and the conjugated oligomer represents 0.1-10 wt % of the polymer precursors. Even more preferably the monomer represents 95-99.5 wt % of the polymer precursors and the conjugated oligomer represents 0.5-5 wt % of the polymer precursors. The preferred monomer is a compound of Formula I and the preferred oligomer is a compound of Formula II.
The conducting polymer is preferably the polymer comprising repeating units of a monomer and oligomer of Formula I and Formula II:
R1 and R2 of Formula I and R4-R9 of Formula II are chosen to prohibit polymerization at the β-site of the ring. It is most preferred that only α-site polymerization be allowed to proceed. Therefore, it is preferred that R1 and R2 are not hydrogen. More preferably R1, R2, R4, R5, R6, R7, R1 and R9 are α-directors. Therefore, ether linkages are preferable over alkyl linkages. It is most preferred that the groups are small to avoid steric interferences. For these reasons R1 and R2, R4 and R5, R6 and R7 or R8 and R9 taken together as —O—(CH2)2—O— are most preferred.
In Formula II n is an integer selected from 0-3.
In Formulas I and II, X and Y independently are S, Se or N. Most preferably X and Y are S.
R1, R2, R4, R5, R6, R7, R8 and R9 independently represent linear or branched C1-C16 alkyl or C1-C18 alkoxyalkyl; or are C3-C8 cycloalkyl, phenyl or benzyl which are unsubstituted or substituted by C1-C6 alkyl, C1-C6 alkoxy, halogen or OR3; or R1 and R2, R4 and R5, R6 and R7 or R8 and R9, taken together, are linear C1-C6 alkylene which is unsubstituted or substituted by C1-C6 alkyl, C1-C6 alkoxy, halogen, C3-C8 cycloalkyl, phenyl, benzyl, C1-C4 alkylphenyl, C1-C4 alkoxyphenyl, halophenyl, C1-C4 alkylbenzyl, C1-C4 alkoxybenzyl or halobenzyl, 5-, 6-, or 7-membered heterocyclic structure containing two oxygen elements. R3 preferably represents hydrogen, linear or branched C1-C16 alkyl or C1-C18 alkoxyalkyl; or are C3-C8 cycloalkyl, phenyl or benzyl which are unsubstituted or substituted by C1-C6 alkyl.
More preferably R1, R2, R4, R5, R6, R7, R8 and R9, independently of one another, represent —CH3, —CH2CH3; —OCH3; —OCH2CH3 or most preferably R1 and R2, R4 and R5, R6 and R7 or R8 and R9 are taken together to represent —CH2CH2— wherein the hydrogen can be replaced with a solubilizing group, a halide or an alkyl.
Terms and chemical formulas used herein to refer to alkyl or aryl moieties refer to either the substituted or unsubstituted unless specifically stated otherwise. A solvent is defined as a single solvent or a mixture of solvents.
The synthesis of conjugated dimers and trimers is well known in the literature. For example. The dimer of 3,4-ethylenedioxythiophene can be made through Ulmann coupling of the monomers with alkyl lithium and cupric chloride [J. Kagan and S. K. Arora, Heterocycles, 20 (1983) 1937].
Conjugated and non-conjugated dimers can be distinguished by Fourier transform infrared (FT-IR) spectroscopy as illustrated in
A complete coverage of the anodized surface by intrinsically conductive polymer is desired to prevent the graphite and other conductive layers of anode materials from contacting the bare surface of dielectric. When high leakage occurs on the dielectric surface intrinsically conductive polymers would degrade, lose the dopant induced delocalized charges and therefore become non-conductive. Through this mechanism intrinsically conductive polymers provide a self-healing protection similar to MnO2 based solid electrolytic capacitors where MnO2 would convert into the non-conductive Mn2O3 at elevated temperature.
The polymer coated capacitor anode bodies, coated with an intrinsically conductive organic polymer cathode layer, may then be processed into completed capacitors by coating the conductive polymer cathode coatings with graphite paint, conductive paint comprising conductive fillers such as silver particles, attachment of electrode leads, etc. as is well known to those skilled in the art. The device is incorporated into a substrate or device or it is sealed in a housing to form a discrete mountable capacitor as known in the art.
Other adjuvants, coatings, and related elements can be incorporated into a capacitor, as known in the art, without diverting from the present invention. Mentioned, as a non-limiting summary include, protective layers, multiple capacitive levels, terminals, leads, etc.
150 uF 6V rated anodized tantalum anodes were dipped into a solution of Fe (III) p-toluenesulfonate (oxidant), dried and subsequently dipped into fresh 3,4-ethylenedioxythiophene (monomer) to initiate the polymerization reaction. Polymerization formed a thin layer of conductive polymer (PEDT) on the dielectric surface of the anodes. They were then washed to remove excess monomer and by-products of the reactions. The anodes were then reformed by subjecting to a DC voltage in a diluted phosphoric acid solution to repair any damage to the dielectric and therefore, reducing the DC leakage. This dipping-reforming process cycle was repeated until a thick polymer layer was formed. Scanning electron microscope (SEM) pictures were taken of the anode surface covered with conductive polymer and are shown in
Carbon and silver coatings were applied onto the anodes by conventional process which is known to those skilled in the art. The parts were then assembled onto leadframes and molded with epoxy based encapsulant. The ESR of the capacitors was measured at 100 KHz. Leakage current under a DC bias was also measured. The number of parts showing short was recorded. The results are listed in Table 1.
The same type of parts as in Group A were processed the same as Group A with one difference. The fresh monomer used in Group A was replaced with a monomer solution after a large number of dips. It contained 2.3% non-conjugated dimer of EDT as measured by GC. SEM picture of the anode surface covered by conductive polymer is shown in
The same type of parts as in Group A were processed the same as Group A with one difference. The fresh monomer used in Group A was replaced with a polymer precursor solution containing 2.3% conjugated dimer of EDT. The conjugated dimer was made according to the procedure in the literature [J. Kagan and S. K. Arora, Heterocycles, 20 (1983) 1937]. The polymer precursor solution was made with the conjugated dimer and fresh monomer liquid. SEM picture of the anode surface covered by conductive polymer is shown in
The data in Table 1 clearly showed that the addition of conjugated dimer into the monomer improved the polymer growth rate and the polymer coverage of the dielectric surface of the anodes while maintaining a low ESR. The improved coverage in turn helped to reduce the number of shorts.
This invention has been described with particular reference to the preferred embodiments without limit thereto. Additional embodiments, alterations and improvements could be envisioned without departure from the meets and bounds of the invention as more specifically set forth in the claims appended hereto.
