Use of fluorocarbon surfactants to improve the productivity of gas and gas condensate wells

Information

  • Patent Application
  • 20070225176
  • Publication Number
    20070225176
  • Date Filed
    March 27, 2006
    19 years ago
  • Date Published
    September 27, 2007
    18 years ago
Abstract
The present invention includes composition having a nonionic, fluorinated polymeric surfactant, water and solvent. Embodiments of compositions according to the present invention are useful, for example, for recovering hydrocarbons from subterranean clastic formations.
Description

BRIEF DESCRIPTION OF THE DRAWINGS

For a more complete understanding of the features and advantages of the present invention, reference is now made to the detailed description of the invention along with the accompanying figures and in which:



FIG. 1 is a schematic illustration of an exemplary embodiment of an offshore oil and gas platform operating an apparatus for progressively treating a zone of a wellbore according to the present invention;



FIG. 2 is a cross-section view of an exemplary embodiment of a production zone at the wellbore next to a graph that describes the problem associated with the productivity of gas-condensate wells;



FIG. 3 is a graph that depicts a calculated near-wellbore condensate saturation;



FIG. 4 is a schematic of core flood set-up used for the Examples;



FIG. 5 is a graph that illustrates pressure drop data observed across different sections and the total length of the core as the process of condensate accumulation occurred in Example 4;



FIG. 6 is a graph that depicts the pressure drop in the core for Example 4 during dynamic condensate accumulation at 1,500 psig and 250° F. at different flow rates ranging from 330 cc/hr to 2637 cc/hr;



FIG. 7 is a graph that depicts the pressure drop across the reservoir core A, for dynamic condensate accumulation at 1,500 psig and 275° F. at flow rates ranging from 1389 cc/hr to 3832 cc/hr for Example 10;



FIG. 8 is graph that depicts the pressure drop in a Berea sandstone core during dynamic condensate accumulation at 1,500 psig and 250° F. before and after Example 4 treatment;



FIG. 9 is graph that depicts the effect of water concentration in the various compositions (i.e., Examples 1-9 and Comparative Examples A-C) on the gas relative permeability after treatment;



FIG. 10 is a graph that depicts shows the effect of treatment flow rate on the relative permeability after treatment with the compositions at different temperatures; and



FIG. 11 is a graph that depicts the durability of the Example 9 composition.


Claims
  • 1. A composition comprising: a nonionic fluorinated polymeric surfactant, wherein the nonionic fluorinated polymeric surfactant comprises: (a) at least one divalent unit represented by the formula:
  • 2. The composition of claim 1, wherein Rf has from 4 to 6 carbon atoms selected from the group consisting of perfluorobutyl, perfluoropentyl, and perfluorohexyl.
  • 3. The composition of claim 1, wherein Rf is perfluorobutyl.
  • 4. The composition of claim 1, wherein the solvent is water-miscible.
  • 5. The composition of claim 1, wherein the solvent comprises at least one of methanol, ethanol, propanol, isopropanol, butanol, ethylene glycol, acetone, a glycol ether, supercritical carbon dioxide, or liquid carbon dioxide.
  • 6. The composition of claim 1, wherein the solvent comprises methanol.
  • 7. The composition of claim 1, wherein the nonionic fluorinated polymeric surfactant is free of hydrolyzable silane groups.
  • 8. The composition of claim 1, wherein the nonionic fluorinated polymeric surfactant has a number average molecular weight in the range from 1,000 to 30,000 g/mole.
  • 9. The composition of claim 1, wherein the composition is interactive with a hydrocarbon-bearing geological clastic formation.
  • 10. The composition of claim 9, wherein the hydrocarbon-bearing geological clastic formation is downhole.
  • 11. The composition of claim 10, wherein downhole conditions comprise a pressure in a range from about 1 bar to 1000 bars and a temperature in a range from about 100° F to 400° F.
  • 12. The composition of claim 1, wherein the nonionic fluorinated polymeric surfactant is preparable by copolymerization of: (a) at least one compound represented by the formula
  • 13. A method of treating a hydrocarbon-bearing subterranean clastic formation, the method comprising injecting the composition of claim 1 into the hydrocarbon-bearing subterranean clastic formation.
  • 14. The method of claim 13, wherein the subterranean clastic formation is downhole.
  • 15. The method of claim 13, wherein the subterranean clastic formation is predominantly sandstone.
  • 16. A method of stimulating hydrocarbon well productivity from a hydrocarbon-bearing subterranean clastic formation, the method comprising injecting the composition of claim 1 into the subterranean clastic formation.
  • 17. The method of claim 16, wherein the hydrocarbon flow exhibits an increase in the gas relative permeability of at least 2 percent as compared to the hydrocarbon flow prior to the injection of the composition.
  • 18. The method of claim 16, wherein the hydrocarbon flow exhibits an increase in the condensate relative permeability of at least 2 percent as compared to the hydrocarbon flow prior to the injection of the composition.
  • 19. A method for recovering hydrocarbons from a hydrocarbon-bearing subterranean clastic formation, the method comprising injecting the composition of claim 1 into the subterranean clastic formation and obtaining hydrocarbons therefrom.
  • 20. A method for recovering hydrocarbons from a hydrocarbon-bearing subterranean clastic formation, the method comprising injecting the composition of claim 1 into the subterranean clastic formation and obtaining hydrocarbons therefrom, the hydrocarbons comprising at least one of methane, ethane, propane, butane, hexane, heptane, or octane.
  • 21. A method of stimulating hydrocarbon flow from a hydrocarbon-bearing subterranean clastic gas formation by injecting the composition of claim 1 into a subterranean clastic gas formation.
  • 22. A method for coating a subterranean clastic formation and having a surface, the method comprising contacting the surface with the composition of claim 1.
  • 23. A gaseous composition comprising methane and a fluorinated thermal decomposition product of the composition of claim 1.
  • 24. A gaseous composition comprising methane and a fluorinated product resulting from hydrolysis of the composition of claim 1.
  • 25. A composition comprising: a nonionic fluorinated polymeric surfactant comprising: (a) at least one divalent unit represented by the formula:
  • 26. A method of treating a hydrocarbon-bearing clastic subterranean formation, the method comprising injecting the composition of claim 25 into the hydrocarbon-bearing clastic subterranean formation.
  • 27. A method of stimulating hydrocarbon well productivity from a hydrocarbon-bearing subterranean clastic formation, the method comprising injecting the composition of claim 25 into the subterranean clastic formation.
  • 28. A method for recovering hydrocarbons from a hydrocarbon-bearing subterranean clastic formation, the method comprising injecting the composition of claim 25 into the subterranean clastic formation and obtaining hydrocarbons therefrom.
  • 29. A method for coating a subterranean clastic formation and having a surface, the method comprising contacting the surface with the composition of claim 25.
  • 30. A method of making a composition, the method comprising: selecting a hydrocarbon-bearing subterranean clastic formation, the formation having a temperature, water content, and ionic strength;determining the temperature, water content, and ionic strength of the hydrocarbon-bearing subterranean clastic formation;generating a formulation comprising nonionic fluorinated polymeric surfactant and at least one of solvent or water such that the nonionic fluorinated polymeric surfactant as in the composition based at least in part on the determined temperature, water content, and ionic strength of the hydrocarbon-bearing subterranean clastic formation, wherein the nonionic fluorinated polymeric surfactant has a cloud point when placed in the hydrocarbon-bearing subterranean clastic formation that is above the temperature of the hydrocarbon-bearing subterranean clastic formation; andmaking a composition having the formulation.
  • 31. The method of claim 30, wherein the composition comprises water.
  • 32. The method of claim 30, wherein the composition comprises solvent, and wherein the solvent comprises methanol.
  • 33. The method of claim 30, wherein the nonionic fluorinated polymeric surfactant comprises: (a) at least one divalent unit represented by the formula:
  • 34. A method of treating a hydrocarbon-bearing subterranean clastic formation, the method comprising injecting the composition of claim 30 into the hydrocarbon-bearing subterranean clastic formation.
  • 35. A method of stimulating hydrocarbon well productivity from a hydrocarbon-bearing subterranean clastic formation, the method comprising injecting the composition of claim 30 into the subterranean clastic formation.
  • 36. A method for recovering hydrocarbons from a hydrocarbon-bearing subterranean clastic formation, the method comprising injecting the composition of claim 30 into the subterranean clastic formation and obtaining hydrocarbons therefrom.
  • 37. A method for recovering hydrocarbons from a hydrocarbon-bearing subterranean clastic formation, the method comprising injecting the composition of claim 30 into the subterranean clastic formation and obtaining hydrocarbons therefrom, the hydrocarbons comprising at least one of methane, ethane, propane, butane, hexane, heptane, or octane.
  • 38. A method of stimulating hydrocarbon flow from a hydrocarbon-bearing subterranean clastic formation, the method comprising injecting the composition of claim 30 into a subterranean clastic formation.
  • 39. A method for coating a subterranean clastic formation and having a surface, the method comprising contacting the surface with the composition of claim 30.