The present invention relates generally to ultraviolet or UV irradiation apparatus for sterilizing liquid to be treated (to-be-treated liquid) by using UV rays, and more particularly to a UV sterilizer apparatus for use, for example, in water purification plants to deactivate chlorine-resistant disease-causing organisms, such as cryptosporidium, in pure water production plants, and in other water treatment plants.
UV irradiation apparatus employed for water treatment include an internal radiation type and an external radiation type. The internal radiation type includes a UV-transmissive protective tube, such as a quartz tube, inserted in a cylindrical stainless steel container, and a UV-emitting lamp accommodated in the protective tube as a light source. The internal radiation type is constructed in such a manner that to-be-treated water is caused to flow in the stainless steel container so that UV rays having passed through the protective tube are radiated to the to-be-treated water within the stainless steel container. Namely, the protective tube for the UV light source is provided in contact with the to-be-treated water within the container. On the other hand, the external radiation type includes a UV light source provided around a UV-transmissive water passage tube (such as a fluorine resin tube or a quartz tube) with a space interposed therebetween. The external radiation type is constructed in such a manner that to-be-treated water is caused to flow through the UV-transmissive water passage tube so that UV rays from the UV light source are radiated to the to-be-treated water within the stainless steel container through the surrounding space and the wall of the water passage tube. Namely, the UV rays are radiated from outside the water passage tube in which the to-be-treated water is caused to pass. Patent Literature 1 below discloses an example of the internal-radiation-type UV irradiation apparatus, and Patent Literature 2 below discloses an example of the external-radiation-type UV irradiation apparatus.
Patent Literature 1: Japanese Patent Application Laid-open Publication No. 2007-275825
Patent Literature 2: Japanese Patent Application Laid-open Publication No. 2001-120235
Generally, UV irradiation apparatus presently used in water purification plants are of the internal radiation type. In the case of the internal radiation type, when the protective tube (quartz tube) is damaged or broken, broken pieces of the protective tube and the light source lamp and substances within the light source lamp may flow together with to-be-treated water. Because, in general, a mercury lamp is used as the light source lamp, it has to be assumed that mercury may be mixed into the to-be-treated water, if the protective tube (quartz tube) is damaged or broken. Thus, in the water purification plants, a strainer is inserted at a front stage of the UV irradiation apparatus in order to forestall damage or breakage of the protective tube (quartz tube), particularly to prevent a pebble, which may damage or break the protective tube (quartz tube), from flowing into the UV irradiation apparatus. Further, another strainer is provided at a rear stage of the UV irradiation apparatus in case of damage or breakage of the protective tube (quartz tube). In addition, a tank is provided rearward of the rear strainer of the UV irradiation apparatus in case of a situation where the mercury dissolves into the to-be-treated water, and control is performed to automatically close a valve, provided at the exit of the tank, in response to a water leakage signal generated from the irradiation apparatus.
In the case of the external radiation type, on the other hand, even when the water passage tube of the UV irradiation apparatus is damaged or broken, the only possible glitch is that water spurts out of the water passage tube, and there may not arise a situation where broken pieces of the water passage tube and the mercury within the lamp get mixed into the to-be-treated water. Thus, for the external radiation type, there is no need to provide front and rear strainers, rear tank, automatic valve at the exit of the tank, etc. as mentioned above. However, although water pressure resistance performance required in water treatment plants as well as in water purification plants is 1 MPa, it is difficult for the UV-transmissive water passage tube of the external-radiation-type UV irradiation apparatus to achieve the water pressure resistance performance of 1 MPa, because the UV-transmissive water passage is formed of fluorine resin or quartz. In order to achieve the water pressure resistance performance of 1 MPa with the UV-transmissive water passage tube formed of fluorine resin or quartz, it is necessary to reduce the diameter of the water passage tube and increase the wall thickness of the water passage tube. However, because increasing the wall thickness of the water passage tube lowers the UV transmittance and reducing the diameter of the water passage tube reduces the amount of water that can be treated, the number of the tube to be used for the water treatment has to be increased. Such arrangements require high costs and thus are unrealistic or impractical.
In view of the foregoing problems, it is an object of the present invention to provide a UV irradiation apparatus which can, like an external-radiation-type UV irradiation apparatus, eliminate a need to provide various equipment as measures against possible occurrence of damage or breakage of a protective tube (quartz tube), having a UV lamp inserted therein, while possessing water pressure resistance performance equivalent to that of an internal-radiation-type UV irradiation apparatus.
In order to accomplish the aforementioned object, a UV irradiation apparatus of the present invention includes: a pressure resistant container; a UV-transmissive protective tube accommodated in the container; a UV lamp accommodated in the protective tube; and a UV-transmissive water passage tube accommodated in the container and constructed in such a manner that to-be-treated liquid is caused to flow through the water passage tube. The remaining space within the container is filled with a UV-transmissive liquid medium. UV rays from the UV lamp are radiated to the to-be-treated liquid through the protective tube, the liquid medium, and the water passage tube.
With the UV-transmissive water passage accommodated in the container and constructed in such a manner that the to-be-treated liquid is caused to flow through the water passage tube and with the remaining space within the container being filled with the UV-transmissive liquid medium, pressures inside and outside the water passage tube are kept substantially equal, and a liquid pressure produced in the water passage tube is substantively loaded to the wall of the container located outside the water passage tube. Thus, water pressure resistance performance of the water passage tube substantially equals that of the container, and as a result, it is possible to substantively ensure 1 MPa or over as water pressure resistance performance of a liquid treatment system, by constructing the container to possess sufficient water pressure resistance performance and without particularly strengthening a material, structure, etc. of the water passage tube. Further, because UV-transmissive liquid (such as pure water) is used as the liquid medium that fills the remaining space within the container, all or most of the UV rays radiated from the UV lamp within the protective tube transmit, through the liquid medium, to reach the to-be-treated liquid present in the water passage tube, and as an result, efficient liquid treatment (such as sterilization) can be performed. Furthermore, even when the protective tube having the UV lamp accommodated therein is damaged or broken, broken pieces of the protective tube stay in the liquid medium without reaching the interior of the water passage tube, and therefore, there is no need to provide various equipment as measures against possible occurrence of damage or breakage of the protective tube (quartz tube). In this way, the present invention achieves advantageous benefits of both the internal radiation type and the external radiation type. Note that the UV rays irradiated from the UV lamp may be of any suitable wave length as long as the wave length belongs to a wavelength range necessary for the treatment of the to-be-treated liquid (for example, about 190 nm to 400 nm in the case of sterilization). Also, the liquid medium may be of any suitable UV-transmission performance as long as the UV-transmission performance is sufficient with respect to the wavelength range of the UV rays irradiated from the UV lamp employed.
A UV-transmissive protective tube 2 is accommodated at a predetermined position (a position along the center axis of the cylindrical protective tube 2 in the illustrated example) within the container 1. Preferably, the protective tube 2 has an elongated cylindrical shape extending in the axial direction of the cylindrical container 1, and the protective tube 2 is detachably attached to the container 1 from the side of one end surface 1a of the cylindrical container 1. A portion of the one end surface 1a of the container 1 to which the protective tube 2 is attached is constructed in a liquid-tight manner such that a liquid medium 5 within the container 1 does not ooze out from the container 1. A UV lamp 3 is detachably accommodated in the protective tube 2 via one end portion 2a of the protective tube 2. As an example, the UV lamp 3 has a linear shape elongated along the length of the protective tube 2. Needless to say, the UV lamp 3 may be of any desired shape other than a linear shape, such as a ring shape or a spherical shape. In any case, the protective tube 2 is shaped to suit the shape of the UV lamp 3. Of the protective tube 2, a portion accommodated in the container 1 is formed of a material, such as quartz glass, that has sufficient UV transmissivity, and a portion (end portion 2a) projecting out of the container 1 is formed of a suitable material (such as metal). Needless to say, the number of the protective tube 2 (and hence the UV lamp 3) accommodated in the container 1 is not limited to just one as in the illustrated example and may be any desired plural number.
Further. UV-transmissive water passage tubes 4 are accommodated in the container 1. In the illustrated example of
As illustratively shown in
As shown in
In liquid treatment processing by the UV irradiation apparatus arranged in the aforementioned manner, all or most of the UV rays irradiated from the UV lamp 3 transmit through the liquid medium 5 in the container 1 to reach the to-be-treated liquid 6 present within the water passage tubes 4, and as a result, efficient liquid treatment (such as sterilization) can be performed on the to-be-treated liquid 6. Further, even when the protective tube 2 having the UV lamp 3 accommodated therein is damaged or broken, broken pieces of the protective tube 2 stay in the liquid medium 5 without reaching the to-be-treated liquid 6 present within the water passage tubes 4, and therefore, there is no need to provide various equipment as measures against possible occurrence of damage or breakage of the protective tube 2, such as front and rear strainers of the container 1, a rear-stage tank, and an automatic valve at the exist of the tank.
Assuming that the container 1 has an inner diameter of about 210 mm and a length of about 1,000 mm, for example, the protective tube 2 has an outer diameter of about 30 mm, and the water passage tubes 4 each have an outer diameter of 60 mm. In such a case, a low-pressure mercury lamp of about 65 watt can be used as the UV lamp 3.
A structure for supplying the to-be-treated liquid 6 to the plurality of water passage tubes 4 accommodated in the container 1 may be constructed as desired from a design point of view. For example, as shown schematically and conceptually in
In the embodiment of
In each of the above-described embodiments, it is preferable that a reflective layer formed for example of aluminum, PTFE (polytetrafluoroethylene) fluorine resin, etc. for effectively reflecting UV rays be provided on the inner wall of the container 1. In this case, UV rays reflected by the reflective layer are radiated to the surface of the water passage tubes 4 or water passage tube 7 located opposed to the light source (UV lamp 3), and as a result, efficient UV irradiation can be performed on the entire to-be-treated liquid 6 passing through the water passage tubes 4 or water passage tube 7.
Next, a description will be given of the performance and capabilities of the UV lamp 3 employed in the above-described embodiments of the present invention. Wavelengths effective for inactivation, by UV rays, of disease-causing organisms and microorganisms are 400 nm and less. In the present invention, UV rays are radiated to the to-be-treated water 6 through the layer of the liquid medium 5, such as pure water, ion-exchanged water, or ultrapure water, which has high UV transmissivity. Because water absorbs UV rays having wavelengths of 190 mm and less, it is not necessary to construct the UV lamp 3 to possess a capability for radiating UV rays having wavelengths of 190 nm and less. Thus, a wavelength range of UV rays that is effective in the present invention is 190 nm to 400 nm, and the UV lamp 3 only has to have a capability for irradiating UV rays that are of any wavelength or wavelength band belonging to the wavelength range of 190 nm to 400 nm. Particularly, because wavelengths of about 200 nm to 300 nm are effective, it is preferable to employ a UV lamp 3 having such a radiation capability. Any desired one of various light sources, such as a mercury lamp like a low-pressure mercury lamp, medium-pressure mercury lamp or high-pressure mercury lamp, a xenon lamp, a flash lamp, and a UV-LED, may be used as a specific example of the light source, although the light source used in the invention is not limited to the above-mentioned light sources.
The following describe materials and shapes of the water passage tubes 4 and 7, as well as positional relationships of the water passage tubes 4 and 7 with the light source. One of various conditions required of each of the water passage tubes 4 and 7 is that UV rays are transmitted through the water passage tube. Examples of a material that satisfies such a condition include a single material, such as quartz, sapphire, or FEP or PFA (tetrafluoroethylene-perfluoro alkyl vinyl ether copolymer) fluorine resin, a compound material, such as quartz or sapphire covered with fluorine resin (where the quartz or sapphire and the fluorine resin may be adhered to each other by thermal shrinkage, or may be absorbed or joined to each other after processing of their respective contact surfaces), and the like. The shape of the water passage tube is not limited to the cylindrical shape as shown in
Next, a description will be given of a material, shape, etc. of the protective tube 2. Predetermined UV transmissivity and pressure resistance are required of the protective tube 2 in which the UV lamp 3 is to be inserted. Therefore, it is preferable that the protective tube 2 be formed of a single material such as quartz, sapphire, or FEP or PFA fluorine resin, that has superior UV transmissivity, or a compound material comprising quartz or sapphire covered with fluorine resin, similarly to the aforementioned water passage tubes 4 and 7. Further, because the water pressure resistance of 1 MPa or over is required of the protective tube 2, it is desirable that the protective tube 2 be formed in a cylindrical shape. In general, tubes formed of fluorine resin are limited in their inner diameter and wall thickness. Thus, in the case where the water pressure resistance of 1 MPa or over is required of the protective tube 2 formed of fluorine resin, it is necessary that the protective tube 2 have a wall thickness of 2 mm or over for an inner diameter of 20 mm, although a necessary wall thickness of the protective tube 2 depends on a temperature. In the case where the protective tube 2 is formed of quartz or sapphire, or a compound material comprising quartz or sapphire covered with fluorine resin, on the other hand, the water pressure resistance of 1 MPa or over can be ensured even with the protective tube 2 having a wall thickness of 1 mm for the inner diameter of 20 mm.
Next, cooling of the liquid medium 5 will be described. The ion-exchanged water used as the liquid medium 5 rises in temperature with heat generated from the low-pressure mercury lamp and reaches a certain water temperature (for example about 60° C. that may, however, differ depending on an ambient temperature, temperature of the to-be-treated liquid 6, and presence/absence of flows of the to-be-treated liquid 6). Further, UV output of the low-pressure mercury lamp varies with an ambient temperature of the lamp and decreases at about 60° C. by about 50 to 70% relative to the UV output at an optimum temperature (ambient water temperature is 25° C.). In order to reduce adverse influences of such an water temperature rise, it is preferable to provide a cooling means within the container 1 to cool the liquid medium 5 by use of the cooling means in such a manner that the protective tube 2 and the UV lamp 3 accommodated in the protective tube 2 can be cooled, thereby preventing the decrease of the UV output.
An example of such a cooling means is shown in
Today, for UV irradiation apparatus employed in water purification plants, it is required by law to constantly measure a UV radiation intensity. For this purpose, it just suffices that a UV sensor 15 be provided within the water passage tube 4 that is a flow path for the to-be-treated liquid 6, as shown in
Next, a description will be given of influences of the UV reflecting layer provided on the inner wall of the container 1. The to-be-treated liquid 6 within the water passage tube 4 is irradiated with UV rays emitted from the UV lamp 3, after which the UV rays reach the inner wall of the stainless steel container 1. Because the UV reflectance of the stainless steel is approximately 30%, the reflection effect is small if no particular reflective layer is provided. However, with the embodiment of the present invention, where the reflective layer for efficiently using the UV rays having reached the inner wall of the stainless steel container 1 is provided on the inner wall of the container 1, the UV radiation intensity within the water passage tube 4 can be increased. Because the reflective layer is kept in constant contact with pure water, it is desirable that the reflective layer be formed of a material that is not corroded with the pure water. Because the preferred wavelength range in the embodiment is approximately 200 nm to 300 nm, it is preferable that the reflective layer be formed of a material having a high reflectance with respect to the above-mentioned wavelength range. For example, aluminum coated with fluorine resin, or PTFE, FEP or PFA fluorine resin is suitable for reflecting UV rays. As well known, reflection includes specular (or regular) reflection and diffuse (or irregular) reflection, of which the specular reflection occurs in a state where the reflective surface is like a mirror surface while the diffuse reflection occurs in a state where the reflective surface is an uneven surface. The reflective layer may be formed so as to present any one of these reflection effects. As an example, a cylinder formed by winding an FEP sheet having a thickness of 1 mm was closely attached to the inner wall of the container 1, and then, an intensity of UV radiation to the to-be-treated water 6 within the water passage tube 4 was measured. As a result, an increase of the UV radiation intensity that is up to four times as high as a UV radiation intensity in a case where such an FET sheet was not provided could be obtained. The cylinder having such an FEP sheet layer has a circumference of about 660 mm so as to be closely attached to the inner circumference of the stainless steel container 1 having a diameter of 210 mm. In order to obtain such an FEP sheet layer having the circumference of about 660 mm, it is only necessary that an FEP sheet of a rectangular shape having a short side of 700 mm and a long side of 1 m equal to the axial length of the stainless steel container 1 be wound in a short-side direction, and the remaining portion of 40 mm may be left in a natural overlapping state without its overlapping regions having to be welded together. Even in a case where the reflective layer is formed of aluminum, the overlapping regions do not have to be welded together.
Further, the UV reflective surface provided on the inner wall of the container 1 does not have to be fixed to the container 1. Besides, because the liquid medium 5 is present both inside and outside the reflective layer, high water pressure resistance is not required. Thus, the shape of the reflective layer may be chosen with a considerable degree of freedom; for example, the reflective layer may be of a plate shape having flat surfaces rather than a cylindrical shape. Particularly, in a case where a reflective plate constructed to produce specular reflection is used and the reflective plate may be shaped to have a generally elliptical curved surface, and where a light source is provided at one of two focal points, light specularly reflected by the reflective plate focuses at the other focal point. Thus, the light source (protective tube 2), the water passage tube 4, and the reflective plate may be disposed in a positional arrangement utilizing this principle.
Next, a description will be given of anti-freezing and anti-condensation measures. If the UV lamp 3 (such as a low-pressure mercury lamp) is constantly kept on or illuminated, the liquid medium 5 is warmed by the lamp, and thus, there is no possibility of the liquid medium 5 and the to-be-treated liquid 6 being frozen. However, when the lamp 3 is turned off, dew condensation may occur within the protective tube 2 having the lamp 3 inserted therein, and consequently, there may occur problems of the lamp 3 going out and/or a socket connecting the lamp 3 corroding due to the condensation water. Constantly keeping the lamp 3 can also function as anti-condensation measures. However, if the lamp 3 is kept illuminated with the cooling water supply to the spiral pipe 4 stopped during a non-liquid-treatment-processing time, the liquid medium 5 is heated, for example, to approximately 60° C., and thus, the to-be-treated liquid 6, convectively flowing in the water passage tube 4, is also heated. In order to avoid the to-be-treated liquid 6 from being heated due to the constant illumination of the lamp 3 during the non-liquid-treatment-processing time, it suffices that the water passage tube 4 be kept empty during the non-liquid-treatment-processing time.
Cleaning of the water passage tubes 4 and 7 will be described next. It is assumable that dirt and the like adhere to the inner wall surfaces of the water passage tubes 4 and 7. In a case where the UV irradiation apparatus is used in a water purification plant, dirt and the like are more likely to adhere than in a case where the UV irradiation apparatus is used in pure water production. Water having been subjected to membrane treatment used as measures against cryptosporidium in a water purification plant includes permeated water that becomes purified water, and wastewater to be collected or discharged. The wastewater is more likely to cause adherence of dirt and the like than the purified water. It was confirmed that, after ten-year's use of a fluorine resin tube through which the waste water was caused to flow, there was almost no adherence of dirt and the like owning to the effect of non-wettability of the fluorine resin. Thus, using such a fluorine resin tube as the water passage tube 4 (or 7) can be expected to be highly effective in prevention of adherence of dirt and the like.
Further, a cleaning mechanism may be provided for cleaning the interior of the water passage tube 4 (or 7). Such a cleaning mechanism may be based, for example, on at least one of applying ultrasonic waves to the liquid medium 5, imparting mechanical vibrations to the water passage tube 4 (or 7) by use of a vibrator, and cleaning the interior of the water passage tube 4 (or 7) by use of a brush.
Number | Date | Country | Kind |
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2016-108587 | May 2016 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2017/018426 | 5/16/2017 | WO | 00 |