The present invention is directed to a method for UV cross-linking of lacquer-layers according to the generic part of claim 1. The invention further addresses an irradiation apparatus for operating the method.
By means of UV cross-linking lacquers, which are applied upon substrates, are hardened and dried. The lacquer remains flowable up to the cross-linking and may be abruptly solidified after having being applied on a substrate.
As a UV-radiation source mostly a radiation source is used, which emits UV-radiation as well as visible light as well as a high percentage of infrared radiation (IR-radiation). The high portion of IR-radiation leads to high process temperatures, which may harm the substrates to be irritated. Especially, if the lacquered substrates are plastic-material substrates, in case of application of customarily radiation, critical temperatures are reached frequently. As an example for plastic material, known under the name ABS, temperatures of 85° should not be exceeded.
According to the DE 3529800 this problem is resolved in that the rays of the UV-radiation source are led via a ray-selecting mirror to the substrate such that the substrate is exclusively exposed to deflected UV-rays, whereby the heat richer IR part of the rays passes through the mirror straight-lined.
The DE 3529800 addresses also the problem that whenever there occurs an operation shut-down, the radiation source should, if possible, not be switched-off. Thereby, the mirror is, if arranged in an angle of 45° to the optical axis of the ray-beam, realized to be swivable by 90° so that the UV-radiation may be simply and quickly diverted in case of a shut-down of operation. The UV-radiation rich ray-beam is thereby diverted by 180°, so as to impinge on the casing wall of the irradiation apparatus.
Nevertheless, this has the drawback that the mirror must be realized in a specific manner. The mirror may either be provided on one side or on both sides with a UV reflecting layer. Is there provided on both sides of the substrate a UV reflecting layer, one must consider that by this layer always a part of the visible light and/or of the IR-radiation is reflected. This is especially true in case of the radiation impinges on the mirror surface in different impinging angles. Having a double sided UV reflection layer, the part of the non-UV-rays is thus increased, which unwantedly is reflected into the ray-path of UV light and impinges onto the substrate.
If only on one side of the mirror substrate a UV reflecting layer is applied, then on the other side, an anti-reflection layer for visible light and for IR-radiation should be selected across a wide impinging angle range. In this case, a special material which does substantially not absorb UV-radiation, should be selected as mirror substrate material. Otherwise, due to double penetrating of the substrate, excessive UV-radiation would be absorbed and the mirror could be damaged. It is probably also due to this reason that in the DE 3529800 the radiation source is preferably operated on half power. Such UV-radiation non-absorbing materials, as e.g. quartz glass, are nevertheless expensive. This is especially relevant for large apparatuses.
It is an object of the present invention to provide an apparatus, by which the problems of the prior art as addressed above are at least reduced and are preferably completely removed.
According to the invention, the object is resolved in that, departing from a irradiation apparatus as shown in
It is also possible to turn the mirror in this way that only the edges of the mirror substrate is irradiated by the radiation or the radiation impinges on the substrate surface at a very large impinging angle and is reflected to a major part but is hardly deflected due to the large impinging angle.
The mirror substrate may now be made of a UV-radiation absorbing material and it is also possible to apply only on one side of the mirror substrate a UV reflecting coating and, preferably, to provide on the other side of the mirror substrate an anti-reflection layer.
According to a preferred realization form of the present invention, the edges of the mirror substrate are provided with means, which at least to a part, block impinging radiation (being absorbing or reflecting).
According to a further preferred form of realization substrates to be subjected to the radiation are fed to the irradiation apparatus by means of a transport arrangement in a clocked manner. It is thereby especially advantageous, if, during the feeding step, the UV-irradiation of the area, in which the substrates are positioned for irradiation, is interrupted. This may be realized clocked, as well, and preferably synchronized with the addressed feeding by swiveling of the mirror.
According to a further form of realization of the present invention, the mirror is subjected to an oscillating movement during UV-irradiation, whereby a homogenous irradiation of the substrates is achieved.
The invention shall now be further explained by means of an example.
In
Within the ray-paths from the radiation sources to the absorber plate, there is respectively provided a wave-length selective mirror 13, 15. The mirrors are tilted by 45° with respect to the optical axis of the radiation sources so that the radiation is reflected by 90° with respect to the original ray-path. The mirrors 13,15 reflect the UV-radiation and transmit to a substantial part and preferably to a predominant part the W-radiation. Such mirrors may e.g. be realized by means of optical interference filters. It is especially advantageous to provide on one side of the mirror substrate, which can comprise a customarily BK7 glass, the UV-reflector and the W-radiation transmitter and to provide on the other side a broad-band anti-reflex coating. Both may be realized by means of thin multilayers, which show interference.
Spindles 5, 7 are fed into the ray-paths of the UV-radiation being deflected by 90°. Thus, during switched-on radiation sources 9, 11, the W-radiation is not deflected and is transmitted through the mirrors 13, 15 to the absorber plate. In opposition thereto, the UV-radiation is led onto the substrates, which are arranged on the spindles, by reflection at the mirrors. The spindles are commonly realized as rotatable spindles so that they may rotate the respective substrates into the respective impinging areas during UV-irradiation. In the example, the mirrors 13,15 are oscillated with a small amplitude (e.g. 1°) about an axis, which is different from a normal on the mirror surface and which lays in the plane defined by the optical axes of the reflected radiation and of the un-deflected radiation. Thereby, the homogeneity of UV-irradiation is increased.
In order to terminate UV-irradiation, the mirrors 13, 15 are swiveled to an orientation, in which the optical axis of the un-deflected radiation is parallel to the mirror surface. This is preferably realized about an axis, which is located outside the ray-path of the undisturbed radiation source. In this way, the predominant part of the UV-radiation propagates as well un-deflected towards the absorber plate and is absorbed there. The respective situation is shown in
By means of a preferred form of realization of the present invention, there has been disclosed a irradiation apparatus, comprising
The moving means may be realized so that they allow a rotation of the filter about an axis, which is situated outside the ray-path.
The wave-length selective filter may be realized as an interference filter. As an example, there may be provided only on one side of the filter substrate a UV reflecting layer system, and on the other side of the filter substrate there may be provided an anti-reflex layer for W-radiation.
There was disclosed a method for irradiating substrates by UV-radiation, which comprises the steps of:
By this method, the filter is substantially removed from the ray-path during the addressed feeding and/or removal of the substrates.
The filter may be moved out of the ray-path by rotation about an axis, which is located outside the addressed ray-path. The method may be performed more than one time and in a clocked manner.
Number | Date | Country | Kind |
---|---|---|---|
10 2012 020 743 | Oct 2012 | DE | national |
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/EP2013/003176 | 10/22/2013 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2014/063809 | 5/1/2014 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
4149086 | Nath | Apr 1979 | A |
4644899 | Glaus | Feb 1987 | A |
4864145 | Burgio, Jr. | Sep 1989 | A |
5595118 | Villaverde, Sr. | Jan 1997 | A |
5695561 | Tomiyama | Dec 1997 | A |
5782895 | Zarate | Jul 1998 | A |
5932886 | Arai | Aug 1999 | A |
6621087 | Bisges | Sep 2003 | B1 |
6834984 | Tausch | Dec 2004 | B2 |
6883936 | Register | Apr 2005 | B2 |
7692170 | Gaus | Apr 2010 | B2 |
9157642 | Maeng | Oct 2015 | B2 |
20020030882 | Vitt | Mar 2002 | A1 |
20050225999 | Bucher | Oct 2005 | A1 |
Number | Date | Country |
---|---|---|
35 29 800 | Mar 1986 | DE |
2 341 815 | Sep 1977 | FR |
9854525 | Dec 1998 | WO |
Entry |
---|
International Search Report issued in Application No. PCT/EP2013/003176 dated Jan. 21, 2014. |
Number | Date | Country | |
---|---|---|---|
20150375263 A1 | Dec 2015 | US |