This application claims the priority benefit of Taiwan application serial no.92119489, filed on Jul. 17, 2003.
1. Field of the Invention
The present invention relates to an ultraviolet (UV) photodetector. More particularly, the present invention relates to an UV photodetector having a high-resistivity GaN-based interlayer for reducing the leakage current.
2. Description of the Related Art
In general, a conventional UV photodetector can be classified into three type of devices including a photomultiplier Tube (PMT), a silicon-based UV photodetector and a III-V compound semiconductor UV photodetector such as a GaN UV photodetector. Currently, only the photomultiplier tube and the silicon-based UV photodetector are commercialized and produced under mass production. The GaN UV photodetector is just under a preliminary research and development due to the high cost and the complicated technique.
In general, the shortcoming of a photomultiplier tube is that the cost is high, the operational voltage is high, and the vacuum tube is fragile, but the advantage is that a precise detecting result can be obtained. The advantage of the silicon-based UV photodetector is that the manufacturing process is simple, the cost is low, the operation voltage is low, and a wavelength of light in visible and infrared can be detected, but the disadvantages are that the rejection ratio of ultraviolet to visible and/or infrared is poor. The advantage of the GaN UV photodetector is that the detecting wavelength of the detector can be adjusted according to the needs during the manufacturing process. For example, when the desired detecting wavelength is set in a range of about 200 nm to about 365 nm, an excellent detecting sensitivity for AlGaN-based UV photodetector can be obtained by adjusting the Al composition of AlGaN absorption layer. Therefore, the AlGaN-based UV photodetector has become the major trend of the UV photodetector in recent years.
Referring to
Referring to
In a conventional UV photodetector, whether in a Schottky barrier diode (SBD) type UV photodetector, or in a metal-semiconductor-metal (MSM) type UV photodetector, there is an issue of a high leakage current. The leakage current is caused by the thermal emission effect and/or the extraordinary tunneling effect due to the poor Schottky contact property between the semiconductor layer and the electrode. Therefore, if the performance of the Schottky contact between the semiconductor layer and the electrode can be effectively enhanced, the leakage current of the UV photodetector will be drastically reduced.
Accordingly, the purpose of the present invention is to provide a Schottky barrier diode (SBD) type UV photodetector that can effectively reduce the leakage current.
It is another object of the present invention to provide a metal-semiconductor-metal (MSM) type UV photodetector that can effectively reduce the leakage current.
In order to achieve the above objects and other advantages of the present invention, a Schottky barrier diode (SBD) type UV photodetector is provided. The UV photodetector is at least constructed by a substrate, a GaN-based semiconductor layer, a GaN-based interlayer, a first electrode and a second electrode. The GaN-based semiconductor layer is disposed on the substrate, and the GaN-based semiconductor layer has a first protrusion portion. The GaN-based interlayer is disposed on the first protrusion portion of the GaN-based semiconductor layer, and a material of the GaN-based interlayer includes, for example but not limited to, an AlxInyGa1−x−yN, wherein x≧0, y≧0, and 1≧x+y. The first electrode is disposed on the GaN-based interlayer, and the second electrode is disposed on a portion of the GaN-based semiconductor layer except for the first protrusion portion. In addition, in the above-described embodiment of the invention, the first bonding pad and the second bonding pad can be disposed on the first electrode and second electrode respectively.
In the Schottky barrier diode (SBD) type UV photodetector of the preferred embodiment, the substrate includes, for example but not limited to, an aluminum oxide (sapphire) substrate, a silicon carbide (SiC) substrate, a zinc oxide (ZnO) substrate, a silicon substrate, a gallium phosphide (GaP) substrate, and a gallium arsenide (GaAs) substrate.
In the Schottky barrier diode (SBD) type UV photodetector of the preferred embodiment, the GaN-based semiconductor layer, for example, is constructed from a nucleation layer, an ohmic contact layer and an active layer. The nucleation layer is disposed on the substrate. The ohmic contact layer is disposed on nucleation layer, and has a second protrusion portion. The active layer is disposed on the second protrusion portion. The first protrusion portion of the whole GaN-based semiconductor layer is constructed by the second protrusion portion of the ohmic contact layer and the active layer. Moreover, a material of the nucleation layer includes, for example but not limited to, AlaInbGa1−a−bN semiconductor, wherein a, b≧0 and 0≦a+b≦1. The material of the ohmic contact layer includes, for example but not limited to, N-type AlcIndGa1−c−dN semiconductor, wherein c, d≧0 and 0≦c+d≦1. The material of the active layer includes, for example but not limited to, undoped AleInfGa1−e−fN semiconductor, wherein e, f≧0 and 0≦e+f≦1.
In the Schottky barrier diode (SBD) type UV photodetector of the preferred embodiment, the materials of the first electrode and the second electrode include, for example but not limited to, Ni/Au, Cr/Au, Cr/Pt/Au, Ti/Al, Ti/Al/Ti/Au, Ti/Al/Pt/Au, Ti/Al/Ni/Au, Ti/Al/Ti/Au, Ti/Al/Pd/Au, Ti/Al/Cr/Au, Ti/Al/Co/Au, Cr/Al/Cr/Au, Cr/Al/Pt/Au, Cr/Al/Pd/Au, Cr/Al/Ti/Au, Cr/Al/Co/Au, Cr/Al/Ni/Au, Pd/Al/Ti/Au, Pd/Al/Pt/Au, Pd/Al/Ni/Au, Pd/Al/Pd/Au, Pd/Al/Cr/Au, Pd/Al/Co/Au, Nd/Al/Pt/Au, Nd/Al/Ti/Au, Nd/Al/Ni/Au, Nd/Al/Cr/Au Nd/Al/Co/A, Hf/Al/Ti/Au, Hf/Al/Pt/Au, Hf/Al/Ni/Au, Hf/Al/Pd/Au, Hf/Al/Cr/Au, Hf/Al/Co/Au, Zr/Al/Ti/Au, Zr/Al/Pt/Au, Zr/Al/Ni/Au, Zr/Al/Pd/Au, Zr/Al/Cr/Au, Zr/Al/Co/Au, TiNx/Ti/Au, TiNx/Pt/Au, TiNx/Ni/Au, TiNx/Pd/Au, TiNx/Cr/Au, TiNx/Co/Au, TiWNx/Ti/Au, TiWNx/Pt/Au, TiWNx/Ni/Au, TiWNx/Pd/Au, TiWNx/Cr/Au, TiWNx/Co/Au, NiAl/Pt/Au, NiAl/Cr/Au, NiAl/Ni/Au, NiAl/Ti/Au, Ti/NiAl/Pt/Au, Ti/NiAl/Ti/Au, Ti/NiAl/Ni/Au, Ti/NiAl/Cr/Au, N-type conductive indium tin oxide (ITO), cadmium tin oxide (CTO), aluminum zinc oxide (ZnO:Al), indium zinc oxide (ZnO:ln),zinc gallate (ZnGa2O4), SnO2:Sb, Ga2O3:Sn, AglnO2:Sn, In2O3:Zn, P-type conductive CuAlO2, LaCuOS, NiO, CuGaO2 or SrCu2O2.
In order to achieve the above objects and other advantages of the present invention, a metal-semiconductor-metal (MSM) type UV photodetector is provided. The UV photodetector is constructed by a substrate, a GaN-based semiconductor layer, a GaN-based interlayer and a patterned electrode layer. The GaN-based semiconductor layer is disposed on substrate. The GaN-based interlayer is disposed on GaN-based semiconductor layer, and a material of GaN-based interlayer includes, for example but not limited to, AlxInyGa1−x−yN semiconductors, wherein x≧0, y≧0, and 1≧x+y. The patterned electrode layer is disposed on GaN-based interlayer. In addition, the patterned electrode layer of embodiment described above is constructed by a first electrode and a second electrode respectively.
In the metal-semiconductor-metal (MSM)type UV photodetector of the preferred embodiment, the first electrode, for example, has a plurality of first finger-shaped protrusions which are mutually parallel aligned, and the second electrode, for example, has a plurality of second finger-shaped protrusions which are mutually parallel aligned. Moreover, the first finger-shaped protrusions and second finger-shaped protrusions, for example, are mutually interlaced.
In the metal-semiconductor-metal type UV photodetector of the present embodiment, the substrate includes, for example but not limited to, an aluminum oxide (sapphire) substrate, a silicon carbide (SiC)substrate, a zinc oxide (ZnO) substrate, a silicon substrate, a gallium phosphide (GaP) substrate, and a gallium arsenide (GaAs) substrate.
In the metal-semiconductor-metal type UV photodetector of the present embodiment, the GaN-based semiconductor layer, for example is constructed from a nucleation layer and an active layer. The nucleation layer is disposed on the substrate, and the active layer is disposed on the nucleation layer. Moreover, a material of the nucleation layer includes, for example, but not limited to, an AlaInbGa1−a−bN semiconductor, wherein a, b≧0 and 0≦a+b≦1. The material of the active layer includes, for example but not limited to, an undoped AleInfGa1−e−fN semiconductor, wherein e, f≧0 and 0≦e+f≦1.
In the metal-semiconductor-metal type UV photodetector of the present embodiment, a material of the patterned electrode layer includes, for example, but not limited to, Ni/Au, Cr/Au, Cr/Pt/Au, Ti/Al, Ti/Al/Ti/Au, Ti/Al/Pt/Au, Ti/Al/Ni/Au, Ti/Al/Ti/Au, Ti/Al/Pd/Au, Ti/Al/Cr/Au, Ti/Al/Co/Au, Cr/Al/Cr/Au, Cr/Al/Pt/Au, Cr/Al/Pd/Au, Cr/Al/Ti/Au, Cr/Al/Co/Au, Cr/Al/Ni/Au, Pd/Al/Ti/Au, Pd/Al/Pt/Au, Pd/Al/Ni/Au, Pd/Al/Pd/Au, Pd/Al/Cr/Au, Pd/Al/Co/Au, Nd/Al/Pt/Au, Nd/Al/Ti/Au, Nd/Al/Ni/Au, Nd/Al/Cr/Au Nd/Al/Co/A, Hf/Al/Ti/Au, Hf/Al/Pt/Au, Hf/Al/Ni/Au, Hf/Al/Pd/Au, Hf/Al/Cr/Au, Hf/Al/Co/Au, Zr/Al/Ti/Au, Zr/Al/Pt/Au, Zr/Al/Ni/Au, Zr/Al/Pd/Au, Zr/Al/Cr/Au, Zr/Al/Co/Au, TiNx/Ti/Au, TiNx/Pt/Au, TiNx/Ni/Au, TiNx/Pd/Au, TiNx/Cr/Au, TiNx/Co/Au, TiWNx/Ti/Au, TiWNx/Pt/Au, TiWNx/Ni/Au, TiWNx/Pd/Au, TiWNx/Cr/Au, TiWNx/Co/Au, NiAl/Pt/Au, NiAl/Cr/Au, NiAl/Ni/Au, NiAl/Ti/Au, Ti/NiAl/Pt/Au, Ti/NiAl/Ti/Au, Ti/NiAl/Ni/Au, Ti/NiAl/Cr/Au, N-type conductive indium tin oxide (ITO), cadmium tin oxide (CTO), aluminum zinc oxide (ZnO:Al), indium zinc oxide (ZnO:In),, zinc gallate (ZnGa2O4), SnO2:Sb, Ga2O3:Sn, AglnO2:Sn, In2O3:Zn, P-type conductive CuAlO2, LaCuOS, NiO, CuGaO2 or SrCu2O2.
Accordingly, in the present invention, since a high-resistivity GaN-based interlayer is provided, the leakage current of the UV photodetector is thus reduced, and therefore, the performance of the device of the UV photodetector can be enhanced. Moreover, a thermal treatment process after the epitaxy process is not required in the manufacturing of the high-resistivity GaN-based interlayer, therefore the process can be simplified.
It is to be understood that both the foregoing general description and the following detailed description are exemplary, and are intended to provide further explanation of the invention as claimed.
The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification. The following drawings illustrate embodiments of the invention and, together with the description, serve to explain the principles of the invention.
In the present embodiment, the substrate 300 includes, for example, but not limited to, an aluminum oxide (sapphire) substrate, a silicon carbide (SiC)substrate, a zinc oxide (ZnO) substrate, a silicon substrate, a gallium phosphide (GaP) substrate, and a gallium arsenide (GaAs) substrate. The high-resistivity interlayer 303 of the present embodiment is constructed by, for example but not limited to, doping at least one dopant selected from a group consisting of iron (Fe), magnesium (Mg), zinc (Zn), copper (Cu), arsenide (As), phosphorus (P), carbon (C) and beryllium (Be) or by a GaN-based semiconductor layer formed by a low temperature process (a temperature of growth less than 800° C.). The material of the high-resistivity GaN-based interlayer 303 includes, for example but not limited to, AlxInyGa1−x−yN, wherein x≧0, y≧0, and 1≧x+y.
In the present embodiment, the GaN-based semiconductor layer 302 is constructed by, for example, but not limited to, a nucleation layer 302a, an ohmic contact layer 302b and an active layer 302c. The nucleation layer 302a is disposed on the substrate 300. The ohmic contact layer 302b is disposed on the nucleation layer 302a and has a second protrusion portion D. The active layer 302c is disposed on the second protrusion portion D. Referring to
In the present embodiment, the materials of the first electrode 304 includes, for example, but not limited to, Ni/Au, Cr/Au, Cr/Pt/Au, Ti/Al, Ti/Al/Ti/Au, Ti/Al/Pt/Au, Ti/Al/Ni/Au, Ti/Al/Ti/Au, Ti/Al/Pd/Au, Ti/Al/Cr/Au, Ti/Al/Co/Au, Cr/Al/Cr/Au, Cr/Al/Pt/Au, Cr/Al/Pd/Au, Cr/Al/Ti/Au, Cr/Al/Co/Au, Cr/Al/Ni/Au, Pd/Al/Ti/Au, Pd/Al/Pt/Au, Pd/Al/Ni/Au, Pd/Al/Pd/Au, Pd/Al/Cr/Au, Pd/Al/Co/Au, Nd/Al/Pt/Au, Nd/Al/Ti/Au, Nd/Al/Ni/Au, Nd/Al/Cr/Au Nd/Al/Co/A, Hf/Al/Ti/Au, Hf/Al/Pt/Au, Hf/Al/Ni/Au, Hf/Al/Pd/Au, Hf/Al/Cr/Au, Hf/Al/Co/Au, Zr/Al/Ti/Au, Zr/Al/Pt/Au, Zr/Al/Ni/Au, Zr/Al/Pd/Au, Zr/Al/Cr/Au, Zr/Al/Co/Au, TiNx/Ti/Au, TiNx/Pt/Au, TiNx/Ni/Au, TiNx/Pd/Au, TiNx/Cr/Au, TiNx/Co/Au, TiWNx/Ti/Au, TiWNx/Pt/Au, TiWNx/Ni/Au, TiWNx/Pd/Au, TiWNx/Cr/Au, TiWNx/Co/Au, NiAl/Pt/Au, NiAl/Cr/Au, NiAl/Ni/Au, NiAl/Ti/Au, Ti/NiAl/Pt/Au, Ti/NiAl/Ti/Au, Ti/NiAl/Ni/Au, Ti/NiAl/Cr/Au, N-type conductive indium tin oxide (ITO), cadmium tin oxide (CTO), aluminum zinc oxide (ZnO:Al), indium zinc oxide (ZnO:In), zinc gallate (ZnGa2O4), SnO2:Sb, Ga2O3:Sn, AgInO2:Sn, In2O3:Zn, P-type conductive CuAlO2, LaCuOS, NiO, CuGaO2 or SrCu2O2.
Hereinafter, the electrode of the patterned electrode layer 404 and the GaN-based semiconductor layer will be described. Since the materials of the substrate 400 and the patterned electrode layer 404 are the same as that of the substrate and the GaN-based semiconductor layer described in the above embodiments, detailed description of these materials are omitted.
In the preferred embodiment, the first electrode 406 comprises, for example, a plurality of mutually parallel aligned first finger-shaped protrusions 406a, and the second electrode 408 comprises, for example, a plurality of second finger-shaped protrusions 408a. Moreover, the first finger-shaped protrusions 406a and the second finger-shaped protrusions 408a are, for example, mutually interlaced. The high-resistivity interlayer 403 of the embodiment is constructed by doping at least one dopant selected from a group consisting of iron (Fe), magnesium (Mg), zinc (Zn), copper (Cu), arsenide (As), phosphorus (P), carbon (C) and beryllium (Be) or by a GaN-based semiconductor layer formed by a low temperature process (a temperature of growth less than 800° C.). The material of the high-resistivity GaN-based interlayer 403 includes, for example, AlxInyGa1−x−yN, wherein x≧0, y≧0, and 1≧x+y.
In the present embodiment, the GaN-based semiconductor layer 402 is constructed, for example, by a nucleation layer 402a and an active layer 402b. The nucleation layer 402a is disposed on substrate 400, and the active layer 402b is disposed on the nucleation layer 402a. Moreover, a material of the nucleation layer 402a includes, for example, but not limited to, AlaInbGa1−a−bN semiconductor, wherein a, b≧0 and 0≦a+b≦1. The material of the active layer 402b includes, for example, but not limited to, undoped AleInfGa1−e−fN semiconductor, wherein e, f≧0 and 0≦e+f≦1.
Accordingly, an UV photodetector provided by the present invention have at least the following advantages. First, since a high-resistivity GaN-based interlayer is provided to reduce the leakage current of the UV photodetector, the performance of the device of the UV photodetector can be enhanced. Moreover, in the present invention, a high temperature thermal treatment process following an epitaxy process is not required during the manufacturing of the GaN-based interlayer, and therefore the process can be simplified.
It will be apparent to those skilled in the art that various modifications and variations can be made to the structure of the present invention without departing from the scope or spirit of the invention. In view of the foregoing, it is intended that the present invention cover modifications and variations of this invention provided they fall within the scope of the following claims and their equivalents.
Number | Date | Country | Kind |
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92119489 | Jul 2003 | TW | national |