This invention concerns a vacuum arc source for operating an arc discharge according to claim 1, a system outfitted with such an arc source in claim 17, and a method of operating an arc discharge in claim 21.
Arc sources, as they are known in a vacuum chamber for vaporizing different materials and/or as ion sources, are used for coating and pre-treating different workpieces. Because of the high built-in energy pointing at the target surface of the arc, hereinafter called a spark, moving on the target surface of the arc source, besides the emission of gaseous, for the most part ionized particles, especially with spark “burnout” and the resultant explosive-type vaporization, there are also emissions of macroparticles, whose diameter can run up to several micrometers or more. After coating, the surface roughness of previously polished workpieces, for example, is basically determined by the number and size of the macroparticles adhering to the surface of the layer or grown into it. Therefore, layers deposited in this way are relatively rough, which has a negative effect when a coated tool or component is used. Furthermore, a large number of macroparticles leave the surface of the target at a relatively flat angle, and valuable material is lost in coating processes and deposited on the inside of the vacuum chamber.
Different solutions have been proposed for depositing smoother layers. For example, arc sources were placed outside the optical line of sight of the workpiece and ionized particles were guided in the direction of the workpieces by means of magnetic fields, whereby smoother layers were achieved at high technical expense, but the coating rate basically decreased at the same time.
Different arc sources have also been developed to move the spark as quickly as possible on a defined path over the target surface and to prevent too much energy from getting onto a small surface or even “burnout.” The spark was therefore forced onto a closed circuit by one or more magnets moved behind the target, for example.
Another way of controlling the spark is described in U.S. Pat. No. 5,298,136. This document is regarded as the most recent state of the art. An arc source disclosed there has a circular target, which is surrounded laterally from the back by a cup-shaped pole shoe with a central pole piece on the back of the target and a coil in between. This produces a magnetic field over the target, whose vertical component has a positive maximum in the middle of the target, falls symmetrically to smaller values to a negative minimum on the rim and then rises asymptotically in the direction of the abscissa. Similar magnetic fields can also be produced by placing permanent magnets on the back of the target, as known. Here the zero passage of the field lines going through the abscissa (i.e. zero passage corresponds to a change in field direction) on the target surface is a closed (circular) line on which the perpendicular component of the magnetic field is zero.
On this zero line, the spark entering the target from the plasma, with a target connected via the cathode for example, in the technical direction of the current, experiences not radial, but high tangential acceleration, since the parallel component of the magnetic field has a maximum on the same line. The high rotational speed of the spark achieved in this way effectively prevents “seizing,”but at the same time causes poor target utilization, since basically only a narrow circular ring of the target is removed.
To improve this, a solenoid coil surrounding the target and the pole shoe was also provided in the upper area, with which the radius of the zero line produced by the pole shoe and the coil placed in it can be moved radially.
However, the technical expense necessary for this is relatively high, since an independent current/voltage control unit is provided for both coils, whereby at least one of them must be suited for giving off time-altered current/voltage signals, in order to make periodic expansion/contraction of the zero line possible on the target. In any case, despite the high expense, on this type of arc source, a relatively large area in the middle of the target is removed very little or not at all.
The problem of this invention is to remove the disadvantages in the state of the art that have been mentioned.
The problem is especially to make a vacuum arc source and a method of operating an arc discharge that allows generally improved, more economical treatment processes with higher layer quality compared to the source or sources used conventionally or compared to the conventional methods. This involves the following points in particular:
To solve this problem, the invention proposes a vacuum arc source in claim 1, a vacuum system in claim 17 and a procedure according to the method in claim 21.
Surprisingly, it has been shown that when a magnetic field is set to the surface of a target whose perpendicular component B⊥ runs over a large part of the surface basically constantly near or at zero, a spark path is made possible in which the spark runs quickly and evenly over the entire target surface or at least the greater part of it. This way, on one hand, the spark area melted by individual sparks per unit of time on the target surface remains small, and the size and number of macroparticles emitted from the molten bath is reduced. On the other hand, a better yield can be achieved with it than with a spark forced to run over a relatively small area of the target.
Advantageously, the magnetic field component B⊥ chosen is smaller than 30, preferably smaller than 20, and highly preferably smaller than 10 Gauss. On the rim of the target surface, the values B⊥R of the perpendicular magnetic field component can be set to rise, fall and/or change signs in the middle of the target surface.
The greater part of the surface, i.e., the area in which the perpendicular component B⊥ runs basically constantly near or at zero, extends advantageously from the middle of the target surface up to the rim and includes at least 50%, but preferably at least 60% of the geometrically determining mass or masses. In the case of a square target, for example, at least 50% or 60% of sides a, b, in the case of a circular target, at least 50% or 60% of the radius. On the rim of the target surface, the values B⊥R of the perpendicular magnetic field component can be set to rise, fall and/or change signs compared to the values B⊥ in the middle of the target surface.
The value of the parallel magnetic field component B∥ can also basically be set at zero in the middle, in the direction of the rim of the target surface but rise, preferably rise symmetrically toward the middle of the target. For example, if a magnetic field with an approximately linearly rising component B∥ is applied to circular targets from the rim to near the middle, the force acting on the spark tangentially clockwise or counterclockwise toward the rim of the target rises, whereby the spark can run over the radius at an approximately constant angular speed.
Such a magnetic field can be produced with a vacuum arc source with a device for producing a magnetic field that includes at least two magnet systems with opposite poles.
The following embodiments describe, by way of example, various vacuum arc sources with which such a magnetic field can be produced over the target surface.
As the first of the at least two oppositely poled magnet systems, a first electromagnetic coil can be provided, which can in turn be made up of several coils. Advantageously, the inner dimensions of the first coil basically coincide with a deviation of a maximum of plus/minus 30%, preferably plus/minus 20% with the projection of the outer dimensions of the surface of the target. When a voltage is applied from the coil, which then has current flowing through it, a homogeneous magnetic field is produced running basically perpendicular to the surface of the target. The small parallel component of the magnetic field on the greater part of the surface in relation to the perpendicular component is zero in the middle of the surface and rises toward the rim. It is possible, but not very practical to use an even larger first coil; when smaller diameters are used, the parallel portion is too large, or there is even an unwanted change in field direction. Such fields can be produced with solenoid, i.e., source-free coils, without additional pole shoes or magnetic cores. The portion of the parallel component of the magnetic field increases or decreases depending on the distance to the target surface and the diameter of the coil.
Another way of making the first magnet system can consist of one or more permanent magnets placed behind the target, or behind a cooling plate attached to the back of the target. The magnetic fields produced on the target surface should correspond roughly to one field of a solenoid coil, as described above, i.e., be relatively small. Therefore, the permanent magnets should either have low field strength themselves or be spaced accordingly from the target. Care should also be taken that here again, as in the use of a coil as described above, no reversal of field direction on the target surface is brought about by the first magnet system. An arrangement known from the state of the art with alternating poles between the middle and the rim areas must also be avoided. One simple possibility offered here is to use thin, so-called plastoferrite magnets, which, depending on the field strength to be set, can be placed in the form of single or multilayer disks or polygons on the back of the target as uniformly as possible, as above, into an area of plus/minus 30%, preferably plus/mnuus 20% of the outer dimensions of the surface of the target.
Advantageously, at least one coil including the first magnet system and arranged coaxially to it is provided as the second magnet system. It can, for example, be arranged laterally including the first magnet system or taraget or preferably be placed behind the first magnet system or target.
It is also advantageous for a second coil placed behind the first magnet system to have a larger diameter than that of the first magnet system or the first coil. Likewise, a larger number of windings has proven effective, since that makes it easier to set the perpendicular magnetic field basically at zero in connection with the working of the first magnet system on the surface. With the same number of windings, this effect must be set by a basically higher current flow, whereby there can be a thermal overload of the second coil. In addition, with such a second, in this case more powerful coil, a second magnet system oriented against the effect of the first magnet system can produce a magnetic field that works in the vacuum chamber and allows the otherwise diffuse arc plasma to be bundled into a plasma beam, also called a plasma jet. Here, the opposite parallel components of the two magnet systems, depending on their distance from the target, cancel each other out in part or in full, which causes the bundling, while the more powerful perpendicular field of the second magnet system is canceled out only in the direct area of the target surface by the weaker first magnet system. This is an advantage since a stream of particles directed at the workpiece being treated can be produced, which, for example, allows higher etching rates or faster layer growth and because the process time that can be achieved is shortened, lengthens the general tool life of the target.
Placing the first and second magnet systems behind the target also has the advantage that both magnet systems can be mounted so they are accessible from the outside and not exposed to high temperatures and potential coating in the treatment chamber.
A comparable effect can also be achieved with a coil placed some a distance in front of the target. If a coil is also used as the first magnet system, the second coil can now be made similarly or even the same. With such a more or less symmetrical arrangement of the spools opposite the target plane, the magnetic field of the second must not necessarily larger than that of the first coil to produce a plasma jet, whereby both coils can be operated with similar geometries and with a common current/voltage source. The magnetic field can be fine-tuned simply with adjustable resistors or by adjustable spacing at least of one coil. Since, in this case, the second magnet system is exposed to the stream of particles from the arc source, additional protective measures like cooling or removable protective clothing or other known measures must be provided to guarantee constant operation.
If at least one coil is used for both the first and for the second magnet system, the voltage source or sources must be applied, as is easy to follow from the explanations given above, so that the coil currents flow in opposite directions, i.e., basically clockwise or counter-clockwise.
As described above, devices producing magnetic fields are suitable for use with arc sources that operate with both cathodes and anodes, especially flat ones, and can easily be set for different target materials and/or target thicknesses, when at least one coil is used, for example by changing the coil current, but also by changing the distance of at least one magnet system from the target surface. The target geometry can be adjusted to the respective need, and corresponding devices for producing magnetic fields can be made according to the invention, for example for both round and square or polygonal sources.
It is therefore not necessary to change the coil current or currents during an etching or coating process, although it is possible in principle. The spark or sparks also run in a random pattern similar to so-called “random arc” sources over the target surface, but are directed or accelerated by the magnetic fields of the arc source made according to the invention, so that the sparks are distributed more finely and the spatter frequency is much reduced. Astonishingly, no seizing of the spark can be found in the middle of the target, where both perpendicular and parallel magnetic field components are very small or zero.
Due to the directional effect that can be achieved by the arc source in the invention, the plasma beam produced can also be controlled advantageously by a magnetic field produced in the chamber of the vacuum treatment system. For example, if one or more arc sources is arranged in the direction of the axis of a vacuum treatment system and at the same time at least one other electromagnetic coil placed concentrically to the axis of the system is provided, then the plasma beam produced by the arc source can be deflected. If at least one other coil is connected to a time-altered current source with a control unit, the plasma beam can be directed variably at different areas in the chamber. For example, the plasma beam can be directed past the workpieces for etching processes or preferably periodically over the workpieces for coating processes.
Here it has proven advantageous, at least with a symmetrical arrangement of several sources around a system axis, to choose a coil arrangement with which the most uniform possible axis-parallel field can be produced in the chamber. This is achieved, for example, by a system with at least two other electromagnetic coils, in which the other coils are preferably arranged in the upper and lower or corresponding lateral border areas of the system concentric to the axis of the system. The coils can then have a different diameter or basically the same diameter, corresponding to a Helmholz coil arrangement.
The invention will now be explained using schematic figures, by way of example.
∥ path for optimal operation
∥path for spark in middle
∥ path for spark on rim
As targets, circular blanks, for example, with a diameter of 160 mm and a thickness of 6 mm can be made of different materials like Ti or TiAl, for example. Larger and smaller target thicknesses and other shapes are possible, as is known to a person skilled in the art. The coil geometry and a sample setting of the coil currents can be seen in Table 1. To achieve the desired effect, the two coils are connected to the line devices so that the currents flowing through the two coils run in opposite directions electrically.
*Resistance when cold.
Preferred operating parameters and limits for operating a corresponding arc source are summarized in Table 2 (target diameter approx. 160 mm, d=6-12 mm, target material: Ti or TiAl).
Table 3 also shows examples of kinds of operations depositing TiN or TiAlN, whereby a so-called bias voltage was applied to the substrate.
The experiments were done on an RCS coating system from the Balzer Company with an octagonal cross section and approx. 1000-liter coating volume. The diameter of the coating chamber was 1070 mm, the height 830 mm.
Generally, a charged particle moved in the magnetic field is deflected by the force F=Q (v×B). Here, F is the force exerted on a charge Q moved in the magnetic field, V is the speed of the charge Q moved at right angles to the field lines and B is the magnetic induction of the field. If one considers the current flow of a spark directed basically perpendicular to the target surface, while neglecting the small influence on the applied magnetic field by the electromagnetic field of the target cathode, then the charged particle experiences, due to a force F∥ directed parallel to the surface and thus perpendicular to the current flow Iarc of a radially symmetrical magnetic field B∥, an acceleration of the spark path at right angles to the field line, i.e., depending on the field direction clockwise or counter clockwise. Against it a magnetic field component B⊥− or B⊥+ of the outer magnetic field perpendicular to the target surface brings about first a deflection of the charge carrier of the current flow Iacr coming in perpendicular, since the cross product of the vectors V×B here is zero. Only after the spark goes through a counter-clockwise deflection, shown for example in top view, due to the deflection when it hits the target surface, and also has a speed component parallel to the target surface, are the two forces F∥
As mentioned in the consideration of the state of the art, this effect can be used by a two-coil arrangement with a time-altered current feed in order to move the spark along a radially moveable zero line of the perpendicular magnetic field component B⊥ over the target surface.
As an example of a known magnetic field made up of permanent magnets,
In the middle of the target, as shown in
The magnetic field produced in this way is characterized by a path of the perpendicular component that is constant over a wide range, unlike as in
Like
When such an arc source is operated, it can be seen that there is a fine ramification of the arc current into many small sparks, which run off the whole area of the target. The magnetic field created by superimposing the two coil fields also forms a far field, which makes the plasma bundle into a plasma jet, which can in turn be deflected by additional coils. Since with the same target capacity, removal is at least as large as for conventional arc sources, the coating rate is higher when the stream of ions is aligned in the direction of the workpiece 3. This bundling can be set to the requirements to a large extent, for example by setting the coil currents to the respective, especially geometric ratios, like for example the desired coating height, substrate target distance, etc.
FIGS. 11 to 16 show the paths produced at different settings of the coil current of the B⊥ and B∥ components of the magnetic field on the surface of the target. The arc sources were operated according to the operating parameters described in
It was also found that B⊥ distribution on both sides of the zero line allows higher differences in magnetic field strength, i.e., more non-uniform B⊥ distribution on the surface of the target, with approximately constant finely and uniformly distributed spark path than B⊥ distribution lying completely over or under the zero line.
Number | Date | Country | Kind |
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2163/02 | Dec 2002 | CH | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/CH03/00710 | 10/30/2003 | WO | 12/23/2005 |