This invention relates to vacuum cleaners which have a cyclonic separation apparatus. In another aspect, the invention relates to an electrostatic precipitator.
Cyclone separators, which are sometimes referred to merely as cyclones, are devices that utilize centrifugal forces and low pressure caused by spinning motion to separate materials of differing density, size and shape.
Cyclone separator 10 has an inlet pipe 12 and a main body comprising upper cylindrical portion 14 and lower frusto-conical portion 16. The particle laden air stream is injected through inlet pipe 12 which is positioned tangentially to upper cylindrical portion 14. The shape of upper cylindrical portion 14 and frusto-conical portion 16 induces the air stream to spin creating a vortex. Larger or more dense particles are forced outwards to the walls of cyclone separator 10 where the drag of the spinning air as well as the force of gravity causes them to fall down the walls into an outlet or collector 18. The lighter or less dense particles, as well as the air medium itself, reverses course at approximately collector G and pass outwardly through the low pressure centre of separator 10 and exit separator 10 via air outlet 20 which is positioned in the upper portion of upper cylindrical portion 14.
The separation process in cyclones generally requires a steady flow free of fluctuations or short term variations in the flow rate. The inlet and outlets of cyclone separators are typically operated open to the atmosphere so that there is no pressure difference between the two. If one of the outlets must be operated at a back pressure, both outlets would typically be kept at the same pressure.
When a cyclone separator is designed, the principal factors which are typically considered are the efficiency of the cyclone separator in removing particles of different diameters and the pressure drop associated with the cyclone operation. The principle geometric factors which are used in designing a cyclone separator are the inlet height (A); the inlet width (B); the air outlet diameter (C); the outlet duct length (D); the cone height (Lc); the dirt outlet diameter (G); and, the cylinder height (L)
The value d50 represents the smallest diameter particle of which 50 percent is removed by the cyclone. Current cyclones have a limitation that the geometry controls the particle removal efficiency for a given particle diameter. The dimensions which may be varied to alter the d50 value are features (A)–(D), (G), (L) and (Lc) which are listed above.
Typically, there are four ways to increase the small particle removal efficiency of a cyclone. These are (1) reducing the cyclone diameter; (2) reducing the outlet diameter; (3) reducing the cone angle; and (4) increasing the body length. If it is acceptable to increase the pressure drop, then an increase in the pressure drop will (1) increase the particle capture efficiency; (2) increase the capacity and (3) decrease the underflow to throughput ratio.
In terms of importance, it appears that the most important parameter is the cyclone diameter. A smaller cyclone diameter implies a smaller d50 value by virtue of the higher cyclone speeds and the higher centrifugal forces which may be achieved. For two cyclones of the same diameter, the next most important design parameter appears to be L/d, namely the length of the cylindrical section 14 divided by the diameter of the cyclone and Lc/d, the length of the conical section 16 divided by the width of the cone. Varying L/d and Lc/d will affect the d50 performance of the separation process in the cyclone.
Due to its intended use, a vacuum cleaners is designed to filter particles of varying sizes from an air stream. With most vacuum cleaners on the market, a filter material such as a paper bag is used to filter the air. The bag will remove from the air stream any particle larger than the size of the pore in the bag. Thus only a single stage of filtration may be employed. However, if a cyclone is used in a vacuum cleaner, then multiple filtration stages may be employed. This is due to the fact that particle sizes which are generally to be filtered by a vacuum cleaner take on a spectrum of values that necessitates that a plurality of cyclonic separators be used in a series. For example, the first cyclonic separator in a series may have a large d50 specification followed by one with a smaller d50 specification.
For example, in U.S. Pat. No. 3,425,192, a vacuum cleaning assembly was disclosed which used a first frusto-conical cyclone and six secondary cyclones.
More recently, cyclonic technology has been improved and introduced commercially into canister and upright vacuum cleaners. See for example U.S. Pat. No. 4,593,429. This patent discloses a vacuum cleaner design in which sequential cyclones are utilized as the filtration medium for a vacuum cleaner. Pursuant to the teaching of this patent, the first sequential cyclone is designed to be of a lower efficiency to remove only the larger particles which are entrained in an air stream. The smaller particles remain entrained in the air stream and are transported to the second sequential cyclone which is frusto-conical in shape. The second sequential cyclone is designed to remove the smaller particles which are entrained in the air stream. If larger particles are carried over into the second cyclone separator, then they will typically not be removed by the cyclone separator but exit the frusto-conical cyclone with the air stream.
One disadvantage of cyclonic vacuum cleaners is the amount of power which is required to create an air flow sufficient to convey the dirty air through the cyclones at sufficient speeds to maintain the air flowing cyclonically through the cyclones.
In order to achieve high levels of particle removal, cyclonic vacuum cleaners which are currently on the market incorporate a HEPA™ filter. Such filters are effective in removing small particulate matter from the air stream so that the air which exits the vacuum cleaner is essentially for refiltered. One disadvantage of such HEPA™ filters is that they provide substantial resistance to the flow of air there through. By removing the HEPA™ filter, the pressure drop which occurs during the passage of the air through the filter assembly of a vacuum cleaner may be reduced by, eg., up to 20%. Accordingly, by removing the HEPA™ filter, the flow rate through the vacuum cleaner may be substantially increased and/or the size of the motor may be reduced by eg., up to 20%. However, the amount of particulate matter which will be contained in the dirty air stream will be increased.
The instant invention provides an alternate approach to the use of such HEPA™ filters. Electrostatic filters generally provide minimal resistance to the flow of air and accordingly do not generally provide much of the pressure drop as an air stream passes there through. The electrostatic filter may be designed to remove the same size particles as are removed by the HEPA™ filter which is currently in use. Alternately, the electrostatic filter may be designed to remove even larger particles. Accordingly, by using an electrostatic filter, the pressure drops for a vacuum cleaner may be substantially reduced (compared to a vacuum cleaner using a HEPA™ filter). Further, the electrostatic filter may provide enhanced particle remover compared to even a HEPA™ filter and accordingly the clean air outlet from the vacuum cleaner may produce air which is even cleaner than that which is achieved from commercially available cyclonic vacuum cleaners which even incorporate at HEPA™ filter.
In accordance with the instant invention, there is also provided a vacuum cleaner comprising:
In one embodiment, the at least one cyclonic cleaning stage comprises at least a first cyclonic cleaning stage and a second cyclonic cleaning stage downstream from the first cyclonic cleaning stage.
In another embodiment, the at least one electrostatic precipitator is positioned in the air flow path downstream from the first cyclonic cleaning stage and upstream of the second cyclonic cleaning stage.
In another embodiment, the at least one electrostatic precipitator is positioned in the air flow path downstream from the second cyclonic cleaning stage and upstream of the clean air outlet.
In another embodiment, the first cyclonic cleaning stage comprises one cyclone and the second cyclonic cleaning stage consists of from two to five second cyclones.
In another embodiment, the second cyclonic cleaning stage removes particulate material larger than that which is removed by the at least one electrostatic precipitator.
In another embodiment, the at least one cyclonic cleaning stage comprises a cyclone chamber removably mounted in a housing and the at least one electrostatic precipitator comprises an electrostatic. precipitator removably mounted in the cyclone chamber.
In another embodiment, the cyclone chamber has an air outlet and the electrostatic precipitator is positioned in the air outlet of the cyclone chamber.
In another embodiment, the cyclone chamber has an air outlet and the electrostatic precipitator is removably mounted in the air outlet of the cyclone chamber.
In accordance with the instant invention, there is provided a vacuum cleaner for receiving and cleaning a dirty air stream to obtain clean air comprising:
In one embodiment, the vacuum cleaner further comprises second means for further cyclonically treating the dirty air stream positioned downstream from the first means for cyclonically treating a dirty air stream.
In another embodiment, the electrostatic precipitation means is positioned in the air flow path downstream from the first means for cyclonically treating the dirty air stream and upstream of the second means for further cyclonically treating the dirty air stream.
In another embodiment, the electrostatic precipitation means is positioned in the air flow path downstream from the second means for further cyclonically treating the dirty air stream and upstream of the clean air outlet.
In another embodiment, the second means for further cyclonically treating the dirty air stream removes particulate material larger than that which is removed by the electrostatic precipitation means.
In another embodiment, the first means for cyclonically treating the dirty air stream is removably mounted in a housing and the electrostatic precipitation means is removably mounted with the first means for cyclonically treating the dirty air stream.
In another embodiment, the first means is removably mounted in n the vacuum cleaner.
In accordance with the instant invention, there is also provided an electrostatic precipitator for separating chargeable particulate matter from a fluid stream comprising:
In one embodiment, the electrostatic precipitator further comprises a directing member to cause the fluid to rotate the at least one member.
In another embodiment, the at least one member and at least a portion of the housing is constructed from a material that will produce a potential difference between the at least one member and the portion of the housing due to frictional contact of the at least one member with the housing as the at least one member moves in the housing due to the flow of fluid through the housing.
In accordance with the instant invention, there is also provided an electrostatic precipitator for separating chargeable particulate matter from a fluid stream comprising:
In another embodiment, the electrostatic precipitator further comprises a directing means to cause the fluid to rotate the individual chargeable means.
In another embodiment, the individual chargeable means and at least a portion of the housing means is constructed from a material that will produce a potential difference between the individual chargeable means and the portion of the housing means due to frictional contact of the individual chargeable means with the housing means as the individual chargeable means moves in the housing means due to the flow of fluid through the housing means.
As will be appreciated, the electrostatic filter may comprise the portion of the filter assembly of the vacuum cleaner to remove the smaller particles from the dirty air stream. For example, in a vacuum cleaner having first and second cyclonic separation stages, the first cyclonic separation stage is preferably configured to remove the coarsest particles from the air stream and the second cyclonic separation staged is preferably configured to remove the smallest particles from the air stream while the electrostatic filter is designed to remove particles having an intermediate size. Thus, if the second cyclonic separation stage is positioned after the electrostatic filter, then the second cyclonic separation stage may be configured to remove the particles which are not filtered by either the first cyclonic separation stage or the electrostatic filter. As the second cyclonic separation stage need not be designed to remove the finest particulate matter, it may be of a lower efficiency then would otherwise by useable and accordingly may have a larger diameter. By increasing the diameter of second stage cyclones, the pressure drop across each second stage cyclone will be reduced thereby producing a further reduction in the pressure drop which occurs by the passage of air through the filter assembly of the vacuum cleaner and further reducing the power (size of motor) which is required.
If the electrostatic filter is positioned between the first and second cyclonic separation stages, the finest particulate matter is removed prior to the second cyclonic separation stage treatment of the air. The removal of the fine particulate matter prior to this stage prevents this particulate matter from entering the second stage cyclones and contaminating the interior surface of the second stage cyclones.
In a further alternate embodiment, the first and second cyclonic separation stages may be positioned prior to the electrostatic filter.
In a further preferred embodiment, the electrostatic filter is removable so that it may be cleaned, such as by rinsing with water to remove the particulate matter which is collected thereon.
These and other advantages of the instant invention will be more fully and particularly understood in connection with the following description of the preferred embodiments of the invention in which:
The filter assembly of the instant invention may be used in conjunction with any vacuum cleaner. For example, the filter assembly may be used for an upright vacuum cleaner, a canister vacuum cleaner or a central vacuum cleaner or the like. The dirty air stream which is processed using the filter assembly described herein may be collected by, for example, a wand or rotating brush positioned in the head of a vacuum cleaner as is known in the art. Such dirty air streams typically comprise dirt of varying particle sizes entrained in an air stream. It will be appreciated that the invention may also be used with a wet/dry vacuum cleaner.
The filter assembly may be used in conjunction with any design known in the art. For example, as shown in
Referring to
The dirty air may be introduced into first cyclone 32 by any means known in the art. In the embodiment of
As shown in
Container 120 is preferably removable from the vacuum cleaner by any means known in the art. When the container comprising bottom 40 and sidewalls 38 is positioned in the vacuum cleaner, it may abut against lower panel 54 in sealing engagement so as to provide an air tight enclosure but for outlet 36.
The further cleaned air which exits electronic filter 50 passes through outlet 56 to a one or more second stage cyclones 60. The number of second stage cyclones may vary depending upon, inter alia, the type of particulate matter which is to be filtered, the degree of separation which is required and the amount of pressure drop which is acceptable based upon the motor which is provided to the vacuum cleaner. Second cyclones 60 may also be of any particular design known in the art and may be the same or different from first stage cyclone 32. Further, each second stage cyclone 60 need not be the same.
As shown in
In the alternate embodiment shown in
Clean air from clean air outlet 74 may be fed to a motor positioned above clean air outlet 74 and, if desired, to further filtration means, such as additional cyclones (i.e. third stage cyclones), a HEPA™ filter or a further electrostatic filter.
In these embodiments, electronic filter 50 may be of and, particular construction known in the art. Various constructions for electrostatic devices which use charged regions to remove particulate matter from an air stream are known.
In a particular preferred embodiment, electronic filter 50 comprises an electrostatic precipitator. The electrostatic filter is preferably designed to remove the smallest portion of the particulate matter from the air stream (eg. up to 30 microns). However, the actual level of filtration which may be achieved by the electrostatic filter will vary depending upon the design of filter 50.
Cyclone bin 120 has an air inlet 34, preferably at upper end 136 thereof, adapted for providing an air flow tangentially to an inner dirt rotation surface or wall 38 of container 120. Air inlet conduit 138 may alternately be configured to provide an axial flow of air to container 120 and opening 34 at the downstream end of air inlet conduit 138 may have vanes to impart cyclonic flow to the air stream. Preferably, air inlet conduit 138 is configured to introduce the air tangentially to container 120. As shown in
Upstream and downstream portions 116 and 118 may comprise a single member (whether integrally formed or connected together to form a continuous flow path) in which case a separated dirt collection means may be positioned below container 120. Alternately portions 116 and 118 may be flexible so as to allow cyclone container 120 to be removed from housing 106 and emptied. In the preferred embodiment of
Preferably, downstream portion 118 and container 120 are a one piece assembly so that when container 120 is removed from housing 106, downstream portion 118 is automatically removed at the same time. Thus, downstream portion 118 may be manufactured as part of container 120 (such as by moulding it integrally therewith). Alternately, it may be separately manufactured (such as by extrusion) and subsequently affixed to container 120 by any means known in the art (eg. by welding, engagement of male and female engagement members of the like).
In operation, the vacuum fan motor 122 is activated to induce an air flow through vacuum cleaner 100. The air flow causes a partial vacuum to form at end 124. Air, and entrained dirt, is drawn into upstream portion 116, with the aid of brush member 140. The dirty air flow moves vertically in downstream portion 118 to opening 34 in air inlet conduit 138 and is introduced tangentially to container 120. The airflow is then accelerated around wall 38 and proceeds generally downwardly along and around wall 38 until it reaches a position towards bottom 40 of container 120, at which point the air flow travels upwardly through the central portion of cyclone container 120. Wall 142, an extension of outlet 36, may be provided in container 120. Wall 142 assists in preventing the treated air travelling upwardly to outlet 36 from mixing with the dirty air which is introduced into container 120 via inlet conduit 138.
The removability of container 120 from housing 106 of vacuum cleaner 100 is shown by reference to
Container 120 may be lockingly received in housing 106 by any means known in the art. In the preferred embodiment, container 120 is provided with a lid 150 which has a recess 152 provided in handle 154 thereof. Container 120 and lid 150 comprise a cyclone chamber which is removable received in housing 106. Lower surface 156 of upper portion 146 of housing 106 is provided with a protrusion 158 which is receivable in recess 152. By moving handle 154 downwardly to the position shown in dotted outline in
The cleaned air travels upwardly out above container 120 Accordingly, lid 150 is provided with an upper surface 160. Cylindrical wall 142 extends downwardly from upper surface 160. The intersection of upper surface 160 and wall 142 describes opening 36 which is the clean air outlet.
As can be seen in
Lid 150 may be releasably mounted to container 120 by any means known in the art. Referring to
Referring to
As shown in
As shown in
Members 210 and sidewalls 182 are constructed from any material which will generate the high voltage potential and transmit it to conductive layer 204 due to the rotation (eg. cyclonic flow) of members 210 in container 180. Preferably, members 210 are made from styrofoam and walls 182 are constructed from a plastic. The friction of styrofoam balls 210 against one or more of sidewalls 182, bottom 184 and top 186 produce the high voltage potential. It will be appreciated that members 210 may be of any aerodynamic shape the will travel within container 180 to produce frictional engagement with the walls of container 180 due to the air flow there through.
Means is provided to cause members 210 to move within container 180 so that a high voltage potential develops between members 210 and container 180. Preferably, at least one of the air inlets 196, and preferably each of the air inlets 196, are configured so as to cause the air to circulate or rotate within container 180 and entrain members 210. It will be appreciated that directing vanes or the like may also be included with filter 50 (inside or outside container 180) so as to cause the air to circulate within container 180. The vanes, air inlets 196 or the like define means which cause members 210 to move sufficiently within container 180 so as to develop a high voltage potential between members 210 and container 180. In the preferred embodiment of
A conductive layer 204 is provided for receiving and conducting the high voltage potential to electrode means for imparting a corona discharge to particles 212 which are entrained in the air stream travelling towards filter 50. Preferably, the electrode means is positioned upstream from container 180 so as to charge particles 212 prior to their entry into container 180. Referring to
It will be appreciated that electrodes 208 may be of any configuration that will produce a corona discharge so as to charge particles 212 oppositely to the charge of styrofoam balls 210. As shown in
When particles 212 in the air stream come into proximity or in contact with styrofoam balls 210, they are electrostatically attracted to each other as they are oppositely charged. Thus, particles 212 are removed from the air stream and the treated air exits top 186 via outlets 202.
Container 180 may be positioned at any position in the dirty air flow path of the vacuum cleaner. For example, as shown in
Electrostatic filter 50 may be removably receivably mounted in outlet 36 by any means known in the art. Referring to
In another embodiment, the vacuum cleaner may be powered by battery 220 (see
It will be appreciated that the preferred embodiment of the electrostatic precipitator 50 of
The cleaned air after passing motor 122 may then exit housing 106 via outlet 132 or it may first optionally pass through chamber 134, which may contain a further filtration means (eg. a HEPA™ filter) an a further electrostatic filtration means.
It will be appreciated by those skilled in the art that various additions and modifications may be made to the instant invention and all of these are within scope of the following claims.
This applicatin is a continuation of U.S. application Ser. No. 10/043,337, now allowed, which is a continuation of U.S. patent application Ser. No. 09/478,891 filed on Jan. 7, 2000 which has issued as U.S. Pat. No. 6,383,266 which is a continuation-in-part of U.S. patent application Ser. No. 09/227,712 filed on Jan. 8, 1999 which has issued as U.S. Pat. No. 6,238,451.
Number | Name | Date | Kind |
---|---|---|---|
450372 | Morse | Apr 1891 | A |
883413 | Mahony | Mar 1908 | A |
1023082 | Kluge | Apr 1912 | A |
1127896 | Keller | Feb 1915 | A |
1369939 | Shaffer | Mar 1921 | A |
1752231 | Clarkson | Mar 1930 | A |
1759947 | Lee | Mar 1930 | A |
1798510 | Winkslow et al. | Mar 1931 | A |
1826798 | Lee | Oct 1931 | A |
1897144 | Prouty | Feb 1933 | A |
1937765 | Leathers | Dec 1933 | A |
2014287 | Newman | Oct 1935 | A |
2143421 | Loehr et al. | Jan 1939 | A |
2171248 | Van Berkel | Sep 1939 | A |
2267764 | Taylor | Dec 1941 | A |
2300266 | Smellie | Oct 1942 | A |
2392872 | Wolfe | Jan 1946 | A |
2397872 | Kovacs | Apr 1946 | A |
2397980 | Petri | Apr 1946 | A |
2402845 | Rodman | Jun 1946 | A |
2405625 | Whiton et al. | Aug 1946 | A |
2595752 | Batts | May 1952 | A |
2608268 | Gerber | Aug 1952 | A |
2672642 | Tamarin et al. | Mar 1954 | A |
2681124 | Van der Kolk | Jun 1954 | A |
2822060 | Udovich | Feb 1958 | A |
2993223 | Krammes | Jul 1961 | A |
D197459 | Jepson et al. | Feb 1964 | S |
3200568 | McNeil | Aug 1965 | A |
3235090 | Bose et al. | Feb 1966 | A |
3283480 | Szego | Nov 1966 | A |
3320727 | Farley et al. | May 1967 | A |
3425192 | Davis | Feb 1969 | A |
3501014 | Fitch, Jr. et al. | Mar 1970 | A |
3535854 | Taylor | Oct 1970 | A |
3675268 | Nordeen | Jul 1972 | A |
3853518 | Tu et al. | Dec 1974 | A |
3877902 | Eriksson et al. | Apr 1975 | A |
3925045 | Cheng | Dec 1975 | A |
3955236 | Mekelburg | May 1976 | A |
4005998 | Gorman | Feb 1977 | A |
4141698 | Kihlstedt et al. | Feb 1979 | A |
4162149 | Mekelburg | Jul 1979 | A |
4172710 | Van Der Molen | Oct 1979 | A |
4198290 | Summers | Apr 1980 | A |
4251241 | Bothun | Feb 1981 | A |
4251368 | Colman et al. | Feb 1981 | A |
4268288 | Coombs | May 1981 | A |
4326862 | Suzuki | Apr 1982 | A |
4345572 | Suzuki et al. | Aug 1982 | A |
4352681 | Dietz | Oct 1982 | A |
4373228 | Dyson | Feb 1983 | A |
4377882 | Dyson | Mar 1983 | A |
4390426 | Vicard | Jun 1983 | A |
4398928 | Kunsagi | Aug 1983 | A |
4443234 | Carlsson | Apr 1984 | A |
4571772 | Dyson | Feb 1986 | A |
4573236 | Dyson | Mar 1986 | A |
4588423 | Gillingham et al. | May 1986 | A |
4593429 | Dyson | Jun 1986 | A |
RE32257 | Dyson | Oct 1986 | E |
4643748 | Dyson | Feb 1987 | A |
4665582 | Richmond et al. | May 1987 | A |
4756729 | Brunnmair et al. | Jul 1988 | A |
4826515 | Dyson | May 1989 | A |
4853008 | Dyson | Aug 1989 | A |
4853011 | Dyson | Aug 1989 | A |
D305269 | Dyson | Dec 1989 | S |
4905341 | Sunagawa et al. | Mar 1990 | A |
5062870 | Dyson | Nov 1991 | A |
5078761 | Dyson | Jan 1992 | A |
5090976 | Dyson | Feb 1992 | A |
5101532 | Dyson et al. | Apr 1992 | A |
5145499 | Dyson | Sep 1992 | A |
5160356 | Dyson | Nov 1992 | A |
5254147 | Finke | Oct 1993 | A |
5267371 | Soler et al. | Dec 1993 | A |
D343707 | Dyson | Jan 1994 | S |
5307538 | Rench et al. | May 1994 | A |
5350432 | Lee | Sep 1994 | A |
5558697 | Dyson et al. | Sep 1996 | A |
5564160 | Luebbering | Oct 1996 | A |
5584095 | Redding et al. | Dec 1996 | A |
5591253 | Altman et al. | Jan 1997 | A |
D382679 | Dyson | Aug 1997 | S |
5755007 | Dyson | May 1998 | A |
5779745 | Kilstrom | Jul 1998 | A |
5935279 | Kilstrom | Aug 1999 | A |
5950274 | Kilstrom | Sep 1999 | A |
6003196 | Wright et al. | Dec 1999 | A |
6012200 | Murphy et al. | Jan 2000 | A |
6146434 | Scalfani et al. | Nov 2000 | A |
6168716 | Conrad et al. | Jan 2001 | B1 |
6277278 | Conrad et al. | Aug 2001 | B1 |
6312594 | Conrad et al. | Nov 2001 | B1 |
6334234 | Conrad et al. | Jan 2002 | B1 |
20050050863 | Oh | Mar 2005 | A1 |
Number | Date | Country |
---|---|---|
54488 | May 1985 | CA |
2104136 | Jun 1994 | CA |
2156069 | Jun 1996 | CA |
260 776 | Nov 1926 | DE |
1 251 139 | Sep 1967 | DE |
34 35 214 | Apr 1986 | DE |
52195 | Sep 1936 | DK |
69708 | Aug 1949 | DK |
0 408 862 | Jan 1991 | EP |
0 815 788 | Jan 1998 | EP |
0 836 827 | Apr 1998 | EP |
0 839 489 | May 1998 | EP |
1 016 090 | Oct 1952 | FR |
1 037 980 | Sep 1953 | FR |
1 094 603 | May 1955 | FR |
2 670 137 | Jun 1992 | FR |
762070 | Dec 1950 | GB |
2 108 013 | May 1983 | GB |
6 400 783 | Aug 1964 | NL |
148023 | Mar 1961 | SU |
148023 | Jul 1961 | SU |
1042812 | Sep 1983 | SU |
82 00451 | Feb 1982 | WO |
WO 9516382 | Jun 1995 | WO |
WO9622726 | Jan 1996 | WO |
WO9619936 | Apr 1996 | WO |
WO9619937 | Apr 1996 | WO |
WO9619293 | Jun 1996 | WO |
WO9619294 | Jun 1996 | WO |
WO9621389 | Jul 1996 | WO |
WO 9627446 | Sep 1996 | WO |
WO 9802080 | Jan 1998 | WO |
WO9827857 | Feb 1998 | WO |
WO 9810691 | Mar 1998 | WO |
WO9810691 | Mar 1998 | WO |
WO9823381 | Apr 1998 | WO |
WO9802080 | Jun 1998 | WO |
WO 9823381 | Jun 1998 | WO |
WO9833424 | Jun 1998 | WO |
WO 9827857 | Jul 1998 | WO |
WO 9833424 | Aug 1998 | WO |
Number | Date | Country | |
---|---|---|---|
20050028675 A1 | Feb 2005 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 10043337 | Jan 2002 | US |
Child | 10824491 | US | |
Parent | 09478891 | Jan 2000 | US |
Child | 10043337 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 09227712 | Jan 1999 | US |
Child | 09478891 | US |