Protective or hazardous duty garments are used in a variety of industries and settings to protect the wearer from adverse conditions such as heat, flames, smoke, cold, sharp objects, chemicals, liquids, vapors, fumes and the like. Zippers are a useful attachment mechanism for such garments, but when a zipper is used to connect portions of a garment such as a sleeve portion to the body or upper arm portion, a pant leg portion to the body or upper leg portion, a glove to a sleeve, or a hood to the collar of a garment about the diameter thereof a gap is left between the beginning and the end of the zipper. This gap can allow vapors to enter the suit, which can be undesirable, especially if the garment is a chemical protective suit.
Various devices have been used to seal this gap. One example is a “clamshell” seal that has an attachable disc-shaped cover that clamps onto the outside of the garment over the gap created by the zipper by clamping to another disc placed on the inside of the garment. The “clamshell” seal can be uncomfortable for the wearer, since one disc is inside the garment next to the wearer's neck. The “clamshell” seal also sticks out on the outside of the garment and may injure the wearer of the garment if bumped, or may even break the seal.
In one aspect, disclosed herein is a vapor resistant closure that includes a closure mechanism, for example, a zipper having a start end in an inner portion of material and a stop end in an outer portion of material with the outer portion containing the stop end overlapping the inner portion containing the start end. The closure mechanism forming a seal between the outer portion containing the stop end and the inner portion containing the start end when the closure mechanism is closed at the stop end. The seal that is formed is generally impermeable to fluids, gases, vapors, aerosols and particulates. The vapor resistant closure may also include a compressible body between the outer portion of material containing the stop end and the inner portion of material containing the start end. The compressible body is compressed therebetween when the closure mechanism is closed at the stop end.
The closure mechanism may extend more than 360° around the material with the stop end overlapping the inner portion of material containing the start end by about 5° to about 40°.
In one embodiment, the zipper is a watertight zipper and the compressible body is rubber, plastic, or foam. In one embodiment the material is included in a garment. The garment may conform with the NFPA 1994 Class 2 and NFPA 1992 Standards, in particular, for resistant to chemical and/or biological hazards.
The following detailed description will illustrate the general principles of the invention, examples of which are additionally illustrated in the accompanying drawings. In the drawings, like reference numbers indicate identical or functionally similar elements.
Referring to FIGS. 1 and 3-6B, a vapor resistant closure, generally designated 40, is shown connecting a hood 11 to a neck 15 of a garment 14. The vapor resistant closure 40 allows the hood 11 and the neck 15 to be detachably sealingly connectable together. The vapor resistant closure 40, in this embodiment, extends more than 360° around the neck 15 and hood 11 and terminates with overlapping portions 49, 49′ (each a part of the neck 15 and hood 11, respectively as best seen in
In one embodiment, as shown in
Referring to
Referring again to
The closure mechanism 42 is preferably an air-tight, vapor-tight, and/or moisture tight closure when closed, i.e., the connecting mechanism itself as its two sides 53, 54 are mated together form a vapor-tight and/or moisture tight connection with one another. In one embodiment, the closure mechanism 42 is a zipper that includes interlocking teeth, “press-to-close” strips (i.e., a seal analogous to those on ZIPLOC® plastic bags), or slide-to-close strips (similar to those in U.S. Pat. No. 6,014,795, which is incorporated herein by reference in its entirety). The zipper 42 may be a watertight zipper, such as those commercially available from YKK Corporation under the trademarks Aquaseal® and Aquaguard® and/or described in YKK Corporation's U.S. Pat. Nos. 7,591,051, 7,500,291, and 7,337,506, which are incorporated herein by reference in their entirety. Aquaseal® zippers are smooth and flexible and offer protection from water as a result of a film-coated tape and a zip element mechanism that seals the zipper completely. The zippers are available in various sizes and formats (such as rubber or polyurethane tape, opened-end or closed-end).
As discussed above, a compressible body 52, as shown in
The compressible body 52 may be inserted into gap 62 after the closure mechanism 42 is partially closed, preferably, when the closing actuator 60 first begins closing the closure mechanism 42 over the start end 44 so that the amount of overlap formed will hold the compressible body 52 in place for compression as the closure mechanism 42 is further closed by the closing actuator 60. In another embodiment, the compressible body 52 is connected to at least one of the extension pieces 50, 50′ and acts like a flap that is foldable over the closure mechanism 42. The compressible body 52 may be sewn or adhered to at least one of the extension pieces 50, 50′, or the single extension piece 116 shown in
In the embodiment illustrated in
The compressible body 52 may be any suitable compressible material that can be compressed tightly between the start end 44 and stop end 46 of the vapor resistant closure 40 and is generally impermeable to gases, at least when compressed. A material that is itself generally impermeable to gases is preferred. The compressible body 52 may be rubber such as solid natural rubber, synthetic rubber, open or closed cell sponge or foam rubber, composite rubber, or plastic. The compressible body may be or include neoprene, natural rubber, SBR, butyl rubber, butadiene, nitrile, EPDM, ECH, polystyrene, polyethylene, polypropylene, EVA, EMA, Metallocene Resin, Polyurethane, PVC, and blends thereof.
In
The hood 11 shown in
The hood 11 may include a flap 36 fixedly attached to the hood 11 about the base 34 and is positionable over the vapor resistant closure 40. The flap 36 may include a releasable attachment member 38, for example, hook-and-loop fastening material (such as VELCRO® fastening material), snaps, one or more zippers, and/or hooks to releasably couple the flap 36 to the neck 15 of the garment 14. The neck 15 includes a mating releasable attachment member 39 appropriately positioned to mate with the releasable attachment member 38 on the flap 36. While flap 36 is illustrated in
In the embodiment of
In one embodiment, the one-piece suit 20 may be a top-entry suit and/or an improved chemical garment (“ICG”) that provides protection against some of the most dangerous chemical and biological hazards in the world. The ICG may include inner shell 72 and an outer shell 74. In one embodiment, the inner shell 72 is laminated to the outer shell 74. The inner shell 72 may be a GORE™, Chempak® Ultra Barrier Material laminated to an outer shell 74 of NOMEX® textile.
So far the vapor resistant closure 40 has been illustrated and described as connecting a hood 11 to the neck 15 of a garment 14, but the invention is not limited thereto. The vapor resistant closure 40 is applicable to forming a detachable, sealed connection between any two generally circular or oval openings on separate portions of a garment or even as a straight-line joint as shown in
Now referring to
Now referring to
Depending on the application of the garments 20, 80, 90 and 108, the garments may include various layers through their thicknesses to provide various heat, moisture, chemical, and abrasion resistant qualities so that the garments can be used as a protective, hazardous duty, and/or firefighter garment. The various layers may include an outer shell 74, shown in
The garment may also include an optional inner liner or inner face cloth (not shown) located inside of (closer to the wearer when worn) and adjacent to the inner shell 72. The inner face cloth, which may be the innermost layer, can provide a comfortable surface for the wearer and protect the inner shell 72 and/or thermal liner from abrasion and wear. It should be understood that any number of layers, liners, and the like may be included and may be layered in various arrangements as desired, in which the various layers described herein are included, omitted, and/or rearranged.
The outer shell 74 may be made of or include a variety of materials, including a flame, heat and abrasion resistant material such as a compact weave of aramid fibers and/or polybenzamidazole fibers. Commercially available aramid materials include NOMEX® and KEVLAR® fibers (both trademarks of E.I. DuPont de Nemours & Co., Inc. of Wilmington, Del.), and commercially available polybenzamidazole fibers include PBI fibers (a trademark of PBI Performance Materials of Charlotte, N.C.). Thus, the outer shell 74 may be an aramid material, a blend of aramid materials, a polybenzamidazole material, a blend of aramid and polybenzamidazole materials, or other appropriate materials. If desired, the outer shell 74 may be coated with a polymer, such as a durable, water repellent finish (i.e. a perfluorohydrocarbon finish, such as TEFLON® finish sold by E. I. Du Pont de Nemours and Company of Wilmington, Del.). The materials of the outer shell 74 may have a weight of, for example, between about five and about ten oz/yd2.
The thermal liner and/or inner shell 72 may be generally coextensive with the outer shell 74, or spaced slightly inwardly from the outer edges of the outer shell 74 (i.e., spaced slightly inwardly from the upper ends of the waist and from the lower edge of the garment) to provide moisture and thermal protection throughout the garment. The optional thermal liner may be made of nearly any suitable material that provides sufficient thermal insulation. In one embodiment, the thermal liner may constitute or include a relatively thick (i.e. between about 1/16″- 3/16″) batting, felt or needled non-woven bulk or batting material. The bulk material can also take the form of one or two (or more) layers of E-89® spunlace material made of a combination of NOMEX® and KEVLAR® material. The bulk material can also, or instead, include aramid fiber batting (such as NOMEX® batting), aramid needlepunch material, an aramid non-woven material, an aramid blend needlepunch material, an aramid blend batting material, an aramid blend non-woven material, foam (either open cell or closed cell), or other suitably thermally insulating materials. The bulk material may trap air and possess sufficient loft to provide thermal resistance to the garment. In one embodiment, the thermal liner may have a thermal protection performance (“TPP”) of at least about twenty, and in another embodiment, at least about thirty-five. Moreover, in one embodiment, the garment as a whole has a TPP of at least about twenty, and in another embodiment has a TPP of at least about thirty-five.
The inner shell 72 may include a semi-permeable (selectively permeable) or impermeable membrane material. The selectively permeable membrane material may be generally water vapor permeable but generally impermeable to liquid moisture. The membrane material may be made of or include expanded polytetrafluoroethylene (“PTFE”) such as GORE-TEX® or CROSSTECH® materials (both of which are trademarks of W.L. Gore & Associates, Inc. of Newark, Del.), polyurethane-based materials, neoprene-based materials, cross-linked polymers, polyamid, GORE® CHEMPAK® materials, sold by W.L. Gore & Associates, Inc. including GORE® CHEMPAK® Ultra Barrier Material, GORE® CHEMPAK® Selectively Permeable Material, or GORE® CHEMPAK® Sorptive Material, or other materials.
The semi-permeable membrane material may have microscopic openings that permit moisture vapor (such as water vapor) to pass therethrough, but block liquids (such as liquid water) from passing therethrough. The semi-permeable membrane material may be made of a microporous material that is either hydrophilic, hydrophobic, or somewhere in between. The semi-permeable membrane material may also be monolithic and may allow moisture vapor transmission therethrough by molecular diffusion. The semi-permeable membrane material may also be a combination of microporous and monolithic materials (known as a bicomponent moisture barrier), in which the microporous or monolithic materials are layered or intertwined.
The semi-permeable membrane material, optionally, may be bonded, adhered or otherwise attached to a substrate 76 (
The garment as a whole may meet the National Fire Protection Association (“N.F.P.A.”) 1971 standards for protective firefighting garments (“Protective Clothing for Structural Firefighting”), which are entirely incorporated by reference herein. The NFPA standards specify various minimum requirements for heat/flame resistance and tear strength. For example, in order to meet the NFPA standards, the garment must be able to resist igniting, burning, melting, dripping, separation and/or shrinking by more than 10% in any direction at a temperature of 500° F. for at least five minutes. Furthermore, in order to meet the NFPA standards, the combined layers of the garment must provide a thermal protective performance rating of at least thirty-five.
The inner shell 72 can also help to prevent or reduce the introduction of harmful materials into the garment. Such harmful materials may include liquids (including chemical warfare agents, biological warfare agents and toxic industrial chemicals), vapors and aerosols (including chemical warfare agents and toxic industrial chemicals), and contaminated particulates (such as biological warfare agents). Examples of chemical warfare agents include soman (GD) nerve agent and distilled mustard (HD) blister agent. Examples of toxic industrial chemicals include acrolein (liquid), acrylonitrile (liquid), ammonia (gas), choline (gas), and dimethyl sulfate (liquid).
Thus, in addition to the materials listed above, the inner shell 72 may include various other materials which block harmful materials, gases and/or vapors. For example, the inner shell 72 may be made of or include PTFE (such as GORE-TEX® or CROSSTECH® materials), polyurethane or polyurethane-based materials, neoprene or neoprene-based materials, cross-linked polymers, polyamid, or GORE® CHEMPAK® materials, sold by W.L. Gore & Associates, Inc. including GORE® CHEMPAK® Ultra Barrier Material, GORE® CHEMPAK® Selectively Permeable Material, or GORE® CHEMPAK® Sorptive Material. Besides the materials outlined above, the inner shell 72 can be made of nearly any material that is generally impermeable to a particular harmful material. In general, since gases typically are able to permeate many materials, if the inner shell 72 is able to block gases, the inner shell 72 may thus be able to block the other undesirable materials, such as vapors or aerosols. The various other layers of the garment, such as the outer shell 74, an optional thermal liner or barrier, an optional inner liner or inner face cloth, or other layers thereof, may be generally gas permeable, liquid permeable, or able to be permeated by aerosols or other harmful materials, such that the inner shell 72 is relied upon to provide protection against such materials.
NFPA 1971 standards include a Chem/Bio Option (the entire contents of which are hereby incorporated by reference) which provides specifications that protective ensembles must meet in order to be certified under that Option. For example, the Chem/Bio Option specifies that the garment must pass a Man In Simulant Test (“MIST”). In one case, the MIST essentially consists of introducing the garment into a chamber filled with a vaporized test material (such as oil of wintergreen). Absorbent padding is placed on the wearer and/or inside the garment. After the garment has been exposed to the vaporized material for a sufficient period of time, the garment is removed from the chamber. The absorbent pads are removed and analyzed to determine how much of the vaporized test material they have absorbed. The inner shell 72, in combination with various other protective features, may provide a garment/ensemble which passes the MIST. The inner shell 72, even more broadly, may meet the Chem/Bio Option of NFPA 1971 standards, the NFPA 1994, Class 2 standards, the NFPA 1992 certification, and combinations thereof. In one embodiment, the garment meets the NFPA 1994 Class 2 standards and the NFPA 1992 certification.
In one embodiment, the garment may lack a separable inner shell 72 and may be only a single or multi-ply garment without removable or separable layers. Moreover, the outer shell 74 and inner shell 72 may include various layers thereof or may be made of only a single layer (including, for example, the inner shell 72 comprising solely the semi-permeable membrane material).
In the illustrated embodiment of
Referring now to
The closure mechanism 106 includes a start end 110 fixedly attached in at least one layer 114 of the garment 104 without a gap that could allow gases or vapors into the garment 104. The closure mechanism 106 also includes a stop end 112 fixedly attached in the at least one layer 114 of the garment 104. The garment 104 includes an extension piece 116 extending inward from the layer 114 containing the stop end 112 of the closure mechanism 106 with the extension piece 116 positioned under the stop end 112. Accordingly, the stop end 112 and adjacent portions 118 of the closure mechanism overlap the extension piece 116. The extension piece 116 includes the compressible body 108 with the compressible body 108 positioned between the extension piece 116 and the adjacent portions 118 of the closure mechanism 106. The compressible body 108 is positioned such that, when the closure mechanism 106 is being closed, the closing action compresses the compressible body 108 to form a seal between the stop end 112 of the closure mechanism 106. The seal is generally impermeable to fluids, gases, vapors, aerosols and particulates.
In one embodiment, the closure mechanism 106 is a zipper as described above, preferably, a watertight zipper. The compressible body 108 may be any suitable compressible material that can be compressed tightly between the adjacent portions 118 of the closure mechanism 106 and is generally impermeable to gases, at least when compressed. The compressible body 108 may include any of the materials described above.
While
Although the invention is shown and described with respect to certain embodiments, it should be clear that modifications will occur to those skilled in the art upon reading and understanding the specification, and the present invention includes all such modifications.
This application claims the benefit of U.S. Provisional Application No. 61/322,365, filed Apr. 9, 2010.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/US11/31695 | 4/8/2011 | WO | 00 | 1/7/2013 |
Number | Date | Country | |
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61322365 | Apr 2010 | US |