The invention relates to the field of composite cushioning material having variably tensed components.
The invention relates to a composite structure for use as cushioning material. The composite cushioning material includes a plurality of resilient, shock-absorbing elements bonded to one or two flexible and stretchable substrate layers. The composite material also includes one or more framing elements that cause substrate layers in different areas or zones of the composite structure to be stretched to a different degree, or “variably tensed.” This composite cushioning material is lightweight and stretchable, and it can be made to take on a concave or convex shape, so as to better follow the contour of the wearer's body, hand, or foot, or to fully envelop the body parts that are intended to be protected, yet be flexible and breathable. Once assembled, the material can be used as cushioning component in footwear, as protective padding, or as components in athletic or industrial protective gear. The invention also relates to a method for making the said composite cushioning material.
In one aspect, the invention is drawn to a composite cushioning material comprising two or more resilient elements bonded to one or more flexible or stretchable substrates, further comprising at least one framing element placed around one or more resilient elements, wherein a section of the composite cushioning material corresponding to the area of the framing element is less flexible than the rest of the composite cushioning material, so as to provide a variably tensed composite cushioning material.
The resilient element may be composed, without limitation, of ethylene vinyl acetate foam, olefin or polyolefin foam, polyurethane foam, urethane based foam, thermoplastic foam, or other polymer foam, rubber, elastomer, or other resilient material, including a combination of any such materials. The resilient element may be in the shape, without limitation, of a cube, flattened cube, cuboid, square cuboid, rectangular cuboid, cylinder, circular cylinder, round cylinder, elliptical cylinder, triangular prism, pentagonal prism, hexagonal prism, tapered pyramid, an irregular shape, or a prism with an irregularly shaped cross-section. The resilient elements may have different shapes or dimensions in a group of resilient elements, or may have the same shapes or dimensions in a group of resilient elements. The resilient elements may be sandwiched between two substrates, which may be made of different or same material.
The framing element may be composed, without limitation, of ethylene vinyl acetate foam, olefin or polyolefin foam, polyurethane foam, urethane based foam, thermoplastic or thermoplastic foam, polymer foam, neoprene, natural leather, synthetic leather, elastomer, rubber, plastic, latex, silicone, or other similar material, including a combination of any such materials. The framing element may be bonded to one substrate, or may be bonded to two substrates. The framing element may be comprised of strips or bars of resilient materials that occupy a space between at least two resilient elements. The framing element may be comprised of more than one framing element stacked on top of each other. The framing element may be composed of resilient material, comprised of:
(a) entirely of strips or bars of resilient material;
(b) a lattice of resilient material with apertures; or
(c) a combination of (a) or (b) in the same structure or on separate structures.
The lattice of resilient material may have an outer perimeter that is, without limitation, square-shaped, circularly-shaped, hexagon-shaped, or asymmetrically-shaped, with aperture that is, without limitation, triangular, cylindrical, square, rectangular, pentagonal, or hexagonal.
In another aspect, the invention is drawn to, without limitation, an athletic gear, an industrial protective gear, a shoe upper, a shoe sidewall, a shoe heel counter, a shoe toebox, an elbow pad, a knee pad, or a shoulder pad comprising the composite cushioning material.
In yet another aspect, the invention is drawn to a method of making the composite cushioning material, comprising:
(i) applying a suitable adhesive to one or two opposing surfaces of a sheet of resilient material;
(ii) cutting the sheet of resilient material, to define and make a plurality of resilient elements;
(iii) bonding the plurality of resilient elements to at least one substrate layer;
(iv) stretching the substrate layer to which the resilient elements are bound, and increasing the relative distance between the resilient elements, thereby creating spacing between them;
(v) positioning one or more framing elements shaped and sized to engage one or more resilient elements, or placed between the resilient elements; and
(vi) inserting one or more framing elements between at least two resilient elements, or engaging one or more resilient elements to one or more apertures in the framing element.
The resilient element may be composed of, without limitation, ethylene vinyl acetate foam, olefin or polyolefin foam, polyurethane foam, urethane based foam, thermoplastic foam, or other polymer foam, rubber, elastomer, or other resilient material, including a combination of any such materials. The resilient element may be in the shape of, without limitation, a cube, flattened cube, cuboid, square cuboid, rectangular cuboid, cylinder, circular cylinder, round cylinder, elliptical cylinder, triangular prism, pentagonal prism, hexagonal prism, tapered pyramid, an irregular shape, or a prism with an irregularly shaped cross-section. The resilient elements may have the same or different shapes or dimensions in a group of resilient elements.
The framing element may be composed of, without limitation, ethylene vinyl acetate foam, olefin or polyolefin foam, polyurethane foam, urethane based foam, thermoplastic or thermoplastic foam, polymer foam, neoprene, natural leather, synthetic leather, elastomer, rubber, plastic, latex, silicone, or other similar material, including a combination of any such materials. The framing element may comprise an enclosed structure, wherein the enclosed structure portion comprises one or more apertures, which are engaged with one or more resilient elements. The framing element may comprise strips or bars of resilient materials that occupy a space between at least two resilient elements.
The stretching may occur in an area or zone of the substrate layer to which the resilient elements are bound, and increasing the relative distance between the resilient elements positioned within the said area or zone of the substrate layer, thereby creating spacing between them.
In step (iv), the stretching may be carried out mechanically.
In step (v) the framing element may comprise:
(a) entirely of strips or bars of resilient material;
(b) a lattice of resilient material with apertures; or
(c) a combination of (a) or (b) in the same structure or on separate structures.
The method may alternatively comprise:
(vii) releasing the stretched out substrate so as to retract the substrate; and
(viii) bonding a second substrate to the resilient elements so that the resilient elements and the framing element are sandwiched between the two sheets of substrates to form a dual laminate composite.
The method may also alternatively comprise:
(vii) releasing the stretched out substrate so as to retract the substrate;
(viii) bonding the framing element to the substrate layer, thereby making a single laminate composite; and
(ix) bonding a second substrate to the resilient elements so that the resilient elements and the framing element are sandwiched between the two sheets of substrates to form a dual laminate composite.
An optional step (vii) may involve bonding a second substrate to the resilient elements so that the resilient elements and the framing element are sandwiched between the two sheets of substrates to form a dual laminate composite in which the framing element is not bound to either substrate. The stretched out substrate may then be released so as to retract the substrate after step (vii).
An alternative optional step (vii) may involve bonding the framing element to a substrate layer, thereby making a single laminate composite with the framing element bound to one substrate. The stretched out substrate may then be released so as to retract the substrate after step (vii).
An optional step (viii) may involve bonding a second substrate to the resilient elements so that the resilient elements and the framing element are sandwiched between the two sheets of substrates to form a dual laminate composite in which the framing element is bound to one substrate. The stretched out substrate may then be released so as to retract the substrate after step (viii).
An alternative optional step (viii) may involve bonding a second substrate to the resilient elements and the framing element so that the resilient elements and the framing element are sandwiched between the two sheets of substrates to form a dual laminate composite in which the framing element is bound to both substrates. The stretched out substrate may then be released so as to retract the substrate after step (viii).
In yet another aspect, the invention is directed to a composite cushioning material comprising two or more resilient elements bonded to one or more flexible or stretchable substrates, further comprising at least one framing element placed around one or more resilient elements, wherein with reference to a section of the substrate between (a) at least one resilient element framed by the framing element and (b) at least one other resilient element, the said section of the substrate is stretched out to a greater extent than in at least one other section of the substrate in the composite cushioning material, so as to provide a variably tensed composite cushioning material.
These and other objects of the invention will be more fully understood from the following description of the invention, the referenced drawings attached hereto and the claims appended hereto.
The present invention will become more fully understood from the detailed description given herein below, and the accompanying drawings which are given by way of illustration only, and thus are not limitative of the present invention, and wherein;
In the present application, “a” and “an” are used to refer to both single and a plurality of objects.
The invention relates to a composite cushioning material comprising a plurality of discrete resilient elements attached or bonded to two substrate layers, wherein the resilient elements are “sandwiched” between the two substrate layers, and the two substrate layers are comprised of one or more flexible and stretchable sheeting materials. Non-limiting examples of such dual laminate composite material include first dual laminate composite 373 depicted in
The invention also relates to a composite cushioning material comprising a plurality of discrete resilient elements attached or bonded to a single substrate layer made of a flexible and stretchable sheeting material. Non-limiting examples of such single laminate composite material include first single laminate composite 370A depicted in
In both types of composite cushioning materials, at least one resilient element is bounded on one or more sides, or surrounded partially or completely, by one or more framing elements. In one embodiment of the invention, the framing elements may optionally include one or more holes or apertures, and one or more resilient elements may optionally be engaged to one or more holes in a framing element, or in multiple framing elements.
In both types of composite cushioning materials (namely, single laminate composite materials such as, by way of example only, single laminate composites 370A-370B, 371, and 372, and dual laminate composite materials such as, by way of example only, and dual laminate composites 373-379), one or more regions or zones of the composite material may optionally have a concave or convex shape. The concave or convex shape permits the composite materials to be used as protective or cushioning materials that better follow the contour of the wearer's body, hand, or foot, or more fully envelop the body parts that are intended to be protected, yet are flexible and breathable.
In one aspect of the invention, the framing elements may optionally be more rigid, less flexible, or less compressible than the substrate layers.
In another aspect of the invention, in the areas or zones of the substrate layer on which one or more resilient elements are bounded by or engaged to a framing element, the substrate layer material is in a relatively more stretched, or “tensed,” state than in the rest of the substrate layer.
In yet another aspect of the invention, a substrate layer to which discrete resilient elements are bonded is mechanically stretched, causing the resilient elements to move apart in relation to each other, and creating spacing between the resilient elements. While the substrate layer is in a stretched state, and the resilient elements bonded to the same have spaced out in relation to each other, one or more framing elements are inserted and fitted into the spacing between the resilient elements, and optionally made to engage one or more resilient elements. The framing elements may optionally be bonded to a substrate layer while the substrate layer is in a stretched state.
After the framing elements have been inserted in place (and may have optionally been bonded to a substrate), the substrate layer as a whole is permitted to return to a non-stretched state, causing the resilient elements to come back together and the spacing between them to decrease. It is understood that the framing elements engaged to one or more resilient elements prevent at least two of the resilient elements from coming back together, even as the substrate layer as a whole returns to a non-stretched state. It is also understood that in the areas, regions, or zones of the substrate layer on which one or more resilient elements are engaged to the framing element, the substrate layer material is prevented from returning to a non-stretched or relaxed state. In those areas, the substrate layer material remains in a relatively more stretched, or “tensed,” state than in the rest of the substrate layer.
Optionally, and alternatively, the framing elements may be bonded to a substrate layer after the substrate layer has returned to a non-stretched, or “relaxed,” state. Or alternatively, the framing elements may optionally be left free, not bonded to a substrate layer.
In one aspect, the invention is drawn to a method of making a composite cushioning material, comprising the following: (1) bonding a plurality of discrete resilient elements to at least one substrate layer; (2) mechanically stretching the substrate layer to which the resilient elements are bonded, and increasing the relative distance between the discrete resilient elements, thereby creating spacing between them; (3) positioning a framing element, which may optionally include holes shaped and sized to engage one or more resilient elements, in proximity with the resilient elements; (4) inserting a framing element between at least two resilient elements, or optionally engaging one or more resilient elements to one or more holes in a framing element; (5) optionally bonding a framing element to the substrate layer; and (6) optionally bonding a second substrate layer to the resilient elements, so that the resilient elements and the framing elements are “sandwiched” between the two sheets of substrate layers.
The various aspects of the invention and the alternative embodiments of the same, and their benefits, will be better appreciated once the composite cushioning material and the various alternative and optional processes of making them, described in greater detail below and depicted in the figures referenced below, are fully understood.
Dual and Single Laminate Variably-Tensed Cushioning Composite Materials
Variably-Tensed Dual Laminate Cushioning Composite
In one aspect, the present invention is drawn to a dual laminate composite material comprising a plurality of discrete resilient elements bonded to two substrate layers, wherein one or more resilient elements may optionally be engaged to one or more framing elements. The resilient elements and the framing elements are “sandwiched” between two substrate layers, and each substrate layer may be bonded to one or more resilient elements.
Various non-limiting examples of dual laminate composites are depicted in
Resilient Element Components
In one aspect of the invention, dual laminate composite materials include a plurality of discrete resilient elements bonded to two substrate layers. Non-limiting examples of the resilient elements include resilient elements 353 depicted in
It is understood that, optionally, the same resilient elements incorporated into, or used to make, single laminate composites may also be used to make dual laminate composites. Therefore, a dual laminate composite material may optionally incorporate, by way of example only and without limitations, resilient elements 353B depicted in
By way of illustration,
As depicted in
As depicted in
By way of example only, in the first dual laminate composite 373 and the alternative first dual laminate composite 374 depicted in
The composition of the resilient elements may include, without limitations, a resilient material such as foam, including ethylene vinyl acetate (“EVA”) foam, olefin or polyolefin foam, polyurethane (“PU”) foam, urethane based foam, or thermoplastic foam, or rubber, elastomer, or other material with suitable shock absorbing characteristics, or resistant to puncture or abrasion (including a combination of any such materials). It is understood that depending on the type and material of which the resilient material is made, functionally the resilient materials may act as a cushion against impact, provide structural rigidity, provide protection against abrasion or puncture, or provide thermal insulation to heat or cold.
As depicted in
As depicted in
It is understood that an adhesive is applied to two opposing sides of the resilient elements, in order to bond the resilient elements to the substrate layers. By way of example only, first side 353F of the resilient elements in the dual laminate composite materials depicted in
Second side 353S of the resilient elements in the dual laminate composite materials depicted in
Optionally, adhesive may be applied to first side 353F of one set of resilient elements in a composite material, to second side 353S of a second set of resilient elements, and to both the first side 353F and second 353S of a third set of resilient elements. The three sets of resilient elements may be positioned in a suitable pattern or array, and bonded to first substrate layer 351, second substrate layer 352, or to both substrate layers, depending on whether the resilient elements have adhesive applied on one side (that is, first side 353F), on the other side (that is, second side 353S), or on both sides, provided that at least one resilient element is bonded to two substrate layers.
In one embodiment of the invention, the adhesive applied to the first side 353F of the resilient elements, and to the second side 353S of the resilient elements, is optionally comprised of a hot-melt adhesive (“HMA”) film that is activated by heat, or heat and pressure. Optionally, depending on the type of material and the composition of the resilient elements and the substrate layers, the adhesive may, additionally or alternatively, include ethyl-vinyl acetate, olefin, or polyolefin-based adhesive, glue, or HMA film; polyurethane or urethane based adhesive, glue, or HMA film; or polyamine based adhesive, glue, or HMA film.
However, it is understood that the said adhesive may optionally comprise any glue, bonding agent or compound, adhesive film or laminate, solvent, or tape that permits first side 353F of the resilient elements to bond or adhere to first substrate layer 351. The said adhesive may also be, optionally, any glue, bonding agent or compound, adhesive film or laminate, or tape that permits second side 353S of the resilient elements to bond or adhere to second substrate layer 352. It is also understood that for purposes of this embodiment of the invention, any compound, substance, attachment, or device (including tape, Velcro® or other interlocking mechanical means) suitable for bonding the resilient elements to a substrate layer may be used as an adhesive.
It is further understood that depending on the composition of the first substrate layer 351 and second substrate layer 352, and the composition of the resilient elements, the same or different types of adhesives, or combination of adhesives, may optionally be applied to the first side 353F and second side 353S of the resilient elements.
Framing Element Components
In another aspect of the invention, one or more resilient elements in a dual laminate composite material are bounded on one or more of the sides of the said resilient elements by one or more framing elements, or surrounded partially or completely by one or more framing elements. The framing elements may have a variety of different shapes and dimensions. In one embodiment of the invention, framing elements may be comprised of a lattice of resilient material; alternatively, and optionally, framing elements may also be comprised of “strips” or “bars” of resilient material, or any combinations of “strips” or “bars” and lattices of resilient material. In another embodiment of the invention, framing elements may include one or more holes or apertures, and one or more resilient elements in a dual laminate composite may be engaged to holes in a framing element.
Non-limiting examples of the framing element include framing element 363 depicted by itself in
By way of example only,
Another non-limiting example of the placement of the framing element within a dual laminate composite material is more clearly illustrated in
It is understood that in this optional embodiment of the invention, the framing element (namely, framing element 363) does not engage every resilient element (namely, resilient element 353) in the dual laminate composite; however, optionally, a framing element may be dimensioned and shaped so that the framing element engages every resilient element in the dual laminate composite.
In one aspect of the invention, the composition of the framing elements (such as, by way of example only, framing element 363, framing elements 363A-363M, and framing element 363T) may include, without limitations, polymer foam (such as, by way of example only, EVA foam, olefin or polyolefin foam, PU foam, or urethane based foam), thermoplastic or thermoplastic foam, rubber, elastomer, or neoprene, natural leather, synthetic leather, plastic, or rubber (including without limitation, latex, silicone, or synthetic rubber) and so forth, or any combination of such materials.
In one embodiment of the invention, the framing elements may be more rigid, less flexible, or less compressible that the substrate layers. Optionally, the composition of the framing elements may include one or more materials that are more rigid, less flexible, or less compressible than the materials comprising the substrate layers.
It is understood that the framing elements in a dual laminate composite may be made of the same type of material, or combination of materials, in relation to the resilient elements in the said dual laminate composite; alternatively, and optionally, the framing element may be made of a different type of material or combination of materials in relation to the resilient elements. By way of example only, and without limitations, in the first dual laminate composite 373 depicted in
It is understood that the framing element may take on a variety of different and optional shapes, provided that the framing element, or parts thereof, may be lodged or inserted between two or more discrete resilient elements; or the framing element may optionally bound one or more sides of one or more discrete resilient elements; or the framing element may optionally surround, partially or completely, one or more discrete resilient elements in a dual or single laminate composite.
By way of example only, and without limitations, in one embodiment of the invention, the framing element may be comprised of a lattice of resilient material (such as lattice of resilient material 365, depicted in
Non-limiting examples of such framing elements include framing element 363 depicted in
Alternatively, and optionally, a framing element may be comprised entirely of “strips” or “bars” of resilient material (such as framing bars 354), such as, by way of example only, framing element 363G depicted in
A framing element may also be optionally comprised of a combination of “strips” or “bars” (such as framing bars 354) and lattice structures made of resilient materials. Non-limiting examples of such framing elements include framing element 363C depicted in
It is understood that a framing element may optionally be asymmetrical in shape, such as framing element 363I depicted in
In another aspect of the invention, more than one framing element may optionally be incorporated into a dual laminate composite. By way of example only, a plurality of framing elements may optionally be inserted between or among different sets of resilient elements in a dual laminate composite. As a non-limiting example,
Optionally, framing element 363K and framing element 363M may be made of different types of material. For example, in one embodiment of the invention, both framing elements are made of EVA foam, but framing element 363K is optionally made of an EVA foam denser or stiffer than the EVA foam that makes up framing element 363M.
In yet another aspect of the invention, a plurality of framing elements may optionally be stacked and fitted together into a dual laminate composite, so that more than one framing element is inserted or lodged between or among the same set of resilient elements, or more than one framing element engages the same set of resilient elements. As a non-limiting example,
Alternatively, and optionally,
Substrate Layer Components
In another aspect of the invention, a plurality of resilient elements (such as, by way of example only, resilient elements 353, 353A, 353B, and 353C) in the dual laminate composite material are bonded to two sheeting structures, namely first substrate layer 351 and second substrate layer 352.
It is understood that in such dual laminate composites, the resilient elements, and the framing elements that contact or engage one or more of the said resilient elements, are “sandwiched” between the two substrate layers.
Non-limiting examples of the substrate layers (namely, first substrate layer 351 and second substrate layer 352) are shown in
As shown in
In one embodiment of the invention, the framing elements (such as, by way of example only, framing element 363) in a dual laminate composite are not bonded to a substrate layer. Optionally, the holes in a framing element may be suitably sized and shaped, so that the framing element is held in place through compression or friction with the resilient elements. However, it is understood that, optionally, one or more framing elements may be bonded to one or more substrate layers in a dual laminate composite (such as, by way of example only, first substrate layer 351, second substrate layer 352, or both of them). This may optionally be accomplished by applying a suitable adhesive to one or more sides of the framing elements facing a substrate layer, so that the framing elements adhere to one or more substrate layers.
It is understood that alternatively, and optionally, a framing element (such as, by way of example only, framing element 363) in a dual laminate composite may be optionally bonded to two substrate layers (namely, first substrate layer 351 and second substrate layer 352), while one or more resilient elements (such as, by way of example only, resilient elements 353) in the dual laminate composite may be bonded to only a single substrate layer (such as first substrate layer 351 or second substrate layer 352), or optionally one or more resilient elements engaged to a framing element may not be bonded to any substrate layer. Also optionally, a framing element (such as, by way of example only, framing element 363) in a dual laminate composite may be bonded to one of the two substrate layers (namely, first substrate layer 351 or second substrate layer 352), while one or more resilient elements (such as, by way of example only, resilient elements 353) may be bonded to the other substrate layer (second substrate layer 352 or first substrate layer 351, as the case may be).
In one aspect of the invention, first dual laminate composite 373 is curved in three dimensions, and it has a convex shape on its first side 350A and a concave shape on its second side 350B, as shown in
It is also understood that the region or zone of the first substrate layer 351 located in the variably-tensed zone 350C shown in
In one optional embodiment of the invention, each substrate layer (namely, first substrate layer 351 and second substrate layer 352) is optionally comprised of a sheet or layer of synthetic, non-woven stretchable fabric such as spandex, or stretchable nylon or polyester mesh. However, it is understood the substrate layer (such as first substrate layer 351 and second substrate layer 352) may optionally be comprised of a sheet or layer of any material that is relatively flexible and stretchable and may be used as a sheeting structure, including, without limitations, natural or synthetic fabric (including, by way of example only and without limitations, polyester, nylon, Lycra®, or elastane), stretchable mesh (including open mesh), flexible or pliable plastic, neoprene, natural leather, synthetic leather, or a sheet of synthetic fiber, or a combination of such materials. Optionally, the substrate layers may also be made of any flexible and stretchable sheet of foam, plastic, latex, silicone, rubber, other rubber-like materials, elastomer, and so forth, including any combination of such materials. By way of example only, and without limitations, the substrate layers may optionally be comprised of any such materials encased in, laminated with, or sandwiched between, sheets of natural or synthetic fabric.
It is understood that a suitable composition for the substrate layers may optionally be selected from a wide variety and range of materials that are flexible and stretchable, provided that the resulting substrate layer may be made to bond to the resilient elements (such as, by way of example only, resilient elements 353, 353A, 353B, and 353C). The selection of material, or combination of materials, for the substrate layers may impart the finished product with different functional characteristics or performance parameters, such as, by way of example only and without limitations, distinct stretchability, breathability, permeability to gases or liquids, absorbency of vapors and liquids, resistance to tear and puncture, protection from corrosion, and the like.
In another embodiment of the invention, first substrate layer 351, second substrate layer 352, or both of them, may optionally be comprised of a material, or combination of materials, that is flexible or stretchable at the time of the lamination of the substrate layers onto the resilient elements, but becomes hard, less flexible, or less stretchable thereafter. It is understood that in this embodiment of the invention, the substrate layers may optionally be hardened, or made less flexible or stretchable, by drying, curing, heating, chemical activation, or irradiation with infrared, microwave, radio frequency waves, and the like, depending on the composition of the substrate layers.
In another aspect of the invention, first substrate layer 351 may be made of the same types of materials as second substrate layer 352; alternatively, and optionally, first substrate layer 351 and second substrate layer 352 may be made of different types of materials.
By way of example only, and without limitations, in the second dual laminate composite 375 depicted in
It is understood that any combination or permutation of suitable materials may be selected for the first substrate layer 351 and the second substrate layer 352. It is also understood that depending on the type and material of which the substrate layers are made, functionally the combination substrate layers may provide protection against abrasion or puncture, provide thermal insulation, or permit the finished dual laminate composite material to be breathable or permeable to gases, vapors, or liquids.
By way of example only, and without limitations, first substrate layer 351 in a dual laminate composite may optionally be comprised of open mesh or other fabric permeable to water vapor, and the second substrate layer 352 may optionally be comprised of cotton, felt, or other fabric material capable of absorbing or retaining liquids or condensed humidity.
Alternatively, and optionally, first substrate layer 351 in a dual laminate composite may optionally be comprised of cotton, and the second substrate layer 352 may optionally be comprised of nylon or other synthetic material that permits a layer air to be trapped between the first substrate layer and second substrate layer, and thereby provide thermal insulation.
As shown in
In the various dual laminate materials depicted in
Variably-Tensed Single Laminate Cushioning Composite
In another aspect, the present invention is also drawn to a single laminate composite material comprising a plurality of discrete resilient elements bonded to a single substrate layer, wherein one or more resilient elements may optionally be engaged to one or more framing element. Optionally, one or more framing elements may be bonded to the substrate layer.
Various non-limiting examples of single laminate composites are depicted in
It is understood that in one embodiment of the invention, first single laminate composite 370A may include the same components as first dual laminate composite 373 depicted in
It is understood that in one embodiment of the invention, third single laminate composite 370B may include the same components as first dual laminate composite 373 depicted in
It is understood that in one embodiment of the invention, fourth single laminate composite 372 may include the same components as first dual laminate composite 373 depicted in
Resilient Element Components
In one aspect of the invention, single laminate composite materials include a plurality of discrete resilient elements bonded to a single substrate layer. Non-limiting examples of such resilient elements include resilient elements 353 depicted in
It is understood that, optionally, the same resilient elements used to make dual laminate composites may also be used to make single laminate composites. Therefore, a single laminate composite material may optionally incorporate, by way of example only and without limitations, resilient elements 353 depicted in
As depicted in
As depicted in
As pointed out above, it is understood that the resilient elements may be made from a wide variety and range of resilient materials, including, without limitations, EVA foam, olefin or polyolefin foam, PU foam, urethane based foam, thermoplastic foam, or other polymer foam, rubber, elastomer, or other material with suitable shock absorbing characteristics, or resistant to puncture or abrasion. It is also understood that the resilient elements may be made of a combination of any such materials. By way of example only, resilient elements may be comprised of two or more layers of materials (such as a soft EVA foam layer, and a harder PU foam layer) bonded together.
It is understood that an adhesive is applied to the side of the resilient elements facing the substrate layer, in order to bond the resilient elements to the substrate layer. By way of example only, first side 353F of the resilient elements 353 in the single laminate composite materials depicted in
It is also understood that second sides 353S of the resilient elements in a single laminate composite material (such as, by way of example only, first single laminate composite 370A and third single laminate composite 370B depicted in
It is further understood that in one embodiment of the invention, the adhesive applied to the first side 353F of the resilient elements is optionally comprised of an HMA film that is activated by heat, or heat and pressure. Optionally, depending on the type of material and the composition of the resilient elements and the substrate layer, the adhesive may, additionally or alternatively, include ethyl-vinyl acetate, olefin, or polyolefin-based adhesive, glue, or HMA film; polyurethane or urethane based adhesive, glue, or HMA film; or polyamine based adhesive, glue, or HMA film.
The adhesive applied to first side 353F of the resilient elements in a single laminate composite material may optionally comprise any glue, bonding agent or compound, adhesive film or laminate, solvent, or tape that permits first side 353F of the resilient elements (such as, by way of example only, resilient elements 353, resilient elements 353S, and the like) to bond or adhere to the substrate layer (such as first substrate layer 351). For purposes of this embodiment of the invention, any compound, substance, attachment, or device (including tape, Velcro® or other interlocking mechanical means) suitable for bonding the resilient elements to the substrate layers may be used as an adhesive. Optionally, the same adhesive or combination of adhesives used to assemble dual laminate composite materials may optionally be used to assemble single laminate composite materials.
It is further understood that depending on the composition of the first substrate layer 351 and second substrate layer 352, and the composition of the resilient elements, the same types of adhesives, or combination of adhesives, used to bond the resilient elements to the first substrate layer 351 or second substrate layer 352 in a double laminate composite material may be used to bond the resilient elements to a substrate layer in a single laminate composite material.
Framing Element Components
In another aspect of the invention, one or more resilient elements in the single laminate composite materials may be bounded on one or more of the sides of the said resilient elements by one or more framing elements; and optionally, one or more resilient elements may be surrounded partially or completely by one or more framing elements. It is understood that the framing elements may have a variety of different shapes. By way of example only, and without limitations, a framing element may optionally be comprised of a lattice of a resilient material, or “strips” or “bars” of resilient materials, or any combinations of the same. It is also understood that a framing elements may include one or more holes or apertures, and one or more resilient elements in a single laminate composite may be engaged to one or more holes in the framing element.
Non-limiting examples of the framing elements that may be incorporated into a single laminate composite include, by way of example only and without limitations, framing element 363 (depicted in
By way of example only,
However, optionally, one or more framing elements may be dimensioned and shaped so that one or more framing elements, individually or together, engage every resilient element in a single or dual laminate composite.
The composition of the framing elements in a single laminate composite may optionally include, by way of example only and without limitations, polymer foam (such as, by way of example only, EVA foam, olefin or polyolefin foam, PU foam, or urethane based foam), thermoplastic or thermoplastic foam, rubber, elastomer, or neoprene, natural leather, synthetic leather, plastic, or rubber (including without limitation, latex, silicone, or synthetic rubber) and so forth, or any combination of such materials.
In one embodiment of the invention, the framing elements may be more rigid, less flexible, or less compressible that the substrate layers. Optionally, the composition of the framing elements may include one or more materials that are more rigid, less flexible, or less compressible than the materials comprising the substrate layers.
It is understood that, optionally, the same framing element, or combination of framing elements, used to make a dual laminate composite may also be used to make a single laminate composite. It is also understood that the same composition of materials in the framing elements incorporated into a dual laminate composite may optionally be used to make the framing elements incorporated into a single laminate composite.
It is further understood that the framing elements in a single laminate composite may be made of the same type of material, or combination of materials, in relation to the resilient elements in the said single laminate composite; alternatively, and optionally, the framing element may be made of a different type of material or combination of materials in relation to the resilient elements. By way of example only, and without limitations, in the first single laminate composite 370A depicted in
The framing element may optionally take on a variety of different shapes and dimensions, provided that the framing element or parts thereof may be lodged between two or more discrete resilient elements; or the framing element optionally bounds one or more sides of one or more discrete resilient element; or the framing element optionally surrounds, partially or completely, one or more resilient elements in a single laminate composite.
By way of example only, and without limitations, in one embodiment of the invention, a framing element may be comprised of a lattice of resilient material (such as lattice of resilient material 365, depicted in
Alternatively, and optionally, a framing element may be comprised entirely of “strips” or “bars” of resilient material (such as framing bars 354), such as, by way of example only, framing element 363G.
A framing element may also be optionally comprised of a combination of “strips” or “bars” (such as framing bars 354) and lattice structures made of resilient material, such as, by way of example only, framing element 363C, framing element 363D depicted in
It is understood that a framing element may optionally be asymmetrical in shape, such as framing element 363I depicted in
It is understood that more than one framing element may optionally be incorporated into a single laminate composite, as depicted by way of example only in
Substrate Layer Components
In another aspect of the invention, a plurality of resilient elements in the single laminate composite material (such as, by way of example only, resilient elements 353, 353A, 353B, and 353C) are bonded to a sheeting structure, such as first substrate layer 351.
Non-limiting examples of such sheeting structure or substrate layer (namely, first substrate layer 351) incorporated into single laminate composite materials are shown in
In one embodiment of the invention, one or more framing elements (such as, by way of example only, framing element 363) in a single laminate composite (such as, by way of example only, first single laminate composite 370A shown in
As shown in
As shown in
Another non-limiting example of a substrate layer (namely, first substrate layer 351) incorporated into a single laminate composite material is shown in
As shown in
It is also understood that by optionally varying the size, shape, and composition of the framing elements and the substrate layers in a single laminate composite material, and the size, shape, and placement of the resilient elements, the resulting single laminate composite may optionally take on a greater or lesser degree of concavity or convexity, or a “half-pipe” shape shown in
In one optional embodiment of the invention, the substrate layer in a single laminate composite (namely, the first substrate layer 351) is optionally comprised of a sheet or layer of synthetic, non-woven stretchable fabric such as spandex, or stretchable nylon or polyester mesh. However, it is understood that the substrate layer may optionally be comprised of a sheet or layer of any material that is relatively flexible and stretchable and may be used as a sheeting structure, including, without limitations, natural or synthetic fabric (including, by way of example only and without limitations, polyester, nylon, Lycra®, or elastane), stretchable mesh (including open mesh), flexible or pliable plastic, neoprene, natural leather, synthetic leather, or a sheet of synthetic fiber, or a combination of such materials. Optionally, the substrate layer may also be made of any flexible and stretchable sheet of foam, plastic, latex, silicone, rubber, other rubber-like materials, elastomer, and so forth, including any combination of such materials. By way of example only, and without limitations, the substrate layer may optionally be comprised of any such materials encased in, laminated with, or sandwiched between sheets of natural or synthetic fabric.
It is understood that a suitable composition for the substrate layer may optionally be selected from a wide variety and range of materials that are flexible and stretchable, provided that the resulting substrate layer may be made to bond to the resilient elements (such as, by way of example only, resilient elements 353, 353A, 353B, and 353C).
In another embodiment of the invention, first substrate layer 351 may optionally be comprised of a material, or combination of materials, that is flexible or stretchable at the time of the lamination of the substrate layer onto the resilient elements, but becomes hard, less flexible, or less stretchable thereafter. It is understood that in this embodiment of the invention, the substrate layer may optionally be hardened, or made less flexible or stretchable, by drying, curing, heating, chemical activation, or irradiation with infrared, microwave, radio frequency waves, and the like, depending on the composition of the substrate layers.
In another aspect of the invention, the first substrate layer 351 in a single laminate composite may be made of the same type of material, or combination of materials, used to make the first substrate layer 351 or second substrate layer 352 in a dual laminate composite.
It is understood that the first substrate layer 351 in a single laminate composite does not need to be comprised of a continuous sheeting structure, and that first substrate layer 351 may optionally be comprised of materials cut or shaped in any size, dimension, or shape, including irregular shapes, non-contiguous shapes, or shapes with openings or apertures.
Method for Making Variably-Tensed Composite Cushioning Materials
In another aspect, the invention is drawn to a method of making composite cushioning materials incorporating, among other things and without limitations, one or two sheeting structures or substrate layers. Single laminate composite materials may optionally be made by a process comprising: (1) Applying a suitable adhesive to one or two opposing surfaces of a sheet of resilient material; (2) cutting the sheet of resilient material, to define and make a plurality of discrete resilient elements; (3) bonding a plurality of discrete resilient elements onto at least one sheeting structure or substrate layer; (4) mechanically stretching the substrate layer to which the resilient elements are bound, and increasing the relative distance between the discrete resilient elements, thereby creating spacing between them; (4) positioning one or more framing elements, which may optionally include holes shaped and sized to engage one or more resilient elements, in proximity with the resilient elements; (5) inserting one or more framing elements between at least two resilient elements, or optionally engaging one or more resilient elements to one or more holes in a framing element; and (6) optionally bonding a framing element to a substrate layer, thereby making a single laminate composite. It is understood that (7) a second substrate layer may optionally be bonded to the resilient elements in the single laminate composite, so that the resilient elements and one or more framing elements are “sandwiched” between the two sheets of substrate layer, thereby making a dual laminate composite.
Assembly of Single Laminate Variably-Tensed Cushioning Composites
As an initial step in the process, a sheet of resilient material is optionally coated with adhesive on two opposing sides. Alternatively, the sheet of resilient material may optionally be coated with adhesive on a single side.
In one aspect of the invention, the composition of resilient material may include, without limitations, a foam, including EVA foam, olefin or polyolefin foam, PU foam, urethane based foam, other polymer or thermoplastic foam, or rubber, elastomer, or other material with suitable shock absorbing characteristics, or resistant to puncture or abrasion (including a combination of any such materials). In one embodiment of the invention, the sheet of resilient material is optionally made of EVA foam.
The adhesive applied to one or two sides of the sheet of resilient material may optionally be comprised of an HMA film that is activated by heat, or heat and pressure. Depending on the type of material and the composition of the resilient elements and the substrate layers, the adhesive may optionally include EVA, olefin, or polyolefin-based adhesive, glue, or HMA film; PU or urethane based adhesive, glue, or HMA film; or polyamine based adhesive, glue, or HMA film.
In one embodiment of the invention, the adhesive used for this purpose is optionally an EVA or olefin based HMA film, activated by heat. However, it is understood that the adhesive may optionally comprise any glue, bonding agent or compound, adhesive film or laminate, solvent, or tape that permits the resilient material to bond or adhere to a substrate layer, such as first substrate layer 351 or second substrate layer 352. It is also understood that for purposes of this embodiment of the invention, any compound, substance, attachment, or device (including tape, Velcro® or other interlocking mechanical means) suitable for bonding the resilient material to the substrate layers may be used as an adhesive.
Depending on the composition of the first substrate layer 351 and second substrate layer 352, and the composition of the resilient material, the same or different types of adhesives, or combination of adhesives, may optionally be applied to the opposing sides of the sheet of resilient material.
It is understood that any conventional method for positioning, applying, or coating a HMA film to a suitable resilient element may be used for this purpose, as any HMA film having any particular melting temperature may be used to apply or coat the film to the resilient elements, so as to create adhered material.
It is understood that any conventional method for cutting resilient materials may be used to cut the sheet of resilient material and to make the cut sheet of resilient material 360. Optionally, any of the methods for cutting resilient materials disclosed in U.S. patent application Ser. No. 12/624,881 may be used for this purpose. The contents of U.S. patent application Ser. No. 12/624,881, filed Nov. 24, 2009 is incorporated by reference herein in its entirety, and in particular for its disclosure of various methods of cutting resilient material.
It is understood that the sheet of resilient material may be covered or coated with an adhesive on one or optionally two of its sides prior to the cutting operation. Therefore, following the cutting operation, the surface of first side 353F of the resilient elements (such as, by way of example and without limitations, resilient elements 353) is covered or coated with an adhesive and that, optionally, the surface of second side 353S of the same resilient elements may also be covered or coated with an adhesive.
However, in an optional and alternative embodiment of the invention, the sheet of resilient material may be cut along cutting lines 361 first, defining and forming a plurality of discrete resilient elements 353, and then the adhesive may be applied to first side 353F of the cut resilient elements 353, second side 353F of the cut resilient elements 353, or optionally to both sides of the cut resilient elements.
Cutting lines 361 shown in
In the cut sheet of resilient material 360 depicted in
It is understood that a suitable composition for the substrate layers may optionally be selected from a wide variety and range of materials that are flexible and stretchable, provided that the resulting substrate layer may be made to bond to resilient elements (such as, by way of example only, resilient elements 353, 353A, 353B, 353C, and 353D).
In an alternative embodiment of the invention, adhesive may optionally be applied to a substrate layer (such as, by way of example, first substrate layer 351, or second substrate layer 352), instead of the sides of the resilient elements (such as, by way of example, first side 353F or second side 353S of resilient elements 353), in order to bond the resilient elements to the substrate layer.
The assembly, comprised of first substrate layer 351 positioned adjacent to a plurality of resilient elements 353 in the cut sheet of resilient material 360, is pressed together, so that the resilient elements 353 bond or are made to adhere to first substrate layer 351. If the adhesive on the surface of the resilient elements 353 is a heat activated HMA film, glue, or other bonding agent, the assembly may be heat pressed in order to activate the adhesive.
Any means or device for pressing or optionally heat-pressing first substrate layer 351 and the plurality of resilient elements 353 together, such as a pressure press or a heated press or platen, may be employed for this purpose.
Optionally, the surface of heating element 380B, the lower surface of the pressure platen 380, or the work surface 380C may incorporate or be coated with one or more non-reactive materials (such as silicone, polytetrafluoroethylene/PTFE, perfluoroalkoxy/PFA, fluorinated ethylene propylene/FEP, Teflon, or other similar non-reactive material) that do not adhere to exposed adhesive, if any, on the surface of the resilient elements that are not fully covered by first substrate layer 351 (It is understood that this may be the case if, by way of example only, first substrate layer 351 is optionally shaped so as to cover only some of the plurality of resilient elements).
As depicted in
As depicted in
By way of example only,
In one embodiment of the invention, the framing element (such as framing element 363) is not bonded to a substrate layer (such as first substrate layer 351). However, it is understood that alternatively, and optionally, a suitable adhesive may be applied to first side 365F of the framing element (such as framing element 363, depicted in
It is understood that the resilient elements may optionally have a variety of thicknesses, shapes, and dimensions, as shown, by way of example only and without limitations, in
It is also understood that framing elements may also have a variety of optional shapes, dimensions, and thicknesses, as shown by way of example only and without limitations in
In one aspect of the invention, framing element 363 depicted in
Alternatively, and optionally, framing element 363 may be pressed against second stretched resilient material assembly 362C so that holes 364 engage the resilient elements 353D, and pushed until second side 365S of the framing element 363A makes contact with the first substrate layer 351. Also optionally, second side 365S of the framing element 363 may be covered with an adhesive, and second side 365S of the framing element may optionally be made to bond and adhere to first substrate layer 351.
In one aspect of the invention, framing element 363A depicted in
As depicted in
Another non-limiting example of this step is depicted in
However, it is understood that the framing element or its parts, optionally positioned between two or more resilient elements, or optionally engaged to one or more resilient elements, prevent the portions or zones of the substrate layer located adjacent to the framing element from returning to a non-stretched state, even as the substrate layer as a whole returns to a non-stretched state. It is also understood that the said framing element may also prevent two or more of the resilient elements bounded or engaged by the framing element from coming back together in relation to each other, even as the substrate layer as a whole returns to a non-stretched state and the other resilient elements bonded to the substrate layer come back together, thereby reducing or eliminating the spacing between such other resilient elements.
It is further understood that in the regions or zones of the substrate layer on which a framing element bounds or engages one or more resilient elements, the substrate layer material may be prevented from returning, or shrinking, back to its “relaxed” dimensions. In those zones, the substrate layer material remains in a relatively more stretched, or “tensed,” state than in the rest of the substrate layer.
By way of example only, and without limitations,
As shown in
Optionally, the entire work piece depicted in
In one aspect of the invention, framing element 363 may be optionally bonded to substrate layer 351 in the first single laminate composite 370A after substrate layer 351 has been returned to a non-stretched state. This may be accomplished by treating or covering second side 365S of the framing element 363 with an adhesive, contacting the second side 365S of the framing element to the first substrate layer 351, and optionally pressing or heat pressing the work piece with the first substrate layer 351 in a non-stretched or “relaxed” state. It is understood that the pressing or heat pressing operations may optionally be carried out using the pressure platen 380 depicted in
It is understood that the process generally described above may be used to make a variety of single laminate composite materials, including, by way of example only and without limitations, second single laminate composite 371 depicted in
In another aspect of the invention, the first single laminate composite 370A depicted in
Optionally, single laminate composite materials may be used as a protective padding, or as components in footwear or athletic or industrial protective gear. Alternatively, and optionally, single laminate composites may be processed further to make dual laminate composite materials.
Assembly of Dual Laminate Variably-Tensed Cushioning Composites
In one aspect of the invention, the process for assembling and making single laminate composite materials, described above and herein, may also be used to fabricate a variety of dual laminate composite materials.
In another aspect of the invention, a single laminate composite material may optionally be assembled and made in accordance with the steps described herein. A second substrate layer may be optionally laminated to the said single laminate composite, by bonding a second substrate layer to one or more resilient elements in the single laminate composite, forming a dual laminate composite material.
It is understood that any means for bonding a second substrate layer to the resilient elements in the single laminate composite may be utilized for this purpose, including, but not limited to, pressing or heat pressing operation carried out using the pressure platen 380 depicted in
By way of example only, and without limitations,
As shown in
Second substrate layer 352 is bonded or made to adhere to one or more discrete resilient elements 353 in the first single laminate composite 370A. In one optional embodiment of the invention, adhesive may be applied to the surface of the resilient elements facing the second substrate layer 352, causing the resilient elements to bond to the substrate layer; in another optional embodiment of the invention, adhesive may be applied to the surface of the second substrate layer 352, causing the substrate layer to bond to the resilient elements.
Any means capable of bonding second substrate layer 352 to the resilient elements 353 in the first single laminate composite 370A may be utilized for this purpose. By way of example only, and without limitations, in one embodiment of the invention depicted in
Pressure platen 380, which includes a pressing element 380A and, optionally, a heating element 380B, may optionally be positioned over the work piece, so that the work piece is “sandwiched” between pressure platen 380 and work surface 380C, with the pressing element 380A, and optionally the heating element 380B, facing first side 352A of the second substrate layer 352.
It is understood that the surface of heating element 380B, the lower surface of the pressure platen 380, or the work surface 380C may optionally incorporate or be coated with one or more non-reactive materials (such as silicone, polytetrafluoroethylene/PTFE, perfluoroalkoxy/PFA, fluorinated ethylene propylene/FEP, Teflon, or other similar non-reactive material) that do not adhere to exposed adhesive, if any, on the surface of the resilient elements that are not fully covered by second substrate layer 352 (It is understood that this may be the case if, by way of example only, second substrate layer 352 is optionally shaped so as to cover only some of the plurality of resilient elements).
However, it is understood that, optionally, the second substrate layer (such as second substrate layer 352) may be laminated or bonded to a single laminate composite material (such as first single laminate composite 370A), while the single laminate composite material and the first substrate layer therein (namely, first substrate layer 351) are stretched out, or in a “tensed” state. By way of illustration,
In one embodiment of the invention, the second substrate layer (namely, second substrate laminate 352) is optionally comprised of a sheet or layer of synthetic, non-woven stretchable fabric such as spandex, stretchable nylon or polyester mesh, or a flexible sheet of open mesh. However, it is understood that a second substrate layer may optionally be comprised of a sheet or layer of any material that is relatively flexible and stretchable and may be used as a sheeting structure, including, without limitations, natural or synthetic fabric (including, by way of example only and without limitations, polyester, nylon, Lycra®, or elastane), stretchable mesh (including open mesh), flexible or pliable plastic, neoprene, natural leather, synthetic leather, or a sheet of synthetic fiber, or a combination of such materials. Optionally, the second substrate layer may also be made of any flexible and stretchable sheet of foam, plastic, latex, silicone, rubber, other rubber-like materials, elastomer, and so forth, including any combination of such materials. Optionally, the second substrate layer may also be comprised of any such materials encased in, laminated with, or sandwiched between sheets of natural or synthetic fabric, or other materials. A suitable composition for the second substrate layer may optionally be selected from a wide variety and range of materials that are flexible and stretchable, provided that the resulting substrate layer may be made to bond to resilient elements (such as, by way of example only, resilient elements 353, 353A, 353B, 353C, and 353D).
In another aspect of the invention, the composition of the second substrate layer 352 may optionally comprise the same material or materials as the first substrate layer 351; alternatively, and optionally, the composition of the second substrate layer 352 may comprise different material or materials as the first substrate layer 351.
In yet another aspect of the invention, it is understood that second substrate may take on a variety of shapes and dimensions.
It is further understood that the process described above may be used to make a variety of double laminate composite materials, including, by way of example only and without limitations, first dual laminate composite 373 depicted in
The various dual laminate composites described above, or depicted in the above-referenced illustration, may optionally include one or more regions or zones that have a concave or convex shape, or a “half-pipe” shape. Alternatively, and optionally, the entire dual laminate composite material may take on a concave, convex, or a “half-pipe” shape. By way of example only, and without limitations, first dual laminate composite 373 is curved in three dimensions as shown in
It is understood that by varying the size, shape, and composition of the framing elements and the substrate layers, and the size, shape, and placement of the resilient elements, the resulting dual laminate composite material may take on a greater or lesser degree of concavity or convexity, or greater or lesser curvature.
Non-Limiting Example of an Article Made Using the Variably-Tensed Composite Cushioning Materials
It is understood that various composite cushioning materials including one or two substrate materials or sheeting structures (such as, by way of example only and without limitations, first single laminate composite 370A depicted in
In one embodiment of the invention, first substrate layer 351 of the dual laminate composite 350 depicted in
As depicted in
In one embodiment of the invention, framing element 363K is made of EVA foam, rubber, or other resilient foam material, and the framing element is not bonded to a substrate layer. However, it is understood that, optionally and alternatively, framing element 363K may be bonded to first substrate layer 351, second substrate layer 352, or to both of them.
It is understood that the padded elbow protector described above is a non-limiting example of one application of the composite cushioning material. It is also understood that the various components of the composite materials disclosed herein may be made of any suitable material and may be any size and shape consistent with their functions. The specific embodiments of the process disclosed and illustrated herein are not to be considered in a limiting sense as numerous variations are possible. Ordinal indicators, such as first, second or third, for identified elements in the specification and descriptions herein are used to distinguish between the elements, and do not indicate a required or limited number of such elements, and do not indicate a particular position or order of such elements unless otherwise specifically indicated. The subject matter of this disclosure includes all novel and non-obvious combinations and subcombinations of the various features, elements, functions and/or properties disclosed herein. No single feature, function, element or property of the disclosed embodiments is essential.
The present invention is not to be limited in scope by the specific embodiments described herein. Indeed, various modifications of the invention in addition to those described herein will become apparent to those skilled in the art from the foregoing description and accompanying figures. Such modifications are intended to fall within the scope of the appended claims. The following examples are offered by way of illustration of the present invention, and not by way of limitation.
Those skilled in the art will recognize, or be able to ascertain using no more than routine experimentation, many equivalents to the specific embodiments of the invention specifically described herein. Such equivalents are intended to be encompassed in the scope of the claims.
Number | Date | Country | |
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61427148 | Dec 2010 | US |
Number | Date | Country | |
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Parent | PCT/US11/67429 | Dec 2011 | US |
Child | 13922133 | US |